ES2134500T3 - Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel. - Google Patents
Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel.Info
- Publication number
- ES2134500T3 ES2134500T3 ES95935727T ES95935727T ES2134500T3 ES 2134500 T3 ES2134500 T3 ES 2134500T3 ES 95935727 T ES95935727 T ES 95935727T ES 95935727 T ES95935727 T ES 95935727T ES 2134500 T3 ES2134500 T3 ES 2134500T3
- Authority
- ES
- Spain
- Prior art keywords
- solvent
- gel
- free radicals
- polymerization
- solvents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Colloid Chemistry (AREA)
Abstract
SE DESCRIBE UN PROCEDIMIENTO PARA LA PRODUCCION CONTINUA, CON FORMACION REDUCIDA DE GEL, DE POLIMEROS DE ADICION DE RADICALES LIBRES DE MONOMEROS ETILENICAMENTE INSATURADOS QUE CONTIENEN AL MENOS UN GRUPO HIDROXILO LIBRE COMO METACRILATO DE 2HIDROXIETILO, DE ALREDEDOR DE 0 A ALREDEDOR DEL 5% DE PESO DE UN ACIDO CARBOXILICO ALFA-BETA INSATURADO COMO ACIDO ACRILICO O ACIDO METACRILICO, Y EL RESTO DE LOS MONOMEROS UTILIZADOS SON COMPUESTOS COPOLIMERIZABLES DE ADICION DE RADICALES LIBRES COMO ESTIRENO, METACRILATO DE METILO Y ACRILATO DE BUTILO. LA POLIMERIZACION DE ADICION DE RADICALES LIBRES SE LLEVA A CABO DESDE ALREDEDOR DE 150 (GRADOS) C A ALREDEDOR DE 310 (GRADOS) C BAJO PRESION SUPERATMOSFERICA EN PRESENCIA DE UNO O MAS SOLVENTES. EL SOLVENTE O LA MEDIA DE VOLUMEN DE LA MEZCLA DE SOLVENTE TIENE UN VALOR DE RAIZ CUADRADA MEDIO CALCULADO GLOBAL DE LA UNION DE HIDROGENO Y CONTRIBUCIONES POLARES DE CADA UNO DE LOS PARAMETROS DE SOLUBILIDAD DEL SOLVENTE EN EL RANGO DE DESDE ALREDEDOR DE 6 A ALREDEDOR DE 15. EL SOLVENTE O SOLVENTES EN TOTAL TIENEN VOLATILIDAD SUFICIENTE BAJO LAS CONDICIONES UTILIZADAS PARA LLEVAR A CABO LA POLIMERIZACION DE MODO QUE CUALQUIER CONDENSADO LIQUIDO DE MEZCLA DE VAPOR FORMADA EN LAS SUPERFICIES INTERIORES DEL EQUIPO REACTOR LOCALIZADO ENCIMA DE LA SUPERFICIE DE LOS REACTIVOS DE MONOMERO CONTIENE AL MENOS EL 50 POR CIENTO MOLAR DEL SOLVENTE PARA REDUCIR LA FORMACION DE GEL EN DICHAS SUPERFICIES INTERIORES. EL PROCEDIMIENTO PERMITE LA POLIMERIZACION CONTINUA DE LOS POLIMEROS EN PERIODOS EXTENSOS DE TIEMPO SIN FORMACION REDUCIDA DE PARTICULAS DE GEL Y DEPOSITOS DE GEL.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/325,001 US5508366A (en) | 1994-10-18 | 1994-10-18 | Continuous production of reduced gel content hydroxylated addition polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2134500T3 true ES2134500T3 (es) | 1999-10-01 |
Family
ID=23266019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95935727T Expired - Lifetime ES2134500T3 (es) | 1994-10-18 | 1995-10-13 | Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5508366A (es) |
| EP (1) | EP0787154B1 (es) |
| JP (1) | JP3550152B2 (es) |
| KR (1) | KR100350338B1 (es) |
| CN (1) | CN1083456C (es) |
| AT (1) | ATE182154T1 (es) |
| AU (1) | AU703253B2 (es) |
| CA (1) | CA2202902C (es) |
| DE (1) | DE69510813T2 (es) |
| DK (1) | DK0787154T3 (es) |
| ES (1) | ES2134500T3 (es) |
| FI (1) | FI971636A7 (es) |
| GR (1) | GR3031056T3 (es) |
| NO (1) | NO313050B1 (es) |
| SG (1) | SG50359A1 (es) |
