ES2111635T3 - Metodo de mejorar la estabilidad termica oxidativa de polimeros de etileno. - Google Patents
Metodo de mejorar la estabilidad termica oxidativa de polimeros de etileno.Info
- Publication number
- ES2111635T3 ES2111635T3 ES92908695T ES92908695T ES2111635T3 ES 2111635 T3 ES2111635 T3 ES 2111635T3 ES 92908695 T ES92908695 T ES 92908695T ES 92908695 T ES92908695 T ES 92908695T ES 2111635 T3 ES2111635 T3 ES 2111635T3
- Authority
- ES
- Spain
- Prior art keywords
- improving
- thermal stability
- ethylene polymers
- oxidative
- oxidative thermal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
- C08F6/005—Removal of residual monomers by physical means from solid polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
- B29C48/762—Vapour stripping
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
SE PRESENTA UN METODO PARA MEJORAR LA ESTABILIDAD TERMICA OXIDATIVA DE POLIMEROS DE ETILENO. EL METODO COMPRENDE LA SEPARACION DE LOS MONOMEROS RESIDUALES QUE NO HAN REACCIONADO, DEL SOLVENTE Y DE LAS ESPECIES TERMICAMENTE INESTABLES DEL POLIMERO USANDO UN AGENTE SEPARADOR Y REALIZANDO SUBSECUENTEMENTE UNA DEVOLATILIZACION. EL POLIMERO RESULTANTE SE CARACTERIZA POR TENER UN EXOTERMO OXIDATIVO NO MAYOR DEL 50% DEL POLIMERO ORIGINAL, SEGUN SE MIDE MEDIANTE CALORIMETRIA DE EXPLORACION DIFERENCIAL, ASI COMO MEJORA SUS PROPIEDADES DE OLOR Y SABOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66399591A | 1991-03-04 | 1991-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2111635T3 true ES2111635T3 (es) | 1998-03-16 |
Family
ID=24664075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92908695T Expired - Lifetime ES2111635T3 (es) | 1991-03-04 | 1992-03-04 | Metodo de mejorar la estabilidad termica oxidativa de polimeros de etileno. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5756659A (es) |
| EP (1) | EP0527225B1 (es) |
| JP (1) | JP3174915B2 (es) |
| CA (1) | CA2081105C (es) |
| DE (1) | DE69224242T2 (es) |
| ES (1) | ES2111635T3 (es) |
| FI (1) | FI924965A7 (es) |
| TW (1) | TW246679B (es) |
| WO (1) | WO1992015621A1 (es) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0169505B1 (ko) * | 1992-09-11 | 1999-01-15 | 오오쓰끼 아끼히꼬 | 약제 포장용 폴리올레핀 포장재, 그의 제조방법 및 약제 포장용 용기 |
| US5442041A (en) * | 1995-01-19 | 1995-08-15 | Arco Chemical Technology, L.P. | Removal of volatile substances from thermoplastic resins |
| US5521275A (en) * | 1995-09-05 | 1996-05-28 | General Electric Company | Method for improving catalyst efficiency during polycarbonate redistribution |
| US5861474A (en) * | 1996-07-23 | 1999-01-19 | The Dow Chemical Company | Polymer devolatilization |
| US6576131B1 (en) * | 1997-12-16 | 2003-06-10 | Flint Ink Corporation | Process and apparatus for changing the wetting agent of pigments |
| US6160060A (en) * | 1998-08-04 | 2000-12-12 | Eastman Chemical Company | Process for the synthesis of high molecular weight predominantly amorphous polymers with improved color and adhesive properties |
| US6022946A (en) * | 1998-12-23 | 2000-02-08 | Union Carbide Chemicals & Plastics Technology Corporation | Process for deactivation of polyolefin compositions utilizing carbon dioxide as a deactivation agent |
