ES2126290T3 - Procedimiento para la preparacion de sales de acido carboxilico y catalizadores utiles para dichos procedimientos. - Google Patents
Procedimiento para la preparacion de sales de acido carboxilico y catalizadores utiles para dichos procedimientos.Info
- Publication number
- ES2126290T3 ES2126290T3 ES95922134T ES95922134T ES2126290T3 ES 2126290 T3 ES2126290 T3 ES 2126290T3 ES 95922134 T ES95922134 T ES 95922134T ES 95922134 T ES95922134 T ES 95922134T ES 2126290 T3 ES2126290 T3 ES 2126290T3
- Authority
- ES
- Spain
- Prior art keywords
- carboxylic acid
- procedures
- salts
- procedure
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0217—Pretreatment of the substrate before coating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE PRESENTA UN PROCESO PARA MANUFACTURAR UNA SAL DE ACIDO CARBOXILICO EN EL QUE UNA SOLUCION ACUOSA DE UN ALCOHOL PRIMARIO SE PONE EN CONTACTO CON UN HIDROXIDO DE BASE EN LA PRESENCIA DE UNA CANTIDAD EFECTIVA DE UN CATALIZADOR QUE CONSTA ESENCIALMENTE DE UN SOPORTE RESISTENTE AL ALCALI, DE ENTRE UN 0.5 Y UN 10% DE SU PESO, BASADO SOBRE EL PESO TOTAL DEL CATALIZADOR, DE UN METAL DE ANCLAJE SELECCIONADO ENTRE EL GRUPO QUE CONSTA DE PLATINO, PALADIO, RUTENIO Y ORO, Y ENTRE UN 1 Y UN 50% DE SU PESO, EN BASE AL PESO TOTAL DEL CATALIZADOR, DE UN ELEMENTO SELECCIONADO ENTRE EL GRUPO QUE CONSTA DE COBRE, COBALTO, NIQUEL Y CADMIO COMBINADOS CON EL METAL DE ANCLAJE.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26971894A | 1994-07-01 | 1994-07-01 | |
| US08/407,723 US5689000A (en) | 1994-07-01 | 1995-03-20 | Process for preparing carboxylic acid salts and catalysts useful in such process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2126290T3 true ES2126290T3 (es) | 1999-03-16 |
Family
ID=26953850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95922134T Expired - Lifetime ES2126290T3 (es) | 1994-07-01 | 1995-05-26 | Procedimiento para la preparacion de sales de acido carboxilico y catalizadores utiles para dichos procedimientos. |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US5689000A (es) |
| EP (1) | EP0768917B1 (es) |
| JP (1) | JPH10501728A (es) |
| KR (1) | KR970703816A (es) |
| CN (1) | CN1091649C (es) |
| AT (1) | ATE173956T1 (es) |
| AU (1) | AU711349B2 (es) |
| BR (1) | BR9508163A (es) |
| CA (1) | CA2193989C (es) |
| DE (1) | DE69506412T2 (es) |
| DK (1) | DK0768917T3 (es) |
| ES (1) | ES2126290T3 (es) |
| GR (1) | GR3029541T3 (es) |
| HU (1) | HUT76751A (es) |
| IL (1) | IL114412A (es) |
| MX (1) | MX206593B (es) |
| MY (1) | MY112727A (es) |
| NZ (1) | NZ288027A (es) |
| PL (1) | PL179923B1 (es) |
| RU (1) | RU2157727C2 (es) |
| TW (1) | TW449502B (es) |
| UA (1) | UA46736C2 (es) |
| WO (1) | WO1996001146A1 (es) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054838C (zh) * | 1993-04-12 | 2000-07-26 | 孟山都公司 | 氨基羧酸盐的制备方法 |
| US5916840A (en) * | 1994-07-01 | 1999-06-29 | Monsanto Company | Process for preparing carboxylic acid salts and catalysts useful in such process |
| AU714351B2 (en) * | 1996-09-26 | 1999-12-23 | Akzo Nobel N.V. | Catalysts for dhydrogenation of amino alcohols to amino alcohols to amino carbosylic acids or of ethylene glycol (derivatives) to oxycarboxylic acids, method for their production and their use |
| DE19644107A1 (de) * | 1996-10-31 | 1998-05-07 | Basf Ag | Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen |
| US5948724A (en) * | 1997-10-28 | 1999-09-07 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate |
| US6232494B1 (en) | 1998-02-12 | 2001-05-15 | Monsanto Company | Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine |
| CN1210283C (zh) * | 1998-02-12 | 2005-07-13 | 孟山都技术有限责任公司 | 通过氧化n-取代的草甘膦制备草甘膦的方法 |
