ES2141180T3 - Proceso para la preparacion de poliacetales. - Google Patents

Proceso para la preparacion de poliacetales.

Info

Publication number
ES2141180T3
ES2141180T3 ES94111762T ES94111762T ES2141180T3 ES 2141180 T3 ES2141180 T3 ES 2141180T3 ES 94111762 T ES94111762 T ES 94111762T ES 94111762 T ES94111762 T ES 94111762T ES 2141180 T3 ES2141180 T3 ES 2141180T3
Authority
ES
Spain
Prior art keywords
acid
acide
stabilization
temperature
setiinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94111762T
Other languages
English (en)
Inventor
Michael Hoffmockel
Karl-Friedrich Muck
Helmut Schlaf
Karlheinz Burg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Original Assignee
Ticona GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ticona GmbH filed Critical Ticona GmbH
Application granted granted Critical
Publication of ES2141180T3 publication Critical patent/ES2141180T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18—Copolymerisation of aldehydes or ketones
    • C08G2/24—Copolymerisation of aldehydes or ketones with acetals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/30—Chemical modification by after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

PROCEDIMIENTO PARA LA ELABORACION CONTINUA DE HOMO Y COPOLIOXIMETILENOS ESTABLES DE GRUPOS TERMINALES EN FASE HOMOGENEA, DONDE EN UN REACTOR TUBULAR SON POLIMERIZABLES CON ELEMENTOS ESTATICOS DE FORMALDEHIDO OLIGOMEROS CICLICOS EN PRESENCIA DE ACIDO PROTONICO COMO INICIADOR EN CANTIDAD DESDE 0,005 HASTA 500 PPM EN UNA ZONA DE POLIMERIZACION. EL TIEMPO DE PERMANENCIA DE LOS COMPONENTES DE REACCION EN ESTA ZONA ALCANZA DESDE 0,1 HASTA 10 MINUTOS Y A CONTINUACION DE FORMA INMEDIATA EN LA POLIMERIZACION SE REALIZA UNA DESACTIVIZACION DEL INICIADOR, CON LO CUAL SE DETERMINA UN PASO FLUIDO ENTRE ZONAS DE POLIMERIZACION Y DESACTIVACION, QUE ESTA CONDICIONADO UNICAMENTE A TRAVES DE LA ADICION DEL DESACTIVADOR, Y DONDE JUNTAMENTE A LA DESACTIVACION SE REALIZA UNA ESTABILIZACION DE LOS EXTREMOS DE CADENA EN PRESENCIA DE MONOMEROS RESIDUALES, DONDE EN UN AGREGADO DE DESGASIFICACION COLOCADO A CONTINUACION SE ELIMINAN LOS COMPONENTES VOLATILES A PARTIR DE LA MEZCLA DE REACCION. LA ESTABILIZACION SE REALIZA EN PRESENCIA DE SUSTANCIAS ALCALINAS, BIEN EN UNA TEMPERATURA DESDE 150 RESENCIA DE AGUA O BIEN CON ALCOHOLES PRIMARIOS O A UNA TEMPERATURA DESDE 175 ADICIONALES.
ES94111762T 1993-08-13 1994-07-28 Proceso para la preparacion de poliacetales. Expired - Lifetime ES2141180T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4327245A DE4327245A1 (de) 1993-08-13 1993-08-13 Verfahren zur Herstellung von Polyacetalen

Publications (1)

Publication Number Publication Date
ES2141180T3 true ES2141180T3 (es) 2000-03-16

Family

ID=6495132

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94111762T Expired - Lifetime ES2141180T3 (es) 1993-08-13 1994-07-28 Proceso para la preparacion de poliacetales.

Country Status (11)

Country Link
US (1) US5608030A (es)
EP (1) EP0638599B1 (es)
JP (1) JP3359748B2 (es)
KR (1) KR100328569B1 (es)
CN (1) CN1102417A (es)
BR (1) BR9403237A (es)
CA (1) CA2130030A1 (es)
DE (2) DE4327245A1 (es)
ES (1) ES2141180T3 (es)
RU (1) RU94029668A (es)
TW (1) TW348180B (es)

Families Citing this family (50)

