ES2108067T3 - Estabilizadores para materiales plasticos. - Google Patents
Estabilizadores para materiales plasticos.Info
- Publication number
- ES2108067T3 ES2108067T3 ES92118835T ES92118835T ES2108067T3 ES 2108067 T3 ES2108067 T3 ES 2108067T3 ES 92118835 T ES92118835 T ES 92118835T ES 92118835 T ES92118835 T ES 92118835T ES 2108067 T3 ES2108067 T3 ES 2108067T3
- Authority
- ES
- Spain
- Prior art keywords
- stabilizing
- plastic materials
- weight percent
- formulations
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract 5
- 239000004033 plastic Substances 0.000 title abstract 5
- 229920003023 plastic Polymers 0.000 title abstract 5
- 239000003381 stabilizer Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 9
- 230000000087 stabilizing effect Effects 0.000 abstract 7
- 238000009472 formulation Methods 0.000 abstract 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- -1 polyethylene Polymers 0.000 abstract 2
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 abstract 2
- YOYOQXRPUDEPAK-UHFFFAOYSA-N 1-Hydroxy-3-(octanoyloxy)propan-2-yl decanoate Chemical compound CCCCCCCCCC(=O)OC(CO)COC(=O)CCCCCCC YOYOQXRPUDEPAK-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229940087168 alpha tocopherol Drugs 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229960000984 tocofersolan Drugs 0.000 abstract 1
- 229930003799 tocopherol Natural products 0.000 abstract 1
- 235000010384 tocopherol Nutrition 0.000 abstract 1
- 239000011732 tocopherol Substances 0.000 abstract 1
- 229960001295 tocopherol Drugs 0.000 abstract 1
- 239000002076 α-tocopherol Substances 0.000 abstract 1
- 235000004835 α-tocopherol Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
MEZCLAS ESTABILIZANTES PARA MATERIALES PLASTICOS QUE CONTIENEN POLIETILENO COMPRENDEN (A) UN COMPUESTO TOCOFEROL Y (B) UN ANTIOXIDANTE SECUNDARIO QUE CONTIENE AZUFRE O FOSFORO EN UNA RELACION DE PESO DE ENTRE 1:1''4 A 1:5. FORMULACIONES ESTABILIZANTES RELACIONADAS ESTRECHAMENTE PARA MATERIALES PLASTICOS COMPRENDEN (A) ENTRE 10 A 50 POR CIENTO EN PESO DE UN (ALFA) COFEROL; (B) HASTA 50% EN PESO DE GLICOL DE POLIETILENO Y/O (C) HASTA 50% EN PESO DE CAPRATO MONOCAPRILATO DE GLICEROL; Y OPCIONALMENTE TAMBIEN (D) HASTA 20% EN PESO DE GLICERINA, SIENDO EL PESO TOTAL DE LOS DOS, TRES O CUATRO COMPONENTES DE 100. ESTAS MEZCLAS ESTABILIZANTES O FORMULACIONES PUEDEN OBTENERSE MEZCLANDO LOS COMPONENTES APROPIADOS EN LAS RELACIONES DE PESO APROPIADAS, POR LO QUE ESTA MEZCLA ES CONTINUA PARA LA FORMACION DE UNA SOLUCION CLARA EN EL CASO DE LA FORMULACION ESTABILIZANTE. EL INVENTO TAMBIEN SE REFIERE A ARTICULOS O MATERIALES PLASTICOS QUE INCORPORAN LA MEZCLA ESTABILIZANTE O FORMULACION ESTABILIZANTE, Y ALUSO DE DICHAS FORMULACIONES O MEZCLAS ESTABILIZANTES PARA ESTABILIZAR MATERIALES PLASTICOS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79174491A | 1991-11-12 | 1991-11-12 | |
| US07/955,000 US5308549A (en) | 1991-11-12 | 1992-10-09 | Stabilizers for thermo plastic materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2108067T3 true ES2108067T3 (es) | 1997-12-16 |
Family
ID=27121195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92118835T Expired - Lifetime ES2108067T3 (es) | 1991-11-12 | 1992-11-04 | Estabilizadores para materiales plasticos. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5308549A (es) |
| EP (1) | EP0542108B1 (es) |
| JP (1) | JP2984881B2 (es) |
| AT (1) | ATE158603T1 (es) |
| DE (1) | DE69222394T2 (es) |
| DK (1) | DK0542108T3 (es) |
| ES (1) | ES2108067T3 (es) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4306593A1 (de) * | 1993-03-03 | 1994-09-08 | Hoechst Ag | Stabilisierte Formmasse aus Polyethylen, ein Verfahren zur Herstellung und Verwendung |
| DE4312992A1 (de) * | 1993-04-21 | 1994-10-27 | Rhein Chemie Rheinau Gmbh | alpha-Tocopherol-Zubereitung |
| AU684911B2 (en) * | 1994-01-14 | 1998-01-08 | Exxon Chemical Patents Inc. | Gas fade resistant ultraviolet additive formulations for polyethylene |
