ES2136748T3 - Proceso para la produccion en continuo de poliester. - Google Patents
Proceso para la produccion en continuo de poliester.Info
- Publication number
- ES2136748T3 ES2136748T3 ES94931907T ES94931907T ES2136748T3 ES 2136748 T3 ES2136748 T3 ES 2136748T3 ES 94931907 T ES94931907 T ES 94931907T ES 94931907 T ES94931907 T ES 94931907T ES 2136748 T3 ES2136748 T3 ES 2136748T3
- Authority
- ES
- Spain
- Prior art keywords
- polyester
- continuous production
- esterification
- issued
- oligomeros
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010924 continuous production Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000728 polyester Polymers 0.000 title abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- 230000032050 esterification Effects 0.000 abstract 2
- 238000005886 esterification reaction Methods 0.000 abstract 2
- -1 DIHYDROXY ETHYL Chemical class 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
SE DESCRIBE UN PROCESO DE PRESION ATMOSFERICA PARA LA PRODUCCION CONTINUA DE POLIESTER EN DONDE UNA FUSION DE DIHIDROXI ETIL TEREFTALATO, O SUS OLIGOMEROS MOLECULARES BAJOS, OBTENIDOS MEDIANTE LA ESTERIFICACION DE ACIDO TEREFTALICO O TRANSESTERIFICACION DE DIMETILTEREFTALATO CON ETILENGLICOL, ES PUESTO EN CONTACTO INTIMAMENTE CON UN GAS INERTE PARA FACILITAR LA POLIMERIZACION Y ELIMINACION DE SUBPRODUCTOS DE REACCION. EL ETILENGLICOL EMITIDO Y EL GAS INERTE SE RECICLAN.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/138,312 US5434239A (en) | 1993-10-18 | 1993-10-18 | Continuous polyester process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2136748T3 true ES2136748T3 (es) | 1999-12-01 |
Family
ID=22481471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94931907T Expired - Lifetime ES2136748T3 (es) | 1993-10-18 | 1994-10-18 | Proceso para la produccion en continuo de poliester. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5434239A (es) |
| EP (1) | EP0724607B1 (es) |
| JP (1) | JP3287572B2 (es) |
| KR (1) | KR100330825B1 (es) |
| CN (1) | CN1070511C (es) |
| CA (1) | CA2174312C (es) |
| DE (1) | DE69419930T2 (es) |
| ES (1) | ES2136748T3 (es) |
| MY (1) | MY144046A (es) |
| WO (1) | WO1995011268A1 (es) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5599900A (en) * | 1993-10-18 | 1997-02-04 | E. I. Du Pont De Nemours And Company | Polyesters production process |
| US5538343A (en) * | 1995-03-06 | 1996-07-23 | E. I. Du Pond De Nemours And Company | Apparatus and method for liquid mixing employing nip zones |
| US5623047A (en) * | 1995-03-28 | 1997-04-22 | Industrial Technology Research Institute | Catalytic compositions for the preparation of poly(ethylene terephthalate) with improved color |
| WO1996039456A1 (en) * | 1995-06-06 | 1996-12-12 | The University Of North Carolina At Chapel Hill | Process for the preparation of polyester in carbon dioxide |
| US5648483A (en) * | 1995-06-07 | 1997-07-15 | The Procter & Gamble Company | Continuous transesterification method for preparing polyol polyesters |
| US5786443A (en) * | 1995-12-14 | 1998-07-28 | E. I. Du Pont De Nemours And Company | Process of making polyester prepolymer |
| US6031065A (en) * | 1996-06-28 | 2000-02-29 | Wellman, Inc. | Polyester copolymers from naphthalate and related esters |
| US5663281A (en) * | 1996-07-30 | 1997-09-02 | E. I. Du Pont De Nemours And Company | Process for preparing high molecular weight polyesters |
| JP3557806B2 (ja) * | 1996-09-04 | 2004-08-25 | 株式会社日立製作所 | 蒸発装置 |
| TW541321B (en) * | 1996-09-04 | 2003-07-11 | Hitachi Ltd | Process and apparatus for continuous polycondensation |
| US5760161A (en) * | 1997-02-10 | 1998-06-02 | Albemarle Corporation | Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins |
| US6288202B1 (en) | 1997-04-11 | 2001-09-11 | The University Of North Carolina At Chapel Hill | Synthesis of polycarbonates using Co2 |
| US6034202A (en) * | 1998-03-06 | 2000-03-07 | Alliedsignal Inc. | Polymerization catalysts for polyesters |
| US6582817B2 (en) | 1999-11-19 | 2003-06-24 | Wellman, Inc. | Nonwoven fabrics formed from polyethylene glycol modified polyester fibers and method for making the same |
| US6623853B2 (en) | 1998-08-28 | 2003-09-23 | Wellman, Inc. | Polyethylene glycol modified polyester fibers and method for making the same |
| US6454982B1 (en) | 1999-11-19 | 2002-09-24 | Wellman, Inc. | Method of preparing polyethylene glycol modified polyester filaments |
| US6111064A (en) * | 1998-11-04 | 2000-08-29 | The Regents Of The University Of California | Pressure polymerization of polyester |
| US6127493A (en) * | 1998-11-04 | 2000-10-03 | Arteva North America S.A.R.L. | Pressure polymerization of polyester |
| US6350895B1 (en) | 1999-03-26 | 2002-02-26 | E. I. Du Pont De Nemours And Company | Transesterification process using yttrium and samarium compound catalystis |
| US6312503B1 (en) | 1999-10-13 | 2001-11-06 | Arteva North America S.A.R.L. | System to quench gasses and remove condensables |
| US6509091B2 (en) | 1999-11-19 | 2003-01-21 | Wellman, Inc. | Polyethylene glycol modified polyester fibers |
| EP1246861B1 (en) * | 1999-12-17 | 2006-05-17 | E.I. Du Pont De Nemours And Company | Production of polytrimethylene ether glycol and copolymers thereof |
| US6255442B1 (en) | 2000-02-08 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Esterification process |
| US6951954B1 (en) | 2000-02-11 | 2005-10-04 | E.I. Du Pont De Nemours And Company | Continuous process for producing bis(3-hydroxypropyl) terephthalate |
| US6353062B1 (en) * | 2000-02-11 | 2002-03-05 | E. I. Du Pont De Nemours And Company | Continuous process for producing poly(trimethylene terephthalate) |
| MXPA02007740A (es) * | 2000-02-11 | 2002-10-23 | Du Pont | Proceso continuo para la produccion de poli(trimetilen tereftalato). |
| US6359106B1 (en) | 2000-03-09 | 2002-03-19 | Hitachi, Ltd. | Production process and production apparatus for polybutylene terephthalate |
| DE60112885T2 (de) * | 2000-04-27 | 2006-06-01 | Teijin Ltd. | Verfahren zur kontinuierlichen herstellung von polyester |
| GB2361925A (en) | 2000-05-02 | 2001-11-07 | Shell Internat Res Maatschhapp | High temperature solid state polymerisation of poly(trimethylene terephthalate) |
| US6403762B1 (en) | 2000-08-21 | 2002-06-11 | Shell Oil Company | Solid state polymerization process for poly(trimethylene terephthalate) utilizing a combined crystallization/preheating step |
| US6906164B2 (en) | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
| DE10125678B4 (de) * | 2001-05-25 | 2011-04-14 | Lurgi Zimmer Gmbh | Verfahren und Vorrichtung zur Herstellung von Polyethylenterephthalat |
| DE10155419B4 (de) * | 2001-11-12 | 2005-06-16 | Inventa-Fischer Gmbh & Co. Kg | Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polyester sowie Vorrichtung zur Durchführung des Verfahrens |
| AU2003239385A1 (en) * | 2002-05-10 | 2003-11-11 | Richard R. Reisman | Method and apparatus for browsing using multiple coordinated device |
| MXPA04012278A (es) * | 2002-12-23 | 2005-02-25 | Du Pont | Proceso de fibra bicomponente de poli(tereftalato de trimetileno). |
| DE10316466A1 (de) * | 2003-04-09 | 2004-10-28 | Basf Ag | Kühlung und Reinigung von Gasströmen |
| US20070035057A1 (en) * | 2003-06-26 | 2007-02-15 | Chang Jing C | Poly(trimethylene terephthalate) bicomponent fiber process |
| DE102004013967A1 (de) * | 2004-03-19 | 2005-10-06 | Basf Ag | Kühlung und Reinigung von Gasströmen |
| US20060041039A1 (en) * | 2004-08-20 | 2006-02-23 | Gyorgyi Fenyvesi | Fluorescent poly(alkylene terephthalate) compositions |
| DE102004041370A1 (de) * | 2004-08-25 | 2006-03-02 | Bühler AG | Festphasen-Polykondensation von Polyester mit Prozessgas-Reinigung |