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DE4431575A1 (de) 1994-09-05 1996-03-07 Hoechst Ag Verfahren zur Herstellung von Polyacetalcopolymeren
DE4443150C2 (de) * 1994-12-05 2000-02-24 Hoechst Ag Acetalcopolymere mit verbesserten mechanischen Eigenschaften
JP3037612B2 (ja) * 1996-04-12 2000-04-24 ポリプラスチックス株式会社 ポリアセタール共重合体の製造方法
MY118000A (en) * 1996-04-12 2004-08-30 Polyplastics Co Process for producing polyacetal copolymer
US6001767A (en) * 1997-08-04 1999-12-14 Witco Corporation Heteropoly acid peroxide promoter
US6379711B1 (en) 1999-02-05 2002-04-30 Crompton Corporation Phosphomolybdic acid stabilizer for hydrogen peroxide
DE19936715A1 (de) * 1999-08-06 2001-02-15 Ticona Gmbh Emissionsarme eingefärbte Polyoxymethylen-Formmassen
US6433128B2 (en) * 2000-05-22 2002-08-13 Mitsubishi Gas Chemical Co, Inc. Process for producing oxymethylene copolymer
DE102004005657A1 (de) * 2004-02-04 2005-08-25 Basf Ag Fließfähige Polyesterformmassen
DE102004005652A1 (de) 2004-02-04 2005-08-25 Basf Ag Fließfähige Polyesterformmassen
MY139705A (en) * 2004-07-19 2009-10-30 Basf Ag Mixtures of hyperbranched polyesters with polycarbonates as additive for polyester molding compositions
DE102004035357A1 (de) * 2004-07-21 2006-03-16 Basf Ag Kontinuierliches Verfahren zur Herstellung von Polyalkylenarylaten mit hyperverzweigten Polyestern und/oder Polycarbonaten
DE102004038976A1 (de) * 2004-08-10 2006-02-23 Basf Ag Fließfähige Polyesterformmassen mit ASA/ABS und SAN
DE102004059243A1 (de) * 2004-08-10 2006-02-23 Basf Ag Thermoplastische Formmassen mit verbesserten Fließ- und Entformungseigenschaften
DE102004038979A1 (de) * 2004-08-10 2006-02-23 Basf Ag Schlagzähmodifizierte Polyester mit hyperverzweigten Polyestern
DE102004049342A1 (de) * 2004-10-08 2006-04-13 Basf Ag Fließfähige Thermoplaste mit halogenfreiem Flammschutz
DE102004050025A1 (de) * 2004-10-13 2006-04-20 Basf Ag Fließfähige Thermoplaste mit Halogenflammschutz
DE102004051241A1 (de) * 2004-10-20 2006-05-04 Basf Ag Fließfähige Polyamide mit hyperverzweigten Polyestern/Polycarbonaten
DE102004057867A1 (de) * 2004-11-30 2006-06-01 Basf Ag Verfahren zur Herstellung von Polyoxymethylenen
DE102005002044A1 (de) * 2005-01-14 2006-07-20 Basf Ag Fließfähige Polyester mit Hydrolyseschutz
DE102005002413A1 (de) * 2005-01-18 2006-07-27 Basf Ag Verfahren zur Entfernung von Restmonomeren aus Polyoxymethylenen unter Überdruck
DE102005004856A1 (de) 2005-02-01 2006-08-03 Basf Ag Fliessfähige Polyester mit Carbodilmid-Stabilisatoren
DE102005004855A1 (de) * 2005-02-01 2006-08-03 Basf Ag Verfahren zur Entfernung von Restmonomeren aus Polyoxymethylenen in Gegenwart saurer Katalysatoren
DE102005012480A1 (de) * 2005-03-16 2006-09-21 Basf Ag Verfahren zur Entfernung von Restmonomeren aus Polyoxymethylenen
DE102005012482A1 (de) * 2005-03-16 2006-09-21 Basf Ag Verfahren zur Herstellung von Polyoxymethylenen
DE102005016129A1 (de) * 2005-04-08 2006-10-12 Ticona Gmbh Verfahren zur Herstellung von Polyoxymethylen-Homo-und-Copolymeren und dafür geeignete Vorrichtung
US20060252912A1 (en) * 2005-04-15 2006-11-09 Ticona Gmbh Process for preparing polyoxymethylene homo- and copolymers and apparatus suitable for this purpose
DE102005027549A1 (de) 2005-06-14 2006-12-21 Basf Ag Mehrkomponentenformkörper mit Polyesterschichten
DE102005034490A1 (de) * 2005-07-20 2007-01-25 Basf Ag Zusatzstoff-freies Verfahren zur Herstellung von Polyoxymethylenen
