ES2138224T3 - Procedimiento y catalizador para la hidrogenacion selectiva de butinodiol para dar butenodiol. - Google Patents
Procedimiento y catalizador para la hidrogenacion selectiva de butinodiol para dar butenodiol.Info
- Publication number
- ES2138224T3 ES2138224T3 ES95925826T ES95925826T ES2138224T3 ES 2138224 T3 ES2138224 T3 ES 2138224T3 ES 95925826 T ES95925826 T ES 95925826T ES 95925826 T ES95925826 T ES 95925826T ES 2138224 T3 ES2138224 T3 ES 2138224T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- give
- procedure
- selective hydrogenation
- butinodiol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 238000005457 optimization Methods 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000003440 toxic substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
- C07C33/035—Alkenediols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/60—Platinum group metals with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8953—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA PRESENTE INVENCION DESCRIBE UN PROCEDIMIENTO PARA LA HIDROGENACION SELECTIVA DE BUTIN-2-DIOL (1,4) PARA DAR BUTEN-2DIOL (1,4) CON AYUDA DE UN CATALIZADOR DE PALADIO, QUE TIENE COBRE Y ZINC, O PLATA Y ZINC. EN LA FORMA PREFERIDA DE REALIZACION SE CONSIGUE, MEDIANTE LA OPTIMIZACION DE LA COMPOSICION CATALITICA, ELEVAR LA ACTIVIDAD Y SELECTIVIDAD DE LOS CATALIZADORES Y SIMULTANEAMENTE EVITAR EL MANEJO DE SUSTANCIAS TOXICAS EN LA OBTENCION Y UTILIZACION DEL CATALIZADOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4423738A DE4423738A1 (de) | 1994-07-06 | 1994-07-06 | Verfahren und Katalysator zur Selektivhydrierung von Butindiol zu Butendiol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2138224T3 true ES2138224T3 (es) | 2000-01-01 |
Family
ID=6522420
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95925826T Expired - Lifetime ES2138224T3 (es) | 1994-07-06 | 1995-07-04 | Procedimiento y catalizador para la hidrogenacion selectiva de butinodiol para dar butenodiol. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5714644A (es) |
| EP (1) | EP0770049B1 (es) |
| JP (1) | JP3738032B2 (es) |
| KR (1) | KR100383496B1 (es) |
| CN (1) | CN1064948C (es) |
| AU (1) | AU688539B2 (es) |
| BR (1) | BR9508232A (es) |
| DE (2) | DE4423738A1 (es) |
| ES (1) | ES2138224T3 (es) |
| HU (1) | HU221027B1 (es) |
| IL (1) | IL113995A (es) |
| RU (1) | RU2154527C2 (es) |
| UA (1) | UA44896C2 (es) |
| WO (1) | WO1996001242A1 (es) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6576588B2 (en) * | 2000-04-07 | 2003-06-10 | Catalytic Distillation Technologies | Process for selective hydrogenation of alkynes and catalyst therefor |
| WO2003033136A2 (en) * | 2001-10-15 | 2003-04-24 | Catalytic Distillation Technologies | Hydrogenation catalyst and hydrogenation process |
| WO2005116650A2 (en) * | 2004-04-19 | 2005-12-08 | Sdc Materials, Llc | High throughput discovery of materials through vapor phase synthesis |
| DE102005042185A1 (de) * | 2005-09-06 | 2007-03-08 | Basf Ag | Verfahren zur Abtrennung von polymeren Nebenprodukten aus 1,4-Butindiol |
| ES2494850T3 (es) | 2007-03-06 | 2014-09-16 | Kuraray Co., Ltd. | Método de producción continua de 2,5-dihidrofurano |
| EP2150971B1 (en) | 2007-05-11 | 2018-11-28 | Umicore AG & Co. KG | Method and apparatus for making uniform and ultrasmall nanoparticles |
| US8481449B1 (en) | 2007-10-15 | 2013-07-09 | SDCmaterials, Inc. | Method and system for forming plug and play oxide catalysts |
