ES2128149T3 - Composicion que comprende una dispersion de particulas en un medio no acuoso. - Google Patents

Composicion que comprende una dispersion de particulas en un medio no acuoso.

Info

Publication number
ES2128149T3
ES2128149T3 ES96401312T ES96401312T ES2128149T3 ES 2128149 T3 ES2128149 T3 ES 2128149T3 ES 96401312 T ES96401312 T ES 96401312T ES 96401312 T ES96401312 T ES 96401312T ES 2128149 T3 ES2128149 T3 ES 2128149T3
Authority
ES
Spain
Prior art keywords
medium
copolymers
polyether
graft
alcohols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96401312T
Other languages
English (en)
Inventor
Nathalie Mougin
Jean Mondet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Application granted granted Critical
Publication of ES2128149T3 publication Critical patent/ES2128149T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/044Suspensions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/893Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90Block copolymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/91Graft copolymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/08Anti-ageing preparations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y5/00Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00Macromolecular compounds obtained by polymerising monomers on to block polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/413Nanosized, i.e. having sizes below 100 nm
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/70Nanostructure
    • Y10S977/788Of specified organic or carbon-based composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/84Manufacture, treatment, or detection of nanostructure
    • Y10S977/895Manufacture, treatment, or detection of nanostructure having step or means utilizing chemical property
    • Y10S977/896Chemical synthesis, e.g. chemical bonding or breaking
    • Y10S977/897Polymerization
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/902Specified use of nanostructure
    • Y10S977/904Specified use of nanostructure for medical, immunological, body treatment, or diagnosis
    • Y10S977/926Topical chemical, e.g. cosmetic or sunscreen

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Nanotechnology (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biophysics (AREA)
  • Biotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicinal Preparation (AREA)

Abstract

LA INVENCION SE REFIERE A LA UTILIZACION DE UNA DISPERSION DE PARTICULAS DE POLIMERO ESTABILIZADO EN SUPERFICIE EN UN MEDIO NO ACUOSO, EN UNA COMPOSICION COSMETICA, HIGIENICA O FARMACEUTICA. LA INVENCION SE REFIERE TAMBIEN A LA COMPOSICION QUE COMPRENDE DICHA COMPOSICION DE PARTICULAS DE POLIMEROS.
ES96401312T 1995-06-21 1996-06-17 Composicion que comprende una dispersion de particulas en un medio no acuoso. Expired - Lifetime ES2128149T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9507428A FR2735689B1 (fr) 1995-06-21 1995-06-21 Composition comprenant une dispersion de particules de polymeres dans un milieu non aqueux

Publications (1)

Publication Number Publication Date
ES2128149T3 true ES2128149T3 (es) 1999-05-01

Family

ID=9480227

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96401312T Expired - Lifetime ES2128149T3 (es) 1995-06-21 1996-06-17 Composicion que comprende una dispersion de particulas en un medio no acuoso.

Country Status (9)

Country Link
US (1) US5851517A (es)
EP (1) EP0749747B1 (es)
JP (2) JP3225967B2 (es)
AT (1) ATE174502T1 (es)
CA (1) CA2197496C (es)
DE (1) DE69601147T2 (es)
ES (1) ES2128149T3 (es)
FR (1) FR2735689B1 (es)
WO (1) WO1997000663A1 (es)

Families Citing this family (207)

