ES2105502T3 - Procedimiento para la produccion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados. - Google Patents

Procedimiento para la produccion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados.

Info

Publication number
ES2105502T3
ES2105502T3 ES94300071T ES94300071T ES2105502T3 ES 2105502 T3 ES2105502 T3 ES 2105502T3 ES 94300071 T ES94300071 T ES 94300071T ES 94300071 T ES94300071 T ES 94300071T ES 2105502 T3 ES2105502 T3 ES 2105502T3
Authority
ES
Spain
Prior art keywords
contg
hydrogenation
compounds
surface area
hydrogenation zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94300071T
Other languages
English (en)
Inventor
John Scarlett
Michael Anthony Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10746031&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2105502(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of ES2105502T3 publication Critical patent/ES2105502T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/27—Polyhydroxylic alcohols containing saturated rings
    • C07C31/272—Monocyclic
    • C07C31/276—Monocyclic with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Glass Compositions (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)

Abstract

SE DESCRIBE UN PROCESO PARA LA PRODUCCION DE UN COMPUESTO HIDROXILICO ELEGIDO A PARTIR DE ALCOHOLES Y DIOLES POR HIDROGENACION DE UN MATERIAL HIDROGENABLE ELEGIDO A PARTIR DE MONOESTERES DE ACIDOS CARBOXILICOS, MONOESTERES O ACIDOS DICARBOXILICO, DIESTERES DE ACIDOS DICARBOXILICOS, ALDEHIDOS, OLEFINICAMENTE INSATURADOS Y MEZCLAS DE DOS O MAS DE ESTOS, CUYO PROCESO CONSISTE EN: A) PROPORCIONAR UNA ZONA DE HIDROGENACION QUE CONTIENE UNA CARGA DE UN CATALIZADOR DE HIDROGENACION GRANULAR QUE TIENE UN AREA DE SUPERFICIE TOTAL DE AL MENOS 15 M2%G, UNA DISTRIBUCION DE DIMENSION DE PORO DE MODO QUE MAS DE 50% DEL VOLUMEN DE PORO ESTE PREVISTO POR POROS EN LA GAMA DE DIMENSION INFERIOR A APROXIMADAMENTE 40NM, Y UNA DISTRIBUCION DE AREA DE SUPERFICIE DE MODO QUE MAS DEL 50% DEL AREA DE SUPERFICIE TOTAL ESTA PREVISTA POR POROS EN LA GAMA DE DIMENSION DE APROXIMADAMENTE 40 NM; B) PROPORCIONAR A LA ZONA DE HIDROGENACION UNA CORRIENTE DE ALIMENTACION DE UNA MEZCLA QUE CONTIENEN HIDROGENO Y EL MATERIAL HIDROGENABLE; C) MANTENER LA ZONA DE HIDROGENACION BAJO CONDICIONES DE PRESION Y TEMPERATURA QUE SON PROPICIAS PARA EFECTUAR LA HIDROGENACION DEL MATERIAL HIDROGENABLE; Y D) RECUPERAR DE LA ZONA DE HIDROGENACION UNA CORRIENTE DE PRODUCTO QUE COMPRENDE EL COMPUESTO HIDROXILICO. EL PROCESO ESTA EJEMPLIFICADO POR LA HIDROGENACION DE 1,4CILOHEXANODICARBOXILATO DE DIMETILO PARA PRODUCIR 1,4CICLOHEXANODIMETANOL.
ES94300071T 1993-12-02 1994-01-06 Procedimiento para la produccion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados. Expired - Lifetime ES2105502T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939324753A GB9324753D0 (en) 1993-12-02 1993-12-02 Process

Publications (1)

Publication Number Publication Date
ES2105502T3 true ES2105502T3 (es) 1997-10-16

Family

ID=10746031

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94300071T Expired - Lifetime ES2105502T3 (es) 1993-12-02 1994-01-06 Procedimiento para la produccion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados.

