ES2128786T3 - Polimeros ramificados de cadena larga y su produccion. - Google Patents

Polimeros ramificados de cadena larga y su produccion.

Info

Publication number
ES2128786T3
ES2128786T3 ES95938287T ES95938287T ES2128786T3 ES 2128786 T3 ES2128786 T3 ES 2128786T3 ES 95938287 T ES95938287 T ES 95938287T ES 95938287 T ES95938287 T ES 95938287T ES 2128786 T3 ES2128786 T3 ES 2128786T3
Authority
ES
Spain
Prior art keywords
matta
ziegler
polymerizable
approx
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95938287T
Other languages
English (en)
Inventor
Aspy Keki Mehta
Charles Stanley Speed
Jo Ann Marie Canich
Norbert Baron
Bernard Jean Folie
Makoto Sugawara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
ExxonMobil Chemical Patents Inc
Original Assignee
Mitsubishi Chemical Corp
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23279893&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2128786(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mitsubishi Chemical Corp, Exxon Chemical Patents Inc filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of ES2128786T3 publication Critical patent/ES2128786T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SE PROPORCIONAN COPOLIMEROS, Y PROCEDIMIENTOS DE FABRICACION DE LOS MISMOS, QUE DERIVAN DE MONOMEROS, LOS CUALES COMPRENDEN: A) UNA MONO-OLEFINA, QUE TIENE UN SOLO ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; B) UN SEGUNDO MONOMERO, QUE TIENE AL MENOS UN ENLACE POLIMERIZABLE DE ZIEGLER-MATTA; C) UN TERCER MONOMERO, QUE TIENE AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA, SIENDO DICHO MONOMERO: I) DE CADENA LINEAL Y DE MENOS DE SEIS O AL MENOS SIETE ATOMOS DE CARBONO; II) DE CADENA NO LINEAL; O III) UNA COMBINACION DE LOS MISMOS; COMPRENDIENDO DICHO COPOLIMERO: D) AL MENOS APROX. UN ENLACE INSATURADO CARBONO-CARBONO POR MOLECULA MEDIA EN NUMERO; E) UNA ENERGIA VISCOSA DE ACTIVACION (E{SUB,A}), AL MENOS 1 KCAL/MOL MAYOR, QUE LA DE UN COPOLIMERO CON UN ESQUELETO LINEAL, DERIVADO DE LOS MISMOS MONOMEROS, PERO EXCLUYENDO AQUELLOS QUE POSEEN AL MENOS DOS ENLACES POLIMERIZABLES DE ZIEGLER-MATTA; F) NIVEL DE CRISTALINIDAD, APROX. DEL 10 AL 50%; Y G) M{SUB,Z}/M{SUB,W} AL MENOS APROX. DE 1''7. DICHOSCOPOLIMEROS, MUESTRAN UNA CAPACIDAD MEJORADA DE TRATAMIENTO EN ESTADO FUNDIDO, Y OTRAS PROPIEDADES, DURANTE LA FABRICACION DEL PRODUCTO FINAL.
ES95938287T 1994-10-24 1995-10-24 Polimeros ramificados de cadena larga y su produccion. Expired - Lifetime ES2128786T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/328,187 US6300451B1 (en) 1994-10-24 1994-10-24 Long-chain branched polymers and their production

Publications (1)

Publication Number Publication Date
ES2128786T3 true ES2128786T3 (es) 1999-05-16

Family

ID=23279893

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95938287T Expired - Lifetime ES2128786T3 (es) 1994-10-24 1995-10-24 Polimeros ramificados de cadena larga y su produccion.