* Cited by examiner, † Cited by third party
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ES2110857T3 (es) * 1995-06-21 1998-02-16 Oreal Composicion cosmetica que comprende una dispersion de particulas de polimero.
EP0875234A1 (fr) * 1997-04-28 1998-11-04 L'oreal Composition et produit de maquillage des lèvres à base de polymère filmogène
FR2762509B1 (fr) 1997-04-28 2003-03-07 Oreal Composition cosmetique ou dermatologique comprenant un polymere filmogene, procede de maquillage et de traitement non therapeutique
FR2776515B1 (fr) 1998-03-26 2001-02-09 Oreal Emulsion e/h, composition comprenant une telle emulsion et utilisation en cosmetique, pharmacie ou hygiene
FR2776514B1 (fr) 1998-03-26 2001-03-09 Oreal Emulsion e/h, composition comprenant une telle emulsion et utilisation en cosmetique, pharmacie ou hygiene
FR2783415B1 (fr) * 1998-09-18 2000-11-03 Oreal Composition cosmetique sous forme d'emulsion comprenant une dispersion de particules de polymere stabilisees en surface dans une phase grasse liquide
FR2785530B1 (fr) * 1998-11-09 2000-12-15 Oreal Composition cosmetique sans transfert comprenant une dispersion de particules de polymere et un agent rheologique particulier
FR2785529A1 (fr) * 1998-11-09 2000-05-12 Oreal Composition cosmetique sans transfert comprenant une dispersion de particules de polymere dans une phase grasse liquide
FR2787998B1 (fr) 1999-01-06 2001-02-09 Oreal Composition cosmetique comprenant un copolymere styrene/ acrylate et une phase grasse
ATE338525T1 (de) * 1999-03-25 2006-09-15 3M Innovative Properties Co Nicht stechendes überzugsmittel
FR2794970B1 (fr) * 1999-06-21 2001-08-03 Oreal Mascara comprenant un polymere disperse dans une phase grasse liquide
US6254878B1 (en) 1999-07-01 2001-07-03 E. I. Du Pont De Nemours And Company Nail polish compositions containing acrylic polymers
FR2796271B1 (fr) 1999-07-15 2002-01-11 Oreal Composition sans cire structuree sous forme rigide par un polymere
FR2796272B1 (fr) 1999-07-15 2003-09-19 Oreal Composition sans cire structuree sous forme rigide par un polymere
FR2796269B1 (fr) * 1999-07-16 2002-01-11 Oreal Composition cosmetique contenant un gel organosoluble reticule et un melange de deux solvants volatils et non-volatils
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FR2810238B1 (fr) 2000-06-15 2002-07-19 Oreal Composition cosmetique filmogene
FR2810239B1 (fr) * 2000-06-15 2002-12-20 Oreal Composition cosmetique filmogene
FR2810237B1 (fr) 2000-06-15 2002-07-26 Oreal Composition cosmetique filmogene
FR2815847B1 (fr) * 2000-10-27 2002-12-13 Oreal Composition cosmetique comprenant des fibres et une cire
US6964773B1 (en) * 2000-11-22 2005-11-15 L'oreal S.A. Transfer resistant anhydrous cosmetic composition
FR2816832B1 (fr) * 2000-11-23 2003-09-26 Oreal Composition cosmetique comprenant des particules interferentielles et une matiere colorante
US8080257B2 (en) 2000-12-12 2011-12-20 L'oreal S.A. Cosmetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using
FR2817743B1 (fr) * 2000-12-12 2003-01-10 Oreal Utilisation d'un polymere pour obtenir un maquillage rapide des matieres keratiniques
WO2002047623A1 (en) 2000-12-12 2002-06-20 L'oreal Sa Composition comprising at least one heteropolymer and at least one inert filler and methods for use
US7276547B2 (en) 2000-12-12 2007-10-02 L'oreal S.A. Compositions comprising heteropolymers and at least one oil-soluble polymers chosen from alkyl celluloses and alkylated guar gums
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WO2002047624A1 (en) 2000-12-12 2002-06-20 L'oreal Sa Cosmetic compositions containing at least one heteropolymer and at least one gelling agent and methods of using the same
US6835399B2 (en) 2000-12-12 2004-12-28 L'ORéAL S.A. Cosmetic composition comprising a polymer blend
US6881400B2 (en) 2000-12-12 2005-04-19 L'oreal S.A. Use of at least one polyamide polymer in a mascara composition for increasing the adhesion of and/or expressly loading make-up deposited on eyelashes
DE60132805T2 (de) 2000-12-12 2009-01-29 L'oreal Kosmetische zusammensetzung mit einem polymergemisch
FR2817739B1 (fr) 2000-12-12 2005-01-07 Oreal Composition cosmetique coloree transparente ou translucide
DE10063090A1 (de) * 2000-12-18 2002-06-20 Henkel Kgaa Nanoskaliges ZnO in Hygiene-Produkten
DE10063092A1 (de) * 2000-12-18 2002-06-20 Henkel Kgaa Nanoskalige Materialien in Hygiene-Produkten
FR2819399B1 (fr) 2001-01-17 2003-02-21 Oreal Composition cosmetique contenant un polymere et une huile fluoree
US7025953B2 (en) 2001-01-17 2006-04-11 L'oreal S.A. Nail polish composition comprising a polymer
