ES2108431T3 - Polimeros en estrella preparados a partir de macromonomeros obtenidos mediante un procedimiento de transferencia de cadena con cobalto. - Google Patents
Polimeros en estrella preparados a partir de macromonomeros obtenidos mediante un procedimiento de transferencia de cadena con cobalto.Info
- Publication number
- ES2108431T3 ES2108431T3 ES94907833T ES94907833T ES2108431T3 ES 2108431 T3 ES2108431 T3 ES 2108431T3 ES 94907833 T ES94907833 T ES 94907833T ES 94907833 T ES94907833 T ES 94907833T ES 2108431 T3 ES2108431 T3 ES 2108431T3
- Authority
- ES
- Spain
- Prior art keywords
- star polymer
- macromonomer
- nucleus
- cobalt
- chain transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 2
- 229910017052 cobalt Inorganic materials 0.000 title 1
- 239000010941 cobalt Substances 0.000 title 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title 1
- 150000003254 radicals Chemical class 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/04—Polymers provided for in subclasses C08C or C08F
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
UNA DISPERSION POLIMERICA DE UN POLIMERO DE ESTRELLA DISPERSO EN UN LIQUIDO ORGANICO; EN EL CUAL EL POLIMERO DE ESTRELLA TIENE UN NUCLEO RETICULADO QUE TIENE UNIDO AL MISMO AL MENOS 3 BRAZOS DE MACROMONOMERO: DONDE (1) EL NUCLEO ESTA FORMADO DE MONOMEROS QUE TIENEN AL MENOS 2 ENLACES DOBLES ETILENICAMENTE INSATURADOS QUE ESTAN RETICULADOS ENTRE SI Y EL NUCLEO TIENE AL MENOS 3 SITUACIONES POLIMERIZABLES DE RADICALES LIBRES CADA UNA DE LAS CUALES SE HACE REACCIONAR CON EL MACROMONOMERO; Y (2) EL MACROMONOMERO QUE FORMA LOS BRAZOS DEL POLIMERO DE ESTRELLA ESTA FORMADO DE MONOMEROS ETILENICAMENTE INSATURADOS QUE HAN SIDO POLIMERIZADOS POR LA POLIMERIZACION DE RADICALES LIBRES EN PRESENCIA DE UN INICIADOR DE POLIMERIZACION DE RADICALES LIBRES Y UN AGENTE DE TRANSFERENCIA DE CADENA CATALITICA QUE CONTIENE CO{SUP,+2} PARA PROVEER AL MACROMONOMERO DE UN GRUPO TERMINAL ETILENICAMENTE INSATURADO QUE ES POLIMERIZADO CON LA SITUACION POLIMERIZABLE DE RADICALES LIBRES SOBRE EL NUCLEO PARA FORMAR EL POLIMERO DE ESTRELLA. EL PROCESO PARA FABRICAR EL POLIMERO DE ESTRELLA Y LAS COMPOSICIONES DE REVESTIMIENTO QUE UTILIZA EL POLIMERO DE ESTRELLA SON TAMBIEN PARTE DE ESTA INVENCION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1994/000607 WO1995021205A1 (en) | 1992-12-30 | 1994-02-03 | Star polymers made from macromonomers made by cobalt chain transfer process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2108431T3 true ES2108431T3 (es) | 1997-12-16 |
Family
ID=34572334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94907833T Expired - Lifetime ES2108431T3 (es) | 1994-02-03 | 1994-02-03 | Polimeros en estrella preparados a partir de macromonomeros obtenidos mediante un procedimiento de transferencia de cadena con cobalto. |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5310807A (es) |
| EP (1) | EP0742802B1 (es) |
| JP (1) | JPH09509197A (es) |
| CA (1) | CA2181234C (es) |
| DE (1) | DE69406466T2 (es) |
| ES (1) | ES2108431T3 (es) |
| WO (1) | WO1995021205A1 (es) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7575653B2 (en) * | 1993-04-15 | 2009-08-18 | 3M Innovative Properties Company | Melt-flowable materials and method of sealing surfaces |
| US6485589B1 (en) | 1993-04-15 | 2002-11-26 | 3M Innovative Properties Company | Melt-flowable materials and method of sealing surfaces |
| US5552491A (en) * | 1995-01-27 | 1996-09-03 | Ethyl Additives Corporation | Star-branched acrylate and methacrylate polymers |
| US5618850A (en) * | 1995-03-09 | 1997-04-08 | Focal, Inc. | Hydroxy-acid cosmetics |
| US6624261B1 (en) * | 1997-02-18 | 2003-09-23 | E. I. Du Pont Nemours And Company | Catalytic polymerization process |
