ES2130332T3 - Procedimiento de preparacion de acido cianhidrico. - Google Patents
Procedimiento de preparacion de acido cianhidrico.Info
- Publication number
- ES2130332T3 ES2130332T3 ES94117415T ES94117415T ES2130332T3 ES 2130332 T3 ES2130332 T3 ES 2130332T3 ES 94117415 T ES94117415 T ES 94117415T ES 94117415 T ES94117415 T ES 94117415T ES 2130332 T3 ES2130332 T3 ES 2130332T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- procedure
- preparation
- modified
- alkaline metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000002253 acid Substances 0.000 title 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 abstract 6
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 abstract 4
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0204—Preparation, separation or purification of hydrogen cyanide from formamide or from ammonium formate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
SE DESCRIBE UN PROCESO PARA PRODUCCION RENTABLE DE CIANURO DE HIDROGENO A UNA TEMPERATURA DE REACCION ENTRE 250 Y 550 MEDIANTE REACCION DE DESHIDRATACION CATALITICA DE FORMAMIDA QUE COMPRENDE EL EMPLEO COMO CATALIZADOR DE UN OXIDO DE MANGANESO (MNO) Y/O UN OXIDO DE MAGNESIO (MGO) MODIFICADOS CON UN METAL ALCALINO (NA, K, RB, CS, ETC.). EL MENCIONADO PROCESO ES CAPAZ DE PRODUCIR CIANURO DE HIDROGENO CON INCREMENTADA EFICIENCIA DE CONVERSION DE FORMAMIDA Y CON ELEVADA SELECTIVIDAD MIENTRAS SE MINIMIZA LA PRODUCCION DERIVADA DE AMONIACO. EL EMPLEO DE UN CATALIZADOR QUE COMPRENDE COMO COMPONENTE PRINCIPAL MNO MODIFICADO CON METAL ALCALINO ES PARTICULARMENTE EFECTIVO PARA PROLONGAR SU VIDA UTIL Y POSIBILITA UNA OPERACION ESTABLE A LARGO PLAZO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30522393A JPH07157310A (ja) | 1993-12-06 | 1993-12-06 | シアン化水素の製造方法 |
| JP30522293A JP3509819B2 (ja) | 1993-12-06 | 1993-12-06 | シアン化水素の製造法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2130332T3 true ES2130332T3 (es) | 1999-07-01 |
Family
ID=26564216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94117415T Expired - Lifetime ES2130332T3 (es) | 1993-12-06 | 1994-11-04 | Procedimiento de preparacion de acido cianhidrico. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5439661A (es) |
| EP (1) | EP0657384B1 (es) |
| KR (1) | KR100341873B1 (es) |
| DE (1) | DE69416648T2 (es) |
| ES (1) | ES2130332T3 (es) |
| TW (1) | TW283136B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5618953A (en) * | 1995-02-10 | 1997-04-08 | Mitsubishi Gas Chemical Co., Inc. | Process for producing 3-methyltetrahydrofuran |
| DE19962418A1 (de) * | 1999-12-22 | 2001-06-28 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von Blausäure durch Thermolyse von Formamid |
| AP2007004167A0 (en) * | 2005-03-11 | 2007-10-31 | Nevada Chemicals Inc | Producing calcium cyanide at a mine site using easily transportable starting materials |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1920795A (en) * | 1929-09-16 | 1933-08-01 | Selden Co | Production of hydrocyanic acid |
| US2042451A (en) * | 1933-04-12 | 1936-06-02 | Du Pont | Dehydration of formamide to produce hydrocyanic acid |
| US2086507A (en) * | 1935-07-13 | 1937-07-06 | Du Pont | Preparation of hydrocyanic acid |
| US2534000A (en) * | 1945-10-09 | 1950-12-12 | Du Pont | Process for producing hydrocyanic acid |
-
1994
- 1994-10-27 US US08/330,202 patent/US5439661A/en not_active Expired - Lifetime
- 1994-11-04 EP EP94117415A patent/EP0657384B1/en not_active Expired - Lifetime
- 1994-11-04 DE DE69416648T patent/DE69416648T2/de not_active Expired - Lifetime
- 1994-11-04 ES ES94117415T patent/ES2130332T3/es not_active Expired - Lifetime
- 1994-11-15 TW TW083110562A patent/TW283136B/zh not_active IP Right Cessation
- 1994-12-06 KR KR1019940033231A patent/KR100341873B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TW283136B (es) | 1996-08-11 |
| DE69416648D1 (de) | 1999-04-01 |
| EP0657384A1 (en) | 1995-06-14 |
| EP0657384B1 (en) | 1999-02-24 |
| KR100341873B1 (ko) | 2002-11-23 |
| US5439661A (en) | 1995-08-08 |
| KR950016867A (ko) | 1995-07-20 |
| DE69416648T2 (de) | 1999-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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