ES2096375T3 - Procedimiento de obtencion de beta-yonona. - Google Patents

Procedimiento de obtencion de beta-yonona.

Info

Publication number
ES2096375T3
ES2096375T3 ES94108407T ES94108407T ES2096375T3 ES 2096375 T3 ES2096375 T3 ES 2096375T3 ES 94108407 T ES94108407 T ES 94108407T ES 94108407 T ES94108407 T ES 94108407T ES 2096375 T3 ES2096375 T3 ES 2096375T3
Authority
ES
Spain
Prior art keywords
bar
yonona
procedure
carried out
sulphuric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94108407T
Other languages
English (en)
Inventor
Kurt Steiner
Herwig Ertel
Helmut Tiltscher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F Hoffmann La Roche AG filed Critical F Hoffmann La Roche AG
Application granted granted Critical
Publication of ES2096375T3 publication Critical patent/ES2096375T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C07C403/16—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms not being part of —CHO groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO PARA ELABORACION DE BETA-YONONA A TRAVES DE LA CICLIDIZACION CATALIZADA CON ACIDO SULFURICO DE SEUDOYONONA CON UN SISTEMA DE DISOLVENTE DE DOS FASES COMPUESTO A PARTIR DE ACIDO SULFURICO CONCENTRADO Y UN SEGUNDO DISOLVENTE ESENCIALMENTE NO MISCIBLE CON AGUA, DONDE EL PROCEDIMIENTO ESTA CARACTERIZADO POR LA UTILIZACION DE DIOXIDO DE CARBONO LIQUIDO QUE SE ENCUENTRA BAJO PRESION. ENTRE OTRAS COSAS ESTE PROCESO SE REALIZA BAJO UNA PRESION DESDE APROXIMADAMENTE 50 BAR HASTA APROXIMADAMENTE 150 BAR Y ANTES DE LA ROTURA DE CONEXION (APLASTAMIENTO) DE LA REACCION DE CICLIDIZACION EN TEMPERATURAS DESDE APROXIMADAMENTE 15 PROCESO DE ACUERDO CON LA INVENCION SE REALIZA PREFERENTEMENTE DE FORMA CONTINUA Y REPRESENTA UNA ETAPA INTERMEDIA IMPORTANTE EN LA SINTESIS DE LA VITAMINA A.
ES94108407T 1993-06-11 1994-06-01 Procedimiento de obtencion de beta-yonona. Expired - Lifetime ES2096375T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH175993 1993-06-11

Publications (1)

Publication Number Publication Date
ES2096375T3 true ES2096375T3 (es) 1997-03-01

Family

ID=4217911

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94108407T Expired - Lifetime ES2096375T3 (es) 1993-06-11 1994-06-01 Procedimiento de obtencion de beta-yonona.

Country Status (8)

Country Link
US (1) US5453546A (es)
EP (1) EP0628544B1 (es)
JP (1) JP3553135B2 (es)
CN (1) CN1037837C (es)
AT (1) ATE146777T1 (es)
DE (1) DE59401379D1 (es)
DK (1) DK0628544T3 (es)
ES (1) ES2096375T3 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100513400C (zh) * 2006-09-13 2009-07-15 湖南中烟工业有限责任公司 羟基磷酸铜在合成5,6-环氧-β-紫罗兰酮中的应用及合成5,6-环氧-β-紫罗兰酮的方法
EP1921058A1 (en) * 2006-11-10 2008-05-14 DSMIP Assets B.V. Process for the preparation of ionones and vitamin A, vitamin A derivatives, carotenes and carotenoids
CN111138261B (zh) * 2019-12-31 2023-02-24 上虞新和成生物化工有限公司 一种环合制备β-紫罗兰酮的方法
CN111792988A (zh) * 2020-08-04 2020-10-20 李金国 一种制备化妆品用β-紫罗兰酮的方法
CN117964470A (zh) * 2023-12-18 2024-05-03 万华化学集团股份有限公司 一种β-紫罗兰酮的合成方法
CN118186028B (zh) * 2024-04-09 2025-10-03 漳州市农业科学研究所 一种提高七指毛桃叶片中β-紫罗兰酮含量的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL155006B (nl) * 1968-04-24 1977-11-15 Philips Nv Werkwijze voor de bereiding van beta-ionon.
SU547445A1 (ru) * 1975-07-07 1977-02-25 Всесоюзный Научно-Исследовательский Витаминный Институт Способ получени -ионона
DE3328440A1 (de) * 1983-08-06 1985-02-21 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von jononen
DE3431131A1 (de) * 1984-08-24 1986-03-06 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von jononen

Also Published As

Publication number Publication date
EP0628544B1 (de) 1996-12-27
CN1037837C (zh) 1998-03-25
EP0628544A1 (de) 1994-12-14
JP3553135B2 (ja) 2004-08-11
DE59401379D1 (de) 1997-02-06
JPH06345727A (ja) 1994-12-20
DK0628544T3 (es) 1997-03-17
ATE146777T1 (de) 1997-01-15
US5453546A (en) 1995-09-26
CN1099742A (zh) 1995-03-08

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