ES2139837T3 - Mejoras respecto a las recuperaciones de cauchos naturales y sinteticos. - Google Patents
Mejoras respecto a las recuperaciones de cauchos naturales y sinteticos.Info
- Publication number
- ES2139837T3 ES2139837T3 ES95301399T ES95301399T ES2139837T3 ES 2139837 T3 ES2139837 T3 ES 2139837T3 ES 95301399 T ES95301399 T ES 95301399T ES 95301399 T ES95301399 T ES 95301399T ES 2139837 T3 ES2139837 T3 ES 2139837T3
- Authority
- ES
- Spain
- Prior art keywords
- crumbs
- elastomeric materials
- vulcanised
- compounds
- delink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920003052 natural elastomer Polymers 0.000 title 1
- 229920001194 natural rubber Polymers 0.000 title 1
- 229920003051 synthetic elastomer Polymers 0.000 title 1
- 239000005061 synthetic rubber Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/28—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic compounds containing nitrogen, sulfur or phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Sustainable Development (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Preparing Plates And Mask In Photomechanical Process (AREA)
- Tires In General (AREA)
- Graft Or Block Polymers (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
SE PRESENTA UN PROCESO PARA RECICLAR MATERIALES ELASTOMERICOS POLIMERIZADOS MEDIANTE AZUFRE QUE COMPRENDE LA MASTICACION DE LOS MATERIALES ELASTOMERICOS A TEMPERATURAS POR DEBAJO DE 50 (GRADOS) C CON UNA NUEVA MEZCLA QUIMICA QUE ES CAPAZ DE INICIAR EL INTERCAMBIO DE PROTONES DE FORMA CONTROLADA Y POR LO TANTO DE ABRIR O DESUNIR LA RED VULCANIZADA DE LOS MATERIALES ELASTOMERICOS. LA NUEVA MEZCLA QUIMICA SE HACE A PARTIR DE SAL DE ZINC DE DIMETILDITIOCARBAMATO Y DE MERCAPTOBENZOTIAZOLA EN LA PROPORCION MOLAR EN LA BANDA DE ENTRE 1:1 Y 1:12 DISPERSA EN DIOLES EN LA PRESENCIA DE ACIDO ESTEARICO, OXIDO DE ZINC Y AZUFRE. ESTA MEZCLA QUE PUEDE DENOMINARSE "DELINK" CUANDO SE MEZCLA CON TROZOS DESMENUZADOS DE NEUMATICOS O CUALQUIER OTRO MATERIAL VULCANIZADO EN CONCENTRACIONES DE SEIS PARTES DE AMALGAMADOR POR CIEN PARTES DE MIGAJAS DE GOMA DESUNE LA RED VULCANIZADA Y DEJA EL COMPUESTO LISTO PARA SU MOLDEADO Y VULCANIZACION. EL PERIODO DE DESMENUZAMIENTO TOTAL, QUE SE PRODUCE A TEMPERATURAS POR DEBAJO DE 50 (GRADOS) C, DURA SOLAMENTE ENTRE 7 Y 10 MINUTOS. ALTERNATIVAMENTE, EL AMALGAMADOR Y LOS PEDAZOS DESMENUZADOS PUEDEN MEZCLARSE PRIMERO EN UNA INTER-MEZCLA Y SUBSECUENTEMENTE MOLERSE EN UNA TRITURADORA ABIERTA. LOS COMPUESTOS DE GOMA RECICLADA OBTENIDOS MUESTRAN NIVELES SATISFACTORIOS DE CARACTERISTICAS FISICAS Y DINAMICAS. DICHOS COMPUESTOS PUEDEN UTILIZARSE DIRECTAMENTE EN ARTICULOS MOLDEADOS O MEZCLARSE CON COMPUESTOS FRESCOS EN NEUMATICOS Y AREAS RELACIONADAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MYPI9401654 | 1994-06-25 | ||
| EP94306799 | 1994-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2139837T3 true ES2139837T3 (es) | 2000-02-16 |
Family
ID=26137294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95301399T Expired - Lifetime ES2139837T3 (es) | 1994-06-25 | 1995-03-03 | Mejoras respecto a las recuperaciones de cauchos naturales y sinteticos. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0690091B1 (es) |
| AT (1) | ATE184618T1 (es) |
| DE (1) | DE69512145T2 (es) |
| DK (1) | DK0690091T3 (es) |
| ES (1) | ES2139837T3 (es) |
| GR (1) | GR3032147T3 (es) |
| RO (1) | RO113738B1 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19711050B4 (de) * | 1997-03-03 | 2007-03-22 | Krieg, Gerhard | Verfahren und Anlage zur Replastifizierung von Altgummimehlen |
| MY116864A (en) * | 1997-03-07 | 2004-04-30 | Yap Choo Kiat Lee Kim Huat | Method for reclaiming rubber |
| RU2136708C1 (ru) * | 1997-06-06 | 1999-09-10 | Центр по разработке эластомеров Казанского государственного технологического университета | Способ регенерации резин на основе бутилкаучука |
