ES2107807T3 - Bomba de calor de hidruro organico/hidruro metalico. - Google Patents

Bomba de calor de hidruro organico/hidruro metalico.

Info

Publication number
ES2107807T3
ES2107807T3 ES94904437T ES94904437T ES2107807T3 ES 2107807 T3 ES2107807 T3 ES 2107807T3 ES 94904437 T ES94904437 T ES 94904437T ES 94904437 T ES94904437 T ES 94904437T ES 2107807 T3 ES2107807 T3 ES 2107807T3
Authority
ES
Spain
Prior art keywords
hybrid
bed
heat
sub
metal hybrid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94904437T
Other languages
English (en)
Inventor
Arthur S Kesten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RTX Corp
Original Assignee
United Technologies Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Technologies Corp filed Critical United Technologies Corp
Application granted granted Critical
Publication of ES2107807T3 publication Critical patent/ES2107807T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
    • F25B17/12—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type using desorption of hydrogen from a hydride
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Catalysts (AREA)

Abstract

UNA BOMBA DE CALOR QUE COMPRENDE SISTEMA DE HIBRIDO ORGANICO (12) E HIBRIDO DE METAL (2) REFRIGERA UN ESPACIO ACONDICIONADO (6) TRANSFIRIENDO CALOR DESDE EL ESPACIO ACONDICIONADO A UN LECHO DE HIBRIDO DE METAL (4, COMO LO QUE UN HIBRIDO DE METAL EN EL LECHO FORMA H{SUB,2}.E H{SUB,2} FLUYE HACIA UN ESPACIO DE VAPOR (14) EN EL SISTEMA DE HIBRIDO LIQUIDO (12) Y REACCIONA CON UN PRODUCTO DE DESHIDROGENACION EN UNA SUPERFICIE CATALITICA (32) EN EL ESPACIO DE VAPOR PARA FORMAR UN HIBRIDO ORGANICO Y UN CALOR EXOTERMICO DE REACCION. LA BOMBA DE CALOR TAMBIEN PUEDE SER USADA PARA ACTUALIZAR EL CALOR RESIDUAL TRANSFIRIENDO CALOR DESDE UNA FUENTE DE CALOR DE TEMPERATURA RELATIVAMENTE BAJA PARA DESCOMPONER EL HIBRIDO DE METAL. EL CALOR EXOTERMICO DE REACCION PUEDE SER RETIRADO DEL ESPACIO DE VAPOR Y USADO PARA CALENTAR EL ESPACIO. EN AMBAS REALIZACIONES, EL LECHO DE HIBRIDO DE METAL (4) PUEDE REGENERARSE SUMINISTRANDO UN CALOR ENDOTERMICO DE REACCION A LA SUPERFICIE CATALITICA (32), CON LO QUE SE DESHIDROGENA EL HIBRIDO ORGANICO PARA FORMAR H{SUB.2}. EL H{SUB,2} FLUYE HACIA EL LECHO DE HIBRIDO DE METAL (4) Y Y REACCIONA CON EL LECHO DE HIBIRDO DE METAL PARA REGENERAR EL HIBRIDO DE METAL. ALTERNATIVAMENTE, EL LECHO DE HIBRIDO DE METAL (4) PUEDE REGENERARSE HACIENDO FLUIR UNA MEZCLA DE LIQUIDO QUE COMPRENDE EL HIBRIDO ORGANICO EN UNA ZONA DE REACCION (38) QUE TIENE UN CATALIZADOR DE DESHIDROGENACION (42) Y PROPORCIONANDO UN CALOR ENDOTERMICO DE REACCION A LA ZONA DE REACCION, CON LO QUE LA SE DESHIDROGENA EL HIBRIDO ORGANICO PARA FORMAR H{SUB,2}. COMO ANTES, EL H{SUB,2} FLUYE HACIA EL LECHO DE HIBRIDO DE METAL (4) CUANDO REGENERA EL HIBRIDO DE METAL.
ES94904437T 1993-03-23 1993-12-13 Bomba de calor de hidruro organico/hidruro metalico. Expired - Lifetime ES2107807T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3581193A 1993-03-23 1993-03-23
US08/083,824 US5347828A (en) 1993-03-23 1993-06-25 Organic hydride/metal hydride heat pump

Publications (1)

Publication Number Publication Date
ES2107807T3 true ES2107807T3 (es) 1997-12-01

Family

ID=26712519

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94904437T Expired - Lifetime ES2107807T3 (es) 1993-03-23 1993-12-13 Bomba de calor de hidruro organico/hidruro metalico.

