ES2141439T3 - Uso de un sorbente para separar oxidos de azufre y de nitrogeno presentes en un gas. - Google Patents
Uso de un sorbente para separar oxidos de azufre y de nitrogeno presentes en un gas.Info
- Publication number
- ES2141439T3 ES2141439T3 ES96250043T ES96250043T ES2141439T3 ES 2141439 T3 ES2141439 T3 ES 2141439T3 ES 96250043 T ES96250043 T ES 96250043T ES 96250043 T ES96250043 T ES 96250043T ES 2141439 T3 ES2141439 T3 ES 2141439T3
- Authority
- ES
- Spain
- Prior art keywords
- sorbent
- alumina
- nitrogen oxides
- gas
- alkaline earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002594 sorbent Substances 0.000 title abstract 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- 229910052815 sulfur oxide Inorganic materials 0.000 title 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 6
- 239000002245 particle Substances 0.000 abstract 3
- 239000003381 stabilizer Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- -1 other rare earths Chemical compound 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002912 waste gas Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
Abstract
USO DE UN SORBENTE DE ALUMINA CAPAZ DE ADSORBER EL NOX Y EL SOX DE LOS GASES DE DESECHO Y DE REGENERASE SI SE CALIENTA A MAS DE 650 (GRADOS) C EN UN PROCESO PARA LA RETIRA CONTINUA DE LOS OXIDOS DE NITROGENO Y DE LOS OXIDOS DE AZUFRE DE UN GAS QUE LOS CONTIENE Y PARA LA REGENERACION DEL SORBENTE. EL SORBENTE DE ALUMINA SE FORMA INCORPORANDO UN AGENTE ESTABILIZADOR DE ALUMINA EN EL SORBENTE. UN METODO PREFERENTE ES AÑADIR EL ESTABILIZADOR CUANDO SE PRECIPITA LA ALUMINA. CON EL POLVO PRECIPITADO SE FORMA POSTERIORMENTE UNA SUSPENSION QUE SE TRABAJA Y SE DESHIDRATA POR PULVERIZACION PARA FORMAR LAS PARTICULAS DE ALUMINA ESFERICAS ESTABILIZADAS QUE TIENEN UN TAMAÑO DE PARTICULA MENOR DE 500 MICRAS. LAS PARTICULAS SE IMPREGNAN CON UN METAL ALCALINO O UN METAL ALCALINO-TERREO PARA FORMAR EL SORBENTE ESTABILIZADO. LOS ESTABILIZADORES DE ALUMINA INCLUYEN UNO O MAS DE LOS SIGUIENTES: SILICE, LANTANA, OTRAS TIERRAS RARAS, TITANIA, ZIRCONIA Y TIERRAS ALCALINAS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/021,709 US5427995A (en) | 1993-02-24 | 1993-02-24 | SOx/NOx sorbent and process of use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2141439T3 true ES2141439T3 (es) | 2000-03-16 |
Family
ID=21805704
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94250033T Expired - Lifetime ES2108369T3 (es) | 1993-02-24 | 1994-02-15 | Nuevo sorbente de sox/nox y proceso para su uso. |
| ES96250043T Expired - Lifetime ES2141439T3 (es) | 1993-02-24 | 1994-02-15 | Uso de un sorbente para separar oxidos de azufre y de nitrogeno presentes en un gas. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94250033T Expired - Lifetime ES2108369T3 (es) | 1993-02-24 | 1994-02-15 | Nuevo sorbente de sox/nox y proceso para su uso. |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5427995A (es) |
| EP (2) | EP0720864B1 (es) |
| AT (2) | ATE184809T1 (es) |
| DE (2) | DE69406335T2 (es) |
| DK (2) | DK0720864T3 (es) |
| ES (2) | ES2108369T3 (es) |
| GR (2) | GR3025580T3 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6068824A (en) * | 1993-02-04 | 2000-05-30 | Nippon Shokubai Co., Ltd. | Adsorbent for nitrogen oxides and method for removal of nitrogen oxides by use thereof |
| FR2720296B1 (fr) * | 1994-05-27 | 1996-07-12 | Rhone Poulenc Chimie | Composés à base d'alumine, d'oxyde de cérium et d'oxyde de zirconium à réductibilité élevée, leur procédé de préparation et leur utilisation dans la préparation de catalyseurs. |