FR2819412B1 (fr) * 2001-01-18 2003-02-21 Oreal Composition cosmetique irisee et ses utilisations
US6979440B2 (en) 2001-01-29 2005-12-27 Salvona, Llc Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric
US6491902B2 (en) 2001-01-29 2002-12-10 Salvona Llc Controlled delivery system for hair care products
US6726900B2 (en) * 2001-05-18 2004-04-27 Revlon Consumer Products Corporation Long wearing composition for making up eyes, skin, and lips
FR2826260B1 (fr) * 2001-06-22 2003-09-12 Oreal Composition cosmetique filmogene
US7138110B2 (en) * 2001-07-16 2006-11-21 L'oreal S.A. Mascara comprising solid particles
US7211244B2 (en) * 2001-07-16 2007-05-01 L'oreal, S.A. Mascara comprising solid particles
FR2827163B1 (fr) 2001-07-16 2005-07-22 Oreal Mascara comprenant une dispersion de particules
FR2827164A1 (fr) * 2001-07-16 2003-01-17 Oreal Mascara comprenant une dispersion de particules
US7029662B2 (en) 2001-07-16 2006-04-18 L'oreal Mascara comprising solid particles
US7189388B2 (en) * 2001-07-16 2007-03-13 L'oreal S.A. Mascara comprising solid particles
US6458390B1 (en) 2001-07-27 2002-10-01 Revlon Consumer Products Corporation Long wearing makeup compositions
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JP2003286142A (ja) * 2002-03-29 2003-10-07 Mitsubishi Chemicals Corp 毛髪化粧料用重合体組成物およびそれを用いた毛髪化粧料
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JP4039829B2 (ja) * 2001-09-13 2008-01-30 三菱化学株式会社 化粧料用樹脂組成物およびそれを用いた化粧料
US6716420B2 (en) 2001-10-05 2004-04-06 L′Oreal Methods of use and of making a mascara comprising at least one coloring agent and at least one heteropolymer
FR2830751B1 (fr) * 2001-10-17 2007-01-19 Oreal Composition cosmetique filmogene
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JP2005532994A (ja) * 2002-01-24 2005-11-04 ロレアル 半結晶性重合体およびエステルを含む組成物
US20050008598A1 (en) 2003-07-11 2005-01-13 Shaoxiang Lu Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent
US7008629B2 (en) 2002-07-22 2006-03-07 L'ORéAL S.A. Compositions comprising at least one heteropolymer and fibers, and methods of using the same
US20060128578A9 (en) * 2002-09-20 2006-06-15 Nathalie Jager Lezer Cosmetic composition comprising rigid fibres and at least one compound chosen from film-forming polymers and waxes
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US8728500B2 (en) 2002-12-17 2014-05-20 L'oreal Composition containing a polyorganosiloxane polymer, a thickening agent and at least one volatile alcohol
US20040234564A1 (en) * 2003-02-25 2004-11-25 Xavier Blin Two-coat makeup product, its uses, and makeup kit comprising the product
US20040234612A1 (en) * 2003-02-25 2004-11-25 Xavier Blin Cosmetic composition comprising at least one polymer particle dispersed in at least one liquid fatty phase and at least one compound plasticizing the polymer
US20040228890A1 (en) * 2003-02-25 2004-11-18 Xavier Blin Two-coat cosmetic product, its uses, and makeup kit including the product
FR2851468B1 (fr) * 2003-02-25 2008-07-11 Oreal Composition cosmetique comprenant une dispersion de particules de polymere et un compose plastifiant le polymere
ITMI20030385A1 (it) * 2003-03-04 2004-09-05 Intercos Italia S P A Ora Intercos S P A Composizione cosmetica comprendente poliisoprene.
FR2857255A1 (fr) * 2003-04-11 2005-01-14 Oreal Composition cosmetique presentant un profil thermique particulier
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US7253249B2 (en) * 2003-04-22 2007-08-07 Arizona Chemical Company Ester-terminated poly(ester-amide) in personal care products
FR2855409B1 (fr) * 2003-05-28 2007-05-25 Oreal Composition cosmetique pour le maquillage et/ou le soin de la peau, notamment du visage.
US20050008667A1 (en) * 2003-05-28 2005-01-13 L'oreal Cosmetic compositions for making up and/or caring for skin
FR2863491A1 (fr) * 2003-12-12 2005-06-17 Oreal Composition cosmetique comprenant un polymere et un polymere et un plastifiant
WO2005058257A1 (fr) * 2003-12-12 2005-06-30 L'oreal Composition cosmetique comprenant un polymere et un plastifiant
US20050180936A1 (en) * 2004-01-06 2005-08-18 Karl Pays Keratin fiber make-up composition with long-term stability
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WO1997000663A1 (fr) 1997-01-09
DE69601147D1 (de) 1999-01-28
EP0749747B1 (fr) 1998-12-16
DE69601147T2 (de) 1999-06-02
JP2000044426A (ja) 2000-02-15
JP3225967B2 (ja) 2001-11-05
US5851517A (en) 1998-12-22
EP0749747A1 (fr) 1996-12-27
FR2735689B1 (fr) 1997-08-01
CA2197496A1 (fr) 1997-01-09
ATE174502T1 (de) 1999-01-15
CA2197496C (fr) 2002-08-20
FR2735689A1 (fr) 1996-12-27

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