ES2101498T3 - Derivados de fulereno termicamente estables y procedimiento para su preparacion. - Google Patents
Derivados de fulereno termicamente estables y procedimiento para su preparacion.Info
- Publication number
- ES2101498T3 ES2101498T3 ES94903862T ES94903862T ES2101498T3 ES 2101498 T3 ES2101498 T3 ES 2101498T3 ES 94903862 T ES94903862 T ES 94903862T ES 94903862 T ES94903862 T ES 94903862T ES 2101498 T3 ES2101498 T3 ES 2101498T3
- Authority
- ES
- Spain
- Prior art keywords
- pct
- preparation
- alkyl
- fulerene
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 3
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 229910052731 fluorine Inorganic materials 0.000 abstract 2
- 229910052740 iodine Inorganic materials 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 229910003472 fullerene Inorganic materials 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/70—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a condensed ring system consisting of at least two, mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic ring, e.g. cyclophanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
- C07C205/57—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C205/58—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton the carbon skeleton being further substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
- C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/215—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring having unsaturation outside the six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2604/00—Fullerenes, e.g. C60 buckminsterfullerene or C70
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/735—Carbon buckyball
- Y10S977/737—Carbon buckyball having a modified surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/735—Carbon buckyball
- Y10S977/737—Carbon buckyball having a modified surface
- Y10S977/738—Modified with biological, organic, or hydrocarbon material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
- Y10S977/735—Carbon buckyball
- Y10S977/737—Carbon buckyball having a modified surface
- Y10S977/74—Modified with atoms or molecules bonded to the surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/832—Nanostructure having specified property, e.g. lattice-constant, thermal expansion coefficient
- Y10S977/833—Thermal property of nanomaterial, e.g. thermally conducting/insulating or exhibiting peltier or seebeck effect
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
DERIVADO FULERENO DE LA FORMULA (I), DONDE LOS SIMBOLOS E INDICES TIENE EL SIGUIENTE SIGNIFICADO: F ES UN RESTO FULERENO DE LA FORMULA (C{SUB.20} + {SUB.2M}, DONDE M REPRESENTA LAS CIFRAS DESDE 1 HASTA 50; R{SUP.1} HASTA R{SUP.8} SON IGUALES O DIFERENTES Y SIGNIFICAN H, CO{SUB.2} R{SUP.9}, CN, COR{SUP.10}, CL, BR, J, F, OR{SUP.11}, C{SUB.1} - C{SUB.20} ALQUIL, QUE PUEDE SER SUSTITUIDO CON CL, J, BR, Y F, C{SUB.3} - C{SUB.8} CICLOALQUIL, ARIL, HETEROARIL, DONDE R{SUP.9} HASTA R{SUP.11} SIGNIFICAN C{SUB.1} - C{SUB.20} ALQUIL, FENIL O H; R{SUP.1} R{SUP.4} Y/O R{SUP.5}, R{SUP.7} PUEDEN SER TAMBIEN UNA PARTE DEL SISTEMA CICLOALIFATICO, CICLOAROMATICO O CICLOETEROAROMATICO, QUE POR SU PARTE ES SUSTITUIDO CON C{SUB.1} - C{SUB.20} ALQUIL, ARIL, CARBOXIL, CARBONIL, ALCOXI, ARILOXI, HALOGENO, NITRO, ALCOHOL O AMINA, O R{SUP.1} Y R{SUP.2}, R{SUP.2} Y R{SUP.3}, R{SUP.3} Y R{SUP.4} PUEDEN SE CONJUNTAMENTE DE FORMA RESPECTIVA (A) O (B), DONDE R{SUP.15}, R{SUP.18} SON H, C{SUB.1} - C{SUB.20} ALQUIL, F, CL. BR, J O FENIL Y AR EL RESTO DE UN SISTEMA CICLOAROMATICO ANULADO, R{SUP.5} HASTA R{SUP.8} PUEDEN SER TAMBIEN ELEMENTO DE ESTRUCTURA DE LA FORMULA (V), DONDE I ES UNA DE LAS CIFRAS DESDE 2 HASTA 20 Y K UNA CIFRA MAYOR QUE 1, DONDE R{SUP.5} Y R{SUP.7} CONJUNTAMENTE PUEDEN SER UN PUENTE A BASE DE O -, N ES 1 HASTA 20, ASI COMO PROCESO PARA SU ELABORACION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4301458A DE4301458A1 (de) | 1993-01-20 | 1993-01-20 | Thermisch stabile Fullerenderivate und Verfahren zu Ihrer Herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2101498T3 true ES2101498T3 (es) | 1997-07-01 |