| IL132422A0 (en) * | 1999-10-17 | 2001-03-19 | Levgum Ltd | Modifier for devulcanization of cured elastomers mainly vulcanized rubber and method for devulcanization by means of this modifier |
| WO2001029121A1 (de) * | 1999-10-22 | 2001-04-26 | Ket Kunststoff- Und Elasttechnik Gmbh Liegau-August Usbad | Devulkanisat aus gummiabfällen, devulkanisatcompound, verfahren zu deren herstellung und verwendung zum wiedereinsatz in frischmischungen und zur herstellung von spritzgussformteilen |
| US7531579B2 (en) | 2006-06-22 | 2009-05-12 | Ecser Rubber, Inc. | Method of making and using sorbent and filtering material from secondary waste rubber |
| LU91419B1 (en) * | 2006-07-13 | 2008-04-21 | Elastomer Technologies Ltd | Improvements in and relating to the recycling of natural and synthetic rubbers. |
| US8304458B2 (en) * | 2008-08-18 | 2012-11-06 | Innovert Investments A.L. Ltd | Method and chemical composition for reclaiming of cured elastomer materials |
| DE102010006476A1 (de) | 2010-01-31 | 2011-08-04 | Entex Rust & Mitschke GmbH, 44805 | Devulkanisieren von Altgummi |
| US9926426B2 (en) | 2010-01-31 | 2018-03-27 | Entex Rust & Mitschke Gmbh | Non-chemical, mechanical procedure for the devulcanization of scrap rubber and/or elastomers and apparatus therefor |
| EP2914635B1 (en) | 2012-11-02 | 2020-06-24 | Lehigh Technologies, Inc. | Methods of functionalizing reclaimed elastomer material and compositions comprising the same |
| WO2017042811A1 (en) | 2015-09-09 | 2017-03-16 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Devulcanized rubber, method for its preparation and its use as an absorbent |
| CA3048427C (en) | 2016-12-29 | 2021-06-22 | Appia, Llc | Method of recycling rubber |
| US11434353B2 (en) | 2019-02-12 | 2022-09-06 | Appia, Llc | Method and product of modifying vulcanized rubber |
| CN113527763B (zh) * | 2021-08-18 | 2023-03-17 | 徐州工业职业技术学院 | 一种废轮胎胶粉室温再生的复合再生活化剂及其制备方法和应用 |
| IT202300023412A1 (it) | 2023-11-07 | 2025-05-07 | Reuse S R L | Composizione devulcanizzante, relativo processo di preparazione, e metodo per la devulcanizzazione di elastomeri vulcanizzati mediante detta composizione |
| CN119751765A (zh) * | 2024-12-20 | 2025-04-04 | 华南理工大学 | 一种废橡胶脱硫接枝改性再生的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR494757A (es) * | 1917-04-24 | 1900-01-01 | ||
| GB443831A (en) * | 1935-10-10 | 1936-03-06 | Francis Norman Pickett | Improvements in the treatment of rubber |
| NL67287C (es) * | 1941-06-05 | 1900-01-01 | ||
| US4211676A (en) * | 1977-06-07 | 1980-07-08 | Bridgestone Tire Company Limited | Process for reclaiming scrap vulcanized rubber |
| SU956297A1 (ru) * | 1981-03-27 | 1982-09-07 | Ярославский политехнический институт | Способ измельчени резин |
| SU1620454A1 (ru) * | 1987-07-13 | 1991-01-15 | Предприятие П/Я А-3832 | Композици дл получени регенерата |
| SU1666479A1 (ru) * | 1988-05-20 | 1991-07-30 | Ярославский политехнический институт | Вулканизуема резинова смесь |
-
1995
- 1995-03-03 DE DE69512145T patent/DE69512145T2/de not_active Expired - Fee Related
- 1995-03-03 ES ES95301399T patent/ES2139837T3/es not_active Expired - Lifetime
- 1995-03-03 DK DK95301399T patent/DK0690091T3/da active
- 1995-03-03 EP EP19950301399 patent/EP0690091B1/en not_active Expired - Lifetime
- 1995-03-03 AT AT95301399T patent/ATE184618T1/de not_active IP Right Cessation
- 1995-06-22 RO RO95-01176A patent/RO113738B1/ro unknown
-
1999
- 1999-12-15 GR GR990403233T patent/GR3032147T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK0690091T3 (da) | 2000-04-03 |
| EP0690091A1 (en) | 1996-01-03 |
| DE69512145D1 (de) | 1999-10-21 |
| GR3032147T3 (en) | 2000-04-27 |
| EP0690091B1 (en) | 1999-09-15 |
| DE69512145T2 (de) | 2000-04-06 |
| ATE184618T1 (de) | 1999-10-15 |
| RO113738B1 (ro) | 1998-10-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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