| US5985790A (en) * | 1994-12-07 | 1999-11-16 | Project Earth Industries, Inc. | Method of making acid contacted enhanced aluminum oxide adsorbent particle |
| US6342191B1 (en) | 1994-12-07 | 2002-01-29 | Apyron Technologies, Inc. | Anchored catalyst system and method of making and using thereof |
| US5948726A (en) * | 1994-12-07 | 1999-09-07 | Project Earth Industries, Inc. | Adsorbent and/or catalyst and binder system and method of making therefor |
| US5955393A (en) * | 1995-04-21 | 1999-09-21 | Project Earth Industries, Inc. | Enhanced adsorbent and room temperature catalyst particle and method of making therefor |
| US5830422A (en) * | 1995-06-23 | 1998-11-03 | Ormiston Mining And Smelting Co. Ltd. | Method for production of sodium bicarbonate, sodium carbonate and ammonium sulfate from sodium sulfate |
| US5893940A (en) * | 1997-05-05 | 1999-04-13 | Ppg Industries, Inc. | Reduction of NOx emissions in a glass melting furnace |
| US5990030A (en) * | 1997-06-13 | 1999-11-23 | Tricat Industries, Inc. | Sox reducing additive for FCC systems |
| US5935894A (en) * | 1997-07-02 | 1999-08-10 | Laroche Industries, Inc. | Alumina based adsorbent containing alkali metal compounds |
| FR2774606B1 (fr) * | 1998-02-11 | 2000-03-17 | Rhodia Chimie Sa | Procede d'elimination de composes halogenes contenus dans un gaz ou un liquide |
| US6589494B1 (en) | 1998-03-31 | 2003-07-08 | Institut Francais Du Petrole | Process for eliminating halogen-containing compounds contained in a gas or liquid using an adsorbent composition based on at least one metallic element |
| US6383273B1 (en) | 1999-08-12 | 2002-05-07 | Apyron Technologies, Incorporated | Compositions containing a biocidal compound or an adsorbent and/or catalyst compound and methods of making and using therefor |
| US20020052291A1 (en) * | 1999-09-30 | 2002-05-02 | Ranjani Siriwardane | Low temperature sorbents for removal of sulfur compounds from fluid feed streams |
| JP2001219056A (ja) * | 2000-02-14 | 2001-08-14 | Miura Co Ltd | ダイオキシン類の吸着材 |
| IT1317868B1 (it) | 2000-03-02 | 2003-07-15 | Eni Spa | Catalizzatore a base di cobalto supportato, particolarmente utilenella reazione di fischer-tropsch. |
| US7759288B2 (en) * | 2005-07-27 | 2010-07-20 | Air Products And Chemicals, Inc. | Co-formed base-treated aluminas for water and CO2 removal |
| KR102191088B1 (ko) * | 2014-03-14 | 2020-12-15 | 릴라이언스 인더스트리즈 리미티드 | 이산화탄소포집을 위한 안정화된 무기 산화물 지지체와 그로부터 유도되는 흡착제 |
| EP3384980A1 (en) * | 2017-04-06 | 2018-10-10 | SASOL Germany GmbH | Process for production of attrition stable granulated material |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2647701A1 (de) * | 1975-10-22 | 1977-04-28 | Atomic Energy Authority Uk | Sole und gele und verfahren zu ihrer herstellung |
| US4154812A (en) * | 1977-03-25 | 1979-05-15 | W. R. Grace & Co. | Process for preparing alumina |
| US4780446A (en) * | 1982-09-30 | 1988-10-25 | W. R. Grace & Co. | Alumina-silica cogel |
| JPS6186419A (ja) * | 1984-10-05 | 1986-05-01 | Mitsui Alum Kogyo Kk | 活性アルミナ粒の製造方法 |
| US4755499A (en) * | 1984-10-12 | 1988-07-05 | Noxso Corporation | Sorbent for removing nitrogen oxides, sulfur oxides and hydrogen sulfide from gas streams |
| US4798711A (en) * | 1984-10-12 | 1989-01-17 | Noxso Corporation | Processes for removing nitrogen oxides, sulfur oxides and hydrogen sulfide from gas streams |
| US5126299A (en) * | 1989-10-23 | 1992-06-30 | Texaco Inc. | Catalyst for the control of SOx emission |
| US5096871A (en) * | 1990-07-03 | 1992-03-17 | Alcan International Limited | Alumina-alkali metal aluminum silicate agglomerate acid adsorbents |
| US5180703A (en) * | 1991-04-24 | 1993-01-19 | W. R. