ES2134500T3 - Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel. - Google Patents

Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel.

Info

Publication number
ES2134500T3
ES2134500T3 ES95935727T ES95935727T ES2134500T3 ES 2134500 T3 ES2134500 T3 ES 2134500T3 ES 95935727 T ES95935727 T ES 95935727T ES 95935727 T ES95935727 T ES 95935727T ES 2134500 T3 ES2134500 T3 ES 2134500T3
Authority
ES
Spain
Prior art keywords
solvent
gel
free radicals
polymerization
solvents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95935727T
Other languages
English (en)
Inventor
Kevin M Andrist
J David Campbell
Richard W Chylla
Rakesh K Popli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SC Johnson Commercial Markets Inc
Original Assignee
SC Johnson Commercial Markets Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SC Johnson Commercial Markets Inc filed Critical SC Johnson Commercial Markets Inc
Application granted granted Critical
Publication of ES2134500T3 publication Critical patent/ES2134500T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Colloid Chemistry (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO PARA LA PRODUCCION CONTINUA, CON FORMACION REDUCIDA DE GEL, DE POLIMEROS DE ADICION DE RADICALES LIBRES DE MONOMEROS ETILENICAMENTE INSATURADOS QUE CONTIENEN AL MENOS UN GRUPO HIDROXILO LIBRE COMO METACRILATO DE 2HIDROXIETILO, DE ALREDEDOR DE 0 A ALREDEDOR DEL 5% DE PESO DE UN ACIDO CARBOXILICO ALFA-BETA INSATURADO COMO ACIDO ACRILICO O ACIDO METACRILICO, Y EL RESTO DE LOS MONOMEROS UTILIZADOS SON COMPUESTOS COPOLIMERIZABLES DE ADICION DE RADICALES LIBRES COMO ESTIRENO, METACRILATO DE METILO Y ACRILATO DE BUTILO. LA POLIMERIZACION DE ADICION DE RADICALES LIBRES SE LLEVA A CABO DESDE ALREDEDOR DE 150 (GRADOS) C A ALREDEDOR DE 310 (GRADOS) C BAJO PRESION SUPERATMOSFERICA EN PRESENCIA DE UNO O MAS SOLVENTES. EL SOLVENTE O LA MEDIA DE VOLUMEN DE LA MEZCLA DE SOLVENTE TIENE UN VALOR DE RAIZ CUADRADA MEDIO CALCULADO GLOBAL DE LA UNION DE HIDROGENO Y CONTRIBUCIONES POLARES DE CADA UNO DE LOS PARAMETROS DE SOLUBILIDAD DEL SOLVENTE EN EL RANGO DE DESDE ALREDEDOR DE 6 A ALREDEDOR DE 15. EL SOLVENTE O SOLVENTES EN TOTAL TIENEN VOLATILIDAD SUFICIENTE BAJO LAS CONDICIONES UTILIZADAS PARA LLEVAR A CABO LA POLIMERIZACION DE MODO QUE CUALQUIER CONDENSADO LIQUIDO DE MEZCLA DE VAPOR FORMADA EN LAS SUPERFICIES INTERIORES DEL EQUIPO REACTOR LOCALIZADO ENCIMA DE LA SUPERFICIE DE LOS REACTIVOS DE MONOMERO CONTIENE AL MENOS EL 50 POR CIENTO MOLAR DEL SOLVENTE PARA REDUCIR LA FORMACION DE GEL EN DICHAS SUPERFICIES INTERIORES. EL PROCEDIMIENTO PERMITE LA POLIMERIZACION CONTINUA DE LOS POLIMEROS EN PERIODOS EXTENSOS DE TIEMPO SIN FORMACION REDUCIDA DE PARTICULAS DE GEL Y DEPOSITOS DE GEL.
ES95935727T 1994-10-18 1995-10-13 Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel. Expired - Lifetime ES2134500T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/325,001 US5508366A (en) 1994-10-18 1994-10-18 Continuous production of reduced gel content hydroxylated addition polymers

Publications (1)

Publication Number Publication Date
ES2134500T3 true ES2134500T3 (es) 1999-10-01

Family

ID=23266019

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95935727T Expired - Lifetime ES2134500T3 (es) 1994-10-18 1995-10-13 Produccion continua de polimeros de adicion hidroxilados con contenido reducido de gel.