| US7964114B2 (en) * | 2007-12-17 | 2011-06-21 | Sud-Chemie Inc. | Iron-based water gas shift catalyst |
| US8803025B2 (en) | 2009-12-15 | 2014-08-12 | SDCmaterials, Inc. | Non-plugging D.C. plasma gun |
| US8557727B2 (en) | 2009-12-15 | 2013-10-15 | SDCmaterials, Inc. | Method of forming a catalyst with inhibited mobility of nano-active material |
| US20110144382A1 (en) * | 2009-12-15 | 2011-06-16 | SDCmaterials, Inc. | Advanced catalysts for fine chemical and pharmaceutical applications |
| US20110143930A1 (en) * | 2009-12-15 | 2011-06-16 | SDCmaterials, Inc. | Tunable size of nano-active material on nano-support |
| US9126191B2 (en) | 2009-12-15 | 2015-09-08 | SDCmaterials, Inc. | Advanced catalysts for automotive applications |
| US9149797B2 (en) * | 2009-12-15 | 2015-10-06 | SDCmaterials, Inc. | Catalyst production method and system |
| US8652992B2 (en) * | 2009-12-15 | 2014-02-18 | SDCmaterials, Inc. | Pinning and affixing nano-active material |
| US9119309B1 (en) | 2009-12-15 | 2015-08-25 | SDCmaterials, Inc. | In situ oxide removal, dispersal and drying |
| US8399718B2 (en) | 2010-12-06 | 2013-03-19 | Sud-Chemie Inc. | Promoted copper/zinc catalyst for hydrogenating aldehydes to alcohols |
| US8669202B2 (en) | 2011-02-23 | 2014-03-11 | SDCmaterials, Inc. | Wet chemical and plasma methods of forming stable PtPd catalysts |
| EP2744590A4 (en) | 2011-08-19 | 2016-03-16 | Sdcmaterials Inc | COATED SUBSTRATES FOR USE IN CATALYSIS AND CATALYSTS AND METHOD FOR COATING SUBSTRATES WITH PRIMING COMPOSITIONS |
| US9156025B2 (en) | 2012-11-21 | 2015-10-13 | SDCmaterials, Inc. | Three-way catalytic converter using nanoparticles |
| US9511352B2 (en) | 2012-11-21 | 2016-12-06 | SDCmaterials, Inc. | Three-way catalytic converter using nanoparticles |
| US9586179B2 (en) | 2013-07-25 | 2017-03-07 | SDCmaterials, Inc. | Washcoats and coated substrates for catalytic converters and methods of making and using same |
| US9427732B2 (en) | 2013-10-22 | 2016-08-30 | SDCmaterials, Inc. | Catalyst design for heavy-duty diesel combustion engines |
| JP2016535664A (ja) | 2013-10-22 | 2016-11-17 | エスディーシーマテリアルズ, インコーポレイテッド | リーンNOxトラップの組成物 |
| EP3119500A4 (en) | 2014-03-21 | 2017-12-13 | SDC Materials, Inc. | Compositions for passive nox adsorption (pna) systems |
| CN106040246B (zh) * | 2016-06-27 | 2019-04-05 | 中触媒新材料股份有限公司 | 一种镍基催化剂及其制备方法和催化1,4-丁炔二醇选择性加氢合成1,4-丁烯二醇的应用 |
| CN107537516B (zh) * | 2016-06-28 | 2020-05-12 | 中国石油化工股份有限公司 | 用于制备仲丁醇的催化剂及其制备方法 |
| EP3275537A1 (en) | 2016-07-25 | 2018-01-31 | Omya International AG | Surface-modified calcium carbonate as carrier for transition metal-based catalysts |
| CN106694010B (zh) * | 2016-12-27 | 2018-08-28 | 重庆建峰工业集团有限公司 | 一种用于炔醇半加氢制烯醇的催化剂及其制备方法 |
| CN109107583B (zh) * | 2018-06-13 | 2021-12-03 | 厦门大学 | 一种丁炔二醇半加氢双金属催化剂及其制备方法与应用 |
| CN114452964B (zh) * | 2020-10-21 | 2024-05-10 | 中国石油化工股份有限公司 | 一种双功能催化剂及其制备方法与应用 |
| CN114192161A (zh) * | 2021-12-03 | 2022-03-18 | 大连理工大学 | 一种合成1,4-丁烯二醇的Pt-Zn催化剂、制备方法及应用 |
| FR3134015A1 (fr) * | 2022-03-31 | 2023-10-06 | IFP Energies Nouvelles | Catalyseur a base de palladium et de zinc sur un support d’alumine |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE564339A (es) * | 1957-02-05 | 1900-01-01 | ||
| GB832141A (en) * | 1957-08-01 | 1960-04-06 | Gen Aniline & Film Corp | Hydrogenation catalyst and its use in partial hydrogenation of 1,4-butynediol |
| US2953605A (en) * | 1957-12-23 | 1960-09-20 | Gen Aniline & Film Corp | Hydrogenation of 1, 4-butynediol to 1, 4-butanediol |