| EP1078936B1 (en) * | 1999-08-27 | 2004-11-10 | Rohm And Haas Company | Process for stripping polymer dispersions or solutions |
| US6348091B1 (en) | 1999-09-17 | 2002-02-19 | Flint Ink Corporation | Process and apparatus for preparing pigment flush in response to a material property value |
| KR20040034251A (ko) * | 2002-10-21 | 2004-04-28 | 삼성에스디아이 주식회사 | 전계방출소자 |
| US7785512B1 (en) | 2003-07-31 | 2010-08-31 | Advanced Cardiovascular Systems, Inc. | Method and system of controlled temperature mixing and molding of polymers with active agents for implantable medical devices |
| US7645474B1 (en) * | 2003-07-31 | 2010-01-12 | Advanced Cardiovascular Systems, Inc. | Method and system of purifying polymers for use with implantable medical devices |
| US9169406B2 (en) | 2003-08-25 | 2015-10-27 | Dow Global Technologies Llc | Coating compositions |
| US7803865B2 (en) * | 2003-08-25 | 2010-09-28 | Dow Global Technologies Inc. | Aqueous dispersion, its production method, and its use |
| US8349929B2 (en) * | 2003-08-25 | 2013-01-08 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
| US8779053B2 (en) | 2003-08-25 | 2014-07-15 | Dow Global Technologies Llc | Coating compositions |
| US7763676B2 (en) * | 2003-08-25 | 2010-07-27 | Dow Global Technologies Inc. | Aqueous polymer dispersions and products from those dispersions |
| US8357749B2 (en) * | 2003-08-25 | 2013-01-22 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
| US8722787B2 (en) | 2003-08-25 | 2014-05-13 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
| US7947776B2 (en) | 2003-08-25 | 2011-05-24 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
| US8158711B2 (en) * | 2003-08-25 | 2012-04-17 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
| US8946329B2 (en) | 2003-08-25 | 2015-02-03 | Dow Global Technologies Llc | Coating compositions |
| TW200517426A (en) | 2003-08-25 | 2005-06-01 | Dow Global Technologies Inc | Aqueous dispersion, its production method, and its use |
| KR101184709B1 (ko) * | 2004-08-17 | 2012-09-20 | 플린트 그룹 인코포레이티드 | 유기성 안료 분산물 및 잉크 제조 방법 |
| US8287949B2 (en) * | 2005-07-07 | 2012-10-16 | Dow Global Technologies Inc. | Aqueous dispersions |
| CN101068667A (zh) * | 2005-07-07 | 2007-11-07 | 陶氏环球技术公司 | 长纤维增强热塑性浓缩物及其制备方法 |
| CN101356314B (zh) | 2005-12-15 | 2012-07-04 | 陶氏环球技术有限责任公司 | 含添加剂组合物的改进纤维素制品 |
| US8043713B2 (en) * | 2005-12-15 | 2011-10-25 | Dow Global Technologies Llc | Compositions and aqueous dispersions |
| US7528080B2 (en) * | 2005-12-15 | 2009-05-05 | Dow Global Technologies, Inc. | Aqueous polyolefin dispersions for textile impregnation |
| US20070243331A1 (en) * | 2006-02-17 | 2007-10-18 | Dow Global Technologies Inc. | Heat sealable compositions from aqueous dispersions |
| US8007978B2 (en) * | 2006-03-03 | 2011-08-30 | Dow Global Technologies Llc | Aqueous dispersions for use as toners |
| US9547246B2 (en) * | 2006-03-03 | 2017-01-17 | Dow Global Technologies Llc | Aqueous dispersions for use as toners |