| WO (1) | WO1996011957A1 (es) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3516035B2 (ja) | 1997-05-13 | 2004-04-05 | 綜研化学株式会社 | 粘着剤組成物 |
| US5986020A (en) | 1997-08-05 | 1999-11-16 | Campbell; J. David | Process for producing hyperbranched polymers |
| DE69917280T2 (de) * | 1998-07-10 | 2005-04-14 | Johnson Polymer, LLC, Sturtevant | Verfahren zur herstellung von polymeren durch ein freies radikal verfahren, polymerisations- und condensationsreaktion und apparat dafür sowie hergestellte produkte |
| EP1198481B1 (en) | 1999-07-14 | 2006-01-04 | Johnson Polymer, Inc. | Process for the continuous production of epoxy - (meth)acrylic - styrene polymers and their use in coating |
| WO2001005841A1 (en) * | 1999-07-14 | 2001-01-25 | Johnson Polymer, Inc. | Process for the continuous production of gel free polymers, and powder and liquid coating applications containing gel free polymers |
| US6706836B1 (en) * | 2000-03-31 | 2004-03-16 | Avery Dennison Corporation | Hydrophilic polymers, pressure sensitive adhesives and coatings |
| US6743880B2 (en) * | 2000-03-31 | 2004-06-01 | Avery Denison Corporation | Hydrophilic polymers and methods of preparation |
| US6653427B2 (en) | 2000-03-31 | 2003-11-25 | Avery Dennison Corporation | Hydrophilic polymers, pressure sensitive adhesives and coatings |
| US6605681B1 (en) | 2000-07-12 | 2003-08-12 | Johnson Polymer, Inc. | Process for the continuous production of epoxylated addition polymers, and powder and liquid coating applications containing epoxylated addition polymers |
| BR0115118A (pt) | 2000-11-03 | 2004-10-19 | Johnson & Johnson Vision Care | Solventes úteis na preparação de polìmeros contendo monÈmeros hidrofìlicos e hidrofóbicos |
| US7315896B2 (en) * | 2002-06-06 | 2008-01-01 | International Business Machines Corporation | Server network controller including packet forwarding and method therefor |
| US20040029757A1 (en) * | 2002-08-08 | 2004-02-12 | Ecolab Inc. | Hand dishwashing detergent composition and methods for manufacturing and using |
| US20070066777A1 (en) * | 2004-09-03 | 2007-03-22 | Bzowej Eugene I | Methods for producing crosslinkable oligomers |
| RU2012117414A (ru) | 2009-09-30 | 2013-11-10 | Басф Се | Алкоксилированные полимеры |
| CN102295513A (zh) * | 2010-06-25 | 2011-12-28 | 中国石油化工股份有限公司 | 萃取精馏法精制异戊二烯的方法 |
| JP5751055B2 (ja) * | 2010-11-30 | 2015-07-22 | Jnc株式会社 | 光ナノインプリント用硬化性組成物および硬化性組成物から得られた硬化膜 |
| US9540513B2 (en) | 2012-11-21 | 2017-01-10 | Basf Se | Lignocellulosic article and method of producing same |
| SG11201701080QA (en) | 2014-08-15 | 2017-03-30 | Basf Se | Composition comprising silver nanowires and fibers of crystalline cellulose for the preparation of electroconductive transparent layers |
| CN106575543B (zh) | 2014-08-15 | 2019-10-25 | 巴斯夫欧洲公司 | 用于制备导电透明层的含有银纳米线和分散的聚合物珠粒的组合物 |
| CA2957837A1 (en) | 2014-08-15 | 2016-02-18 | Basf Se | Composition comprising silver nanowires and styrene/(meth)acrylic copolymers for the preparation of electroconductive transparent layers |
| JP6783791B2 (ja) | 2015-04-09 | 2020-11-11 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 導電性透明層の調製のためのアルコール／水混合物中の銀ナノワイヤ、及び分散したスチレン／（メタ）アクリル共重合体を含む組成物 |