| US6417133B1 (en) * | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| ITTO980249A1 (it) * | 1998-03-23 | 1999-09-23 | Finchimica Srl | Procedimento per la preparazione di sali di acidi carbossilici |
| IES980552A2 (en) | 1998-07-09 | 1999-08-11 | Agritech Chemical Ltd | Improved process for preparing N-phosphonomethyl iminodiacetic acid |
| AR043078A1 (es) * | 1998-09-14 | 2005-07-20 | Dow Agrosciences Llc | Procesos para preparar acidos carboxilicos |
| KR20020009601A (ko) | 1999-05-03 | 2002-02-01 | 추후보정 | 일차 알코올로부터 카르복실산 염들의 제조방법 |
| US6414188B1 (en) * | 1999-07-05 | 2002-07-02 | Atanor S.A. | Method of preparing amino-, imino-, and nitrilocarboxylic acids and silver-promoted copper catalyst for use in said method |
| KR20020073147A (ko) | 1999-12-21 | 2002-09-19 | 몬산토 테크놀로지 엘엘씨 | 탄소-지지된, 귀금속-함유 촉매의 존재하에 보충적촉진제의 액상 산화 반응에서의 용도 |
| US20020038051A1 (en) * | 2000-02-18 | 2002-03-28 | Degussa-Huls Ag | Raney copper |
| EP1125634B1 (de) | 2000-02-18 | 2010-12-08 | Evonik Degussa GmbH | Geformter Festbettraney-Kupferkatalysator |
| DE50111760D1 (de) * | 2000-02-18 | 2007-02-15 | Degussa | Verfahren zur Herstellung von Carbonsäuren durch Dehydrierung von Alkoholen |
| US6376708B1 (en) * | 2000-04-11 | 2002-04-23 | Monsanto Technology Llc | Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
| CN100354256C (zh) | 2000-05-15 | 2007-12-12 | 孟山都技术有限责任公司 | 以单乙醇胺为原料制备亚氨基二乙酸化合物 |
| AR038654A1 (es) | 2000-05-22 | 2005-01-26 | Monsanto Technology Llc | Sistemas de reaccion para producir compuestos de n-(fosfonometil) glicina |
| ES2227249T3 (es) | 2000-07-03 | 2005-04-01 | Shell Internationale Research Maatschappij B.V. | Catalizador y procedimiento de preparacion de hidrocarburos. |
| CN100393683C (zh) * | 2000-08-18 | 2008-06-11 | 因维斯塔技术有限公司 | 选择性氧化用金催化剂 |
| EP1401763B2 (en) * | 2001-07-03 | 2010-02-10 | Facultés Universitaires Notre-Dame de la Paix | Catalyst supports and carbon nanotubes produced thereon |
| MX244781B (es) | 2001-10-18 | 2007-04-03 | Monsanto Technology Llc | Procedimiento y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico. |
| US7196033B2 (en) | 2001-12-14 | 2007-03-27 | Huntsman Petrochemical Corporation | Advances in amination catalysis |
| DE10161674A1 (de) * | 2001-12-14 | 2003-06-26 | Basf Ag | Katalysatoren zur Herstellung von Carbonsäuresalzen |
| US7390920B2 (en) * | 2002-02-14 | 2008-06-24 | Monsanto Technology Llc | Oxidation catalyst and process |
| MX261990B (es) * | 2002-02-14 | 2008-11-07 | Monsanto Technology Llc | Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo. |
| WO2004035466A1 (en) * | 2002-10-18 | 2004-04-29 | Monsanto Technology Llc | Use of metal supported copper catalysts for reforming alcohols |
| US6992039B2 (en) * | 2003-03-13 | 2006-01-31 | General Motors Corporation | Method for making monodispersed noble metal nanoparticles supported on oxide substrates |
| US7375053B2 (en) * | 2003-04-07 | 2008-05-20 | W. R. Grace & Co.- Conn. | Nickel and cobalt plated sponge catalysts |
| CN102276644B (zh) | 2003-08-14 | 2014-09-03 | 孟山都技术公司 | 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途 |
| EP1664068A2 (en) * | 2003-08-22 | 2006-06-07 | Monsanto Technology, LLC | Process for the preparation of n-phosphono-methylglycine and derivatives thereof |
| DE10349095A1 (de) | 2003-10-17 | 2005-05-19 | Basf Ag | Verfahren zur Herstellung von Aminen |
| US20050100493A1 (en) * | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
| US20050100494A1 (en) | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
