ES2099569T3 - Calix(4)arenos-bis-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y de actinidos. - Google Patents

Calix(4)arenos-bis-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y de actinidos.

Info

Publication number
ES2099569T3
ES2099569T3 ES94900876T ES94900876T ES2099569T3 ES 2099569 T3 ES2099569 T3 ES 2099569T3 ES 94900876 T ES94900876 T ES 94900876T ES 94900876 T ES94900876 T ES 94900876T ES 2099569 T3 ES2099569 T3 ES 2099569T3
Authority
ES
Spain
Prior art keywords
coronas
calix
arenos
actinides
cesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94900876T
Other languages
English (en)
Inventor
Jean-Francois Dozol
Zouhair Asfari
Clement Hill
Jacques Vicens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Application granted granted Critical
Publication of ES2099569T3 publication Critical patent/ES2099569T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/38—Liquid-membrane separation
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/302—Ethers or epoxides
    • C22B3/304—Crown ethers
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/36—Heterocyclic compounds
    • C22B3/362—Heterocyclic compounds of a single type
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02—Obtaining thorium, uranium, or other actinides
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21C—NUCLEAR REACTORS
    • G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
    • G21C19/42—Reprocessing of irradiated fuel
    • G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
    • G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/30—Nuclear fission reactors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

LA INVENCION SE REFIERE A CALIX[4]ARENOS-BIS-CORONAS, SU PROCESO DE PREPARACION Y SU UTILIZACION PARA LA EXTRACCION SELECTIVA DEL CESIO Y DE LOS ACTINIDOS. ESTOS CALIX[A]ARENOSBIS-CORONAS RESPONDEN A LA FORMULA (I) EN LA QUE R1 Y R2 REPRESENTAN RESPECTIVAMENTE X(C2H4X)M Y X(C2H4X)N CON X 0 =, NHG Y/O N(CH3), M Y N = 3,4,5 O X(CH2H4X)P/2 YX(C2H4Z)P/2 CON P = 2 O 4 Y Y = CICLOALKILENO O ARILENO. ESTOS CALIX[4]ARENOSBIS-CORONAS CUYOS NUCLEOS BENCENICSO ESTAN EVENTUALMENTE SUSTITUIDOS POR GRUPOS ALKILO, PUEDEN UTILIZARSE COMO EXTRACTANTE, POR EJEMPLO EN FORMA DE MEMBRANA LIQUIDO, PARA SEPARAR E CESIO DE SOLUCIONES ACIDAS QUE CONTIENEN SODIO EN CANTIDAD IMPORTANTE RESPECTO DE A CANTIDAD DE CESIO, POR EJEMPLO EFLUENTES DE FABRICAS DE REPROCESAMIENTO DE COMBUSTIBLE IRRADIADO
ES94900876T 1992-11-26 1993-11-25 Calix(4)arenos-bis-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y de actinidos. Expired - Lifetime ES2099569T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9214245A FR2698362B1 (fr) 1992-11-26 1992-11-26 Calix [4] arènes-bis-couronnes, leur procédé de préparation et leur utilisation pour l'extraction sélective du césium et des actinides.

Publications (1)

Publication Number Publication Date
ES2099569T3 true ES2099569T3 (es) 1997-05-16

Family

ID=9435946

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94900876T Expired - Lifetime ES2099569T3 (es) 1992-11-26 1993-11-25 Calix(4)arenos-bis-coronas, su procedimiento de preparacion y su utilizacion para la extraccion selectiva de cesio y de actinidos.

Country Status (7)