| WO2018007355A1 (en) | 2016-07-06 | 2018-01-11 | Basf Se | Coating containing metal particles |
| WO2018019813A1 (en) | 2016-07-29 | 2018-02-01 | Basf Se | Transparent electroconductive layer and ink for production thereof |
| CN108610447B (zh) * | 2016-12-09 | 2021-02-05 | 中国石油化工股份有限公司 | 适于烯烃共聚的物料混合方法及混合装置和烯烃共聚方法 |
| CN110167985A (zh) | 2017-01-12 | 2019-08-23 | 巴斯夫欧洲公司 | 聚氨酯的物理性能改进 |
| CN111933974B (zh) * | 2020-07-31 | 2021-09-07 | 广东国鸿氢能科技有限公司 | 一种燃料电池增湿反应气体的露点温度的测试方法 |
| KR20250025848A (ko) * | 2023-08-16 | 2025-02-25 | 에스케이이노베이션 주식회사 | 에틸렌-아크릴산 공중합체 제조공정의 플러깅 억제방법 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4351931A (en) * | 1961-06-26 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Polyethylene copolymers |
| CH532090A (de) * | 1966-05-24 | 1972-12-31 | Ceskoslovenska Akademie Ved | Verfahren zur Herstellung von löslichen Polymeren bzw. Copolymeren von Glykolmonomethacrylaten bzw. -acrylaten |
| US3764384A (en) * | 1970-07-24 | 1973-10-09 | Gaf Corp | Process for removing polyvinyl halide residues from processing equipment |
| US3988213A (en) * | 1972-09-25 | 1976-10-26 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method of distilling vinyl compounds |
| US4276432A (en) * | 1973-07-18 | 1981-06-30 | Celanese Corporation | Low molecular weight acrylates or methacrylates and methods for their preparation |
| FR2295972A1 (fr) * | 1974-12-23 | 1976-07-23 | Michelin & Cie | Polymerisation ou copolymerisation en solution d'un ou plusieurs dienes conjugues avec eventuellement un ou plusieurs composes vinylaromatiques |
| US4014754A (en) * | 1975-04-25 | 1977-03-29 | Gaf Corporation | Recovery of lactam solvent from vinyl polymer solution |
| US4172177A (en) * | 1975-06-17 | 1979-10-23 | Kyowa Gas Chemical Industry Co., Ltd. | Water insoluble hydrophilic polymer composition |
| DE2757329C2 (de) * | 1977-12-22 | 1980-02-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Polymerisaten der Acrylsäure oder Methacrylsäure |
| DE2850872A1 (de) * | 1978-11-24 | 1980-06-04 | Bayer Ag | Wasserverduennbare lackbindemittel fuer chemikalienfeste beschichtungen |
| US4324868A (en) * | 1979-06-19 | 1982-04-13 | Mitsubishi Rayon Co., Ltd. | Process and apparatus for preparation of vinyl polymers |
| US4414370A (en) * | 1981-01-09 | 1983-11-08 | S. C. Johnson & Son, Inc. | Process for continuous bulk copolymerization of vinyl monomers |
| EP0062002B1 (de) * | 1981-03-25 | 1986-06-04 | Ciba-Geigy Ag | Haarfixierungszubereitung, deren Herstellung und deren Verwendung in Aerosolsprays |
| CA1215495A (en) * | 1981-07-28 | 1986-12-16 | Kenji Satoh | Method of continuous copolymerization of ethylene and vinylacetate |
| US4529787A (en) * | 1982-06-15 | 1985-07-16 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
| US4728701A (en) * | 1983-09-19 | 1988-03-01 | Jarvis Marvin A | Process for the polymerization of acrylates |
| US4546160A (en) * | 1984-02-29 | 1985-10-08 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
| DE3628119A1 (de) * | 1986-08-19 | 1988-02-25 | Herberts Gmbh | Fremdvernetzende bindemittelkombination, diese enthaltende waessriges ueberzugsmittel und dessen verwendung |
