ES2093166T3 - Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores. - Google Patents

Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.

Info

Publication number
ES2093166T3
ES2093166T3 ES92120287T ES92120287T ES2093166T3 ES 2093166 T3 ES2093166 T3 ES 2093166T3 ES 92120287 T ES92120287 T ES 92120287T ES 92120287 T ES92120287 T ES 92120287T ES 2093166 T3 ES2093166 T3 ES 2093166T3
Authority
ES
Spain
Prior art keywords
metalochenes
benzo
ligands
catalysts
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92120287T
Other languages
English (en)
Inventor
Jurgen Dr Rohrmann
Volker Dr Dolle
Andreas Dr Winter
Frank Dr Kuber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2093166T3 publication Critical patent/ES2093166T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/665—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system
    • C07C49/675—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings a keto group being part of a condensed ring system having three rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

UN SISTEMA DE CATALIZADORES MUY EFECTIVO PARA LA POLIMERIZACION DE OLEFINAS, COMPUESTO POR UN COCATALIZADOR, PREFERENTEMENTE UN ALUMINOXANO Y UN METALOCENO, DE FORMULA I, DONDE PREFERENTEMENTE, M1 EQUIVALE A ZR O HF, R1 Y R2 EQUIVALEN A HALOGENO O ALQUILO, R3 EQUIVALE A ALQUILO, R4 A R10 EQUIVALEN A ALQUILO O HIDROGENO, Y R11 EQUIVALE A UN PUENTE ALQUILENO (SUST.) O HETEROATOMO.
ES92120287T 1991-11-30 1992-11-27 Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores. Expired - Lifetime ES2093166T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4139595 1991-11-30

Publications (1)

Publication Number Publication Date
ES2093166T3 true ES2093166T3 (es) 1996-12-16

Family

ID=6446019

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92120287T Expired - Lifetime ES2093166T3 (es) 1991-11-30 1992-11-27 Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.

Country Status (11)

Country Link
US (1) US5455366A (es)
EP (1) EP0549900B1 (es)
JP (1) JP3371118B2 (es)
KR (1) KR100284726B1 (es)
AT (1) ATE141609T1 (es)
AU (1) AU651915B2 (es)
CA (1) CA2084017C (es)
DE (1) DE59206948D1 (es)
ES (1) ES2093166T3 (es)
RU (1) RU2098423C1 (es)
ZA (1) ZA929213B (es)