| US20050232839A1 (en) | 2004-04-15 | 2005-10-20 | George Yaluris | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| US7304011B2 (en) * | 2004-04-15 | 2007-12-04 | W.R. Grace & Co. -Conn. | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| AR051926A1 (es) * | 2004-09-15 | 2007-02-21 | Monsanto Technology Llc | Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma |
| JP2006142137A (ja) * | 2004-11-16 | 2006-06-08 | Nissan Motor Co Ltd | 排ガス浄化用触媒及びその製造方法 |
| BRPI0608355B1 (pt) | 2005-02-17 | 2016-05-24 | Monsanto Technology Llc | processo para oxidação de ácido n-(fosfonometil) iminodiacético ou seu sal e catalisador de oxidação |
| EP1888231A1 (en) | 2005-04-27 | 2008-02-20 | W.R. Grace & Co.-Conn. | Compositions and processes for reducing nox emissions during fluid catalytic cracking |
| DE102005041532A1 (de) | 2005-08-31 | 2007-03-01 | Basf Ag | Verfahren zur Herstellung von Aminen |
| AU2007217054A1 (en) * | 2006-02-17 | 2007-08-30 | Monsanto Technology Llc | Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts |
| CN101529075B (zh) * | 2006-06-13 | 2012-07-18 | 孟山都技术公司 | 重整醇动力系统 |
| US20090075156A1 (en) | 2007-09-13 | 2009-03-19 | Velocys Inc. | Porous Electrolessly Deposited Coatings |
| US20090263300A1 (en) * | 2008-04-16 | 2009-10-22 | Yang Xiaolin D | Stabilized Iridium and Ruthenium Catalysts |
| US20090264283A1 (en) * | 2008-04-16 | 2009-10-22 | Basf Catalysts Llc | Stabilized Iridium and Ruthenium Catalysts |
| US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
| US20110011772A1 (en) * | 2009-07-15 | 2011-01-20 | Stephen Raymond Schmidt | Nickel and Cobalt Plated Sponge Catalysts |
| AU2011217344B2 (en) | 2010-02-19 | 2016-03-24 | Basf Se | Method for the production of ether carboxylates |
| AU2011217307B2 (en) | 2010-02-19 | 2016-07-28 | Basf Se | Method for the production of ether carboxylates |
| US8309759B2 (en) | 2010-02-19 | 2012-11-13 | Basf Se | Preparing ether carboxylates |
| US9062278B2 (en) | 2010-02-19 | 2015-06-23 | Basf Se | Preparing ether carboxylates |
| US9770705B2 (en) | 2010-06-11 | 2017-09-26 | Rennovia Inc. | Oxidation catalysts |
| RU2452565C1 (ru) * | 2011-02-16 | 2012-06-10 | Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН | Катализатор, способ его приготовления и способ получения динатриевой соли иминодиуксусной кислоты |
| WO2013149112A1 (en) | 2012-03-30 | 2013-10-03 | Monsanto Technology Llc | Alcohol reforming system for internal combustion engine |
| WO2013149118A1 (en) | 2012-03-30 | 2013-10-03 | Monsanto Technology Llc | Alcohol reformer for reforming alcohol to mixture of gas including hydrogen |
| CN111153788A (zh) * | 2018-11-08 | 2020-05-15 | 中国科学院大连化学物理研究所 | 一种有机醇脱氢反应制备有机酸的方法、有机醇脱氢反应热力学可控调节的方法 |
| WO2020198716A1 (en) * | 2019-03-27 | 2020-10-01 | Kemin Industries, Inc. | Methods for preparing metal carboxylates in one-pot reaction |
| EP4277890B1 (en) * | 2021-01-15 | 2025-10-08 | Basf Se | Process for manufacturing carboxylic acids |
| CN116144009B (zh) * | 2022-12-22 | 2025-02-11 | 上海发凯化工有限公司 | 一种聚乙二醇二羧酸的制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2384817A (en) * | 1942-09-05 | 1945-09-18 | Carbide & Carbon Chem Corp | Catalytic alkaline oxidation of alcohols |
| DE1262264B (de) * | 1964-04-10 | 1968-03-07 | Dynamit Nobel Ag | Verfahren zur Herstellung von Alkalisalzen der Acrylsaeure durch Oxydation von Allylalkohol |
| US4321285A (en) * | 1974-10-04 | 1982-03-23 | Surface Technology, Inc. | Electroless plating |
| US4547324A (en) * | 1982-07-29 | 1985-10-15 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| GB2148287B (en) * | 1983-10-05 | 1987-04-15 | Nippon Catalytic Chem Ind | Preparation of aminocarboxylic acid salts from amino alcohols |
| JPS61101250A (ja) * | 1984-10-24 | 1986-05-20 | Idemitsu Kosan Co Ltd | 金属担持粒子の製造法 |
| US5068404A (en) * | 1984-12-28 | 1991-11-26 | Monsanto Company | Thermal dealkylation of N-alkyl N-phosphonomethylglycine |