Country Status (16)

Country Link
US (1) US5508366A (es)
EP (1) EP0787154B1 (es)
JP (1) JP3550152B2 (es)
KR (1) KR100350338B1 (es)
CN (1) CN1083456C (es)
AT (1) ATE182154T1 (es)
AU (1) AU703253B2 (es)
CA (1) CA2202902C (es)
DE (1) DE69510813T2 (es)
DK (1) DK0787154T3 (es)
ES (1) ES2134500T3 (es)
FI (1) FI971636A7 (es)
GR (1) GR3031056T3 (es)
NO (1) NO313050B1 (es)
SG (1) SG50359A1 (es)
WO (1) WO1996011957A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3516035B2 (ja) 1997-05-13 2004-04-05 綜研化学株式会社 粘着剤組成物
US5986020A (en) * 1997-08-05 1999-11-16 Campbell; J. David Process for producing hyperbranched polymers
ES2241298T3 (es) * 1998-07-10 2005-10-16 Johnson Polymer, Llc. Procedimiento para producir polimeros por polimerizacion por radicales libres y reaccion de condensacion, y aparatos y productos relacionados.
PT1203029E (pt) * 1999-07-14 2005-01-31 Johnson Polymer Inc Processo para a preparacao continua de polimeros livres de gel e aplicacoes em revestimento em po e liquidos contendo polimeros livres de gel
EP1544217B1 (en) 1999-07-14 2010-01-20 BASF Corporation Process for the continuous production of epoxy-(meth)acrylicstyrene polymers and their use in coating
US6706836B1 (en) 2000-03-31 2004-03-16 Avery Dennison Corporation Hydrophilic polymers, pressure sensitive adhesives and coatings
US6743880B2 (en) * 2000-03-31 2004-06-01 Avery Denison Corporation Hydrophilic polymers and methods of preparation
US6653427B2 (en) 2000-03-31 2003-11-25 Avery Dennison Corporation Hydrophilic polymers, pressure sensitive adhesives and coatings
US6605681B1 (en) 2000-07-12 2003-08-12 Johnson Polymer, Inc. Process for the continuous production of epoxylated addition polymers, and powder and liquid coating applications containing epoxylated addition polymers
AU2002227331B2 (en) 2000-11-03 2005-10-13 Johnson & Johnson Vision Care, Inc Solvents useful in the preparation of polymers containing hydrophilic and hydrophobic monomers
US7315896B2 (en) * 2002-06-06 2008-01-01 International Business Machines Corporation Server network controller including packet forwarding and method therefor
US20040029757A1 (en) * 2002-08-08 2004-02-12 Ecolab Inc. Hand dishwashing detergent composition and methods for manufacturing and using
US20070066777A1 (en) * 2004-09-03 2007-03-22 Bzowej Eugene I Methods for producing crosslinkable oligomers
BR112012007190A2 (pt) 2009-09-30 2016-03-29 Basf Se processo para a preparação de polímeros alcoxilados, polímero alcoxilado, processo para preparar poliuretanos, poliuretanos, reagente tensoativo, e, formulação detergente
CN102295513A (zh) * 2010-06-25 2011-12-28 中国石油化工股份有限公司 萃取精馏法精制异戊二烯的方法
JP5751055B2 (ja) * 2010-11-30 2015-07-22 Jnc株式会社 光ナノインプリント用硬化性組成物および硬化性組成物から得られた硬化膜
US9540513B2 (en) 2012-11-21 2017-01-10 Basf Se Lignocellulosic article and method of producing same
CA2957846A1 (en) 2014-08-15 2016-02-18 Basf Se Composition comprising silver nanowires and fibers of crystalline cellulose for the preparation of electroconductive transparent layers
SG11201700953QA (en) 2014-08-15 2017-03-30 Basf Se Composition comprising silver nanowires and dispersed polymer beads for the preparation of electroconductive transparent layers
SG11201701081WA (en) 2014-08-15 2017-03-30 Basf Se Composition comprising silver nanowires and styrene/(meth)acrylic copolymers for the preparation of electroconductive transparent layers
KR20170135909A (ko) 2015-04-09 2017-12-08 바스프 에스이 전기 전도성 투명층의 제조를 위한 알코올/물 혼합물 중의 은 나노와이어 및 분산된 스티렌/(메트)아크릴 공중합체를 포함하는 조성물
WO2018007355A1 (en) 2016-07-06 2018-01-11 Basf Se Coating containing metal particles
WO2018019813A1 (en) 2016-07-29 2018-02-01 Basf Se Transparent electroconductive layer and ink for production thereof
CN108610447B (zh) * 2016-12-09 2021-02-05 中国石油化工股份有限公司 适于烯烃共聚的物料混合方法及混合装置和烯烃共聚方法
CA3048653A1 (en) 2017-01-12 2018-07-19 Basf Se Physical property improvement of polyurethanes
CN111933974B (zh) * 2020-07-31 2021-09-07 广东国鸿氢能科技有限公司 一种燃料电池增湿反应气体的露点温度的测试方法
KR20250025848A (ko) * 2023-08-16 2025-02-25 에스케이이노베이션 주식회사 에틸렌-아크릴산 공중합체 제조공정의 플러깅 억제방법