| JP3651905B2 (ja) * | 1996-02-23 | 2005-05-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 分枝ポリマー合成 |
| US6294708B1 (en) | 1998-02-11 | 2001-09-25 | E. I. Du Pont De Nemours And Company | Alpha-methylstyrene dimer derivatives |
| NZ505056A (en) * | 1998-03-12 | 2003-05-30 | Lucite Int Uk Ltd | A branched polymer composition containing a monofunctional monomer, a polyfunctional monomer and a chain transfer agent |
| US6355718B1 (en) * | 1998-07-10 | 2002-03-12 | E. I. Du Pont De Nemours And Company | Microgels and process for their preparation |
| JP3984381B2 (ja) * | 1998-12-08 | 2007-10-03 | 株式会社カネカ | 星型重合体の製造方法 |
| FR2791989A1 (fr) | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| FR2791986A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| FR2791987A1 (fr) | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| US6946525B2 (en) | 1999-04-06 | 2005-09-20 | L'oreal S.A. | Composition comprising polymers having a star structure, the polymers, and their use |
| FR2791990A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition cosmetique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation notamment en capillaire |
| FR2791988A1 (fr) * | 1999-04-06 | 2000-10-13 | Oreal | Composition notamment cosmetique ou pharmaceutique comprenant des polymeres ayant une structure en etoiles, lesdits polymeres et leur utilisation |
| DE10015533A1 (de) * | 1999-11-30 | 2001-06-28 | Rohmax Additives Gmbh | Blockcopolymere sowie Verfahren zur Hestellung und Verwendung |
| DE10035119A1 (de) * | 2000-07-19 | 2002-01-31 | Basf Ag | Teilverzweigte Polymere |
| US6559327B2 (en) | 2001-01-03 | 2003-05-06 | E. I. Du Pont De Nemours And Company | Alkyl cobalt (III) dioximates and process for forming the same |
| US6632880B2 (en) * | 2001-07-09 | 2003-10-14 | E. I. Du Pont De Nemours And Company | Coating compositions containing isocyanate-functional non-aqueous dispersed polymers |
| US7022792B2 (en) * | 2004-03-16 | 2006-04-04 | E. I. Dupont De Nemours And Company | Initiation of polymerization by hydrogen atom donation |
| US7402624B2 (en) | 2004-11-08 | 2008-07-22 | E.I. Du Pont De Nemours & Company | Graft copolymers with segmented arms and their preparation and use |
| CN101273068B (zh) * | 2005-10-07 | 2010-06-16 | 纳幕尔杜邦公司 | 支化丙烯酸聚合物的高温聚合制造法、己内酯改性的支化丙烯酸聚合物、及其用途 |
| US20070142591A1 (en) * | 2005-10-07 | 2007-06-21 | Johnson Jeffery W | High temperature polymerization process for making caprolactone-modified branched acrylic polymers |
| EP1964903B1 (en) | 2005-12-19 | 2017-03-22 | Kureha Corporation | Heat-expandable microspheres, process for production of the same and uses thereof |
| US20090221757A1 (en) * | 2008-02-29 | 2009-09-03 | Ppg Industries Ohio, Inc. | Polymers containing an oligomeric macromonomer |
| US8822610B2 (en) | 2008-12-22 | 2014-09-02 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| US8815971B2 (en) | 2008-12-22 | 2014-08-26 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
| US8962764B2 (en) | 2009-03-27 | 2015-02-24 | Carnegie Mellon University | Preparation of functional star macromolecules |
| US9783628B2 (en) | 2009-04-23 | 2017-10-10 | ATRP Solutions, Inc. | Dual-mechanism thickening agents for hydraulic fracturing fluids |
| US8173750B2 (en) | 2009-04-23 | 2012-05-08 | ATRP Solutions, Inc. | Star macromolecules for personal and home care |
| WO2010123574A1 (en) | 2009-04-23 | 2010-10-28 | Atrp Solutions Inc | Star macromolecules for personal and home care |
| US9587064B2 (en) * | 2010-12-08 | 2017-03-07 | ATRP Solutions, Inc. | Salt-tolerant star macromolecules |
| US9644042B2 (en) | 2010-12-17 | 2017-05-09 | Carnegie Mellon University | Electrochemically mediated atom transfer radical polymerization |