Country Status (13)

Country Link
US (1) US6300451B1 (es)
EP (1) EP0788521B1 (es)
JP (1) JPH10512600A (es)
KR (1) KR100358857B1 (es)
CN (2) CN1091774C (es)
AU (1) AU694812B2 (es)
BR (1) BR9509427A (es)
CA (1) CA2202402C (es)
DE (1) DE69506906T2 (es)
ES (1) ES2128786T3 (es)
RU (1) RU2165437C2 (es)
TW (1) TW422857B (es)
WO (1) WO1996012744A1 (es)

Families Citing this family (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5792534A (en) * 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
BR9609483A (pt) * 1995-06-29 1999-03-02 Dsm Nv Copolímero elastomérico
CA2190678A1 (en) 1995-11-22 1997-05-23 Robert Joseph Noel Bernier Process for preparing elastomeric compounds from granular elastomers and polymers and articles manufactured therefrom
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
EP0784062A3 (en) * 1995-12-15 1998-04-22 Union Carbide Chemicals & Plastics Technology Corporation Process for production of long-chain branched polyolefins
BR9810350B1 (pt) * 1997-06-27 2012-02-22 processo para a preparação de copolìmeros elastoméricos e copolìmeros elastoméricos
NL1006421C2 (nl) * 1997-06-27 1998-12-29 Dsm Nv Elastomeer copolymeer.
WO1999041294A1 (en) * 1998-02-17 1999-08-19 Exxon Chemical Patents Inc. Ethylene copolymerization process
US6294631B1 (en) 1998-12-15 2001-09-25 Exxonmobil Chemical Patents Inc. Hyperbranched polymers by coordination polymerization
US6281316B1 (en) 1999-03-22 2001-08-28 Union Carbide Chemicals & Plastics Technology Corporation Enhanced crosslinking terpolymer
BR0011524A (pt) * 1999-05-14 2002-03-26 Dupont Dow Elastomers Llc Composição de interpolìmero, processo para a preparação de uma composição de interpolìmero, artigo de manufatura e artigo de múltiplas camadas
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6509431B1 (en) * 2000-01-18 2003-01-21 Exxonmobil Oil Corporation Terpolymers
JP4945080B2 (ja) * 2002-06-19 2012-06-06 エクソンモービル・ケミカル・パテンツ・インク エチレン、より高級なα−オレフィンコモノマー及びジエン、特にビニルノルボルネン、並びにそのような方法を用いて製造されるポリマー
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7807769B2 (en) 2002-09-20 2010-10-05 Exxonmobil Chemical Patents Inc. Isotactic polypropylene produced from supercritical polymerization process
AU2003291627A1 (en) * 2002-09-20 2004-04-08 Exxonmobil Chemical Patents Inc. Supercritical polymerization process and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1586591A4 (en) * 2003-01-23 2006-06-14 Mitsui Chemicals Inc PROCESS FOR PRODUCING NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER AND NON-CONJUGATED ETHYLENE / α-OLEFIN / POLYENE COPOLYMER THUS OBTAINED
US7906586B2 (en) * 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
US20050209403A1 (en) * 2003-12-09 2005-09-22 Walton Kim L Thermoplastic olefinic compositions
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
DE602005010255D1 (de) * 2004-07-08 2008-11-20 Exxonmobil Chem Patents Inc Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung
US7741420B2 (en) 2004-07-14 2010-06-22 Exxonmobil Chemical Patents Inc. Polymer production at supercritical conditions
US8101697B2 (en) * 2005-02-01 2012-01-24 Bridgestone Corporation Multi-functionalized high-trans elastomeric polymers
DE602006005645D1 (de) * 2005-05-12 2009-04-23 Dow Global Technologies Inc Thermogeformte und extrudierte folie mit reduziertem glanz