Country Status (9)

Country Link
US (1) US5347828A (es)
EP (1) EP0688417B1 (es)
JP (1) JPH08507361A (es)
KR (1) KR960701343A (es)
BR (1) BR9307829A (es)
CA (1) CA2158950A1 (es)
DE (1) DE69313873D1 (es)
ES (1) ES2107807T3 (es)
WO (1) WO1994021973A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5670378A (en) * 1995-02-23 1997-09-23 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Method for trace oxygen detection
JP2002274803A (ja) * 2001-03-13 2002-09-25 Sekisui Chem Co Ltd 水素貯蔵・供給システム
JP4657475B2 (ja) * 2001-03-13 2011-03-23 勝 市川 水素貯蔵・供給システム
JP2002274804A (ja) * 2001-03-13 2002-09-25 Sekisui Chem Co Ltd 水素貯蔵・供給システム
JP4662534B2 (ja) * 2004-10-01 2011-03-30 株式会社新エネルギー研究所 水素ガス生成装置
DE102005004592B4 (de) * 2005-02-01 2018-06-28 Bayerische Motoren Werke Aktiengesellschaft Speicher und/oder Druckerhöhungseinrichtung für Wasserstoff
SE530959C2 (sv) 2006-05-29 2008-11-04 Climatewell Ab Publ Kemisk värmepump med hybridsubstans
US8745995B2 (en) * 2010-10-07 2014-06-10 Basf Se Process for heat integration by means of a refrigeration system
US8727312B2 (en) 2011-04-21 2014-05-20 Hamilton Sundstrand Corporation Butterfly valve
JP5871773B2 (ja) 2012-10-30 2016-03-01 Ｊｘ日鉱日石エネルギー株式会社 脱水素触媒及びその製造方法
WO2020200403A1 (en) 2019-03-29 2020-10-08 Ahlstrom-Munksjö Oyj A process of producing a heat storage material and a heat storage material
CN118448673B (zh) * 2024-04-17 2026-03-17 武汉船用电力推进装置研究所(中国船舶集团有限公司第七一二研究所) 一种密闭环境用燃料电池供氢系统
CN118495470A (zh) * 2024-05-31 2024-08-16 中国地质大学（武汉） 一种复合浆态储制氢材料及制备方法

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4161211A (en) * 1975-06-30 1979-07-17 International Harvester Company Methods of and apparatus for energy storage and utilization
DE2629441A1 (de) * 1976-06-30 1978-01-05 Linde Ag Verfahren zur erhoehung der temperatur eines waermetraegers
US4055962A (en) * 1976-08-18 1977-11-01 Terry Lynn E Hydrogen-hydride absorption systems and methods for refrigeration and heat pump cycles
DE2715990A1 (de) * 1977-04-09 1978-10-12 Daimler Benz Ag Standheizung durch hydride in wasserstoff-fahrzeugen
DE2921451A1 (de) * 1979-05-26 1980-12-04 Daimler Benz Ag Verfahren zum vorwaermen von kraftfahrzeugen mit verbrennungsmotor
US4346752A (en) * 1981-01-19 1982-08-31 United Technologies Corporation Self-driven chemical heat pipe
CA1146725A (fr) * 1981-05-27 1983-05-24 Hydro-Quebec Hydrure liquide pour le stockage de l'hydrogene
US4436539A (en) * 1981-10-06 1984-03-13 Technion Research And Development Foundation Ltd. Method and apparatus for air-conditioning by means of a hydrogen heat pump
US4476918A (en) * 1982-06-28 1984-10-16 United Technologies Corporation Method and apparatus for a temperature-shifted chemical heat pipe
CA1212284A (en) * 1982-08-23 1986-10-07 Mitsuyoshi Miura Heat-generating device
US4478814A (en) * 1982-09-30 1984-10-23 United Technologies Corporation Gas transporting system
DE3408192C2 (de) * 1984-03-06 1987-03-26 Markus 8058 Erding Rothmeyer Verfahren zum Hochtransformieren der Temperatur von Wärme sowie Wärmetransformator
GB2157415B (en) * 1984-04-12 1987-08-05 Exxon Research Engineering Co Coupled heat pumps
US4567033A (en) * 1984-10-25 1986-01-28 United Technologies Corporation Low-energy method for freeing chemically bound hydrogen
DE3610332A1 (de) * 1985-03-30 1986-10-09 Kabushiki Kaisha Toshiba, Kawasaki, Kanagawa Regenerativheizgeraet
FR2582790B1 (fr) * 1985-06-04 1987-07-24 Elf Aquitaine Procede et dispositif thermochimiques de stockage et destockage de chaleur
US4614176A (en) * 1985-10-23 1986-09-30 United Technologies Corporation Catalytic metal hydride space heater
DE3639545C1 (de) * 1986-11-20 1988-06-01 Studiengesellschaft Kohle Mbh Verfahren zur Waermespeicherung und -transformation sowie Kaelteerzeugung
US4712610A (en) * 1986-11-28 1987-12-15 United Technologies Corporation Chemical heat pipe employing self-driven chemical pump based on a molar increase
EP0287319B1 (en) * 1987-04-14 1992-11-11 Uwe Rockenfeller Chemical energy storage system
FR2615601B1 (fr) * 1987-05-22 1989-11-10 Faiveley Ets Dispositif et procede pour produire du froid et/ou de la chaleur par reaction solide-gaz
US4949549A (en) * 1987-07-07 1990-08-21 International Thermal Packaging, Inc. Cooling device with improved waste-heat handling capability
US4993239A (en) * 1987-07-07 1991-02-19 International Thermal Packaging, Inc. Cooling device with improved waste-heat handling capability
FR2620048B1 (fr) * 1987-09-07 1989-12-22 Elf Aquitaine Procede de conduite d'une reaction thermochimique et installation permettant la mise en oeuvre de ce procede
US4850859A (en) * 1988-09-30 1989-07-25 United Technologies Corporation Liquid fueled hydrogen heater
JPH02101355A (ja) * 1988-10-05 1990-04-13 Honda Motor Co Ltd 水素貯蔵合金を用いた空調装置
JPH02130360A (ja) * 1988-11-09 1990-05-18 Toyota Autom Loom Works Ltd 金属水素化物を利用した冷暖房装置
JPH02259375A (ja) * 1989-03-31 1990-10-22 Sanyo Electric Co Ltd 金属水素化物利用の冷却装置
JPH02259374A (ja) * 1989-03-31 1990-10-22 Sanyo Electric Co Ltd 金属水素化物利用の冷却装置
US4928496A (en) * 1989-04-14 1990-05-29 Advanced Materials Corporation Hydrogen heat pump
JPH086608B2 (ja) * 1989-08-11 1996-01-29 株式会社日立製作所 熱回収装置およびその運転方法
US5018368A (en) * 1989-10-12 1991-05-28 International Thermal Packaging, Inc. Multi-staged desiccant refrigeration device
JPH0428973A (ja) * 1990-05-22 1992-01-31 Sanyo Electric Co Ltd 冷房装置

