ES2111852T3 - Procedimiento para la preparacion de polimeros de cloruro de vinilo. - Google Patents
Procedimiento para la preparacion de polimeros de cloruro de vinilo.Info
- Publication number
- ES2111852T3 ES2111852T3 ES94303257T ES94303257T ES2111852T3 ES 2111852 T3 ES2111852 T3 ES 2111852T3 ES 94303257 T ES94303257 T ES 94303257T ES 94303257 T ES94303257 T ES 94303257T ES 2111852 T3 ES2111852 T3 ES 2111852T3
- Authority
- ES
- Spain
- Prior art keywords
- vinyl chloride
- polymerization
- suspension
- saponification
- principle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 2
- 238000007127 saponification reaction Methods 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000001879 gelation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN POLIMERO DE CLORURO DE VINILO SE PREPARA POR POLIMERIZACION EN SUSPENSION DE CLORURO DE VINILO MONOMERICO O UNA MEZCLA DE CLORURO DE VINILO Y OTRO MONOMERO EN UN MEDIO ACUOSO MIENTRAS SE AGITA LA SUSPENSION. UN PRIMER ALCOHOL POLIVINILO PARCIALMENTE SAPONIFICADO QUE TIENE UN GRADO DE SAPONIFICACION DEL 60 .000 SE AÑADE COMO ESTABILIZADOR DE LA SUSPENSION AL PRINCIPIO DE LA POLIMERIZACION, Y UN SEGUNDO ALCOHOL POLIVINILO PARCIALMENTE SAPONIFICADO QUE TIENE UN GRADO DE SAPONIFICACION DEL 75% DE AGITACION SE CONTROLA A 80 DE EL PRINCIPIO DE LA POLIMERIZACION HASTA UN CONVERSION DEL 20% AL 50% Y A 130 HASTA EL ACABADO DE LA POLIMERIZACION. EL POLIMERO DE CLORURO DE VINILO RESULTANTE ES DE CALIDAD DEMOSTRADA POR UNA ALTA DENSIDAD DE VOLUMEN Y UN FLUJO LIBRE MEJORADO, LA RETIRAD DEL MONOMERO, LA GELACION Y LA ABSORCION PLASTIFICADORA ASI COMO UN MINIMO OJO DE PEZ. SE MINIMIZA LA FORMACION DE ESCAMA SOBRE LA PARED DEL REACTOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13127493 | 1993-05-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2111852T3 true ES2111852T3 (es) | 1998-03-16 |
Family
ID=15054106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94303257T Expired - Lifetime ES2111852T3 (es) | 1993-05-07 | 1994-05-05 | Procedimiento para la preparacion de polimeros de cloruro de vinilo. |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5478900A (es) |
| EP (1) | EP0623632B1 (es) |
| CN (1) | CN1107860A (es) |
| ES (1) | ES2111852T3 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5849831A (en) * | 1996-04-19 | 1998-12-15 | Kuraray Co., Ltd. | Process for producing vinyl resin |
| JPH10251339A (ja) * | 1997-03-17 | 1998-09-22 | Kanegafuchi Chem Ind Co Ltd | ペーストブレンド用塩化ビニル系樹脂の製造方法 |
| JP4421715B2 (ja) * | 1999-10-28 | 2010-02-24 | 日本合成化学工業株式会社 | ビニル系樹脂の製造方法 |
| AUPQ453499A0 (en) * | 1999-12-08 | 2000-01-06 | Herbert Mcivor Holdings Pty Ltd | A system and method for automatically logging article use and an article adapted for such |
| WO2003087168A1 (en) * | 2002-04-12 | 2003-10-23 | Akzo Nobel N.V. | Co-metering of organic initiators and protective colloids during polymerization reactions |
| JP3995584B2 (ja) * | 2002-12-11 | 2007-10-24 | 株式会社クラレ | ビニル系化合物の懸濁重合用分散安定剤の製造法 |
| BRPI0411751B1 (pt) * | 2003-06-27 | 2020-03-17 | Akzo Nobel Chemicals International B.V. | Processo de polimerização para preparação de um (co)polímero de cloreto de vinila, e formulação adequada para uso em um processo de polimerização de dispersão aquosa |
| JP2010511081A (ja) * | 2006-11-30 | 2010-04-08 | ニューヴィル ソシエタ ア レスポンサビリタ リミタータ | 反応器内での触媒の直接製造によるポリ塩化ビニルの懸濁重合法と前記反応のために前記反応器に添加する懸濁安定剤 |
| WO2009011187A1 (ja) * | 2007-07-13 | 2009-01-22 | Kuraray Co., Ltd. | ビニル系樹脂の製造方法 |
| DE102007033970A1 (de) * | 2007-07-19 | 2009-01-22 | Kuraray Europe Gmbh | Verwendung von getemperten Polyvinylalkoholen als Stabilisatorzusatz von PVC |
| DE102007033971A1 (de) * | 2007-07-19 | 2009-01-22 | Kuraray Europe Gmbh | Verwendung von Carboxylgruppen-haltigen Polyvinylalkoholen als Stabilisatorzusatz von PVC |
| CN101812149B (zh) * | 2009-11-22 | 2011-12-28 | 天津渤天化工有限责任公司 | 中高聚合度蓄电池隔板专用聚氯乙烯树脂的生产方法 |
| JPWO2012114441A1 (ja) * | 2011-02-21 | 2014-07-07 | 電気化学工業株式会社 | 懸濁重合用分散剤、塩化ビニル系樹脂及びその製造方法 |
| US20130269537A1 (en) | 2012-04-16 | 2013-10-17 | Eugenio Minvielle | Conditioning system for nutritional substances |
| US20130269538A1 (en) * | 2012-04-16 | 2013-10-17 | Eugenio Minvielle | Transformation system for nutritional substances |