ES2370416T5 (es) * 2005-05-20 2016-04-25 Bridgestone Corporation Método para preparar polímeros de bajo peso molecular
US8288480B2 (en) 2005-06-22 2012-10-16 Exxonmobil Chemical Patents Inc. In-reactor polymer blends
JP5225846B2 (ja) * 2005-09-12 2013-07-03 ダウ グローバル テクノロジーズ エルエルシー エチレン/α−オレフィン組成物、該組成物から製造された物品およびその製造方法
US8557938B2 (en) 2005-11-10 2013-10-15 Arkema Inc. Branched fluoropolymers
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) * 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
CA2668397A1 (en) 2006-11-01 2008-05-15 Dow Global Technologies Inc. Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use
US8242237B2 (en) * 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8143352B2 (en) * 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
CN104927184B (zh) * 2006-12-21 2019-06-14 陶氏环球技术有限责任公司 填充的热塑性聚烯烃组合物、制备其的方法和由其制得的制品
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
KR20080101791A (ko) * 2007-05-16 2008-11-21 주식회사 엘지화학 장쇄분지를 포함하는 에틸렌-알파올레핀 공중합체
JP2010529253A (ja) 2007-06-04 2010-08-26 エクソンモービル・ケミカル・パテンツ・インク 非常に均一なプロピレンの溶液重合法
JP5340292B2 (ja) * 2007-09-07 2013-11-13 ダウ グローバル テクノロジーズ エルエルシー 良好な低温延性を有する充填材入りtpo組成物
US7910637B2 (en) * 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
CN101855249B (zh) * 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
EP2209625B1 (en) 2007-11-14 2019-03-20 Dow Global Technologies LLC Multi-layered article
US7910679B2 (en) * 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN103254513B (zh) * 2007-12-20 2015-08-26 埃克森美孚研究工程公司 全同立构聚丙烯和乙烯-丙烯共聚物的共混物
EP2231779B1 (en) * 2007-12-20 2012-06-06 ExxonMobil Research and Engineering Company In-line process to produce pellet-stable polyolefins
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US8524793B2 (en) 2008-06-18 2013-09-03 Dow Global Technologies, Llc Interpolymer compositions of ethylene, α-olefin and nonconjugated polyene, methods of making the same, and foam and articles prepared from the same
CN102458385A (zh) * 2009-05-08 2012-05-16 3M创新有限公司 口腔护理方法和套件
KR101741857B1 (ko) 2009-07-15 2017-05-30 다우 글로벌 테크놀로지스 엘엘씨 중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품
EP2488556B1 (en) 2009-10-14 2013-09-11 Bridgestone Corporation Processes for preparation of cyclic acyclic diene copolymer and rubber composition
US9458310B2 (en) 2009-10-16 2016-10-04 Exxonmobil Chemical Patents Inc. Modified polyethylene film compositions
US20130216812A1 (en) * 2011-09-23 2013-08-22 Exxonmobil Chemical Patents Inc. Modified Polyethylene Compositions with Enhanced Melt Strength
US9321911B2 (en) 2011-09-23 2016-04-26 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions for cast film
US9580533B2 (en) * 2011-09-23 2017-02-28 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions
US9340664B2 (en) 2011-09-23 2016-05-17 Exxonmobil Chemical Patents Inc. Modified polyethylene compositions for blown film
US20160272798A1 (en) * 2011-09-23 2016-09-22 Exxonmobil Chemical Patents Inc. Modified Polyethylene Compositions with Enhanced Melt Strength
US8629217B2 (en) 2011-11-22 2014-01-14 Exxonmobil Chemical Patents Inc. Modified polyethylene blown film compositions having excellent bubble stability
US10836853B2 (en) 2012-09-20 2020-11-17 Exxonmobil Chemical Patents Inc. Crack-resistant polyethylene compositions
US10822479B2 (en) * 2012-09-20 2020-11-03 Exxonmobil Chemical Patents Inc. Foamed polyethylene compositions