| US7357985B2 (en) * | 2005-09-19 | 2008-04-15 | E.I. Du Pont De Nemours And Company | High crimp bicomponent fibers |
| KR101390488B1 (ko) | 2005-11-22 | 2014-05-26 | 세게티스, 인코포레이티드. | 글리세롤 레불리네이트 케탈 및 그의 용도 |
| US20070128459A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films |
| US20070129503A1 (en) * | 2005-12-07 | 2007-06-07 | Kurian Joseph V | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles |
| US7666501B2 (en) * | 2005-12-07 | 2010-02-23 | E. I. Du Pont De Nemours And Company | Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments |
| US7943094B2 (en) | 2006-12-07 | 2011-05-17 | Grupo Petrotemex, S.A. De C.V. | Polyester production system employing horizontally elongated esterification vessel |
| US7649109B2 (en) | 2006-12-07 | 2010-01-19 | Eastman Chemical Company | Polyester production system employing recirculation of hot alcohol to esterification zone |
| US20080179247A1 (en) * | 2007-01-30 | 2008-07-31 | Eastman Chemical Company | Elimination of Wastewater Treatment System |
| US7892498B2 (en) | 2007-03-08 | 2011-02-22 | Eastman Chemical Company | Polyester production system employing an unagitated esterification reactor |
| US7863477B2 (en) | 2007-03-08 | 2011-01-04 | Eastman Chemical Company | Polyester production system employing hot paste to esterification zone |
| US7872090B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Reactor system with optimized heating and phase separation |
| US7872089B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Multi-level tubular reactor with internal tray |
| US7842777B2 (en) | 2007-07-12 | 2010-11-30 | Eastman Chemical Company | Sloped tubular reactor with divided flow |
| US7858730B2 (en) | 2007-07-12 | 2010-12-28 | Eastman Chemical Company | Multi-level tubular reactor with dual headers |
| US7868129B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Sloped tubular reactor with spaced sequential trays |
| US7868130B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Multi-level tubular reactor with vertically spaced segments |
| US7847053B2 (en) | 2007-07-12 | 2010-12-07 | Eastman Chemical Company | Multi-level tubular reactor with oppositely extending segments |
| US7829653B2 (en) | 2007-07-12 | 2010-11-09 | Eastman Chemical Company | Horizontal trayed reactor |
| BRPI0816422A2 (pt) | 2007-09-04 | 2017-05-16 | Segetis Inc | compostos de cetal a partir de polióis e oxocarboxilatos. |
| US8575367B2 (en) * | 2008-09-25 | 2013-11-05 | Segetis, Inc. | Ketal ester derivatives |
| EP2287225A1 (en) * | 2009-08-20 | 2011-02-23 | Saudi Basic Industries Corporation | Process for making polyethylene terephthalate |
| EP2637999A4 (en) | 2010-11-11 | 2015-02-18 | Segetis Inc | CEREOCARBOXYLIC ACIDS, CEREOCARBOXYL ESTERS, METHODS OF MAKING THE SAME AND USES THEREOF |
| KR20140009155A (ko) | 2010-11-11 | 2014-01-22 | 세게티스, 인코포레이티드. | 폴리하이드록시 케탈 에스터 부가물, 그의 제조방법 및 용도 |
| KR20140009179A (ko) | 2010-11-11 | 2014-01-22 | 세게티스, 인코포레이티드. | 폴리케탈 부가물, 그의 제조방법 및 용도 |
| DE102012003417A1 (de) * | 2012-02-17 | 2013-08-22 | Uhde Inventa-Fischer Gmbh | Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters |
| US20140005352A1 (en) * | 2012-06-29 | 2014-01-02 | Invista North America S.A R.L. | Gas scrubber and related processes |
| JP2014214166A (ja) * | 2013-04-22 | 2014-11-17 | 株式会社日立製作所 | ポリエステルの製造方法及び製造装置 |
| CN109232872B (zh) * | 2018-07-18 | 2021-02-02 | 万华化学集团股份有限公司 | 一种带有外循环系统的高效缩聚反应装置及其生产聚酯多元醇工艺 |
| FR3092324B1 (fr) * | 2019-02-01 | 2021-04-23 | Ifp Energies Now | Procédé de production d’un polyester téréphtalate intégrant un procédé de dépolymérisation |
| TWI771686B (zh) * | 2020-05-26 | 2022-07-21 | 遠東新世紀股份有限公司 | 氧化鋅分散液及其製備方法 |
| CN112129852B (zh) * | 2020-08-31 | 2021-08-10 | 中国科学院福建物质结构研究所 | 一种反应气体循环利用且气氛可控的co脱氢净化催化剂评价装置 |
