ES2116461T3 - Procedimiento para preparar material compuesto a partir de resinas termoendurecibles, mesogenicas orientadas. - Google Patents
Procedimiento para preparar material compuesto a partir de resinas termoendurecibles, mesogenicas orientadas.Info
- Publication number
- ES2116461T3 ES2116461T3 ES93917218T ES93917218T ES2116461T3 ES 2116461 T3 ES2116461 T3 ES 2116461T3 ES 93917218 T ES93917218 T ES 93917218T ES 93917218 T ES93917218 T ES 93917218T ES 2116461 T3 ES2116461 T3 ES 2116461T3
- Authority
- ES
- Spain
- Prior art keywords
- continuous fiber
- fiber substrate
- mesogen
- healing
- oriented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011347 resin Substances 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 title abstract 2
- 239000002131 composite material Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000001029 thermal curing Methods 0.000 title 1
- 239000000835 fiber Substances 0.000 abstract 9
- 239000000758 substrate Substances 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 5
- 239000011159 matrix material Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000002118 epoxides Chemical group 0.000 abstract 1
- 239000013003 healing agent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000009738 saturating Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
- C09K2323/055—Epoxy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Epoxy Resins (AREA)
- Liquid Crystal Substances (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
LOS COMPUESTOS DE MATRICES DE RESINAS QUE CONTIENEN UN MESOGEN ORIENTADOS Y REFORZADOS CON FIBRAS CONTINUAS SE PREPARAN (A) SATURANDO UN MATERIAL DE SUSTRATO DE FIBRAS CONTINUAS CON UNA COMPOSICION CURABLE QUE CONTIENE (1) AL MENOS UNA RESINA QUE CONTIENE UN MESOGEN QUE CONTIENE UNA MEDIA DE MAS DE UN GRUPO EPOXIDO CERCANO, GRUPO TIIRANO, GRUPO CIANATO O GRUPO VINILETER POR MOLECULA; Y, OPCIONALMENTE, (2) UNA CANTIDAD DE CURACION DE AL MENOS UN AGENTE DE CURACION Y/O UN CATALIZADOR DE CURACION PARA LA MISMA; (B) COLOCANDO UNO O MAS DE LOS MATERIALES DE SUSTRATO DE FIBRAS CONTINUAS FORMADOS EN EL PASO (A) SEGUN LA FORMA DESEADA; (C) SOMETIENDO A LOS MATERIALES DE SUSTRATO DE FIBRAS CONTINUAS SATURADOS YA COLOCADOS DEL PASO (B) A UNA TEMPERATURA QUE HACE QUE LA RESINA QUE CONTIENE EL MESOGEN SE CONVIERTA EN UN ESTADO CRISTALINO LIQUIDO; (D) SOMETIENDO A LOS MATERIALES DE SUSTRATO DE FIBRAS CONTINUAS SATURADOS YA DISPUESTOS Y CALENTADOS DEL PASO (C) A UNA PRESION SUFICIENTE COMO PARA PROVOCARUN ESFUERZO CORTANTE INDUCIDO POR EL FLUJO EN LOS INTERSTICIOS DE DICHO SUSTRATO DE FIBRAS CONTINUAS; (E) SOMETIENDO EL MATERIAL DE SUSTRATO DE FIBRAS CONTINUAS DEL PASO (D) A UNAS CONDICIONES DE CURACION BIEN SIMULTANEAMENTE AL APLICAR LA PRESION DEL PASO (D) Y/O TRAS DICHA APLICACION DE PRESION; (F) DEJANDO QUE SE ENFRIE EL COMPUESTO REFORZADO CON FIBRAS CONTINUAS DEL PASO (E) A TEMPERATURA AMBIENTE; CON LO QUE SE FORMA UN COMPUESTO REFORZADO CON FIBRAS CONTINUAS CURADO QUE CONTIENE UNA MATRIZ DE RESINA QUE CONTIENE UN MESOGEN ORIENTADO. ESTOS COMPUESTOS TIENEN UNAS PROPIEDADES MEJORADAS EN COMPARACION A LOS COMPUESTOS NO ORIENTADOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/830,105 US5248360A (en) | 1992-02-03 | 1992-02-03 | Process for preparing composites based on oriented mesogenic thermoset resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2116461T3 true ES2116461T3 (es) | 1998-07-16 |
Family
ID=25256325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93917218T Expired - Lifetime ES2116461T3 (es) | 1992-02-03 | 1993-07-15 | Procedimiento para preparar material compuesto a partir de resinas termoendurecibles, mesogenicas orientadas. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5248360A (es) |
| EP (1) | EP0708796B1 (es) |
| JP (1) | JP3399958B2 (es) |
| AU (1) | AU4680493A (es) |
| DE (1) | DE69318858T2 (es) |