US8901236B2 (en) * 2012-10-09 2014-12-02 Lion Copolymer Geismar, Llc Process for creating an ethylene elastomer
US9139727B2 (en) 2012-10-09 2015-09-22 Lion Copolymer Geismar, Llc Low damping high strength polymer with long chain branching for use in anti-vibration applications
US9139726B2 (en) 2012-10-09 2015-09-22 Lion Copolymer Geismar, Llc Process for making an ethylene elastomer with long chain branching for use in anti-vibration applications
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
EP2928958B1 (en) 2012-12-05 2019-08-21 ExxonMobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
CN103304743B (zh) * 2013-06-24 2015-04-29 苏州新区佳合塑胶有限公司 一种含有4-甲基-1-戊烯的阻燃耐热塑胶
CN103304742B (zh) * 2013-06-24 2015-04-15 苏州新区佳合塑胶有限公司 一种含有1,3-环己二烯的阻燃耐热塑胶
JP6439280B2 (ja) * 2013-08-09 2018-12-19 三菱ケミカル株式会社 熱可塑性エラストマー組成物の製造方法
WO2015126797A1 (en) 2014-02-24 2015-08-27 Dow Global Technologies Llc Thermoplastic polyolefin with reduced gloss for non-carpeted flooring
US10125247B2 (en) 2014-05-29 2018-11-13 Exxonmobil Chemical Patents Inc. Polyethylene compositions
WO2015183577A1 (en) 2014-05-29 2015-12-03 Exxonmobil Chemical Patents Inc. Cyclic-diene additives in polyethylene films and enhanced film orientation balance in production thereof
EP3149073B1 (en) 2014-05-29 2020-12-02 ExxonMobil Chemical Patents Inc. Polyethylene films and production of such films
EP3440118A1 (en) 2016-05-20 2019-02-13 Chevron Phillips Chemical Company LP Low pressure process for preparing low-density polyethylene
KR20220152582A (ko) 2016-08-12 2022-11-16 다우 글로벌 테크놀로지스 엘엘씨 탄소 섬유 및 열가소성 폴리올레핀 탄성중합체를 포함하는 프로필렌계 조성물
US9574034B1 (en) 2016-08-12 2017-02-21 Lion Copolymer Geismar, Llc Process for making high molecular weight tetrapolymer and articles produced therefrom
US9574033B1 (en) 2016-08-12 2017-02-21 Lion Copolymer Geismar, Llc Process for continuously making high molecular weight tetrapolymer for use in anti-vibration applications
US9574035B1 (en) 2016-08-12 2017-02-21 Lion Copolymer Geismar, Llc Process for making high molecular weight tetrapolymer and articles produced therefrom
WO2018182943A1 (en) 2017-03-29 2018-10-04 Exxonmobil Chemical Patents Inc. Polyethylene compositions
US10550252B2 (en) 2017-04-20 2020-02-04 Chevron Phillips Chemical Company Lp Bimodal PE resins with improved melt strength
WO2019173605A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy
US11041035B2 (en) 2018-03-08 2021-06-22 Exxonmobil Chemical Patents Inc. Process to produce long-chain branched polyolefins using dienes
WO2020069370A1 (en) * 2018-09-28 2020-04-02 Dow Global Technologies Llc Tetra-functional long-chain branched ethylene-based polymers
US10961331B2 (en) 2018-12-19 2021-03-30 Chevron Phillips Chemical Company Lp Ethylene homopolymers with a reverse short chain branch distribution
CN113661188B (zh) * 2019-03-29 2023-12-29 陶氏环球技术有限责任公司 聚合三官能长链支化烯烃的方法
EP3947483A1 (en) * 2019-03-29 2022-02-09 Dow Global Technologies LLC Process of polymerizing tri-functional long-chain branched olefin
EP3947484B1 (en) * 2019-03-29 2025-04-23 Dow Global Technologies LLC Tri-functional long-chain branched polyolefin
EP3990506A1 (en) 2019-06-26 2022-05-04 Dow Global Technologies LLC Epdm blends with long chain branching
KR20240108533A (ko) 2021-11-30 2024-07-09 다우 글로벌 테크놀로지스 엘엘씨 연질 열가소성 올레핀 및 이로부터 제조된 제품

