ES2128786T3 - Polimeros ramificados de cadena larga y su produccion. - Google Patents
Polimeros ramificados de cadena larga y su produccion.Info
- Publication number
- ES2128786T3 ES2128786T3 ES95938287T ES95938287T ES2128786T3 ES 2128786 T3 ES2128786 T3 ES 2128786T3 ES 95938287 T ES95938287 T ES 95938287T ES 95938287 T ES95938287 T ES 95938287T ES 2128786 T3 ES2128786 T3 ES 2128786T3
- Authority
- ES
- Spain
- Prior art keywords
- matta
- ziegler
- polymerizable
- approx
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 4
- 229920001577 copolymer Polymers 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical class [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 abstract 1
- 230000004913 activation Effects 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
SE PROPORCIONAN COPOLIMEROS, Y PROCEDIMIENTOS DE FABRICACION DE LOS MISMOS, QUE DERIVAN DE MONOMEROS, LOS CUALES COMPRENDEN: A) UNA MONO-OLEFINA, QUE TIENE UN SOLO ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; B) UN SEGUNDO MONOMERO, QUE TIENE AL MENOS UN ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; C) UN TERCER MONOMERO, QUE TIENE AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA, SIENDO DICHO MONOMERO: I) DE CADENA LINEAL Y DE MENOS DE SEIS O AL MENOS SIETE ATOMOS DE CARBONO; II) DE CADENA NO LINEAL; O III) UNA COMBINACION DE LOS MISMOS; COMPRENDIENDO DICHO COPOLIMERO: D) AL MENOS APROX. UN ENLACE INSATURADO CARBONO-CARBONO POR MOLECULA MEDIA EN NUMERO; E) UNA ENERGIA VISCOSA DE ACTIVACION (E{SUB,A}), AL MENOS 1 KCAL/MOL MAYOR, QUE LA DE UN COPOLIMERO CON UN ESQUELETO LINEAL, DERIVADO DE LOS MISMOS MONOMEROS, PERO EXCLUYENDO AQUELLOS QUE POSEEN AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA; F) NIVEL DE CRISTALINIDAD, APROX. DEL 10 AL 50%; Y G) M{SUB,Z}/M{SUB,W} AL MENOS APROX. DE 1''7. DICHOSCOPOLIMEROS, MUESTRAN UNA CAPACIDAD MEJORADA DE TRATAMIENTO EN ESTADO FUNDIDO, Y OTRAS PROPIEDADES, DURANTE LA FABRICACION DEL PRODUCTO FINAL.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/328,187 US6300451B1 (en) | 1994-10-24 | 1994-10-24 | Long-chain branched polymers and their production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2128786T3 true ES2128786T3 (es) | 1999-05-16 |
Family
ID=23279893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95938287T Expired - Lifetime ES2128786T3 (es) | 1994-10-24 | 1995-10-24 | Polimeros ramificados de cadena larga y su produccion. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6300451B1 (es) |
| EP (1) | EP0788521B1 (es) |
| JP (1) | JPH10512600A (es) |
| KR (1) | KR100358857B1 (es) |
| CN (2) | CN1091774C (es) |
| AU (1) | AU694812B2 (es) |
| BR (1) | BR9509427A (es) |
| CA (1) | CA2202402C (es) |
| DE (1) | DE69506906T2 (es) |
| ES (1) | ES2128786T3 (es) |
| RU (1) | RU2165437C2 (es) |
| TW (1) | TW422857B (es) |
| WO (1) | WO1996012744A1 (es) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5792534A (en) * | 1994-10-21 | 1998-08-11 | The Dow Chemical Company | Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus |
| BR9609483A (pt) * | 1995-06-29 | 1999-03-02 | Dsm Nv | Copolímero elastomérico |
| CA2190678A1 (en) | 1995-11-22 | 1997-05-23 | Robert Joseph Noel Bernier | Process for preparing elastomeric compounds from granular elastomers and polymers and articles manufactured therefrom |
| US5814714A (en) * | 1995-11-30 | 1998-09-29 | The Dow Chemical Company | Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof |
| EP0784062A3 (en) * | 1995-12-15 | 1998-04-22 | Union Carbide Chemicals & Plastics Technology Corporation | Process for production of long-chain branched polyolefins |