DE102005034980A1 (de) * 2005-07-22 2007-01-25 Basf Ag Fasern und Flüssigkeitsbehälter aus PET
DE102005034999A1 (de) * 2005-07-22 2007-01-25 Basf Ag Fließfähige Polyester mit Polyesterelastomeren
DE102005054877A1 (de) * 2005-11-17 2007-05-24 Basf Ag Verfahren zur Herstellung eines Polyoxymethylenhomo- oder -Copolymer-Endproduktes
DE102005062326A1 (de) * 2005-12-24 2007-06-28 Ticona Gmbh Verfahren zur Herstellung von Oxymethylen-Polymeren, ausgewählte Polymere und deren Verwendung
DE102005062327A1 (de) * 2005-12-24 2007-06-28 Ticona Gmbh Verfahren zur Herstellung von Oxymethylen-Polymeren in homogener Phase und Verwendung
US20100004409A1 (en) * 2006-07-26 2010-01-07 Basf Se Method for producing polyoxymethylenes with certain deactivators
AU2008328032A1 (en) * 2007-11-22 2009-05-28 Dsm Ip Assets B.V. Process for the preparation of a condensation resin
JP2009215340A (ja) * 2008-03-07 2009-09-24 Polyplastics Co 安定化ポリアセタール共重合体の製造方法
DE102008018967A1 (de) * 2008-04-16 2009-10-22 Ticona Gmbh Oxymethylenpolymere, Verfahren zu deren Herstellung und deren Verwendung
DE102008018966A1 (de) * 2008-04-16 2009-10-22 Ticona Gmbh Verfahren zur Herstellung von Oxymethylen-Polymeren und dafür geeignete Vorrichtung
CN102079801A (zh) 2009-09-25 2011-06-01 提克纳有限公司 氧亚甲基聚合物及其制备方法
US8840976B2 (en) 2010-10-14 2014-09-23 Ticona Llc VOC or compressed gas containment device made from a polyoxymethylene polymer
EP2505609B1 (en) 2011-04-01 2015-01-21 Ticona GmbH High impact resistant polyoxymethylene for extrusion blow molding
WO2013101624A1 (en) 2011-12-30 2013-07-04 Ticona Llc Printable molded articles made from a polyoxymethylene polymer composition
US20130203958A1 (en) * 2012-02-02 2013-08-08 Basf Se Polyoxymethylene copolymers
US20130203921A1 (en) * 2012-02-02 2013-08-08 Basf Se Thermoplastic pom composition
US9745467B2 (en) 2012-12-27 2017-08-29 Ticona, Llc Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light
WO2015002147A1 (ja) 2013-07-01 2015-01-08 三菱瓦斯化学株式会社 オキシメチレン共重合体の製造方法
WO2016104065A1 (ja) 2014-12-25 2016-06-30 三菱瓦斯化学株式会社 オキシメチレン共重合体の製造方法
KR102467119B1 (ko) 2016-11-07 2022-11-14 미츠비시 가스 가가쿠 가부시키가이샤 옥시메틸렌 공중합체의 제조 방법
WO2023017741A1 (ja) * 2021-08-10 2023-02-16 ポリプラスチックス株式会社 変性ポリアセタール樹脂の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1176748A (en) 1967-04-29 1970-01-07 Sir Soc Italiana Resine Spa Process for Polymerizing Gaseous Formaldehyde.
DE3066423D1 (en) * 1979-11-06 1984-03-08 Ube Industries Process for polymerizing formaldehyde
DE3147309A1 (de) * 1981-11-28 1983-06-01 Basf Ag, 6700 Ludwigshafen Kontinuierliches verfahren zur herstellung von oxymethylenpolymeren
JPH0737504B2 (ja) * 1987-12-25 1995-04-26 ポリプラスチックス株式会社 アセタール重合体又は共重合体の製造法
JPH0730149B2 (ja) * 1988-06-13 1995-04-05 ポリプラスチックス株式会社 アセタール重合体又は共重合体の製造法
US4975520A (en) * 1989-03-20 1990-12-04 Hoechst Celanese Corp. Production of acetal copolymers from gaseous formaldehyde and cyclic ethers

Also Published As

Publication number Publication date
EP0638599A3 (de) 1995-10-18
KR100328569B1 (ko) 2002-11-22
DE4327245A1 (de) 1995-02-16
DE59408901D1 (de) 1999-12-16
KR950005863A (ko) 1995-03-20
RU94029668A (ru) 1996-07-10
CA2130030A1 (en) 1995-02-14
US5608030A (en) 1997-03-04
JPH0790037A (ja) 1995-04-04
EP0638599B1 (de) 1999-11-10
BR9403237A (pt) 1995-04-11
TW348180B (es) 1998-12-21
JP3359748B2 (ja) 2002-12-24
CN1102417A (zh) 1995-05-10
EP0638599A2 (de) 1995-02-15

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