ES2108233T3 - Catalizador de polimerizacion de olefinas y procedimiento de polimerizacion que lo utiliza. - Google Patents

Catalizador de polimerizacion de olefinas y procedimiento de polimerizacion que lo utiliza.

Info

Publication number
ES2108233T3
ES2108233T3 ES93309249T ES93309249T ES2108233T3 ES 2108233 T3 ES2108233 T3 ES 2108233T3 ES 93309249 T ES93309249 T ES 93309249T ES 93309249 T ES93309249 T ES 93309249T ES 2108233 T3 ES2108233 T3 ES 2108233T3
Authority
ES
Spain
Prior art keywords
copolymer
polymerization
ethylene
catalyst
alphaolefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93309249T
Other languages
English (en)
Inventor
Toshiyuki Tsutsui
Ken Yoshitsugu
Mamoru Takahashi
Akira Todo
Seiji Ohta
Hajime Inagaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Petrochemical Industries Ltd
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of ES2108233T3 publication Critical patent/ES2108233T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/653—Pretreating with metals or metal-containing compounds with metals of C08F4/64 or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

SE DESCRIBE UN CATALIZADOR DE POLIMERIZACION DE OLEFINA QUE COMPRENDE UN OXI-COMPUESTO DE ORGANOALUMINIO (A) Y DOS COMPUESTOS DE METAL DE TRANSICION CICLOPENTADIENILO (B-I) Y B-II). UN PROCESO PARA LA POLIMERIZACION EN PRESENCIA DE UN CATALIZADOR Y UN COPOLIMERO ETILENO/ALFA-OLEFINA OBTENIBLE AL COPOLIMERIZAR ETILENO CON UNA ALFAOLEFINA EN PRESENCIA DEL CATALIZADOR. EL COPOLIMERO ETILENO/ALFAOLEFINA OBTENIBLE AL POLIMERIZAR CON INJERTO EL COPOLIMERO MENCIONADO CON UN MONOMERO POLAR, Y COMPOSICION QUE COMPRENDE LA POLIOLEFINA Y COPOLIMERO INJERTO MODIFICADO. EL COPOLIMERO PRODUCIDO ES EXCELENTE EN MOLDABILIDAD Y TIENE ALTA TENSION DE FUSION Y ALTA FLUIDEZ. DE EL SE PUEDE PRODUCIR UNA CAPA TIENE ALTA TRANSPARENCIA Y ALTA RESISTENCIA MECANICA.
ES93309249T 1992-11-19 1993-11-19 Catalizador de polimerizacion de olefinas y procedimiento de polimerizacion que lo utiliza. Expired - Lifetime ES2108233T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP31063192 1992-11-19
JP31063092 1992-11-19
JP31062992 1992-11-19
JP31061492 1992-11-19

Publications (1)

Publication Number Publication Date
ES2108233T3 true ES2108233T3 (es) 1997-12-16

Family

ID=27480027

Family Applications (2)

Application Number Title Priority Date Filing Date
ES00127819T Expired - Lifetime ES2336638T3 (es) 1992-11-19 1993-11-19 Copolimero de etileno/alfa olefina.
ES93309249T Expired - Lifetime ES2108233T3 (es) 1992-11-19 1993-11-19 Catalizador de polimerizacion de olefinas y procedimiento de polimerizacion que lo utiliza.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES00127819T Expired - Lifetime ES2336638T3 (es) 1992-11-19 1993-11-19 Copolimero de etileno/alfa olefina.

Country Status (6)

Country Link
US (1) US5703180A (es)
EP (3) EP0598628B1 (es)
KR (1) KR0142071B1 (es)
CA (1) CA2103379C (es)
DE (3) DE69314137T2 (es)
ES (2) ES2336638T3 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6001941A (en) 1992-11-19 1999-12-14 Mitsui Chemicals, Inc. Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin
CA2103379C (en) * 1992-11-19 2000-05-23 Toshiyuki Tsutsui Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition
NO315857B1 (no) * 1995-03-28 2003-11-03 Japan Polyolefines Co Ltd Etylen-<alfa>-olefin-kopolymer, blanding, film, laminert material, elektrisk isolerende material og strömkabel inneholdende denne
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
US6166153A (en) * 1995-07-18 2000-12-26 Fina Technology, Inc. Process for the syndiotactic propagation of olefins
WO1997021745A1 (en) * 1995-12-08 1997-06-19 Kaneka Corporation Grafted polyolefin resin and thermoplastic resin composition containing the same
WO1998005706A1 (en) * 1996-08-02 1998-02-12 Cryovac, Inc. Film having grafted fatty amide in outerfilm layer
DE69728623T2 (de) 1996-10-31 2005-04-14 Mitsubishi Chemical Corp. Film, hergestellt aus einem Ethylen-Alhaolefin-Copolymer
US6153551A (en) * 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6455638B2 (en) 2000-05-11 2002-09-24 Dupont Dow Elastomers L.L.C. Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
MY137183A (en) * 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
WO2003002616A1 (en) * 2001-06-29 2003-01-09 Japan Polychem Corporation Catalyst for olefin polymerization and method for polymerization of olefin
RU2326904C2 (ru) * 2002-06-04 2008-06-20 Юнион Карбайд Кемикалз Энд Пластикс Текнолоджи Корпорейшн Полимерные композиции и способ изготовления труб
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US8748361B2 (en) 2005-07-19 2014-06-10 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
DE202013009855U1 (de) 2013-12-06 2015-03-09 Hewitech Gmbh & Co. Kg Einbaueinrichtung für eine Vorrichtung zur Behandlung eines strömenden Fluids
EP2881694B1 (de) 2013-12-06 2019-02-20 Hewitech GmbH & Co. KG Einbaueinrichtung für eine Vorrichtung zur Behandlung eines strömenden Fluids
JP7359018B2 (ja) * 2019-02-28 2023-10-11 日本ポリエチレン株式会社 樹脂系粘土