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4351931A (en) * 1961-06-26 1982-09-28 E. I. Du Pont De Nemours And Company Polyethylene copolymers
CH532090A (de) * 1966-05-24 1972-12-31 Ceskoslovenska Akademie Ved Verfahren zur Herstellung von löslichen Polymeren bzw. Copolymeren von Glykolmonomethacrylaten bzw. -acrylaten
US3764384A (en) * 1970-07-24 1973-10-09 Gaf Corp Process for removing polyvinyl halide residues from processing equipment
US3988213A (en) * 1972-09-25 1976-10-26 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method of distilling vinyl compounds
US4276432A (en) * 1973-07-18 1981-06-30 Celanese Corporation Low molecular weight acrylates or methacrylates and methods for their preparation
FR2295972A1 (fr) * 1974-12-23 1976-07-23 Michelin & Cie Polymerisation ou copolymerisation en solution d'un ou plusieurs dienes conjugues avec eventuellement un ou plusieurs composes vinylaromatiques
US4014754A (en) * 1975-04-25 1977-03-29 Gaf Corporation Recovery of lactam solvent from vinyl polymer solution
US4172177A (en) * 1975-06-17 1979-10-23 Kyowa Gas Chemical Industry Co., Ltd. Water insoluble hydrophilic polymer composition
DE2757329C2 (de) * 1977-12-22 1980-02-07 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Polymerisaten der Acrylsäure oder Methacrylsäure
DE2850872A1 (de) * 1978-11-24 1980-06-04 Bayer Ag Wasserverduennbare lackbindemittel fuer chemikalienfeste beschichtungen
US4324868A (en) * 1979-06-19 1982-04-13 Mitsubishi Rayon Co., Ltd. Process and apparatus for preparation of vinyl polymers
US4414370A (en) * 1981-01-09 1983-11-08 S. C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
DE3271521D1 (en) * 1981-03-25 1986-07-10 Ciba Geigy Ag Composition for fixing the hair, its preparation and its use in aerosol sprays
CA1215495A (en) * 1981-07-28 1986-12-16 Kenji Satoh Method of continuous copolymerization of ethylene and vinylacetate
US4529787A (en) * 1982-06-15 1985-07-16 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
US4728701A (en) * 1983-09-19 1988-03-01 Jarvis Marvin A Process for the polymerization of acrylates
US4546160A (en) * 1984-02-29 1985-10-08 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
DE3628119A1 (de) * 1986-08-19 1988-02-25 Herberts Gmbh Fremdvernetzende bindemittelkombination, diese enthaltende waessriges ueberzugsmittel und dessen verwendung
US5003021A (en) * 1988-03-22 1991-03-26 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing an aromatic vinyl compound-vinyl cyanide compound copolymer
US4921755A (en) * 1988-03-23 1990-05-01 Eastman Kodak Company Coating composition and coated article
IT1241155B (it) * 1990-05-18 1993-12-29 Vedril Procedimento per la produzione di polimeri acrilici in massa continua
US5028674A (en) * 1990-06-06 1991-07-02 E. I. Du Pont De Nemours And Company Methanol copolymerization of ethylene
US5057593A (en) * 1990-06-11 1991-10-15 E. I. Du Pont De Nemours And Company Free radical copolymerization of ethylene and CO with acetone
US5064557A (en) * 1990-10-15 1991-11-12 Isp Investments Inc. Resin cleaner composition
US5210111A (en) * 1991-08-22 1993-05-11 Ciba-Geigy Corporation Crosslinked hydrogels derived from hydrophilic polymer backbones