Family
ID=6478580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94903862T Expired - Lifetime ES2101498T3 (es) | 1993-01-20 | 1993-12-22 | Derivados de fulereno termicamente estables y procedimiento para su preparacion. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5763719A (es) |
| EP (1) | EP0680462B1 (es) |
| JP (1) | JPH08505859A (es) |
| AT (1) | ATE151401T1 (es) |
| DE (2) | DE4301458A1 (es) |
| ES (1) | ES2101498T3 (es) |
| WO (1) | WO1994017018A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2968710B2 (ja) * | 1995-09-19 | 1999-11-02 | 核燃料サイクル開発機構 | 金属内包フラーレン誘導体及びその製造方法 |
| WO2003029137A2 (en) | 2001-10-01 | 2003-04-10 | Tda Research, Inc. | Derivatization and solubilization of insoluble classes of fullerenes |
| US7812190B2 (en) * | 2001-10-01 | 2010-10-12 | Tda Research, Inc. | Derivatization and solubilization of fullerenes for use in therapeutic and diagnostic applications |
| RU2294928C2 (ru) * | 2005-06-14 | 2007-03-10 | Институт нефтехимии и катализа РАН | Способ получения 1-[1-гидрокси-1-(пирид-4-ил)метил]-1,2-дигидро[60]фуллеренов |
| RU2294929C2 (ru) * | 2005-06-14 | 2007-03-10 | Институт нефтехимии и катализа РАН | Способ получения 1-[3-гидрокси-3-(пирид-4-ил)проп-1-ил)]-1,2-дигидро[60]фуллеренов |
| CN101529610B (zh) | 2006-06-13 | 2013-01-02 | 普雷克托尼克斯公司 | 包含富勒烯及其衍生物的有机光伏器件 |
| US20120004476A1 (en) * | 2009-01-29 | 2012-01-05 | Korea Research Institute Of Chemical Technology | Fullerene Derivatives and Organic Electronic Device Comprising the Same |
| JP5883639B2 (ja) | 2010-12-21 | 2016-03-15 | 住友化学株式会社 | 炭素クラスター構造を有する高分子化合物及びそれを用いた有機デバイス |
| JP5652712B2 (ja) * | 2010-12-28 | 2015-01-14 | 三菱化学株式会社 | 光電変換素子及びその製造方法、並びにインク |
| CN102391078A (zh) * | 2011-09-01 | 2012-03-28 | 中国科学院化学研究所 | 一种含苯环富勒烯衍生物及其制备方法与应用 |
| AU2014256484A1 (en) * | 2013-04-22 | 2015-12-03 | Merck Patent Gmbh | Improved fullerene derivatives and related materials, methods and devices |
| US9502658B2 (en) | 2013-04-22 | 2016-11-22 | Nano-C, Inc. | Fullerene derivatives and related materials, methods, and devices |
| CN104925779B (zh) * | 2014-03-21 | 2016-09-07 | 国家纳米科学中心 | 一种富勒烯衍生物及其制备方法和应用 |
| EP3157895B9 (en) * | 2014-06-17 | 2022-03-30 | Nano-C, Inc. | Fullerene derivatives for organic semiconductors |
| US10438808B2 (en) * | 2016-05-25 | 2019-10-08 | Irresistible Materials, Ltd | Hard-mask composition |
| US11746255B2 (en) * | 2016-05-25 | 2023-09-05 | Irresistible Materials Ltd | Hard-mask composition |
| CN106380380A (zh) * | 2016-08-29 | 2017-02-08 | 北京化工大学 | 一种富勒烯衍生物及其在钙钛矿太阳能电池中的应用 |
| EP3877328A4 (en) | 2018-12-17 | 2022-01-05 | Nano-C, Inc. | MIXTURE OF FULLER-END DERIVATIVES, METHOD OF MANUFACTURING AND USE THEREOF |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2082593A1 (en) * | 1991-11-27 | 1993-05-28 | Glen P. Miller | Synthesis of derivatized fullerenes with superacid catalysts |
-
1993
- 1993-01-20 DE DE4301458A patent/DE4301458A1/de not_active Withdrawn
- 1993-12-22 JP JP6516596A patent/JPH08505859A/ja active Pending
- 1993-12-22 ES ES94903862T patent/ES2101498T3/es not_active Expired - Lifetime
- 1993-12-22 WO PCT/EP1993/003658 patent/WO1994017018A1/de not_active Ceased
- 1993-12-22 US US08/492,021 patent/US5763719A/en not_active Expired - Fee Related
- 1993-12-22 AT AT94903862T patent/ATE151401T1/de not_active IP Right Cessation
- 1993-12-22 EP EP94903862A patent/EP0680462B1/de not_active Expired - Lifetime
- 1993-12-22 DE DE59306140T patent/DE59306140D1/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE59306140D1 (de) | 1997-05-15 |
| DE4301458A1 (de) | 1994-07-21 |
| JPH08505859A (ja) | 1996-06-25 |
| EP0680462A1 (de) | 1995-11-08 |
| US5763719A (en) | 1998-06-09 |
| WO1994017018A1 (de) | 1994-08-04 |
| EP0680462B1 (de) | 1997-04-09 |
| ATE151401T1 (de) | 1997-04-15 |
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