| US5003021A (en) * | 1988-03-22 | 1991-03-26 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing an aromatic vinyl compound-vinyl cyanide compound copolymer |
| US4921755A (en) * | 1988-03-23 | 1990-05-01 | Eastman Kodak Company | Coating composition and coated article |
| IT1241155B (it) * | 1990-05-18 | 1993-12-29 | Vedril | Procedimento per la produzione di polimeri acrilici in massa continua |
| US5028674A (en) * | 1990-06-06 | 1991-07-02 | E. I. Du Pont De Nemours And Company | Methanol copolymerization of ethylene |
| US5057593A (en) * | 1990-06-11 | 1991-10-15 | E. I. Du Pont De Nemours And Company | Free radical copolymerization of ethylene and CO with acetone |
| US5064557A (en) * | 1990-10-15 | 1991-11-12 | Isp Investments Inc. | Resin cleaner composition |
| US5210111A (en) * | 1991-08-22 | 1993-05-11 | Ciba-Geigy Corporation | Crosslinked hydrogels derived from hydrophilic polymer backbones |
-
1994
- 1994-10-18 US US08/325,001 patent/US5508366A/en not_active Expired - Lifetime
-
1995
- 1995-10-13 AU AU37636/95A patent/AU703253B2/en not_active Ceased
- 1995-10-13 CN CN95196326A patent/CN1083456C/zh not_active Expired - Lifetime
- 1995-10-13 DE DE69510813T patent/DE69510813T2/de not_active Expired - Lifetime
- 1995-10-13 CA CA002202902A patent/CA2202902C/en not_active Expired - Fee Related
- 1995-10-13 ES ES95935727T patent/ES2134500T3/es not_active Expired - Lifetime
- 1995-10-13 AT AT95935727T patent/ATE182154T1/de not_active IP Right Cessation
- 1995-10-13 DK DK95935727T patent/DK0787154T3/da active
- 1995-10-13 EP EP95935727A patent/EP0787154B1/en not_active Expired - Lifetime
- 1995-10-13 JP JP51331696A patent/JP3550152B2/ja not_active Expired - Lifetime
- 1995-10-13 WO PCT/US1995/012836 patent/WO1996011957A1/en not_active Ceased
- 1995-10-13 KR KR1019970702537A patent/KR100350338B1/ko not_active Expired - Lifetime
- 1995-10-17 SG SG1995001570A patent/SG50359A1/en unknown
-
1997
- 1997-04-17 FI FI971636A patent/FI971636A7/fi unknown
- 1997-04-18 NO NO19971818A patent/NO313050B1/no not_active IP Right Cessation
-
1999
- 1999-08-23 GR GR990402135T patent/GR3031056T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10511992A (ja) | 1998-11-17 |
| MX9702860A (es) | 1997-07-31 |
| SG50359A1 (en) | 1998-07-20 |
| FI971636A0 (fi) | 1997-04-17 |
| CA2202902A1 (en) | 1996-04-25 |
| FI971636A7 (fi) | 1997-06-16 |
| JP3550152B2 (ja) | 2004-08-04 |
| WO1996011957A1 (en) | 1996-04-25 |
| NO313050B1 (no) | 2002-08-05 |
| ATE182154T1 (de) | 1999-07-15 |
| CN1164239A (zh) | 1997-11-05 |
| DE69510813T2 (de) | 1999-11-04 |
| GR3031056T3 (en) | 1999-12-31 |
| US5508366A (en) | 1996-04-16 |
| CN1083456C (zh) | 2002-04-24 |
| KR970707167A (ko) | 1997-12-01 |
| NO971818D0 (no) | 1997-04-18 |
| AU3763695A (en) | 1996-05-06 |
| NO971818L (no) | 1997-06-17 |
| EP0787154B1 (en) | 1999-07-14 |
| DE69510813D1 (de) | 1999-08-19 |
| AU703253B2 (en) | 1999-03-25 |
| EP0787154A1 (en) | 1997-08-06 |
| DK0787154T3 (da) | 1999-12-06 |
| CA2202902C (en) | 2000-06-20 |
| MX199818B (es) | 2000-11-27 |
| KR100350338B1 (ko) | 2003-02-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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