| BR9810350B1 (pt) * | 1997-06-27 | 2012-02-22 | processo para a preparação de copolìmeros elastoméricos e copolìmeros elastoméricos | |
| NL1006421C2 (nl) * | 1997-06-27 | 1998-12-29 | Dsm Nv | Elastomeer copolymeer. |
| WO1999041294A1 (en) * | 1998-02-17 | 1999-08-19 | Exxon Chemical Patents Inc. | Ethylene copolymerization process |
| US6294631B1 (en) | 1998-12-15 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Hyperbranched polymers by coordination polymerization |
| US6281316B1 (en) | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
| BR0011524A (pt) * | 1999-05-14 | 2002-03-26 | Dupont Dow Elastomers Llc | Composição de interpolìmero, processo para a preparação de uma composição de interpolìmero, artigo de manufatura e artigo de múltiplas camadas |
| US7041617B2 (en) * | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| US6509431B1 (en) * | 2000-01-18 | 2003-01-21 | Exxonmobil Oil Corporation | Terpolymers |
| JP4945080B2 (ja) * | 2002-06-19 | 2012-06-06 | エクソンモービル・ケミカル・パテンツ・インク | エチレン、より高級なα−オレフィンコモノマー及びジエン、特にビニルノルボルネン、並びにそのような方法を用いて製造されるポリマー |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
| AU2003291627A1 (en) * | 2002-09-20 | 2004-04-08 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| EP1586591A4 (en) * | 2003-01-23 | 2006-06-14 | Mitsui Chemicals Inc | PROCESS FOR PRODUCING NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER AND NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER THUS OBTAINED |
| US7906586B2 (en) * | 2003-12-09 | 2011-03-15 | Dow Global Technologies Llc | Thermoplastic olefinic compositions |
| US20050209403A1 (en) * | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
| US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| DE602005010255D1 (de) * | 2004-07-08 | 2008-11-20 | Exxonmobil Chem Patents Inc | Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung |
| US7741420B2 (en) | 2004-07-14 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
| US8101697B2 (en) * | 2005-02-01 | 2012-01-24 | Bridgestone Corporation | Multi-functionalized high-trans elastomeric polymers |
| DE602006005645D1 (de) * | 2005-05-12 | 2009-04-23 | Dow Global Technologies Inc | Thermogeformte und extrudierte folie mit reduziertem glanz |
| ES2370416T5 (es) * | 2005-05-20 | 2016-04-25 | Bridgestone Corporation | Método para preparar polímeros de bajo peso molecular |
| US8288480B2 (en) | 2005-06-22 | 2012-10-16 | Exxonmobil Chemical Patents Inc. | In-reactor polymer blends |
| JP5225846B2 (ja) * | 2005-09-12 | 2013-07-03 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α−オレフィン組成物、該組成物から製造された物品およびその製造方法 |
| US8557938B2 (en) | 2005-11-10 | 2013-10-15 | Arkema Inc. | Branched fluoropolymers |
| US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7576163B2 (en) * | 2006-03-31 | 2009-08-18 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing polymers with low levels of long chain branching |
| CA2668397A1 (en) | 2006-11-01 | 2008-05-15 | Dow Global Technologies Inc. | Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use |
| US8242237B2 (en) * | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| US8143352B2 (en) * | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| CN104927184B (zh) * | 2006-12-21 | 2019-06-14 | 陶氏环球技术有限责任公司 | 填充的热塑性聚烯烃组合物、制备其的方法和由其制得的制品 |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
| KR20080101791A (ko) * | 2007-05-16 | 2008-11-21 | 주식회사 엘지화학 | 장쇄분지를 포함하는 에틸렌-알파올레핀 공중합체 |
| JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
| JP5340292B2 (ja) * | 2007-09-07 | 2013-11-13 | ダウ グローバル テクノロジーズ エルエルシー | 良好な低温延性を有する充填材入りtpo組成物 |
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| CN101855249B (zh) * | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