Country Status (9)

Country Link
US (1) US5395990A (es)
EP (1) EP0656336B1 (es)
JP (1) JP4050336B2 (es)
KR (1) KR100281491B1 (es)
AT (1) ATE157074T1 (es)
DE (1) DE69405079T2 (es)
ES (1) ES2105502T3 (es)
GB (1) GB9324753D0 (es)
TW (1) TW279847B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2990568B2 (ja) * 1993-12-13 1999-12-13 花王株式会社 銅含有水素化触媒の調製法およびアルコールの製造法
US5463143A (en) * 1994-11-07 1995-10-31 Shell Oil Company Process for the direct hydrogenation of wax esters
US5475160A (en) * 1994-11-07 1995-12-12 Shell Oil Company Process for the direct hydrogenation of triglycerides
US5475159A (en) * 1994-11-07 1995-12-12 Shell Oil Company Process for the direct hydrogenation of methyl esters
US5663488A (en) * 1995-05-31 1997-09-02 Hewlett-Packard Co. Thermal isolation system in an analytical instrument
US5536889A (en) * 1995-09-29 1996-07-16 Shell Oil Company Process for the two-stage hydrogenation of methyl esters
DE19757554A1 (de) 1997-12-23 1999-06-24 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
DE19807268A1 (de) * 1998-02-20 1999-08-26 Basf Ag Verfahren zur Herstellung von Alkoholen
DE19815639A1 (de) * 1998-04-07 1999-10-14 Basf Ag Verfahren zur Herstellung von Zuckeralkoholen
EP1108702A1 (en) * 1999-12-13 2001-06-20 Kvaerner Process Technology Limited Process for the co-production of aliphatic diols and cyclic ethers
DE10061553A1 (de) * 2000-12-11 2002-06-13 Basf Ag Poröser Katalysator für die Hydrierung von Maleinsäureanhydrid zu Tetrahydrofuran
GB0117090D0 (en) * 2001-07-12 2001-09-05 Kvaerner Process Tech Ltd Process
DE10207443A1 (de) * 2002-02-22 2003-09-04 Bayer Ag Verfahren und Katalysator zur Herstellung von Alkoholen
DE10225926A1 (de) * 2002-06-11 2003-12-24 Basf Ag Verfahren zur Herstellung von Butandiol
DE10225929A1 (de) * 2002-06-11 2003-12-24 Basf Ag Zweistufiges Verfahren zur Herstellung von Butandiol mit Zwischenabtrennung von Bernsteinsäureanhydrid
DE10225927A1 (de) * 2002-06-11 2003-12-24 Basf Ag Verfahren zur Herstellung von Butandiol durch kombinierte Gasphasen- und Flüssigphasensynthese
GB0329152D0 (en) * 2003-12-16 2004-01-21 Davy Process Techn Ltd Process
US6919489B1 (en) 2004-03-03 2005-07-19 Eastman Chemical Company Process for a cyclohexanedimethanol using raney metal catalysts
AR072446A1 (es) * 2008-03-02 2010-09-01 Dow Global Technologies Inc Proceso de hidrogenacion mejorado
US9108895B2 (en) 2012-10-26 2015-08-18 Eastman Chemical Company Promoted ruthenium catalyst for the improved hydrogenation of carboxylic acids to the corresponding alcohols
US9115155B1 (en) 2014-03-20 2015-08-25 Eastman Chemical Company Low-pressure synthesis of cyclohexanedimethanol and derivatives
DE102014013530A1 (de) 2014-09-12 2016-03-17 Clariant International Ltd. Extrudierter Cu-Al-Mn-Hydrierkatalysator
JP6732431B2 (ja) 2014-11-20 2020-07-29 花王株式会社 脂肪族アルコールの製造方法
CN110637003B (zh) * 2017-05-16 2022-11-04 巴斯夫欧洲公司 用于醛和/或醇的大规模制备的氢甲酰化方法
GB202404470D0 (en) * 2024-03-28 2024-05-15 Johnson Matthey Davy Technologies Ltd Hydrogenolysis catalysts for the hydrogenolysis of a dialkyl maleate of a dialkyl maleate or dialkyl succinate to 1,4-butanediol
CN118084835A (zh) * 2024-04-07 2024-05-28 华东师范大学 一种钴锌碳基材料氧化酯化2,5-呋喃二甲醇制备2,5-呋喃二甲酸二甲酯的方法