| BE1008068A3 (nl) * | 1994-02-08 | 1996-01-09 | Dsm Nv | Gebruik van lage-dichtheidpolyetheen voor extrusiecoaten. |
| US5663223A (en) * | 1994-08-11 | 1997-09-02 | Zapata Technologies, Inc. | Flavor protectant closure liner compositions |
| DE19501053A1 (de) * | 1995-01-16 | 1996-07-18 | Basf Ag | Stabilisatorgemisch aus Chromanderivaten und inerten organischen Lösungsmitteln sowie dieses Stabilisatorgemisch enthaltende Mikrokapseln |
| US5670255A (en) * | 1995-01-23 | 1997-09-23 | Ppg Industries, Inc. | Antioxidant compositions for coating substrates, substrates coated with the same and methods for inhibiting the oxidation of such compositions applied to a substrate |
| US5594055A (en) * | 1995-02-22 | 1997-01-14 | Hoffmann-La Roche Inc. | Antioxidant system for polyolefins |
| DE19516283A1 (de) * | 1995-05-04 | 1996-11-07 | Basf Ag | Thermoplastische Formmasse |
| US5574082A (en) * | 1995-05-25 | 1996-11-12 | Quantum Chemical Company | Propylene polymer compositions having improved color and stabilizers therefor. |
| EP0781803A1 (en) * | 1995-12-29 | 1997-07-02 | General Electric Company | Stabilized thermoplastic polymer compositions |
| US5844027A (en) * | 1996-05-03 | 1998-12-01 | Ciba Specialty Chemicals Corporation | Stabilizer composition for thermoplastic materials |
| AU3910597A (en) * | 1996-08-06 | 1998-02-25 | Southwest Research Institute | Non-catalytically cured bisoxazoline-phenolic copolymers having improved thermo-oxidative stability |
| IT1289935B1 (it) * | 1997-02-20 | 1998-10-19 | Great Lakes Chemical Italia | Forma solida di uno stabilizzante per polimeri organici |
| US6156421A (en) * | 1997-04-02 | 2000-12-05 | Kimberly-Clark Worldwide, Inc. | Stretched-filled microporous films and methods of making the same |
| EP0995450B1 (de) * | 1998-10-21 | 2002-06-26 | Sulzer Orthopädie AG | UHMW-Polyethylen für Implantate |
| EP0995449A1 (de) | 1998-10-21 | 2000-04-26 | Sulzer Orthopädie AG | UHMW-Polyethylen für Implantate |
| CA2619502C (en) | 2005-08-18 | 2012-11-20 | Zimmer Gmbh | Ultra high molecular weight polyethylene articles and methods of forming ultra high molecular weight polyethylene articles |
| US8664290B2 (en) | 2007-04-10 | 2014-03-04 | Zimmer, Inc. | Antioxidant stabilized crosslinked ultra-high molecular weight polyethylene for medical device applications |
| ES2662102T3 (es) | 2007-04-10 | 2018-04-05 | Zimmer, Inc. | Un polietileno reticulado de peso molecular ultra alto estabilizado con antioxidantes para aplicaciones en dispositivos médicos |
| US8133436B2 (en) | 2008-08-05 | 2012-03-13 | Howmedica Osteonics Corp. | Polyethylene cross-linked with an anthocyanin |
| US8399535B2 (en) * | 2010-06-10 | 2013-03-19 | Zimmer, Inc. | Polymer [[s]] compositions including an antioxidant |
| KR102128986B1 (ko) | 2010-12-13 | 2020-07-02 | 사이텍 테크놀러지 코포레이션 | 가공 첨가제 및 회전 성형에서의 이의 용도 |
| US11267951B2 (en) | 2010-12-13 | 2022-03-08 | Cytec Technology Corp. | Stabilizer compositions containing substituted chroman compounds and methods of use |
| JP2016520149A (ja) * | 2013-05-24 | 2016-07-11 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系組成物 |
| EP3052562B1 (en) | 2013-10-01 | 2017-11-08 | Zimmer, Inc. | Polymer compositions comprising one or more protected antioxidants |
| EP3116941A1 (en) | 2014-03-12 | 2017-01-18 | Zimmer, Inc. | Melt-stabilized ultra high molecular weight polyethylene and method of making the same |
| CA2969751C (en) | 2014-12-03 | 2020-09-22 | Zimmer, Inc. | Antioxidant-infused ultra high molecular weight polyethylene |
| FR3100544A1 (fr) * | 2019-09-09 | 2021-03-12 | Polybridge | Colle thermofusible |
| US11597859B2 (en) * | 2020-01-24 | 2023-03-07 | Oatey Co. | Solvent cement formulations having extended shelf life |
| WO2023137140A1 (en) * | 2022-01-14 | 2023-07-20 | Dow Global Technologies Llc | Glycol compositions including tocopherols |
| KR20250169347A (ko) | 2023-04-04 | 2025-12-02 | 바스프 에스이 | 안정화제 혼합물을 함유하는 열가소성 중합체 조성물 |