| US9541536B2 (en) | 2012-04-16 | 2017-01-10 | Eugenio Minvielle | Preservation system for nutritional substances |
| US10219531B2 (en) | 2012-04-16 | 2019-03-05 | Iceberg Luxembourg S.A.R.L. | Preservation system for nutritional substances |
| US9414623B2 (en) | 2012-04-16 | 2016-08-16 | Eugenio Minvielle | Transformation and dynamic identification system for nutritional substances |
| US9080997B2 (en) | 2012-04-16 | 2015-07-14 | Eugenio Minvielle | Local storage and conditioning systems for nutritional substances |
| US8733631B2 (en) | 2012-04-16 | 2014-05-27 | Eugenio Minvielle | Local storage and conditioning systems for nutritional substances |
| US9069340B2 (en) | 2012-04-16 | 2015-06-30 | Eugenio Minvielle | Multi-conditioner control for conditioning nutritional substances |
| US9429920B2 (en) | 2012-04-16 | 2016-08-30 | Eugenio Minvielle | Instructions for conditioning nutritional substances |
| US9072317B2 (en) | 2012-04-16 | 2015-07-07 | Eugenio Minvielle | Transformation system for nutritional substances |
| US9564064B2 (en) | 2012-04-16 | 2017-02-07 | Eugenio Minvielle | Conditioner with weight sensors for nutritional substances |
| US20140069838A1 (en) | 2012-04-16 | 2014-03-13 | Eugenio Minvielle | Nutritional Substance Label System For Adaptive Conditioning |
| US9121840B2 (en) | 2012-04-16 | 2015-09-01 | Eugenio Minvielle | Logistic transport system for nutritional substances |
| US9016193B2 (en) | 2012-04-16 | 2015-04-28 | Eugenio Minvielle | Logistic transport system for nutritional substances |
| US9460633B2 (en) | 2012-04-16 | 2016-10-04 | Eugenio Minvielle | Conditioner with sensors for nutritional substances |
| US9171061B2 (en) | 2012-04-16 | 2015-10-27 | Eugenio Minvielle | Local storage and conditioning systems for nutritional substances |
| US9528972B2 (en) | 2012-04-16 | 2016-12-27 | Eugenio Minvielle | Dynamic recipe control |
| US9702858B1 (en) | 2012-04-16 | 2017-07-11 | Iceberg Luxembourg S.A.R.L. | Dynamic recipe control |
| US9436170B2 (en) | 2012-04-16 | 2016-09-06 | Eugenio Minvielle | Appliances with weight sensors for nutritional substances |
| US10790062B2 (en) | 2013-10-08 | 2020-09-29 | Eugenio Minvielle | System for tracking and optimizing health indices |
| USD762081S1 (en) | 2014-07-29 | 2016-07-26 | Eugenio Minvielle | Device for food preservation and preparation |
| TWI669318B (zh) * | 2014-11-12 | 2019-08-21 | 日商可樂麗股份有限公司 | 懸浮聚合用分散安定劑及乙烯系樹脂之製造方法 |
| CN105801732B (zh) * | 2014-12-31 | 2018-03-16 | 青岛阿莫斯资源科技有限公司 | 一种聚氯乙烯的悬浮聚合制备方法及加料装置 |
| CN107778394B (zh) * | 2016-08-27 | 2019-12-27 | 中国石油化工股份有限公司 | 多孔性结构聚氯乙烯树脂的制备方法 |
| CN114555696B (zh) * | 2019-12-17 | 2024-03-05 | 电化株式会社 | 聚乙烯醇系树脂组合物、悬浮聚合用分散稳定剂以及乙烯基系树脂的制造方法 |
| CN112706431B (zh) * | 2020-12-09 | 2022-09-13 | 北方华锦化学工业股份有限公司 | 一种降低abs不良品发生率的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2014016C3 (de) * | 1970-03-24 | 1978-05-18 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Vinylchlorid-Polymerisaten |
| JPS5121671B2 (es) * | 1972-11-21 | 1976-07-03 | ||
| IT1160355B (it) * | 1978-12-15 | 1987-03-11 | Sigma Italiana Prod Chimici | Procedimento perfezionato per la produzione di cloruro di polivinile |
| DE2707259A1 (de) * | 1977-02-19 | 1978-08-24 | Hoechst Ag | Verfahren zur herstellung von suspensionspolymerisaten und copolymerisaten des vinylchlorids |
| DE3132421A1 (de) * | 1981-08-17 | 1983-02-24 | Hoechst Ag, 6000 Frankfurt | Kontinuierliches verfahren zur herstellung von vinylchloridpolymerisaten in waessriger suspension |
| US5292836A (en) * | 1990-04-05 | 1994-03-08 | Shin-Etsu Chemical Co., Ltd. | Preparation of vinyl chloride polymers using high-speed and low-speed shear agitation |
-
1994
- 1994-04-28 US US08/234,664 patent/US5478900A/en not_active Expired - Lifetime
- 1994-05-05 ES ES94303257T patent/ES2111852T3/es not_active Expired - Lifetime
- 1994-05-05 EP EP94303257A patent/EP0623632B1/en not_active Expired - Lifetime
- 1994-05-07 CN CN94105386A patent/CN1107860A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0623632A3 (en) | 1995-05-03 |
| CN1107860A (zh) | 1995-09-06 |
| US5478900A (en) | 1995-12-26 |
| EP0623632B1 (en) | 1997-11-12 |
| EP0623632A2 (en) | 1994-11-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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