Families Citing this family (160)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451649A (en) * 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
TW309523B (es) * 1991-11-30 1997-07-01 Hoechst Ag
TW318184B (es) * 1991-11-30 1997-10-21 Hoechst Ag
ATE177436T1 (de) * 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
TW275076B (es) * 1992-12-02 1996-05-01 Hoechst Ag
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE59409642D1 (de) * 1993-11-24 2001-03-01 Targor Gmbh Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
EP0668157B1 (de) * 1994-02-21 2003-05-21 Basell Polyolefine GmbH Siegelbare polyolefinische Mehrschichtfolie, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4406109A1 (de) * 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
DE4416894A1 (de) * 1994-05-13 1995-11-16 Witco Gmbh Verfahren zur Synthese von Mono- und Dimethylmetallocenen und deren Lösungen speziell für den Einsatz zur Polymerisation von Olefinen
US5692481A (en) * 1994-05-18 1997-12-02 Lockheed Corporation Method and apparatus for reducing contaminants in exhaust gases of an engine
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
ES2142426T3 (es) * 1994-06-13 2000-04-16 Targor Gmbh Compuestos de metales de transicion.
IT1270070B (it) 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
DE4436113A1 (de) * 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
DE69533310T2 (de) * 1994-12-20 2005-07-21 Mitsui Chemicals, Inc. Verfahren zur herstellung von ethylenpolymer und ethylenpolymer
TW383314B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Ethylene-alpha-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer
TW383313B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
EP0739897A1 (de) 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
US5648308A (en) * 1995-08-10 1997-07-15 Albemarle Corporation Process for upgrading metallocene catalysts
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
EP0780396B1 (de) 1995-12-18 2002-10-02 Basell Polyolefine GmbH Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen
DE19548788A1 (de) 1995-12-27 1997-07-03 Hoechst Ag Folien und Schichten
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
JP3181920B2 (ja) * 1996-04-22 2001-07-03 日本ポリオレフィン株式会社 ポリオレフィン製造用触媒及びポリオレフィンの製造方法
DE19624828C1 (de) 1996-06-21 1998-03-26 Basf Ag Verfahren zur Herstellung substituierter Benzoindanone
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
CA2230365A1 (en) * 1996-06-27 1997-12-31 Albermarle Corporation Production of bridged metallocene complexes and intermediates therefor
US6262200B1 (en) 1996-08-19 2001-07-17 Northwestern University (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon
US6130302A (en) * 1996-08-19 2000-10-10 Northwestern University Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium
DE19634684C1 (de) * 1996-08-28 1998-03-12 Basf Ag Verfahren zur Herstellung von Indenderivaten
DE19637669A1 (de) * 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
US5780660A (en) * 1996-11-07 1998-07-14 Albemarle Corporation Zirconocene ismerization process
US5965756A (en) * 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
US6329541B1 (en) * 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
US6107501A (en) * 1997-01-30 2000-08-22 Fina Technology, Inc. Synthesis of metallocenes and enrichment of their rac isomer
EP0856506A1 (en) * 1997-02-04 1998-08-05 Akzo Nobel N.V. Process of preparing 2-alkyl-2,3-dihydro-1H-benz(e)indene-1-one derivatives
JPH10259207A (ja) * 1997-03-21 1998-09-29 Idemitsu Kosan Co Ltd オレフィン重合体の製造方法
US6489424B2 (en) 1997-04-17 2002-12-03 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, aromatic vinyl compound polymer having stereoregularity and method for its preparation by means of the catalyst component
US6235855B1 (en) 1997-04-17 2001-05-22 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal compound as catalyst component in method for producing aromatic vinyl compound polymer or aromatic vinyl compound-olefin copolymer having stereoregularity
FI972946L (fi) * 1997-07-11 1999-01-12 Borealis As Uudet metalloseeniyhdisteet etyleenisesti tyydyttämätt"mien monomeerien polymeroimiseksi
US5905162A (en) * 1997-08-12 1999-05-18 Albemarle Corporation Enhanced production of bridged hafnocenes
JP2008121030A (ja) * 1997-08-15 2008-05-29 Chisso Corp 多分散性プロピレン重合体およびその製造方法