| US8785531B2 (en) * | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
| US8916640B2 (en) * | 2006-07-06 | 2014-12-23 | Dow Global Technologies Llc | Blended polyolefin dispersions |
| AR062738A1 (es) * | 2006-09-11 | 2008-11-26 | Dow Global Technologies Inc | Tecnologia de dispersion poliolefinica usada para arena recubierta con resina |
| US8476326B2 (en) * | 2006-09-22 | 2013-07-02 | Dow Global Technologies Llc | Fibrillated polyolefin foam |
| US20080118728A1 (en) | 2006-10-20 | 2008-05-22 | Dow Global Technologies Inc. | Aqueous dispersions disposed on glass-based fibers and glass-containing substrates |
| EP2399615B1 (en) | 2006-10-25 | 2014-08-06 | Dow Global Technologies LLC | Polyolefin dispersions, froths, and foams |
| DE602007006683D1 (de) * | 2006-11-02 | 2010-07-01 | Dow Global Technologies Inc | Verfahren zur herstellung hochqualitativer ionomere |
| BRPI0806751B1 (pt) * | 2007-01-17 | 2018-08-14 | Agrofresh Inc. | Liberação de agentes de bloqueio e/ou promoção de etileno |
| EP2115213A1 (en) * | 2007-02-08 | 2009-11-11 | Dow Global Technologies Inc. | Flexible conductive polymeric sheet |
| EP2543393A3 (en) * | 2007-09-28 | 2013-10-30 | Dow Global Technologies LLC | Foam produced from a dispersion of higher crystallinity olefins |
| US8475878B2 (en) * | 2007-10-25 | 2013-07-02 | Dow Global Technologies Llc | Polyolefin dispersion technology used for porous substrates |
| CN102119194B (zh) | 2007-11-15 | 2013-07-10 | 陶氏环球技术有限责任公司 | 涂料组合物、涂覆制品和制备该制品的方法 |
| EP2568023B1 (en) | 2007-11-15 | 2014-06-25 | Dow Global Technologies LLC | A coated article, and method of forming such articles |
| CA2706726C (en) * | 2007-11-29 | 2013-11-12 | Dow Global Technologies Inc. | Compounds and methods of forming compounds useful as a toner |
| EP2225098B1 (en) | 2007-12-21 | 2020-09-30 | Dow Global Technologies LLC | Carpet comprising an olefin block copolymer adhesive backing |
| CN104438026B (zh) | 2008-12-22 | 2018-05-15 | 陶氏环球技术有限责任公司 | 织造地毯涂料混合物、相关的使用方法、和由该混合物制得的制品 |
| CA2823300C (en) | 2010-12-29 | 2019-10-22 | Dow Global Technologies Llc | Method of making a cable strength member |
| EP2718364B1 (en) | 2011-06-10 | 2016-11-02 | Dow Global Technologies LLC | Method t0 make an aqueous pour point depressant dispersion composition |
| EP2551298B1 (en) | 2011-07-27 | 2014-12-31 | Dow Global Technologies LLC | Redispersible polymer powder from polyolefin dispersions and the use thereof in construction applications |
| CN104755535B (zh) | 2012-06-29 | 2017-03-08 | 陶氏环球技术有限公司 | 环氧树脂掺混物分散体及该分散体的制备方法 |
| CN105026502B (zh) | 2012-12-28 | 2020-12-04 | 陶氏环球技术有限责任公司 | 涂料组合物和由其制成的物品 |
| EP2922925B1 (en) | 2012-12-28 | 2019-12-04 | Dow Global Technologies LLC | Coating compositions |
| EP2945994B1 (en) | 2013-01-18 | 2018-07-11 | Basf Se | Acrylic dispersion-based coating compositions |
| EP3013369B1 (en) | 2013-08-29 | 2017-12-27 | Dow Global Technologies LLC | A process to produce an aqueous dispersion |
| AU2014373830B2 (en) | 2013-12-30 | 2018-10-11 | Avery Dennison Corporation | Compostable films and compostable labels |