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53145856A (en) * 1977-05-26 1978-12-19 Furukawa Electric Co Ltd:The Preparation of polyethylene molding articles
JPS58168642A (ja) * 1982-03-30 1983-10-05 Mitsui Petrochem Ind Ltd 熱可塑性樹脂組成物
MX167872B (es) * 1983-06-06 1993-04-20 Exxon Research Engineering Co Proceso y catalizador para producir poliolefinas dmezclas del reactor
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
JPH0657444B2 (ja) * 1986-01-07 1994-08-03 三井石油化学工業株式会社 積層体
DE3639564A1 (de) * 1986-11-20 1988-06-01 Basf Ag Peroxidfreie pfropfung von homo- bzw. copolymerisaten des ethylens mit dichten gleich oder groesser als 0,930 g/cm(pfeil hoch)3(pfeil hoch) und verwendung der pfropfcopolymeren zur herstellung in ionomeren oder haftvermittlern
JPH07103283B2 (ja) * 1987-06-30 1995-11-08 三井石油化学工業株式会社 接着用変性ポリオレフィン組成物
DE68928696T2 (de) * 1988-12-26 1998-12-03 Mitsui Chemicals, Inc., Tokio/Tokyo Olefin-kopolymer und verfahren zur herstellung
JP2765094B2 (ja) * 1989-09-08 1998-06-11 三井化学株式会社 環状オレフィン系熱可塑性樹脂組成物
MY107639A (en) * 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
JPH06104762B2 (ja) * 1990-06-08 1994-12-21 昭和電工株式会社 ポリエチレン系樹脂組成物
JP2614352B2 (ja) * 1990-08-10 1997-05-28 昭和電工株式会社 ポリエチレン系樹脂組成物
JP2972324B2 (ja) * 1990-11-26 1999-11-08 三井化学株式会社 直鎖状低密度エチレン・α―オレフィン共重合体からなるフィルムおよびその製造方法
DE69213069T2 (de) * 1991-04-09 1997-04-10 Nippon Petrochemicals Co Ltd Matter Film und dessen Herstellungsverfahren
EP0516458B2 (en) * 1991-05-31 2007-12-19 Mitsui Chemicals, Inc. Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5459217A (en) * 1993-04-09 1995-10-17 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin copolymer
EP0641362B1 (en) * 1992-04-20 1998-11-11 Exxon Chemical Patents Inc. Ethylene/branched olefin copolymers
CA2103379C (en) * 1992-11-19 2000-05-23 Toshiyuki Tsutsui Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition
US5464905A (en) * 1992-11-19 1995-11-07 Mitsui Petrochemical Industries, Ltd. Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
ES2141833T3 (es) * 1993-08-06 2000-04-01 Exxon Chemical Patents Inc Catalizadores de polimerizacion, su produccion y uso.

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EP0749989B1 (en) 2001-07-11
EP0598628B1 (en) 1997-09-24
EP0598628A2 (en) 1994-05-25
KR0142071B1 (ko) 1998-07-01
DE69330437D1 (de) 2001-08-16
EP1114831B1 (en) 2009-12-23
ES2336638T3 (es) 2010-04-15
DE69314137D1 (de) 1997-10-30
CA2103379A1 (en) 1994-05-20
EP0749989A2 (en) 1996-12-27
EP1114831A3 (en) 2004-08-04
DE69334307D1 (de) 2010-02-04
EP0749989A3 (en) 1997-06-04
DE69330437T2 (de) 2001-10-25
EP0598628A3 (en) 1995-03-15
US5703180A (en) 1997-12-30
KR940011490A (ko) 1994-06-21
DE69314137T2 (de) 1998-02-26
CA2103379C (en) 2000-05-23
EP1114831A2 (en) 2001-07-11

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