DE69810781T2 (de) * 1997-08-15 2003-09-25 Chisso Corp., Osaka Polydisperses propylenpolymer und verfahren zu dessen herstellung
KR100274973B1 (ko) * 1997-11-24 2000-12-15 성재갑 올레핀계 단량체의 중합 촉매
EP1043339A1 (en) * 1997-12-25 2000-10-11 Denki Kagaku Kogyo Kabushiki Kaisha Polymerization catalyst and process for producing olefin polymer or copolymer with the same
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
ES2220058T3 (es) 1998-05-13 2004-12-01 Exxonmobil Chemical Patents Inc. Homopolimeros de propileno y metodos de fabricarlos.
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
DE69940653D1 (de) 1998-06-25 2009-05-07 Idemitsu Kosan Co Propylenpolymer und Zusammensetzung damit, Formobjekt und Laminat damit sowie Verfahren zur Herstellung von Propylenpolymer und einer Zusammensetzung damit
JP2000143733A (ja) * 1998-09-07 2000-05-26 Denki Kagaku Kogyo Kk 芳香族ビニル化合物―エチレン共重合体及びその製造方法
US5965759A (en) * 1998-09-23 1999-10-12 Albemarle Corporation Catalytic process for isomerizing metallocenes
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
ES2192408T3 (es) 1998-11-25 2003-10-01 Basell Polyolefine Gmbh Procedimiento para la fabricacion de monoariloxi-ansa-metalocenos.
DE59914158D1 (de) 1998-11-25 2007-03-08 Basell Polyolefine Gmbh Metallocenmonohalogenide
US6900343B1 (en) 1998-11-25 2005-05-31 Basell Polyolefine Gmbh Method for the purification of metallocenes
JP2000178319A (ja) * 1998-12-14 2000-06-27 Mitsubishi Chemicals Corp 医療容器用プロピレン系ランダム共重合体及びその組成物、並びに医療容器
US6239060B1 (en) 1998-12-31 2001-05-29 Phillips Petroleum Company Supported metallocene catalyst system and method for polymerizing olefins
WO2000049029A1 (en) * 1999-02-19 2000-08-24 Fina Research S.A. Polyolefin production
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
ATE288508T1 (de) 1999-05-13 2005-02-15 Exxonmobil Chem Patents Inc Elastische fasern und daraus hergestellte artikel,die kristalline und kristallisierbare propylenpolymere enthalten
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
RU2160277C1 (ru) * 1999-06-21 2000-12-10 Институт химической физики РАН им. Н.Н. Семенова Анса-цирконоцены, функционализированные по циклосилановому мостику, и способ их получения
RU2160276C1 (ru) * 1999-06-21 2000-12-10 Институт химической физики им. Н.Н. Семенова РАН Анса-цирконоцены с непредельным циклосилановым мостиком и способ их получения
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins
WO2001032758A1 (en) 1999-11-04 2001-05-10 Exxon Chemical Patents Inc. Propylene copolymer foams and their use
US6977287B2 (en) 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
US6809168B2 (en) 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
ES2239631T3 (es) 1999-12-10 2005-10-01 Exxonmobil Chemical Patents Inc. Polimeros compolimerizados de propileno y dieno.
US6627723B2 (en) 1999-12-22 2003-09-30 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
KR20010091694A (ko) * 2000-03-17 2001-10-23 박성범 알루미늄 분말 및 합금분말을 이용한 브레이크라이닝과 그제조방법
US6875719B2 (en) * 2000-04-27 2005-04-05 Industrial Technology Research Institute Catalyst composition for preparing olefin polymers
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
DE10126265A1 (de) 2001-05-29 2002-12-05 Basell Polyolefine Gmbh Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte
US7459511B2 (en) 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
JP2003128720A (ja) 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
US6916892B2 (en) 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US7074865B2 (en) 2002-04-12 2006-07-11 Dow Global Technologies Inc. Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
KR100452450B1 (ko) * 2002-06-14 2004-10-12 현대자동차주식회사 자동차 엔진 블록용 실린더 라이너 소재의 제조 방법
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US6846884B2 (en) * 2002-09-27 2005-01-25 Union Carbide Chemicals & Plastics Technology Corporation Control of resin properties
US7098354B2 (en) * 2002-10-25 2006-08-29 Basell Polyolefine Gmbh Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl)zirconium compounds
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
DE60318616T2 (de) * 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
US7195806B2 (en) 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
CN100351275C (zh) 2003-03-21 2007-11-28 陶氏环球技术公司 形态控制的烯烃聚合方法
CN100348623C (zh) * 2003-05-30 2007-11-14 联合碳化化学及塑料技术公司 气相聚合及其控制方法