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3624056A (en) * 1965-09-28 1971-11-30 Goodrich Co B F Olefin interpolymers prepared with a catalyst system of a titanium compound, alkyl aryl halide and diaryl magnesium
CA849081A (en) 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
NL153224C (nl) 1967-03-24 1982-09-16 Du Pont Werkwijze voor het bereiden van een onverzadigd copolymeer.
NL6817611A (es) * 1967-12-15 1969-06-17
US3472829A (en) 1968-06-10 1969-10-14 Exxon Research Engineering Co Process for broadening the molecular weight distribution in polymers
CA980498A (en) 1971-04-16 1975-12-23 Du Pont Of Canada Limited Ethylene polymers with long chain branching
US3821143A (en) 1973-03-22 1974-06-28 Du Pont Hot melt adhesive composition containing a branched elastomeric copolymer
DE3007725A1 (de) 1980-02-29 1981-09-17 Hansjörg Prof. Dr. 2000 Hamburg Sinn Verfahren zur herstellung von polyethylen, polypropylen und copolymeren
AU9008382A (en) 1981-11-03 1983-05-12 Baker, R.W. Ratchet tool
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4882406A (en) 1983-06-15 1989-11-21 Exxon Research & Engineering Company Nodular copolymers formed of alpha-olefin copolymers coupled by non-conjugated dienes
FR2562546B1 (fr) 1984-04-09 1987-01-23 Bp Chimie Sa Procede de traitement de polyethylene de basse densite lineaire destine a la fabrication par extrusion de corps creux, tubes et gaines
IN172494B (es) 1986-12-19 1993-09-04 Exxon Chemical Patents Inc
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US4668834B1 (en) 1985-10-16 1996-05-07 Uniroyal Chem Co Inc Low molecular weight ethylene-alphaolefin copolymer intermediates
BR8607039A (pt) 1985-12-16 1988-02-23 Exxon Research Engineering Co Composicoes de copolimero contendo um componente de mwd estreita e processo para producao das mesmas
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
IL84641A (en) 1986-12-19 1992-05-25 Exxon Chemical Patents Inc Unsaturated ethylene polymers
IL84642A0 (en) 1986-12-19 1988-04-29 Exxon Chemical Patents Inc Ethylene copolymers and their preparation
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA1327673C (en) 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
JP2883641B2 (ja) 1989-08-11 1999-04-19 三井化学株式会社 ポリウレタン樹脂
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
EP0446013B1 (en) 1990-03-06 1996-07-03 Tosoh Corporation Polyethylene and process of production thereof
GB2244276A (en) 1990-05-21 1991-11-27 Ici Plc Amorphous polyolefins
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5096743A (en) 1990-11-09 1992-03-17 E. I. Du Pont De Nemours And Company Process for making roofing membrane of epdm elastomer and ethylene-containing polymer
GB9103527D0 (en) 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
NL9101536A (nl) 1991-09-11 1993-04-01 Dsm Nv Katalysator en werkwijze voor de bereiding van een amorf copolymeer van etheen.
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
IT1252069B (it) 1991-11-25 1995-05-29 Enichem Elastomers Processo per la preparazione di copolimeri elastomerici dell'etilene
EP0552946B1 (en) 1992-01-23 1997-04-16 Mitsui Petrochemical Industries, Ltd. Ethylene/alpha-olefin/7-methyl-1,6-octadiene copolymer rubber and composition of the same
EP0647243B1 (en) 1992-06-18 1998-03-18 Montell Technology Company bv Process for preparing an ethylenic copolymer
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
KR950703595A (ko) 1992-09-29 1995-09-20 벤셔 카펜헤르 장쇄 분지된 중합체 및 그의 제조방법(long chain branched polymers and a process to make long chain branched polymers)
WO1994013175A1 (en) * 1992-12-16 1994-06-23 Paul Solomon Door comprising recessed cabinet
CA2110654C (en) 1992-12-17 2006-03-21 Albert Rossi Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems
US5410003A (en) * 1994-03-31 1995-04-25 Union Carbide Chemicals & Plastics Technology Corporation Process for production of homogeneous polyethylenes
US5552489A (en) * 1994-07-22 1996-09-03 Exxon Chemical Patents Inc. Tackifiers and a process to obtain tackifiers
JPH1054010A (ja) 1997-06-06 1998-02-24 Ohbayashi Corp 鋼管・コンクリート複合構造橋脚