| US4810426A (en) * | 1986-01-28 | 1989-03-07 | Monsanto Company | Process for making glyphosate from n-phosphonomethyl-2-oxazolidone |
| DE3721285A1 (de) * | 1987-06-27 | 1989-01-12 | Hoechst Ag | Verfahren zur herstellung von n-phosphonomethylglycin |
| KR970009569B1 (ko) * | 1990-11-27 | 1997-06-14 | 닛뽕 쇼꾸 바이가가꾸 고오교 가부시끼가이샤 | 아미노카르복실산염의 제조방법 |
| USH1193H (en) * | 1991-08-12 | 1993-06-01 | The United States Of America As Represented By The Secretary Of The Army | Method of producing copper alloys with manganese and selenium to improve thermal stability |
| JPH067679A (ja) * | 1992-06-25 | 1994-01-18 | Tanaka Kikinzoku Kogyo Kk | りん酸型燃料電池用白金合金触媒の製造方法 |
| US5292936A (en) * | 1993-04-12 | 1994-03-08 | Monsanto Company | Process to prepare amino carboxylic acid salts |
-
1995
- 1995-03-20 US US08/407,723 patent/US5689000A/en not_active Expired - Lifetime
- 1995-05-26 MX MX9700060A patent/MX206593B/es unknown
- 1995-05-26 BR BR9508163A patent/BR9508163A/pt not_active IP Right Cessation
- 1995-05-26 JP JP7523724A patent/JPH10501728A/ja not_active Ceased
- 1995-05-26 UA UA97010326A patent/UA46736C2/uk unknown
- 1995-05-26 NZ NZ288027A patent/NZ288027A/en unknown
- 1995-05-26 AU AU26926/95A patent/AU711349B2/en not_active Ceased
- 1995-05-26 CA CA002193989A patent/CA2193989C/en not_active Expired - Fee Related
- 1995-05-26 EP EP95922134A patent/EP0768917B1/en not_active Expired - Lifetime
- 1995-05-26 RU RU97101492/04A patent/RU2157727C2/ru active
- 1995-05-26 ES ES95922134T patent/ES2126290T3/es not_active Expired - Lifetime
- 1995-05-26 HU HU9603630A patent/HUT76751A/hu unknown
- 1995-05-26 PL PL95317849A patent/PL179923B1/pl unknown
- 1995-05-26 DK DK95922134T patent/DK0768917T3/da active
- 1995-05-26 DE DE69506412T patent/DE69506412T2/de not_active Expired - Lifetime
- 1995-05-26 WO PCT/US1995/006754 patent/WO1996001146A1/en not_active Ceased
- 1995-05-26 CN CN95194794A patent/CN1091649C/zh not_active Expired - Fee Related
- 1995-05-26 AT AT95922134T patent/ATE173956T1/de not_active IP Right Cessation
- 1995-05-27 TW TW084105374A patent/TW449502B/zh not_active IP Right Cessation
- 1995-05-31 US US08/454,757 patent/US5627125A/en not_active Expired - Lifetime
- 1995-06-28 MY MYPI95001787A patent/MY112727A/en unknown
- 1995-06-30 IL IL11441295A patent/IL114412A/xx not_active IP Right Cessation
-
1996
- 1996-12-31 KR KR19967007600A patent/KR970703816A/ko not_active Abandoned
-
1999
- 1999-03-01 GR GR990400636T patent/GR3029541T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10501728A (ja) | 1998-02-17 |
| AU2692695A (en) | 1996-01-25 |
| CN1091649C (zh) | 2002-10-02 |
| ATE173956T1 (de) | 1998-12-15 |
| RU2157727C2 (ru) | 2000-10-20 |
| CA2193989C (en) | 2006-11-14 |
| DE69506412T2 (de) | 1999-06-24 |
| EP0768917A1 (en) | 1997-04-23 |
| WO1996001146A1 (en) | 1996-01-18 |
| BR9508163A (pt) | 1997-12-23 |
| UA46736C2 (uk) | 2002-06-17 |
| PL317849A1 (en) | 1997-04-28 |
| HU9603630D0 (en) | 1997-02-28 |
| HUT76751A (en) | 1997-11-28 |
| AU711349B2 (en) | 1999-10-14 |
| NZ288027A (en) | 1998-11-25 |
| IL114412A (en) | 1999-06-20 |
| TW449502B (en) | 2001-08-11 |
| PL179923B1 (pl) | 2000-11-30 |
| DK0768917T3 (da) | 1999-08-16 |
| IL114412A0 (en) | 1995-10-31 |
| GR3029541T3 (en) | 1999-06-30 |
| CA2193989A1 (en) | 1996-01-18 |
| EP0768917B1 (en) | 1998-12-02 |
| MY112727A (en) | 2001-08-30 |
| KR970703816A (es) | 1997-08-09 |
| MX9700060A (es) | 1997-04-30 |
| CN1156419A (zh) | 1997-08-06 |
| US5627125A (en) | 1997-05-06 |
| US5689000A (en) | 1997-11-18 |
| DE69506412D1 (de) | 1999-01-14 |
| MX206593B (es) | 2002-02-08 |
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