Country Link
US (1) US5607591A (es)
EP (1) EP0670840B1 (es)
JP (1) JP3257797B2 (es)
DE (1) DE69307733T2 (es)
ES (1) ES2099569T3 (es)
FR (1) FR2698362B1 (es)
WO (1) WO1994012502A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704225B1 (fr) * 1993-04-19 1995-05-24 Commissariat Energie Atomique Calix¦4¦arènes-couronnes, leur procédé de préparation et leur utilisation pour l'extraction sélective du césium et des actinides.
FR2729958A1 (fr) * 1995-02-01 1996-08-02 Commissariat Energie Atomique Derives de calixarenes , leur procede de preparation et leur utilisation pour l'extraction des actinides et des lanthanides.
US6086769A (en) * 1996-09-16 2000-07-11 Commodore Separation Technologies, Inc. Supported liquid membrane separation
FR2760236B1 (fr) * 1997-03-03 1999-11-26 Commissariat Energie Atomique Calix (4) arenes-couronnes, leur procede de preparation et leur utilisation pour l'extraction selective du cesium
EP1020532B1 (en) * 1997-06-25 2009-04-08 Sysmex Corporation Method for assaying biological specimens for substances contained in the components thereof and reagent to be used in this method
GB9713292D0 (en) * 1997-06-25 1997-08-27 Secr Defence Novel cation receptor
US6114134A (en) * 1997-06-25 2000-09-05 International Reagents Corporation Method for assaying biological specimens for substances contained in the components thereof and reagent to be used in this method
FR2767490B1 (fr) * 1997-08-25 1999-10-01 Commissariat Energie Atomique Procede de separation des actinides et des lanthanides par extraction liquide-liquide au moyen de calixarenes
WO1999012878A1 (en) * 1997-09-05 1999-03-18 Lockheed Martin Energy Res Cor Solvent and process for extracting cesium from alkaline waste solutions
US6075130A (en) * 1997-11-12 2000-06-13 Battelle Memorial Institute Ion binding compounds, radionuclide complexes, methods of making radionuclide complexes, methods of extracting radionuclides, and methods of delivering radionuclides to target locations
US6174503B1 (en) 1998-09-03 2001-01-16 Lockheed Martin Energy Research Corporation Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions
US6566561B1 (en) 1998-09-03 2003-05-20 The United States Of America As Represented By The Department Of Energy Fluoro-alcohol phase modifiers and process for cesium solvent extraction
KR100264357B1 (ko) * 1998-09-28 2000-08-16 이종훈 세슘이온을 선택적으로 추출할 수 있는 칼릭[4]아렌 크라운유도체의 합성
FR2788523B1 (fr) * 1999-01-18 2001-02-16 Commissariat Energie Atomique Derives de calixarenes, leur procede de preparation et leur utilisation pour l'extraction des actinides et des lanthanides
FR2792317B1 (fr) * 1999-04-13 2003-05-16 Commissariat Energie Atomique Calix(4) arenes-bis-couronnes, leur procede de preparation et leur utilisation pour separer le cesium du sodium dans des effluents aqueux par nanofiltration
FR2797442B1 (fr) 1999-08-13 2003-10-03 Commissariat Energie Atomique Derives acetamido de calixarenes, leur preparation et leur utilisation pour l'extraction du strontium
KR100352815B1 (ko) * 1999-12-23 2002-09-16 김태선 신규한 캘릭스크라운 유도체, 그의 제조 방법, 그를이용하여 제조된 자기조립 단분자층 및 그의 자기조립단분자층을 이용하는 단백질 단분자층의 고정화 방법
KR20020005085A (ko) * 2000-07-06 2002-01-17 최의열 아민기가 부착된 고체기질에 비스크라운-4 유도체를화학결합시켜 비스크라운 -4단분자층의 제조법 및 이기질을 이용한 단백질 단분자층의 제조방법
US7291316B2 (en) * 2004-03-23 2007-11-06 Battelle Energy Alliance, Llc Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants
DE102004022200B4 (de) * 2004-05-05 2006-07-20 Actinium Pharmaceuticals, Inc. Radium-Target sowie Verfahren zu seiner Herstellung
JP4569173B2 (ja) * 2004-05-28 2010-10-27 住友ベークライト株式会社 ビスアミノフェノール化合物
DE102006008023B4 (de) 2006-02-21 2008-05-29 Actinium Pharmaceuticals, Inc. Verfahren zum Reinigen von 225Ac aus bestrahlten 226Ra-Targets
EP2796575B8 (en) * 2006-09-08 2020-04-01 Actinium Pharmaceuticals, Inc. Method for the purification of radium from different sources
RU2389812C2 (ru) * 2008-03-31 2010-05-20 Государственное образовательное учреждение высшего профессионального образования "Казанский государственный университет им. В.И. Ульянова-Ленина" Способ извлечения из водных растворов солей щелочных металлов и серебра
US8158088B2 (en) * 2008-11-10 2012-04-17 Battelle Energy Alliance, Llc Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
US8270554B2 (en) * 2009-05-19 2012-09-18 The United States Of America, As Represented By The United States Department Of Energy Methods of producing cesium-131
EP2631917A1 (en) * 2012-02-24 2013-08-28 Commissariat à l'Énergie Atomique et aux Énergies Alternatives Solid-liquid process for extraction of radionuclides from waste solutions
CN110180512A (zh) * 2019-06-04 2019-08-30 东华理工大学 一种碳基非对称含萘并双冠超分子杂化材料及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477377A (en) * 1982-06-17 1984-10-16 Brigham Young University Recovery of cesium
CA1281246C (en) * 1986-04-03 1991-03-12 Thomas Fyles Polymer membrane for proton driven ion transport

Also Published As

Publication number Publication date
EP0670840B1 (fr) 1997-01-22
DE69307733D1 (de) 1997-03-06
FR2698362A1 (fr) 1994-05-27
WO1994012502A1 (fr) 1994-06-09
US5607591A (en) 1997-03-04
JP3257797B2 (ja) 2002-02-18
EP0670840A1 (fr) 1995-09-13
FR2698362B1 (fr) 1994-12-23
JPH08503937A (ja) 1996-04-30
DE69307733T2 (de) 1997-07-24

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