| ES (1) | ES2116461T3 (es) |
| WO (1) | WO1995002631A1 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5414150A (en) * | 1993-12-03 | 1995-05-09 | The Dow Chemical Company | Preparation of 4,4'-dihydroxy-alpha-alkylstilbenes and 4,4'-dihydroxy-alpha, alpha'-dialkylstilbenes |
| US5686551A (en) * | 1994-01-07 | 1997-11-11 | The Dow Chemical Company | Hydroxy ether polymers as thermoplastic barrier resins |
| US5614599A (en) * | 1994-10-31 | 1997-03-25 | The Dow Chemical Company | Stilbene-based polyester and polycarbonate compositions |
| US5512368A (en) * | 1995-03-16 | 1996-04-30 | E. I. Du Pont De Nemours And Company | Fibers reinforced with inorganic whiskers |
| WO1998011043A1 (en) * | 1996-09-13 | 1998-03-19 | The Dow Chemical Company | Process for preparing stilbene diols |
| US5874645A (en) * | 1997-04-25 | 1999-02-23 | The Dow Chemical Company | Process for the preparation and purification of 4,4'-dihydroxy-alpha-substituted stilbene |
| US5968641A (en) * | 1998-04-28 | 1999-10-19 | Trw Inc. | Compliant thermoset matrix, fiber reinforced, syntactic foam sandwich panel |
| CN102146197A (zh) * | 2011-04-20 | 2011-08-10 | 东华大学 | 一种纳米蒙脱土插层环氧树脂层状复合材料的制备方法 |
| NL2016357B1 (en) | 2016-03-03 | 2017-09-20 | Allotropica Tech Inc | Pre-preg and composite products |
| WO2018121856A1 (en) * | 2016-12-28 | 2018-07-05 | Kordsa Teknik Tekstil Anonim Sirketi | Fiber reinforced thermoplastic composite |
| WO2018173953A1 (ja) * | 2017-03-24 | 2018-09-27 | 東レ株式会社 | プリプレグおよび炭素繊維強化複合材料 |
| CN111909402B (zh) * | 2020-09-03 | 2021-06-29 | 华南农业大学 | 一种碳纤维增强热固性树脂基复合材料的制备方法及其产品 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4479999A (en) * | 1982-04-15 | 1984-10-30 | Celanese Corporation | Fabric comprised of fusible and infusible fibers, the former comprising a polymer which is capable of forming an anisotropic melt phase |
| DE3622610A1 (de) | 1986-07-05 | 1988-01-14 | Bayer Ag | Fluessig-kristalline diglycidylverbindungen, ihre herstellung und verwendung in haertbaren epoxid-gemischen |
| US5066750A (en) * | 1989-01-17 | 1991-11-19 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
| US5024785A (en) * | 1989-01-17 | 1991-06-18 | The Dow Chemical Company | Liquid crystal/rigid rodlike polymer modified epoxy/vinyl ester resins |
| US4962163A (en) * | 1989-01-17 | 1990-10-09 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
| US5078910A (en) * | 1989-06-20 | 1992-01-07 | Edison Polymer Innovation Corp. | Polimerization of liquid crystalline monomers |
| US5077380A (en) | 1989-07-17 | 1991-12-31 | The Dow Chemical Company | Mesogenic cyanate functional maleimides and thermosets thereof |
| ATE177079T1 (de) * | 1989-07-17 | 1999-03-15 | Dow Chemical Co | Mesogene cyanatgruppen enthaltende maleimide |
| US5206321A (en) * | 1991-10-03 | 1993-04-27 | The Dow Chemical Company | Polycyanates containing mesogenic moieties as lateral substituents |
-
1992
- 1992-02-03 US US07/830,105 patent/US5248360A/en not_active Expired - Fee Related
-
1993
- 1993-07-15 WO PCT/US1993/006691 patent/WO1995002631A1/en not_active Ceased
- 1993-07-15 DE DE69318858T patent/DE69318858T2/de not_active Expired - Fee Related
- 1993-07-15 EP EP93917218A patent/EP0708796B1/en not_active Expired - Lifetime
- 1993-07-15 JP JP50450695A patent/JP3399958B2/ja not_active Expired - Fee Related
- 1993-07-15 AU AU46804/93A patent/AU4680493A/en not_active Abandoned
- 1993-07-15 ES ES93917218T patent/ES2116461T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09500158A (ja) | 1997-01-07 |
| DE69318858T2 (de) | 1998-10-08 |
| AU4680493A (en) | 1995-02-13 |
| DE69318858D1 (de) | 1998-07-02 |
| EP0708796A1 (en) | 1996-05-01 |
| WO1995002631A1 (en) | 1995-01-26 |
| US5248360A (en) | 1993-09-28 |
| JP3399958B2 (ja) | 2003-04-28 |
| EP0708796B1 (en) | 1998-05-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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