| KR20240106326A (ko) * | 2022-12-29 | 2024-07-08 | 코오롱인더스트리 주식회사 | 재생 화합물을 사용한 폴리에스테르계 수지 및 이의 제조 방법 |
| NL2034182B1 (en) * | 2023-02-20 | 2024-09-03 | Cure Tech Bv | A method to recycle a stream of polyester waste material and a system for applying the method |
| KR20260010196A (ko) * | 2024-07-12 | 2026-01-20 | 에스케이케미칼 주식회사 | 재생 폴리에스테르 수지 및 이의 제조 방법 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2578660A (en) * | 1949-09-21 | 1951-12-18 | Du Pont | Process for polymerizing ethylene glycol terephthalate |
| US2647885A (en) * | 1951-09-28 | 1953-08-04 | Du Pont | Production of polyethylene terephthalate using antimony trioxide as polymerization catalyst |
| US2789972A (en) * | 1954-02-02 | 1957-04-23 | Eastman Kodak Co | Interpolycarbonates from 4, 4'-bis (beta-hydroxyethyl) biphenyl-bis |
| US2973341A (en) * | 1956-01-25 | 1961-02-28 | Glanzstoff Ag | Continuous process for production of a polyethylene terephthalate condensate |
| US3110547A (en) * | 1961-07-26 | 1963-11-12 | Du Pont | Polymerization process |
| US3390135A (en) * | 1962-09-04 | 1968-06-25 | Pittsburgh Plate Glass Co | Continuous polyester process |
| US3545520A (en) * | 1964-10-30 | 1970-12-08 | Snia Viscosa | Apparatus for removing substances and fractions from polymers |
| US3469618A (en) * | 1964-10-30 | 1969-09-30 | Snia Viscosa | Solvent removal from polymeric materials |
| GB1111815A (en) * | 1966-04-22 | 1968-05-01 | Ici Ltd | Polyester preparation |
| US3594356A (en) * | 1967-04-24 | 1971-07-20 | Phillips Petroleum Co | Polymer recovery process and apparatus |
| DE1770350A1 (de) * | 1968-05-08 | 1971-10-14 | Hoechst Ag | Verfahren zur Herstellung von Polyestern |
| GB1558910A (en) * | 1977-05-04 | 1980-01-09 | Bayer Ag | Continuous process for the production of polybutylene terephthalates |
| JPS61123624A (ja) * | 1984-11-20 | 1986-06-11 | Mitsubishi Rayon Co Ltd | ポリエステルの製法 |
| US4835293A (en) * | 1987-02-24 | 1989-05-30 | E. I. Du Pont De Nemours And Company | Atmospheric pressure process for preparing pure cyclic esters |
| US5064935A (en) * | 1990-08-01 | 1991-11-12 | E. I. Dupont De Nemours And Company | Continuous process for preparing poly(butylene terephthalate) oligomer or poly(butylene isophthalate) oligomer |
-
1993
- 1993-10-18 US US08/138,312 patent/US5434239A/en not_active Expired - Lifetime
-
1994
- 1994-10-18 KR KR1019960701978A patent/KR100330825B1/ko not_active Expired - Fee Related
- 1994-10-18 CN CN94194456A patent/CN1070511C/zh not_active Expired - Fee Related
- 1994-10-18 JP JP51216595A patent/JP3287572B2/ja not_active Expired - Fee Related
- 1994-10-18 CA CA002174312A patent/CA2174312C/en not_active Expired - Fee Related
- 1994-10-18 EP EP94931907A patent/EP0724607B1/en not_active Expired - Lifetime
- 1994-10-18 WO PCT/US1994/011862 patent/WO1995011268A1/en not_active Ceased
- 1994-10-18 ES ES94931907T patent/ES2136748T3/es not_active Expired - Lifetime
- 1994-10-18 DE DE69419930T patent/DE69419930T2/de not_active Expired - Fee Related
-
1995
- 1995-01-20 MY MYPI95000140A patent/MY144046A/en unknown
- 1995-05-10 US US08/438,299 patent/US5552513A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1137278A (zh) | 1996-12-04 |
| JP3287572B2 (ja) | 2002-06-04 |
| EP0724607B1 (en) | 1999-08-04 |
| JPH09504048A (ja) | 1997-04-22 |
| MY144046A (en) | 2011-07-29 |
| DE69419930D1 (de) | 1999-09-09 |
| CN1070511C (zh) | 2001-09-05 |
| US5434239A (en) | 1995-07-18 |
| KR960704962A (ko) | 1996-10-09 |
| CA2174312A1 (en) | 1995-04-27 |
| WO1995011268A1 (en) | 1995-04-27 |
| DE69419930T2 (de) | 2000-03-30 |
| KR100330825B1 (ko) | 2002-12-06 |
| US5552513A (en) | 1996-09-03 |
| EP0724607A1 (en) | 1996-08-07 |
| CA2174312C (en) | 2005-02-15 |
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| FG2A | Definitive protection |
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