Also Published As

Publication number Publication date
EP0688417A1 (en) 1995-12-27
US5347828A (en) 1994-09-20
EP0688417B1 (en) 1997-09-10
JPH08507361A (ja) 1996-08-06
WO1994021973A1 (en) 1994-09-29
KR960701343A (ko) 1996-02-24
DE69313873D1 (de) 1997-10-16
BR9307829A (pt) 1995-11-14
CA2158950A1 (en) 1994-09-29

Similar Documents

Publication Publication Date Title
ES2107807T3 (es) Bomba de calor de hidruro organico/hidruro metalico.
ES2104004T3 (es) Catalizador y procedimiento para la oxicloracion de etileno en diclorometano.
ES2101977T3 (es) Procedimiento y dispositivo de deshidrogenacion catalitica de una carga parafinica c2+ que comprende medios para inhibir el agua en el efluente.
BR0100130A (pt) Sistema de fornecimento de lìquido criogênico, aparelho montado dentro de um vaso de reação, e, aparelho de fornecimento de lìquido criogênico
ES2113133T3 (es) Procedimiento para producir metanol.
EP1402948A4 (en) CATALYST FOR THE HYDROGEN TREATMENT OF GAS OIL, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR THE HYDROGENATION OF GAS OIL
ES2155677T3 (es) Sistema convertidor catalitico y procedimiento correspondiente.
MY109267A (en) Activation of hydrocarbon synthesis catalyst
AR247191A1 (es) Un proceso y un aparato para convertir olefinas en hidrocarburos superiores
MY110163A (en) Rejuvenation of hydrocarbon synthesis catalyst
ES2176819T3 (es) Enfriamiento de un reactor por contacto directo usando un liquido criogenico.
ES2030499T5 (es) Procedimiento de reaccion exotermica en un reactor catalitico de lecho fijo.
ES2151259T3 (es) Procedimiento para la obtencion de aminas y aminonitrilos.
MX171197B (es) Proceso para la produccion de hidrogeno de alta pureza mediante la reformacion catalitica del metanol
ES2186267T3 (es) Procedimiento para la hidrogenacion en fase liquida selectiva de compuestos de carbonilo alfa,beta-insaturados.
EP0248224A3 (en) Mass for removing by chemisorption homogeneous dissolved mixtures, particularly oxygen, from gases or liquids
ES2127488T3 (es) Hidrogenacion selectiva de fracciones hidrocarbonadas que incluyen hidrocarburos monoinsaturados y poliinsaturados.
ES2053940T3 (es) Procedimiento para la obtencion de caprolactama.
CA2285032A1 (en) Process for the preparation of high activity hydrocarbon synthesis catalysts; and catalyst compositions
ES2184520T3 (es) Procedimiento para la puesta a punto de un sistema de catalizador de hidrogenacion.
ES2002534A6 (es) Procedimiento para la obtencion de compuestos de ciclohexilo por hidrogenacion catalitica de compuestos de bencilo
EG13905A (en) Catalytic cracking of hydrocarbons
Ikenaga et al. Coal hydroliquefaction using highly dispersed catalyst precursors
ES2052790T3 (es) Un proceso para preparar bisfenol a.
AR059164A1 (es) Integracion de calor

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 688417

Country of ref document: ES