| US20140275420A1 (en) | 2011-08-22 | 2014-09-18 | Carnegie Mellon University | Atom transfer radical polymerization under biologically compatible conditions |
| US9533297B2 (en) | 2012-02-23 | 2017-01-03 | Carnegie Mellon University | Ligands designed to provide highly active catalyst complexes |
| CN105189643B (zh) | 2012-08-30 | 2019-01-15 | 派诺聚合物技术公司 | 用于水力压裂液的双重机制增稠剂 |
| EP2951220B1 (en) | 2013-02-04 | 2020-11-25 | Pilot Polymer Technologies, Inc. | Salt-tolerant star macromolecules |
| CN107075015B (zh) | 2014-07-03 | 2019-08-23 | 派诺聚合物技术公司 | 表面活性剂-相容性星形大分子 |
| US9982070B2 (en) | 2015-01-12 | 2018-05-29 | Carnegie Mellon University | Aqueous ATRP in the presence of an activator regenerator |
| TW201730284A (zh) * | 2015-12-07 | 2017-09-01 | Mitsubishi Chem Corp | 非溶解性防污塗料用聚合物、樹脂組成物、防污塗料、塗膜、水中摩擦降低方法及非溶解性防污塗料用聚合物的製造方法 |
| WO2018020732A1 (ja) * | 2016-07-27 | 2018-02-01 | 三菱ケミカル株式会社 | 樹脂組成物及びそれを用いた立体造形物 |
| WO2018132582A1 (en) | 2017-01-12 | 2018-07-19 | Carnegie Mellon University | Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes |
| JP2019099728A (ja) * | 2017-12-06 | 2019-06-24 | 三菱ケミカル株式会社 | 共重合体、レベリング剤、塗料組成物及び塗装物品 |
| EP4029910A1 (en) | 2021-01-19 | 2022-07-20 | Bridgestone Europe NV/SA | Self-healing rubber comprising a poly(methacrylic acid) oligomer |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4737550A (en) * | 1983-01-07 | 1988-04-12 | The Dow Chemical Company | Bridged dense star polymers |
| US4568737A (en) * | 1983-01-07 | 1986-02-04 | The Dow Chemical Company | Dense star polymers and dendrimers |
| US4558120A (en) * | 1983-01-07 | 1985-12-10 | The Dow Chemical Company | Dense star polymer |
| KR910002473B1 (ko) * | 1984-07-05 | 1991-04-23 | 이 아이 듀우판 디 네모아 앤드 캄파니 | 아크릴 별모양 중합체 |
| DE3574260D1 (en) * | 1984-07-05 | 1989-12-21 | Du Pont | Acrylic star polymers |
| US4794144A (en) * | 1984-07-05 | 1988-12-27 | E. I. Du Pont De Nemours And Company | Acrylic star polymers containing multi-functional monomers in the core, made by group transfer polymerization |
| ZA855083B (en) * | 1984-07-05 | 1987-03-25 | Du Pont | Acrylic star polymers |
| US4587329A (en) * | 1984-08-17 | 1986-05-06 | The Dow Chemical Company | Dense star polymers having two dimensional molecular diameter |
| US5162426A (en) * | 1990-12-17 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Coatings comprising dispersed polymers with silane crosslinking |
| US5231131A (en) * | 1991-12-24 | 1993-07-27 | E. I. Du Pont De Nemours And Company | Aqueous graft copolymer pigment dispersants |
-
1992
- 1992-12-30 US US07/998,350 patent/US5310807A/en not_active Expired - Lifetime
-
1993
- 1993-12-22 US US08/172,293 patent/US5362813A/en not_active Expired - Lifetime
-
1994
- 1994-02-03 ES ES94907833T patent/ES2108431T3/es not_active Expired - Lifetime
- 1994-02-03 DE DE69406466T patent/DE69406466T2/de not_active Expired - Fee Related
- 1994-02-03 JP JP7520560A patent/JPH09509197A/ja active Pending
- 1994-02-03 CA CA002181234A patent/CA2181234C/en not_active Expired - Fee Related
- 1994-02-03 EP EP94907833A patent/EP0742802B1/en not_active Expired - Lifetime
- 1994-02-03 WO PCT/US1994/000607 patent/WO1995021205A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0742802B1 (en) | 1997-10-22 |
| EP0742802A1 (en) | 1996-11-20 |
| US5310807A (en) | 1994-05-10 |
| CA2181234A1 (en) | 1995-08-10 |
| DE69406466T2 (de) | 1998-05-07 |
| JPH09509197A (ja) | 1997-09-16 |
| US5362813A (en) | 1994-11-08 |
| WO1995021205A1 (en) | 1995-08-10 |
| DE69406466D1 (de) | 1997-11-27 |
| CA2181234C (en) | 2005-05-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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