DE10352139A1 (de) * 2003-11-04 2005-06-09 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen
ATE418567T1 (de) * 2003-12-22 2009-01-15 Basell Polyolefine Gmbh Metallocenverbindungen
JP2007515533A (ja) 2003-12-23 2007-06-14 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング オレフィン重合用の触媒組成物
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
JP5198872B2 (ja) 2004-12-17 2013-05-15 ダウ グローバル テクノロジーズ エルエルシー レオロジー改変相対的高溶融強度ポリエチレン組成物並びにパイプ、フィルム、シート、およびブロー成型品の製造方法
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
WO2007130553A2 (en) 2006-05-02 2007-11-15 Dow Global Technologies Inc. High-density polyethylene compositions, method of making the same, wire and cable jackets made therefrom, and method of making such wire and cable jackets
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US8722831B2 (en) 2006-05-29 2014-05-13 Denki Kagaku Kogyo Kabushiki Kaisha Process for production of cross copolymers, cross copolymers obtained by the process, and use thereof
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
BR122018012418B1 (pt) 2006-09-21 2019-09-24 Union Carbide Chemicals & Plastics Technology Llc. Método para controlar um processo de produção de uma composição de polímero
CA2683693C (en) 2007-04-09 2012-12-18 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
CA2656845C (en) * 2007-05-02 2015-09-22 Dow Global Technologies Inc. High-density polyethylene compositions, method of making the same, injection molded articles made therefrom, and method of making such articles
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
CA2707511C (en) * 2007-12-04 2013-04-02 Mitsui Chemicals, Inc. Processes for preparing organic alkali metal compound and organic transition metal compound
CN102007180A (zh) 2008-04-15 2011-04-06 电气化学工业株式会社 热塑性树脂组合物
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
MX2011008053A (es) 2009-01-30 2012-01-12 Dow Global Technologies Llc Composiciones de polietileno de alta densidad, metodo para producir las mismas, dispositivos de cierre elaborados de las mismas, y metodo para elaborar dichos dispositivos de cierre.
JP5557835B2 (ja) 2009-03-30 2014-07-23 三井化学株式会社 オレフィンと共役ジエンとの共重合体、およびその製造方法
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
WO2011159400A1 (en) 2010-06-15 2011-12-22 Exxonmobil Chemical Patents Inc. Nonwoven fabrics made from polymer blends and methods for making same
WO2012149391A1 (en) 2011-04-28 2012-11-01 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
CN110452318A (zh) 2013-01-14 2019-11-15 尤尼威蒂恩技术有限责任公司 制备高产率催化剂系统的方法
WO2015161241A1 (en) 2014-04-18 2015-10-22 IFS Industries Inc. Low density and high performance packaging hot melt
US10377841B2 (en) 2015-05-08 2019-08-13 Exxonmobil Chemical Patents Inc. Polymerization process
KR101790672B1 (ko) 2015-08-24 2017-10-26 주식회사 엘지화학 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조 방법
US20180273669A1 (en) 2015-09-28 2018-09-27 Denka Company Limited Cross-copolymer and method for producing same
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US11591417B2 (en) 2017-12-13 2023-02-28 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization processes
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
US11447587B2 (en) 2018-05-02 2022-09-20 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
EP3788082A1 (en) 2018-05-02 2021-03-10 ExxonMobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
WO2020023207A1 (en) 2018-07-26 2020-01-30 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
WO2020056119A1 (en) 2018-09-14 2020-03-19 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
WO2020102385A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene films
EP3880738B1 (en) 2018-11-13 2025-03-19 ExxonMobil Chemical Patents Inc. Polyethylene blends and films
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
CA3121960A1 (en) 2019-02-20 2020-08-27 Fina Technology, Inc. Polymer compositions with low warpage
US20230018505A1 (en) 2019-12-17 2023-01-19 Exxonmobil Chemical Patents Inc. Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
WO2022014599A1 (ja) 2020-07-15 2022-01-20 デンカ株式会社 組成物及び硬化体
MX2023011768A (es) 2021-04-26 2023-10-10 Fina Technology Laminas de polimero delgadas catalizadas en un solo sitio.
EP4330294A1 (en) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
JP7780002B2 (ja) 2022-03-28 2025-12-03 デンカ株式会社 組成物
CN120225576A (zh) 2022-12-27 2025-06-27 电化株式会社 共聚物、其制造方法及包含共聚物的固化体

