ES2110233T3 - Calix(4)arenos-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y actinidos. - Google Patents

Calix(4)arenos-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y actinidos.

Info

Publication number
ES2110233T3
ES2110233T3 ES94913659T ES94913659T ES2110233T3 ES 2110233 T3 ES2110233 T3 ES 2110233T3 ES 94913659 T ES94913659 T ES 94913659T ES 94913659 T ES94913659 T ES 94913659T ES 2110233 T3 ES2110233 T3 ES 2110233T3
Authority
ES
Spain
Prior art keywords
calix
cesium
arenos
coronas
actinides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94913659T
Other languages
English (en)
Inventor
Jean-Francois Dozol
Helene Rouquette
Rocco Ungaro
Alessandro Casnati
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Application granted granted Critical
Publication of ES2110233T3 publication Critical patent/ES2110233T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D323/00—Heterocyclic compounds containing more than two oxygen atoms as the only ring hetero atoms
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/007—Recovery of isotopes from radioactive waste, e.g. fission products

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Physical Water Treatments (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

LA INVENCION SE REFIERE A CALIX (4) ARENOS-CORONAS SU PROCESO DE PREPARACION Y SU UTILIZACION PARA LA EXTRACCION SELECTIVA DEL CESIO Y DE LOS ACTINIDAS. ESTOS CALIX{(4ARENOS-CORONAS RESPONDEN A LA FORMULA (I) EN LA QUE R1 REPRESENTA UN GRUPO DE FORMULA (X(C2H4 X)M Y X(C2H4 X)N X (C2H4X)N CON X=0 O N(R4) M=3,4,5 O 6, Y=CICLOALKILENO O ARILENO Y N=1, 2 O 3. ESTOS CALIX{(4ARENOS-CORONAS CUYOS NUCLEOS BENCENICOS ESTAN EVENTUALMENTE SUSTITUIDOS POR GRUPOS ALKILO, PUEDEN SER UTILIZADOS COMO EXTRACTANTS, POR EJEMPLO EN FORMA DE MEMBRANA LIQUIDA, PARA SEPARAR EL CESIO DE SOLUCIONES ACIDAS QUE CONTIENEN SODIO EN CANTIDAD IMPORTANTE RESPECTO DE LA CANTIDAD DE CESIO, POR EJEMPLO EFLUENTES DE FABRICAS DE RETRATAMIENTO DE COMBUSTIBLES IRRADIADOS.
ES94913659T 1993-04-19 1994-04-18 Calix(4)arenos-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y actinidos. Expired - Lifetime ES2110233T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9304566A FR2704225B1 (fr) 1993-04-19 1993-04-19 Calix¦4¦arènes-couronnes, leur procédé de préparation et leur utilisation pour l'extraction sélective du césium et des actinides.

Publications (1)

Publication Number Publication Date
ES2110233T3 true ES2110233T3 (es) 1998-02-01

Family

ID=9446183

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94913659T Expired - Lifetime ES2110233T3 (es) 1993-04-19 1994-04-18 Calix(4)arenos-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y actinidos.

Country Status (7)

Country Link
US (1) US5926687A (es)
EP (1) EP0695304B1 (es)
JP (1) JP3773252B2 (es)
DE (1) DE69405986T2 (es)
ES (1) ES2110233T3 (es)
FR (1) FR2704225B1 (es)
WO (1) WO1994024138A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113999157A (zh) * 2021-11-15 2022-02-01 扬州大学 利用磺酰化杯[4]芳烃/表面活性剂复配双水相体系萃取有机酸的方法