Also Published As

Publication number Publication date
AU3763695A (en) 1996-05-06
MX9702860A (es) 1997-07-31
JP3550152B2 (ja) 2004-08-04
DK0787154T3 (da) 1999-12-06
EP0787154A1 (en) 1997-08-06
CA2202902A1 (en) 1996-04-25
GR3031056T3 (en) 1999-12-31
NO971818D0 (no) 1997-04-18
NO313050B1 (no) 2002-08-05
MX199818B (es) 2000-11-27
FI971636A0 (fi) 1997-04-17
FI971636A7 (fi) 1997-06-16
US5508366A (en) 1996-04-16
AU703253B2 (en) 1999-03-25
DE69510813D1 (de) 1999-08-19
ATE182154T1 (de) 1999-07-15
WO1996011957A1 (en) 1996-04-25
CN1083456C (zh) 2002-04-24
JPH10511992A (ja) 1998-11-17
CA2202902C (en) 2000-06-20
NO971818L (no) 1997-06-17
SG50359A1 (en) 1998-07-20
KR970707167A (ko) 1997-12-01
CN1164239A (zh) 1997-11-05
EP0787154B1 (en) 1999-07-14
DE69510813T2 (de) 1999-11-04
KR100350338B1 (ko) 2003-02-11

Similar Documents

Publication Publication Date Title
AU540766B2 (en) Nonapeptide and decapeptide analogs of lhrh
ATE182154T1 (de) Kontinuierliche herstellung von hydroxylierten additionspolymeren mit vermindertem gelgehalt
ES8200906A1 (es) Procedimiento para la produccion de microparticulas de poli-meros de adicion
ES8607370A1 (es) Procedimiento de obtencion de un copolimero de acrilato con grupos hidroxilos y revestimientos en base al copolimero de acrilato
ES8306122A1 (es) Procedimiento para la obtencion de derivados de imidazol trisustituidos.
ES8603919A1 (es) Procedimiento para preparar dispersiones poliacrilicas este-ricamente estabilizadas
ES2155604T3 (es) Mezclas de polimeros que contienen acrilato.
ATE150340T1 (de) Elektrostatische sprühvorrichtung und verfahren
MX167731B (es) Procedimiento para la polimerizacion de uno o mas ompuestos de vidrio polimerizables de radicales lires en reactores de superficie limpia
DE10344527A1 (de) Schäumende Zubereitungen mit Fließgrenze
ES2105108T3 (es) Esteroides para el tratamiento de la hipertrofia prostatica, su preparacion y su utilizacion.
ES2067036T3 (es) Productos de alcoxilacion de derivados de acidos carboxilicos y/o acidos carboxilicos que contienen grupos oh.
ES2088283T3 (es) Copolimeros de acidos carboxilicos y compuestos de amonio cuaternarios, y su empleo como agente espesante o dispersante.
PT99722B (pt) Processo para a preparacao de composicoes decapantes de tintas a base de dissolventes polares aproticos e eteres
ES8706766A1 (es) Procedimiento para la obtencion de una composicion absorbente del hidrogeno para cables de fibras opticas y sus componentes
ES2107802T3 (es) Dispersiones polimeras acuosas para barnices transparentes.
ATE176487T1 (de) Copolymerisate mit cyclischen oder polycyclischen monomeren mit einer speziellen isomerenverteilung und deren einsatz in beschichtungsmittel
ES2173944T3 (es) Compuesto capaz de introducir al menos una molecula en una celula.
ATE106095T1 (de) Lackbindemittel.
ES2145480T3 (es) Amidas de acido carbamoilcarboxilico.
ES2081533T3 (es) Procedimiento para preparar acido 2,5-di-(fenilamino)-tereftalico y sus esteres dialquilicos con alta pureza.
ES2095555T3 (es) Polimeros conductivos con conductancia ionica.
PT963394E (pt) Solucoes de resina de poliester de impregnacao e de recobrimento e sua utilizacao
SU865880A1 (ru) Водовытесн юща композици
FR1252241A (fr) Obtention de nouveaux peroxydes organiques tels que peroxydes de diacyle et leur application comme catalyseurs pour la polymérisation de composés éthyléniquement non saturés

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 787154

Country of ref document: ES