| US3119879A (en) * | 1960-05-27 | 1964-01-28 | Gen Aniline & Film Corp | Hydrogenation of 1, 4-butynediol to 1, 4-butenediol |
| US3450776A (en) * | 1968-02-16 | 1969-06-17 | Snam Progetti | Process for the hydrogenation of water-miscible acetylene compounds into olefin compounds |
| HU168073B (es) * | 1973-12-19 | 1976-02-28 | ||
| DE2431929C3 (de) * | 1974-07-03 | 1981-04-02 | Basf Ag, 6700 Ludwigshafen | Katalysator zur partiellen Hydrierung |
| CA1090829A (en) * | 1977-05-20 | 1980-12-02 | G A F Corporation | Process for the partial catalytic hydrogenation of butynediol to butenediol in high yield |
| JPS6014003B2 (ja) * | 1978-11-08 | 1985-04-11 | 信越化学工業株式会社 | シス−オレフィン化合物の選択的製造方法 |
| JPS56120687A (en) * | 1980-02-28 | 1981-09-22 | Takeda Chem Ind Ltd | Cephalosporin derivative and its preparation |
| DE3438851A1 (de) * | 1984-10-24 | 1986-04-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinisch ungesaettigten verbindungen, insbesondere alkenolen |
| DE3444112A1 (de) * | 1984-12-04 | 1986-06-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von olefinisch ungesaettigten verbindungen, insbesondere alkenolen |
| DD246986A1 (de) * | 1986-02-24 | 1987-06-24 | Buna Chem Werke Veb | Verfahren zur herstellung von butendiol-1,4 |
| EP0489722B1 (en) * | 1987-10-16 | 1995-02-01 | Kao Corporation | Process for preparing N-substituted amine |
| DE3913839A1 (de) * | 1989-04-27 | 1990-10-31 | Basf Ag | Verfahren zur hydrierung von acetylenalkoholen |
-
1994
- 1994-07-06 DE DE4423738A patent/DE4423738A1/de not_active Withdrawn
-
1995
- 1995-06-02 IL IL11399595A patent/IL113995A/en not_active IP Right Cessation
- 1995-07-04 ES ES95925826T patent/ES2138224T3/es not_active Expired - Lifetime
- 1995-07-04 BR BR9508232A patent/BR9508232A/pt not_active IP Right Cessation
- 1995-07-04 UA UA97010048A patent/UA44896C2/uk unknown
- 1995-07-04 AU AU29812/95A patent/AU688539B2/en not_active Ceased
- 1995-07-04 WO PCT/EP1995/002592 patent/WO1996001242A1/de not_active Ceased
- 1995-07-04 HU HU9700013A patent/HU221027B1/hu not_active IP Right Cessation
- 1995-07-04 JP JP50367896A patent/JP3738032B2/ja not_active Expired - Fee Related
- 1995-07-04 KR KR1019970700018A patent/KR100383496B1/ko not_active Expired - Fee Related
- 1995-07-04 US US08/765,215 patent/US5714644A/en not_active Expired - Fee Related
- 1995-07-04 EP EP95925826A patent/EP0770049B1/de not_active Expired - Lifetime
- 1995-07-04 DE DE59506904T patent/DE59506904D1/de not_active Expired - Fee Related
- 1995-07-04 RU RU97101900/04A patent/RU2154527C2/ru not_active IP Right Cessation
- 1995-07-04 CN CN951939556A patent/CN1064948C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU2981295A (en) | 1996-01-25 |
| AU688539B2 (en) | 1998-03-12 |
| UA44896C2 (uk) | 2002-03-15 |
| IL113995A0 (en) | 1995-10-31 |
| KR970704655A (ko) | 1997-09-06 |
| EP0770049A1 (de) | 1997-05-02 |
| KR100383496B1 (ko) | 2003-08-19 |
| BR9508232A (pt) | 1998-05-19 |
| CN1064948C (zh) | 2001-04-25 |
| JP3738032B2 (ja) | 2006-01-25 |
| HU9700013D0 (en) | 1997-02-28 |
| RU2154527C2 (ru) | 2000-08-20 |
| US5714644A (en) | 1998-02-03 |
| CN1151725A (zh) | 1997-06-11 |
| HU221027B1 (hu) | 2002-07-29 |
| DE59506904D1 (de) | 1999-10-28 |
| JPH10502363A (ja) | 1998-03-03 |
| IL113995A (en) | 1999-01-26 |
| WO1996001242A1 (de) | 1996-01-18 |
| DE4423738A1 (de) | 1996-01-11 |
| EP0770049B1 (de) | 1999-09-22 |
| HUT76706A (en) | 1997-10-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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