| EP4750842A1 (en) * | 2023-07-24 | 2026-06-03 | SABIC Global Technologies B.V. | Composition for increased stability of recycled polyethylene |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2535058A (en) * | 1947-03-03 | 1950-12-26 | Universal Oil Prod Co | Stabilization process |
| US3282891A (en) * | 1959-02-16 | 1966-11-01 | Humble Oil & Refining Company | Polypropylene stabilized with a combination of glycerol and phenols |
| BE620180A (es) * | 1961-07-26 | |||
| BE655915A (es) * | 1963-11-18 | |||
| US3432300A (en) * | 1965-05-03 | 1969-03-11 | Eastman Kodak Co | 6-hydroxy chromans used as stabilizing agents in a color photographic element |
| US3880805A (en) * | 1970-06-17 | 1975-04-29 | Phillips Petroleum Co | Stabilized polyolefin compositions |
| DE2324922C3 (de) * | 1973-05-17 | 1978-03-02 | Ciba-Geigy Ag, Basel (Schweiz) | Polyolefinformmassen mit erhöhter Verarbeitungsstabilität und mit verbesserter Farbe |
| US4187212A (en) * | 1975-02-20 | 1980-02-05 | Ciba-Geigy Corporation | Stabilization systems from triarylphosphites and phenols |
| JPS6016456B2 (ja) * | 1976-01-26 | 1985-04-25 | 三井化学株式会社 | ポリオレフイン配合物 |
| JPS53114852A (en) * | 1977-03-18 | 1978-10-06 | Mitsui Petrochem Ind Ltd | Polyolefin composition |
| JPS53137244A (en) * | 1977-05-04 | 1978-11-30 | Riken Vitamin Co Ltd | Non-toxic stabilized composition of olefinic high polymer |
| JPS5420056A (en) * | 1977-07-18 | 1979-02-15 | Mitsui Petrochem Ind Ltd | Thermoplastic polymer composition |
| JPS5434352A (en) * | 1977-08-22 | 1979-03-13 | Riken Vitamin Co Ltd | Non-toxically stabilized olefinic polymer composition |
| JPS55747A (en) * | 1978-06-20 | 1980-01-07 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| DE3010505A1 (de) * | 1980-03-19 | 1981-10-01 | Basf Ag, 6700 Ludwigshafen | Chromanderivate, verfahren zu ihrer herstellung, ihre verwendung als stabilisatoren von organischen materialien sowie diese stabilisatoren enthaltende organische materialien |
| DE3103707A1 (de) * | 1981-02-04 | 1982-08-19 | Basf Ag, 6700 Ludwigshafen | Chromanderivate |
| US4532165A (en) * | 1983-05-09 | 1985-07-30 | Mitsui Petrochemical Industries Ltd. | Poly-1-butene resin composition |
| DE3504981A1 (de) * | 1985-02-14 | 1986-08-14 | Basf Ag, 6700 Ludwigshafen | Stabilisatoren |
| DE3634531A1 (de) * | 1986-10-10 | 1988-04-14 | Basf Ag | Stabilisatorgemische fuer kunststoffe |
| GB8803439D0 (en) * | 1988-02-15 | 1988-03-16 | Sandoz Ltd | Improvements in/relating to organic compounds |
| JPH02102241A (ja) * | 1988-10-11 | 1990-04-13 | Mitsui Toatsu Chem Inc | ポリプロピレン樹脂組成物 |
| WO1990007547A1 (de) * | 1988-12-23 | 1990-07-12 | Basf Aktiengesellschaft | Stabilisatorgemische für kunststoffe |
| EP0384472B1 (en) * | 1989-02-23 | 1997-09-10 | Fuji Photo Film Co., Ltd. | Resin composition and packaging material for photosensitive materials |
| CA2019884A1 (en) * | 1989-07-07 | 1991-01-07 | Yoshiharu Fukui | Food container |
| GB9123976D0 (en) * | 1991-11-12 | 1992-01-02 | Hoffmann La Roche | Stabilizers for thermoplastic materials |
-
1992
- 1992-10-09 US US07/955,000 patent/US5308549A/en not_active Expired - Lifetime
- 1992-11-04 AT AT92118835T patent/ATE158603T1/de not_active IP Right Cessation
- 1992-11-04 DK DK92118835.5T patent/DK0542108T3/da active
- 1992-11-04 DE DE69222394T patent/DE69222394T2/de not_active Expired - Fee Related
- 1992-11-04 ES ES92118835T patent/ES2108067T3/es not_active Expired - Lifetime
- 1992-11-04 EP EP92118835A patent/EP0542108B1/en not_active Expired - Lifetime
- 1992-11-10 JP JP4323735A patent/JP2984881B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2984881B2 (ja) | 1999-11-29 |
| JPH05320411A (ja) | 1993-12-03 |
| EP0542108B1 (en) | 1997-09-24 |
| DK0542108T3 (da) | 1998-05-04 |
| EP0542108A3 (en) | 1993-08-11 |
| ATE158603T1 (de) | 1997-10-15 |
| US5308549A (en) | 1994-05-03 |
| DE69222394D1 (de) | 1997-10-30 |
| DE69222394T2 (de) | 1998-01-29 |
| EP0542108A2 (en) | 1993-05-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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