| KR20170030092A (ko) | 2014-07-17 | 2017-03-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸셀룰로오스 분산물 및 필름 |
| US20170226329A1 (en) | 2014-08-15 | 2017-08-10 | Dow Global Technologies Llc | Ethylcellulose dispersion and powder |
| EP3201259A1 (en) | 2014-09-30 | 2017-08-09 | Dow Global Technologies Llc | Aqueous ethylcellulose dispersions with polymeric additive |
| KR20170128362A (ko) | 2015-03-18 | 2017-11-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 탄성중합체성 폴리올레핀 스킨의 제조방법 |
| BR112017020199A2 (pt) | 2015-03-31 | 2018-06-05 | Dow Global Technologies Llc | pó de elastômero de poliolefina seca em spray para processos de moldagem rotativa |
| EP3400331A1 (en) | 2016-01-05 | 2018-11-14 | Dow Global Technologies, LLC | Composites for cured-in-place pipe |
| CN109526215A (zh) | 2016-06-08 | 2019-03-26 | 陶氏环球技术有限责任公司 | 制造汽车装饰复合部件的方法 |
| US20210078218A1 (en) | 2017-06-06 | 2021-03-18 | Dow Global Technologies Llc | Process to make a composite automotive trim part |
| CN111132825A (zh) | 2017-09-27 | 2020-05-08 | 陶氏环球技术有限责任公司 | 原位固化管的耐磨柔性复合材料和多层管衬垫 |
| WO2019113142A1 (en) | 2017-12-06 | 2019-06-13 | Dow Global Technologies Llc | Flotation separation aid useful for collection of mineral ore fines |
| WO2020081279A1 (en) | 2018-10-17 | 2020-04-23 | Dow Global Technologies Llc | A coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric |
| US12227141B2 (en) | 2018-10-17 | 2025-02-18 | Dow Global Technologies Llc | Coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric |
| EP3867105A1 (en) | 2018-10-17 | 2021-08-25 | Dow Global Technologies, LLC | A coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric |
| CN113454178B (zh) * | 2019-02-26 | 2024-04-02 | 株式会社Moresco | 热熔粘接剂的制造方法以及热熔粘接剂 |
| CN113454179B (zh) * | 2019-02-26 | 2023-12-05 | 株式会社Moresco | 乙烯-乙酸乙烯酯系热熔粘接剂的制造方法以及热熔粘接剂 |
| JP7805567B1 (ja) * | 2024-12-23 | 2026-01-26 | 江蘇越升科技股▲ふん▼有限公司 | 高物質移動界面に基づくポリマー/揮発性成分システムの継続的でダイナミックかつ効率的な脱揮方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3156009A (en) * | 1960-12-30 | 1964-11-10 | Standard Oil Co | Devolatilizing extruder |
| US3476736A (en) * | 1966-04-14 | 1969-11-04 | Phillips Petroleum Co | Solvent removal from polyolefin in vented extruder with water addition |
| US3799235A (en) * | 1970-11-27 | 1974-03-26 | Firestone Tire & Rubber Co | Method and apparatus for desolventizing elastomers |
| US3799234A (en) * | 1971-02-22 | 1974-03-26 | Welding Engineers | Countercurrent vapor stripping in screw devolatilizer |
| US3917507A (en) * | 1971-02-22 | 1975-11-04 | Welding Engineers | Countercurrent combined liquid and vapor stripping in screw devolatilizer |
| US3992500A (en) * | 1974-06-07 | 1976-11-16 | Koehring Company | Vented extruder |
| JPS5111882A (en) * | 1974-07-20 | 1976-01-30 | Sumitomo Chemical Co | Mihannotanryotaio jokyosuruhoho |
| JPS5249267A (en) * | 1975-10-17 | 1977-04-20 | Japan Steel Works Ltd | Degassing modifying extruder |
| US4107422A (en) * | 1977-02-02 | 1978-08-15 | Phillips Petroleum Company | Solvent removal from polymer solutions |
| DE2800632C3 (de) * | 1978-01-07 | 1981-02-19 | Hermann Berstorff Maschinenbau Gmbh, 3000 Hannover | Schneckenstrangpresse für thermoplastische Kunststoffe |