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2105664A (en) * 1930-04-17 1938-01-18 Du Pont Catalytic hydrogenation of hydroaromatic carboxylic acids and their esters
US2137407A (en) * 1931-05-11 1938-11-22 Du Pont Catalytic hydrogenation process
US2091800A (en) * 1931-09-15 1937-08-31 Rohm & Haas Method of hydrogenating esters
US2079414A (en) * 1932-08-20 1937-05-04 Du Pont Process for producing alcohols from esters of nonaromatic carboxylic acids
US2040944A (en) * 1933-09-22 1936-05-19 Du Pont Process for producing polyhydroxy alcohols
US2755317A (en) * 1952-11-10 1956-07-17 Universal Oil Prod Co Hydrogenation of benzene to cyclohexane
US2818393A (en) * 1953-05-05 1957-12-31 Kellogg M W Co Method of preparing a catalyst
US2830095A (en) * 1953-05-07 1958-04-08 Olin Mathieson Production of ethylene chlorohydrin
DE965236C (de) * 1955-08-22 1957-06-06 Dehydag Gmbh Verfahren zur kontinuierlichen Herstellung einfach ungesaettigter, hoehermolekularerFettalkohole
BE592181A (es) * 1955-12-22
US2884450A (en) * 1956-04-20 1959-04-28 Du Pont Hydrogenation of unsaturated dilactones to 1,8-octanedioic acids and 1,8-octanediolswith copper chromite catalysts
US2917549A (en) * 1958-01-07 1959-12-15 Eastman Kodak Co Preparation of trans-1,4-cyclohexanedimethanol
NL132671C (es) * 1960-02-09
DE1144703B (de) * 1960-10-06 1963-03-07 Eastman Kodak Co Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Estern
FR1276722A (fr) * 1960-10-11 1961-11-24 Eastman Kodak Co Procédé de préparation d'un catalyseur en vue de la réduction des esters en alcools
NL292315A (es) * 1962-05-05
CH438269A (it) * 1963-05-10 1967-06-30 Snam Spa Processo di idrogenazione di composti acetilenici miscibili con acqua a composti etilenici
US3334149A (en) * 1964-07-21 1967-08-01 Eastman Kodak Co Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite
US4052467A (en) * 1967-11-08 1977-10-04 Phillips Petroleum Company Catalytic reduction of aldehydes to alcohols
GB1454440A (en) * 1974-10-03 1976-11-03 Ucb Sa Process for the production of butane-1,4-diol from but-2-ene- 1,4-dioic acid
GB1464263A (en) * 1974-12-03 1977-02-09 Ucb Sa Production of butane-1,4-diol
US4172961A (en) * 1975-08-08 1979-10-30 Denka Chemical Corporation Production of 1,4-butanediol
US4032458A (en) * 1975-08-08 1977-06-28 Petro-Tex Chemical Corporation Production of 1,4-butanediol
DE2719867A1 (de) * 1977-05-04 1978-11-09 Bayer Ag Verfahren zur herstellung von butandiol-1,4
DE2845905C3 (de) * 1978-10-21 1983-05-26 Chemische Werke Hüls AG, 4370 Marl Verfahren zur kontinuierlichen Herstellung von Butandiol-1,4
DE3106819A1 (de) * 1981-02-24 1982-09-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von 1,4-butandiol
IT1190783B (it) * 1981-04-29 1988-02-24 Davy Mckee Oil & Chem Processo per l'idrogenolisi di esteri di acidi carbossilici
GB8331793D0 (en) * 1983-11-29 1984-01-04 Davy Mckee Ltd Process
GB8514002D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
EP0204730A1 (en) * 1984-11-21 1986-12-17 DAVY McKEE (LONDON) LIMITED Process for the production of butane-1,4-diol
GB8514001D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
DE3610698A1 (de) * 1986-03-29 1987-10-01 Henkel Kgaa Katalysator und verfahren zur katalytischen hydrierung von fettsaeuremethylestern im festbett
WO1988000937A1 (en) * 1986-08-01 1988-02-11 Davy Mckee (London) Limited Process for the co-production of butane-1,4-diol and gamma-butyrolactone
GB8717989D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Catalyst
US4837368A (en) * 1988-02-01 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
EP0397650B1 (en) * 1987-08-03 1993-10-27 Eastman Chemical Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and catalysts therefor
US4999090A (en) * 1988-04-10 1991-03-12 Towa Chemical Industry Co., Ltd. Process for preparing trans-1,4-cyclohexanedimethanol and powder of the same
US5185476A (en) * 1988-07-15 1993-02-09 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
DE3843956A1 (de) * 1988-12-24 1990-06-28 Huels Chemische Werke Ag Verfahren zur herstellung von aliphatischen und cycloaliphatischen diolen durch katalytische hydrierung von dicarbonsaeureestern
US5124435A (en) * 1988-12-28 1992-06-23 Mitsubishi Rayon Co., Ltd. Polyester copolymer from terephthalic acid glycol and cycloaliphatic diol
US5157168A (en) * 1989-01-17 1992-10-20 Davy Mckee (London) Limited Process for the production of fatty alcohols
US4929777A (en) * 1989-02-13 1990-05-29 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
US5191091A (en) * 1989-12-21 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al catalysts
US5142067A (en) * 1989-12-21 1992-08-25 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al-X catalysts
GB9025708D0 (en) * 1990-11-27 1991-01-09 Unilever Plc Fatty ester hydrogenation
DE4141199A1 (de) * 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten

Also Published As

Publication number Publication date
US5395990A (en) 1995-03-07
HK1002329A1 (en) 1998-08-14
DE69405079T2 (de) 1998-01-15
JP4050336B2 (ja) 2008-02-20
KR950017891A (ko) 1995-07-20
EP0656336A1 (en) 1995-06-07
GB9324753D0 (en) 1994-01-19
ATE157074T1 (de) 1997-09-15
KR100281491B1 (ko) 2001-02-15
DE69405079D1 (de) 1997-09-25
JPH07196549A (ja) 1995-08-01
EP0656336B1 (en) 1997-08-20
TW279847B (es) 1996-07-01

Similar Documents

Publication Publication Date Title
ES2105502T3 (es) Procedimiento para la produccion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados.
ES2115871T3 (es) Procedimiento para la fabricacion de compuestos hidroxilicos por hidrogenacion de compuestos oxigenados.
EP0922690B1 (en) Process for the preparation of cyclohexanedimethanol
ES2119075T3 (es) Procedimiento para la produccion de compuestos hidroxi mediante hidrogenacion de compuestos oxigenados.
US6008418A (en) Process for preparing 1,6 hexanediol with a level of purity over 99%
SG47920A1 (en) Process for the production of cydohexanedimenthanol with preponderance of the trans-isomer
US5030771A (en) Method of producing aliphatic and cycloaliphatic diols by catalytic hydrogenation of dicarboxylic acid esters
ATE156112T1 (de) Verfahren zur herstellung von 1,4- cyclohexandimethanol
WO1994006738A1 (en) Process for the production of alcohols
MY114491A (en) Process for the production of n-butanol
CA2394270A1 (en) Process for the co-production of aliphatic diols and cyclic ethers
CA1110638A (en) Process for producing a hydrofuran and a 1,4-diol
KR100945988B1 (ko) 1,4-부탄디올의 제조 방법
US20040039214A1 (en) Method for the production of tetrahydrofuran
KR20050007603A (ko) 숙신산 무수물의 중간 분리를 포함하는 부탄디올의 2 단계제조 방법
KR100898455B1 (ko) 결합된 기상 및 액상 수소화에 의한 1,4-부탄디올의 제조방법
JPS6485937A (en) Production of 1,5-pentanediol
CA2247991C (en) Process for preparing 1,6 hexane diol with a level of purity over 99 %
JP2005008586A (ja) １，６−ヘキサンジオールの製造法
JPS6485938A (en) Production of 1,6-hexanediol
KR20050007604A (ko) 두 반응기에서 부탄디올을 2 단계로 제조하는 방법
JP2004131410A (ja) α−ヒドロキシカルボン酸エステルの製造方法

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 656336

Country of ref document: ES