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2729958A1 (fr) * 1995-02-01 1996-08-02 Commissariat Energie Atomique Derives de calixarenes , leur procede de preparation et leur utilisation pour l'extraction des actinides et des lanthanides.
FR2760236B1 (fr) * 1997-03-03 1999-11-26 Commissariat Energie Atomique Calix (4) arenes-couronnes, leur procede de preparation et leur utilisation pour l'extraction selective du cesium
GB9713292D0 (en) 1997-06-25 1997-08-27 Secr Defence Novel cation receptor
FR2767490B1 (fr) 1997-08-25 1999-10-01 Commissariat Energie Atomique Procede de separation des actinides et des lanthanides par extraction liquide-liquide au moyen de calixarenes
US6075130A (en) * 1997-11-12 2000-06-13 Battelle Memorial Institute Ion binding compounds, radionuclide complexes, methods of making radionuclide complexes, methods of extracting radionuclides, and methods of delivering radionuclides to target locations
US6117413A (en) * 1997-11-12 2000-09-12 Battelle Memorial Institute Radionuclide-binding compound, a radionuclide delivery system, a method of making a radium complexing compound, a method of extracting a radionuclide, and a method of delivering a radionuclide
US6174503B1 (en) * 1998-09-03 2001-01-16 Lockheed Martin Energy Research Corporation Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions
US6566561B1 (en) 1998-09-03 2003-05-20 The United States Of America As Represented By The Department Of Energy Fluoro-alcohol phase modifiers and process for cesium solvent extraction
NL1010549C2 (nl) * 1998-11-13 2000-05-16 Priva Hortimation B V Systeem en werkwijze voor het verwijderen van ionen uit waterige vloeistofstromen.
FR2788523B1 (fr) * 1999-01-18 2001-02-16 Commissariat Energie Atomique Derives de calixarenes, leur procede de preparation et leur utilisation pour l'extraction des actinides et des lanthanides
FR2792317B1 (fr) * 1999-04-13 2003-05-16 Commissariat Energie Atomique Calix(4) arenes-bis-couronnes, leur procede de preparation et leur utilisation pour separer le cesium du sodium dans des effluents aqueux par nanofiltration
JP3066499B1 (ja) * 1999-06-11 2000-07-17 佐賀大学長 カリックス［４］アレ―ン重合体、その製造方法およびこれを使用した２価鉛イオンの分離方法
FR2797442B1 (fr) * 1999-08-13 2003-10-03 Commissariat Energie Atomique Derives acetamido de calixarenes, leur preparation et leur utilisation pour l'extraction du strontium
KR20020005085A (ko) * 2000-07-06 2002-01-17 최의열 아민기가 부착된 고체기질에 비스크라운-4 유도체를화학결합시켜 비스크라운 -4단분자층의 제조법 및 이기질을 이용한 단백질 단분자층의 제조방법
US20020072936A1 (en) * 2000-08-08 2002-06-13 Newman Jeffrey Marc Children's income protection and benefit health insurance policy and method of underwriting the same
US7214538B2 (en) * 2003-02-12 2007-05-08 Worcester Polytechnic Institute Device and method for the determination of lithium ion concentration in a biological fluid
JP4149330B2 (ja) * 2003-08-11 2008-09-10 和則 鈴木 アクチノイドの分離方法
US7291316B2 (en) 2004-03-23 2007-11-06 Battelle Energy Alliance, Llc Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants
US8343450B2 (en) 2007-10-09 2013-01-01 Chemnano Materials, Ltd. Functionalized carbon nanotubes, recovery of radionuclides and separation of actinides and lanthanides
US8158088B2 (en) * 2008-11-10 2012-04-17 Battelle Energy Alliance, Llc Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
US8270554B2 (en) * 2009-05-19 2012-09-18 The United States Of America, As Represented By The United States Department Of Energy Methods of producing cesium-131
CN109053390B (zh) * 2018-09-14 2021-07-20 成都丽璟科技有限公司 25,27-二异丙氧基-26,28-二羟基杯[4]芳烃的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477377A (en) * 1982-06-17 1984-10-16 Brigham Young University Recovery of cesium
US5210216A (en) * 1985-03-28 1993-05-11 Loctite (Ireland) Limited Calixarene and oxacalixarene derivatives and use thereof of sequestration metals
JP2928363B2 (ja) * 1990-09-13 1999-08-03 ダイセル化学工業株式会社 新規カリックスアレーン誘導体及びその製造法
GB9126829D0 (en) * 1991-12-18 1992-02-19 Kodak Ltd Ion-sensitive dyes
FR2698362B1 (fr) * 1992-11-26 1994-12-23 Commissariat Energie Atomique Calix [4] arènes-bis-couronnes, leur procédé de préparation et leur utilisation pour l'extraction sélective du césium et des actinides.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113999157A (zh) * 2021-11-15 2022-02-01 扬州大学 利用磺酰化杯[4]芳烃/表面活性剂复配双水相体系萃取有机酸的方法
CN113999157B (zh) * 2021-11-15 2023-11-03 扬州大学 利用磺酰化杯[4]芳烃/表面活性剂复配双水相体系萃取有机酸的方法

Also Published As

Publication number Publication date
JPH08508989A (ja) 1996-09-24
US5926687A (en) 1999-07-20
FR2704225A1 (fr) 1994-10-28
DE69405986D1 (de) 1997-11-06
JP3773252B2 (ja) 2006-05-10
EP0695304B1 (fr) 1997-10-01
EP0695304A1 (fr) 1996-02-07
DE69405986T2 (de) 1998-04-02
FR2704225B1 (fr) 1995-05-24
WO1994024138A1 (fr) 1994-10-27

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