| EP2209625B1 (en) | 2007-11-14 | 2019-03-20 | Dow Global Technologies LLC | Multi-layered article |
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| EP2231779B1 (en) * | 2007-12-20 | 2012-06-06 | ExxonMobil Research and Engineering Company | In-line process to produce pellet-stable polyolefins |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US8524793B2 (en) | 2008-06-18 | 2013-09-03 | Dow Global Technologies, Llc | Interpolymer compositions of ethylene, α-olefin and nonconjugated polyene, methods of making the same, and foam and articles prepared from the same |
| CN102458385A (zh) * | 2009-05-08 | 2012-05-16 | 3M创新有限公司 | 口腔护理方法和套件 |
| KR101741857B1 (ko) | 2009-07-15 | 2017-05-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품 |
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| US9321911B2 (en) | 2011-09-23 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for cast film |
| US9580533B2 (en) * | 2011-09-23 | 2017-02-28 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions |
| US9340664B2 (en) | 2011-09-23 | 2016-05-17 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for blown film |
| US20160272798A1 (en) * | 2011-09-23 | 2016-09-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
| US8629217B2 (en) | 2011-11-22 | 2014-01-14 | Exxonmobil Chemical Patents Inc. | Modified polyethylene blown film compositions having excellent bubble stability |
| US10836853B2 (en) | 2012-09-20 | 2020-11-17 | Exxonmobil Chemical Patents Inc. | Crack-resistant polyethylene compositions |
| US10822479B2 (en) * | 2012-09-20 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Foamed polyethylene compositions |
| US8901236B2 (en) * | 2012-10-09 | 2014-12-02 | Lion Copolymer Geismar, Llc | Process for creating an ethylene elastomer |
| US9139727B2 (en) | 2012-10-09 | 2015-09-22 | Lion Copolymer Geismar, Llc | Low damping high strength polymer with long chain branching for use in anti-vibration applications |
| US9139726B2 (en) | 2012-10-09 | 2015-09-22 | Lion Copolymer Geismar, Llc | Process for making an ethylene elastomer with long chain branching for use in anti-vibration applications |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| EP2928958B1 (en) | 2012-12-05 | 2019-08-21 | ExxonMobil Chemical Patents Inc. | Hdpe modified polyethylene blown film compositions having excellent bubble stability |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| CN103304743B (zh) * | 2013-06-24 | 2015-04-29 | 苏州新区佳合塑胶有限公司 | 一种含有4-甲基-1-戊烯的阻燃耐热塑胶 |
| CN103304742B (zh) * | 2013-06-24 | 2015-04-15 | 苏州新区佳合塑胶有限公司 | 一种含有1,3-环己二烯的阻燃耐热塑胶 |
| JP6439280B2 (ja) * | 2013-08-09 | 2018-12-19 | 三菱ケミカル株式会社 | 熱可塑性エラストマー組成物の製造方法 |
| WO2015126797A1 (en) | 2014-02-24 | 2015-08-27 | Dow Global Technologies Llc | Thermoplastic polyolefin with reduced gloss for non-carpeted flooring |
| US10125247B2 (en) | 2014-05-29 | 2018-11-13 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
| WO2015183577A1 (en) | 2014-05-29 | 2015-12-03 | Exxonmobil Chemical Patents Inc. | Cyclic-diene additives in polyethylene films and enhanced film orientation balance in production thereof |
| EP3149073B1 (en) | 2014-05-29 | 2020-12-02 | ExxonMobil Chemical Patents Inc. | Polyethylene films and production of such films |
| EP3440118A1 (en) | 2016-05-20 | 2019-02-13 | Chevron Phillips Chemical Company LP | Low pressure process for preparing low-density polyethylene |
| KR20220152582A (ko) | 2016-08-12 | 2022-11-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 탄소 섬유 및 열가소성 폴리올레핀 탄성중합체를 포함하는 프로필렌계 조성물 |
| US9574034B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