Also Published As

Publication number Publication date
CN1204157C (zh) 2005-06-01
DE69506906D1 (de) 1999-02-04
US6300451B1 (en) 2001-10-09
CN1341672A (zh) 2002-03-27
WO1996012744A1 (en) 1996-05-02
KR100358857B1 (ko) 2003-02-07
CA2202402C (en) 2006-10-17
CA2202402A1 (en) 1996-05-02
BR9509427A (pt) 1998-01-06
EP0788521B1 (en) 1998-12-23
AU694812B2 (en) 1998-07-30
DE69506906T2 (de) 1999-05-27
JPH10512600A (ja) 1998-12-02
AU3897095A (en) 1996-05-15
TW422857B (en) 2001-02-21
KR970707184A (ko) 1997-12-01
CN1091774C (zh) 2002-10-02
EP0788521A1 (en) 1997-08-13
MX9702954A (es) 1998-07-31
CN1161700A (zh) 1997-10-08
RU2165437C2 (ru) 2001-04-20

Similar Documents

Publication Publication Date Title
ES2128786T3 (es) Polimeros ramificados de cadena larga y su produccion.
ATE335025T1 (de) Pfropfpolymerisate mit stickstoffheterocyclen enthaltenden seitenketten
BR9202400A (pt) Processo para fabricacao de copolimeros de enxerto e composicao de polimero
MX174438B (es) Polimeros mejorados que contienen silicona y procedimiento para su manufactura
ES2153845T3 (es) Perfluoropolioxialquilenos termoplasticos y elastomericos.
ES2108431T3 (es) Polimeros en estrella preparados a partir de macromonomeros obtenidos mediante un procedimiento de transferencia de cadena con cobalto.
AR014705A1 (es) Estructuras o articulos manufacturados que poseen memoria de forma, proceso para conformar articulos y estructuras a partir de polimeros que tienen unmodulo original, fibras de bicomponentes que se comportan con memoria de forma, telas y articulos fabricados con dichas fibras.
ES2147192T3 (es) Procedimiento de preparacion de una composicion de polimeros de etileno, composicion de polimeros de etileno y su utilizacion.
MX173812B (es) Dispositivo quirurgico
DK1093469T3 (da) Lineære cyclodextrincopolymerer
ES459990A1 (es) Procedimiento mejorado para la obtencion de un copolimero resinoso dienico copulado de notable resistencia a la fle- xion y elevada dureza.
ES8104352A1 (es) Un procedimiento para producir una composicion polimera derivada de un producto de reaccion resinoso.
DE59309700D1 (de) Wasserlösliche Polymerdispersionen
KR890009989A (ko) 폴리 프로필렌 및 연신 폴리 프로필렌 필름 제조방법
BR0214120A (pt) Polìmeros de enxerto, processo para a preparação e uso dos mesmos
AR039858A1 (es) (co) polimeros de buteno-1 y procedimiento para su preparacion
ES2135812T3 (es) Copolicondensados en bloque de polisulfona/polieter.
DE69325711D1 (de) Schmelzgesponnene polyethylenfasern mit hoher festigkeit
ES2193457T3 (es) Uso de oxido nitrico para reducir la suciedad de reactor durante la copolimerizacion de injerto de polipropileno.
ES2102850T3 (es) Polimeros de butadieno que tienen grupos sililos terminales.
WO2003097704A8 (fr) Procedes de polymerisation radicalaire et polymeres halogenes
CO5031270A1 (es) Polimeros lineales injertados de silicona endurecidos
IL107147A (en) Polymers formed by combining linear polymer chains, their production and compositions containing them
ATE393173T1 (de) Herstellung von expandierbaren styrol-polymeren
IE45370L (en) Allyl-acrylic monomers and derived polymers

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 788521

Country of ref document: ES