ES2128606T3 - Aditivo detergente dispersante para aceites lubricantes de motores de combustion interna y procedimiento para la preparacion del mismo. - Google Patents
Aditivo detergente dispersante para aceites lubricantes de motores de combustion interna y procedimiento para la preparacion del mismo.Info
- Publication number
- ES2128606T3 ES2128606T3 ES95105672T ES95105672T ES2128606T3 ES 2128606 T3 ES2128606 T3 ES 2128606T3 ES 95105672 T ES95105672 T ES 95105672T ES 95105672 T ES95105672 T ES 95105672T ES 2128606 T3 ES2128606 T3 ES 2128606T3
- Authority
- ES
- Spain
- Prior art keywords
- polyisobutylene
- molecular weight
- anhydride
- internal combustion
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000654 additive Substances 0.000 title abstract 3
- 230000000996 additive effect Effects 0.000 title abstract 3
- 238000002485 combustion reaction Methods 0.000 title abstract 2
- 239000010687 lubricating oil Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000003599 detergent Substances 0.000 title 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 7
- 150000008064 anhydrides Chemical class 0.000 abstract 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/56—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/86—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of 30 or more atoms
- C10M129/95—Esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol-fuelled engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
Abstract
UN ADITIVO PARA ACEITES LUBRICANTES PARA MOTORES DE COMBUSTION INTERNA QUE CONTIENE IMIDA-Y/O ETER Y/O ETER-AMIDA, DERIVADOS DE LA REACCION PRODUCTO DE UN POLISOBUTILENO INSATURADO Y ALGUNOS ACIDOS REACTIVOS DICARBOXILICOS INSATURADOS Y/O SUS ANHIDRIDOS CONTENIENDO LA REACCION PRODUCTO DE UN POLISOBUTILENO Y DE UNA MEDIA MOLECULAR DE PESO DE 800 - 30 000 Y UN ACIDO REACTIVO DCARBOXILICO INSATURADO Y/O SUS ANHIDRIDOS PREFERIBLEMENTE ANHÑIDRIDOS MALEICOS QUE CONTENGAN 1.6 - 6.0 SA DERIVADOS POR CADENA DE POLISOBUTILENO O LA MEDIA QUE TENGA UNA CONCENTRACION MOLECULAR MAYOR QUE UNA SA QUE CONTENGA UN POLIMERO FORMADO POR UNO O MAS REACTIVOS, UN COMONOMERO DE BAJO PESO MOLECULAR MENOR DE 500, QUE CONTENGA UN ENLACE DOBLE OLEFINICO O DE UNA MEZCLA DE DICHOS COMONOMEROS Y DE UN ACIDO DICARBOXILICO REACTIVO Y/O SUS ANHIDRIDOS, PREFERIBLEMENTE ANHIDRIDOS MALEICOS QUE USEN EL RATIO MOLAR 1.2 -5.5:0.1 -3.5: 1 = MAH : COMONOMERO : POLISOBUTILENO, Y EN EL CUAL EL ENSANCHAMIENTO DE LA DISTRIBUCION DEL PESO MOLECULAR SEA MENOR DEL 70 PORCIENTO, REFERIDO ALPOLISOBUTILENO DE COMIENZO, MIENTRAS QUE LOS GRUPOS SA DE COPOLIMEROS UNIDOS AL POLISOBUTILENO SON REACCIONADOS, EN UN RATIO 0.7 - 5.5, CON COMPUESTOS QUE CONTENGAN AL MENOS AMINA BIFUNCIONAL Y/O GRUPOS HIDROXILOS. EL INVENTO EXPONE EL PROCESO DE PREPARACION DEL ADITIVO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU9401100A HU214008B (hu) | 1994-04-15 | 1994-04-15 | Detergens-diszpergens adalékok belső égésű motorok kenőolajaihoz és előállítási eljárásuk |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2128606T3 true ES2128606T3 (es) | 1999-05-16 |
Family
ID=10985081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95105672T Expired - Lifetime ES2128606T3 (es) | 1994-04-15 | 1995-04-13 | Aditivo detergente dispersante para aceites lubricantes de motores de combustion interna y procedimiento para la preparacion del mismo. |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0677572B1 (es) |
| AT (1) | ATE175439T1 (es) |
| CZ (1) | CZ292648B6 (es) |
| DE (1) | DE69507068T2 (es) |
| DK (1) | DK0677572T3 (es) |
| ES (1) | ES2128606T3 (es) |
| GR (1) | GR3029741T3 (es) |
| HU (1) | HU214008B (es) |
| PL (1) | PL180877B1 (es) |
| RO (1) | RO119551B1 (es) |
| RU (1) | RU2139921C1 (es) |
| SI (1) | SI0677572T1 (es) |
| SK (1) | SK281687B6 (es) |
| UA (1) | UA45337C2 (es) |
| WO (1) | WO1995028460A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69608159T2 (de) * | 1995-03-24 | 2001-01-11 | Ethyl Petroleum Additives Ltd., Bracknell | Nachbehandelte Dispergiermittel |
| EP0733696B1 (en) * | 1995-03-24 | 2002-10-30 | Ethyl Petroleum Additives Limited | Lubricating oil dispersants |
| HU213255B (en) * | 1995-09-25 | 1997-05-28 | Mol Magyar Olaj Es Gazipari Rt | Multiple- stage engineoil and lubricant composition and additive-pocket |
| CA2189918C (en) * | 1995-11-13 | 2005-01-25 | Richard Mark Scott | Dispersant additives |