| US4690981A (en) * | 1983-03-21 | 1987-09-01 | E. I. Du Pont De Nemours And Company | Ionomers having improved low temperature properties |
| DE3310676A1 (de) * | 1983-03-24 | 1984-09-27 | Basf Ag, 6700 Ludwigshafen | Verfahren und vorrichtung zum entfernen von fluechtigen anteilen aus polymerenschmelzen oder paste |
| US4927888A (en) * | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| JPH0621130B2 (ja) * | 1985-04-09 | 1994-03-23 | 三菱油化株式会社 | アイオノマ−樹脂の製造法 |
| FR2598350B1 (fr) * | 1986-05-06 | 1989-11-17 | Bp Chimie Sa | Procede et dispositif pour degazer et pour transformer en granules des particules de polyolefines obtenues par polymerisation en phase gazeuse |
| US4909898A (en) * | 1986-10-01 | 1990-03-20 | Polysar Limited | Polymer recovery from solution |
| JP2635354B2 (ja) * | 1988-03-02 | 1997-07-30 | 住友ゴム工業株式会社 | 変性アイオノマー樹脂の製法 |
| DE3815487A1 (de) * | 1988-05-06 | 1989-11-16 | Basf Ag | Verfahren zur niederdruckcopolymerisation von ethylen mit (alpha)-olefinen und ethylencopolymerisate mit niederem restmonomerengehalt |
| US4958006A (en) * | 1988-06-28 | 1990-09-18 | Union Carbide Chemicals And Plastics Inc. | Fluidized bed product discharge process |
| DE3822069A1 (de) * | 1988-06-30 | 1990-01-18 | Basf Ag | Verfahren zur ionischen vernetzung eines ethylencopolymerisates, ionisch vernetzte ethylencopolymerisate und deren verwendung als haftvermittler, spritzgussartikel oder beschichtungsfolie |
| US4952672A (en) * | 1988-08-11 | 1990-08-28 | The Dow Chemical Company | Method for the devolatilization of thermoplastic materials |
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| DE3840293A1 (de) * | 1988-11-30 | 1990-05-31 | Werner & Pfleiderer | Verfahren zum entfernen von verunreinigungen aus polymeren kunststoffen und vorrichtung zur durchfuehrung des verfahrens |
-
1992
- 1992-03-04 DE DE69224242T patent/DE69224242T2/de not_active Revoked
- 1992-03-04 CA CA002081105A patent/CA2081105C/en not_active Expired - Lifetime
- 1992-03-04 WO PCT/US1992/001720 patent/WO1992015621A1/en not_active Ceased
- 1992-03-04 EP EP92908695A patent/EP0527225B1/en not_active Revoked
- 1992-03-04 ES ES92908695T patent/ES2111635T3/es not_active Expired - Lifetime
- 1992-03-04 JP JP50785592A patent/JP3174915B2/ja not_active Expired - Lifetime
- 1992-03-04 FI FI924965A patent/FI924965A7/fi unknown
- 1992-03-12 TW TW081101891A patent/TW246679B/zh not_active IP Right Cessation
-
1994
- 1994-10-21 US US08/326,981 patent/US5756659A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0527225A1 (en) | 1993-02-17 |
| JP3174915B2 (ja) | 2001-06-11 |
| WO1992015621A1 (en) | 1992-09-17 |
| EP0527225B1 (en) | 1998-01-28 |
| FI924965L (fi) | 1992-11-03 |
| CA2081105A1 (en) | 1992-09-05 |
| FI924965A0 (fi) | 1992-11-03 |
| DE69224242T2 (de) | 1998-05-14 |
| TW246679B (es) | 1995-05-01 |
| FI924965A7 (fi) | 1992-11-03 |
| DE69224242D1 (de) | 1998-03-05 |
| US5756659A (en) | 1998-05-26 |
| JPH05506692A (ja) | 1993-09-30 |
| CA2081105C (en) | 2004-10-05 |
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