| US9574033B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for continuously making high molecular weight tetrapolymer for use in anti-vibration applications |
| US9574035B1 (en) | 2016-08-12 | 2017-02-21 | Lion Copolymer Geismar, Llc | Process for making high molecular weight tetrapolymer and articles produced therefrom |
| WO2018182943A1 (en) | 2017-03-29 | 2018-10-04 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions |
| US10550252B2 (en) | 2017-04-20 | 2020-02-04 | Chevron Phillips Chemical Company Lp | Bimodal PE resins with improved melt strength |
| WO2019173605A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy |
| US11041035B2 (en) | 2018-03-08 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Process to produce long-chain branched polyolefins using dienes |
| WO2020069370A1 (en) * | 2018-09-28 | 2020-04-02 | Dow Global Technologies Llc | Tetra-functional long-chain branched ethylene-based polymers |
| US10961331B2 (en) | 2018-12-19 | 2021-03-30 | Chevron Phillips Chemical Company Lp | Ethylene homopolymers with a reverse short chain branch distribution |
| CN113661188B (zh) * | 2019-03-29 | 2023-12-29 | 陶氏环球技术有限责任公司 | 聚合三官能长链支化烯烃的方法 |
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| EP3947484B1 (en) * | 2019-03-29 | 2025-04-23 | Dow Global Technologies LLC | Tri-functional long-chain branched polyolefin |
| EP3990506A1 (en) | 2019-06-26 | 2022-05-04 | Dow Global Technologies LLC | Epdm blends with long chain branching |
| KR20240108533A (ko) | 2021-11-30 | 2024-07-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 연질 열가소성 올레핀 및 이로부터 제조된 제품 |
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|---|---|---|---|---|
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-
1994
- 1994-10-24 US US08/328,187 patent/US6300451B1/en not_active Expired - Fee Related
-
1995
- 1995-10-24 CN CN95195850A patent/CN1091774C/zh not_active Expired - Fee Related
- 1995-10-24 EP EP95938287A patent/EP0788521B1/en not_active Revoked
- 1995-10-24 JP JP8514092A patent/JPH10512600A/ja active Pending
- 1995-10-24 BR BR9509427A patent/BR9509427A/pt not_active IP Right Cessation
- 1995-10-24 WO PCT/US1995/013643 patent/WO1996012744A1/en not_active Ceased
- 1995-10-24 RU RU97108600/04A patent/RU2165437C2/ru not_active IP Right Cessation
- 1995-10-24 CA CA002202402A patent/CA2202402C/en not_active Expired - Fee Related
- 1995-10-24 AU AU38970/95A patent/AU694812B2/en not_active Ceased
- 1995-10-24 ES ES95938287T patent/ES2128786T3/es not_active Expired - Lifetime
- 1995-10-24 KR KR1019970702672A patent/KR100358857B1/ko not_active Expired - Fee Related
- 1995-10-24 DE DE69506906T patent/DE69506906T2/de not_active Revoked
-
1996
- 1996-04-26 TW TW085105107A patent/TW422857B/zh not_active IP Right Cessation
-
2001
- 2001-09-06 CN CNB011328118A patent/CN1204157C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1204157C (zh) | 2005-06-01 |
| DE69506906D1 (de) | 1999-02-04 |
| US6300451B1 (en) | 2001-10-09 |
| CN1341672A (zh) | 2002-03-27 |
| WO1996012744A1 (en) | 1996-05-02 |
| KR100358857B1 (ko) | 2003-02-07 |
| CA2202402C (en) | 2006-10-17 |
| CA2202402A1 (en) | 1996-05-02 |
| BR9509427A (pt) | 1998-01-06 |
| EP0788521B1 (en) | 1998-12-23 |
| AU694812B2 (en) | 1998-07-30 |
| DE69506906T2 (de) | 1999-05-27 |
| JPH10512600A (ja) | 1998-12-02 |
| AU3897095A (en) | 1996-05-15 |
| TW422857B (en) | 2001-02-21 |
| KR970707184A (ko) | 1997-12-01 |
| CN1091774C (zh) | 2002-10-02 |
| EP0788521A1 (en) | 1997-08-13 |
| MX9702954A (es) | 1998-07-31 |
| CN1161700A (zh) | 1997-10-08 |
| RU2165437C2 (ru) | 2001-04-20 |
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