| FI112796B (fi) * | 2000-04-14 | 2004-01-15 | Valtion Teknillinen | Menetelmä oligo-/polymeripihkahappoaimididendrimeerien valmistamiseksi ja niiden käyttö |
| RU2203930C1 (ru) * | 2001-10-30 | 2003-05-10 | Открытое акционерное общество "Ефремовский завод синтетического каучука" | Способ получения сукцинимидной присадки |
| US6906011B2 (en) * | 2001-11-09 | 2005-06-14 | Chevron Oronite Company Llc | Polymeric dispersants prepared from copolymers of low molecular weight polyisobutene and unsaturated acidic reagent |
| CN101284897B (zh) * | 2008-06-05 | 2010-06-02 | 上海交通大学 | 马来酸酐接枝聚异丁烯共聚物的溶剂热制备方法 |
| CN108730770A (zh) | 2017-04-13 | 2018-11-02 | 通用电气公司 | 用于油的防蜡剂以及用防蜡剂来减少油产生蜡沉积的方法 |
| CN114717037A (zh) * | 2021-01-06 | 2022-07-08 | 中国石油天然气股份有限公司 | 一种耐高温无灰分散剂的制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US440659A (en) * | 1890-11-18 | Darning-last | ||
| US161452A (en) * | 1875-03-30 | Improvement in rotary reversing and cut-off valves | ||
| US4036772A (en) * | 1975-03-03 | 1977-07-19 | The Lubrizol Corporation | Esters made from the reaction product of low molecular weight ethylenically unsaturated acylating agents and oxidized ethylene-propylene interpolymers |
| US4235731A (en) * | 1976-10-18 | 1980-11-25 | Shell Oil Company | Modified terpolymer dispersant - VI improver |
| US4160739A (en) * | 1977-12-05 | 1979-07-10 | Rohm And Haas Company | Polyolefinic copolymer additives for lubricants and fuels |
| US4234435A (en) * | 1979-02-23 | 1980-11-18 | The Lubrizol Corporation | Novel carboxylic acid acylating agents, derivatives thereof, concentrate and lubricant compositions containing the same, and processes for their preparation |
| CA1146944A (en) * | 1979-12-20 | 1983-05-24 | Peter J.N. Brown | Lubricant additives, their method of preparation and lubricants containing them |
| CA1175411A (en) * | 1981-06-29 | 1984-10-02 | Phillip W. Brewster | Haze-free polymer additives for fuels and lubricants |
| GB8329082D0 (en) * | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
| IN172215B (es) * | 1987-03-25 | 1993-05-08 | Lubrizol Corp | |
| GB8818711D0 (en) * | 1988-08-05 | 1988-09-07 | Shell Int Research | Lubricating oil dispersants |
| CA2015061A1 (en) * | 1989-05-30 | 1990-11-30 | Antonio Gutierrez | Multifunctional viscosity index modifier additives derived from polyamines containing one primary amino group and at least one secondary amino group |
| CN103717146B (zh) * | 2012-05-30 | 2016-01-13 | 奥林巴斯株式会社 | 超声波观测装置、超声波观测装置的动作方法 |
-
1994
- 1994-04-15 HU HU9401100A patent/HU214008B/hu not_active IP Right Cessation
-
1995
- 1995-04-13 WO PCT/HU1995/000008 patent/WO1995028460A1/en not_active Ceased
- 1995-04-13 RU RU96122492A patent/RU2139921C1/ru not_active IP Right Cessation
- 1995-04-13 RO RO96-01988A patent/RO119551B1/ro unknown
- 1995-04-13 SI SI9530234T patent/SI0677572T1/xx not_active IP Right Cessation
- 1995-04-13 ES ES95105672T patent/ES2128606T3/es not_active Expired - Lifetime
- 1995-04-13 UA UA96114351A patent/UA45337C2/uk unknown
- 1995-04-13 PL PL95316793A patent/PL180877B1/pl not_active IP Right Cessation
- 1995-04-13 EP EP95105672A patent/EP0677572B1/en not_active Expired - Lifetime
- 1995-04-13 DE DE69507068T patent/DE69507068T2/de not_active Expired - Lifetime
- 1995-04-13 AT AT95105672T patent/ATE175439T1/de not_active IP Right Cessation
- 1995-04-13 SK SK1315-96A patent/SK281687B6/sk not_active IP Right Cessation
- 1995-04-13 CZ CZ19962997A patent/CZ292648B6/cs not_active IP Right Cessation
- 1995-04-13 DK DK95105672T patent/DK0677572T3/da active
-
1999
- 1999-03-19 GR GR990400826T patent/GR3029741T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69507068T2 (de) | 1999-07-01 |
| DE69507068D1 (de) | 1999-02-18 |
| CZ299796A3 (en) | 1997-04-16 |
| HU9401100D0 (en) | 1994-07-28 |
| EP0677572B1 (en) | 1999-01-07 |
| RU2139921C1 (ru) | 1999-10-20 |
| PL180877B1 (pl) | 2001-04-30 |
| GR3029741T3 (en) | 1999-06-30 |
| HU214008B (hu) | 1998-04-28 |
| ATE175439T1 (de) | 1999-01-15 |
| UA45337C2 (uk) | 2002-04-15 |
| EP0677572A2 (en) | 1995-10-18 |
| EP0677572A3 (en) | 1996-12-18 |
| RO119551B1 (ro) | 2004-12-30 |
| CZ292648B6 (cs) | 2003-11-12 |
| SI0677572T1 (en) | 1999-06-30 |
| PL316793A1 (en) | 1997-02-17 |
| WO1995028460A1 (en) | 1995-10-26 |
| SK131596A3 (en) | 1997-07-09 |
| SK281687B6 (sk) | 2001-06-11 |
| DK0677572T3 (da) | 1999-09-13 |
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