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
EP0426643B1 (en) * 1989-10-30 1995-12-27 Fina Research S.A. Process for the preparation of metallocenes
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE59104869D1 (de) * 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
JP3402473B2 (ja) * 1991-08-20 2003-05-06 日本ポリケム株式会社 オレフィン重合用触媒

Also Published As

Publication number Publication date
EP0549900A1 (de) 1993-07-07
CA2084017A1 (en) 1993-05-31
US5455366A (en) 1995-10-03
ATE141609T1 (de) 1996-09-15
EP0549900B1 (de) 1996-08-21
JPH06184179A (ja) 1994-07-05
KR100284726B1 (ko) 2002-08-21
AU2972892A (en) 1993-06-03
KR930010044A (ko) 1993-06-21
DE59206948D1 (de) 1996-09-26
ZA929213B (en) 1993-05-24
JP3371118B2 (ja) 2003-01-27
CA2084017C (en) 2006-11-21
RU2098423C1 (ru) 1997-12-10
AU651915B2 (en) 1994-08-04

Similar Documents

Publication Publication Date Title
ES2169288T3 (es) Catalizadores que contienen metalocenos con derivados de indenilo arilsubstituidos como ligandos, procedimientos y productos intermedios para la obtencion de estos metalocenos, y su empleo.
ES2048871T3 (es) Catalizadores para la polimerizacion de olefinas.
FI953456A0 (fi) Katalyyttijärjestelmiä sekä menetelmä laajan molekyylipainoalueen omaavan polyolefiinin valmistamiseksi
ZA929213B (en) Metallocenes having benzo-fusen indenyl derivatives as ligands, processes for their preparation and their use as catalysts.
NO893898D0 (no) Katalysatorer for polymerisering av olefiner.
ES2091273T3 (es) Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
DE69712652D1 (de) Metallocen-Alumoxan-Trägerkatalysator für die Herstellung von Polyethylen mit breiter monomodaler Molekulargewichtsverteilung
IT7819503A0 (it) Catalizzatori a base di sililcromato modificati con titanio per la polimerizzazione di etilene.
NO156289C (no) Kontinuerlig katalytisk fremgangsmaate for fremstilling av etylenpolymerer samt katalysatorpreparat til bruk i fremgangsmaaten.
ES2113448T3 (es) Catalizador de polimerizacion de olefinas, procedimiento para su preparacion y su utilizacion.
IL80888A0 (en) Olefin polymerization catalysts,their preparation and use thereof
NO153180C (no) Katalytisk fremgangsmaate for fremstilling av etylen-kopolymerer i en hvirvelsjiktreaktor.
NO178153C (no) Katalysatorer for polymerisering av olefiner
MX9100015A (es) Catalizador de vanadio y zirconio coimpregnado novedoso para producir polietileno con distribucion de peso molecular (mw) amplia o bimodal.
EP0743317A3 (de) Metallocene mit einem heterocyclischen Ring und Katalysatoren, die sie enthalten
FI885472A0 (fi) Propenpolymerer och deras framstaellning.
NO885282D0 (no) Nye katalysatorer for polymerisering av olefiner.
NO895321D0 (no) Katalysator for regulering av molekylvektsfordelingen av etylenpolymerer.
ES2020265B3 (es) Preparacion de un componente del catalizador de polimerizacion de la olefina.
ATE199732T1 (de) Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
NO891447L (no) Katalysator for regulering av molekylvektsfordelingen foretylenpolymerer.
DE69714767D1 (de) Herstellung von polyethylen mit bimodaler molekulargewichtsverteilung
NO905189L (no) Fremgangsmaate til fremstilling av en polymer inneholdendestivelse.
RU94001575A (ru) Каталитические композиции и способ изготовления полиолефинов
FI882517A7 (fi) Etyleenin polymerointikatalyytti.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 549900

Country of ref document: ES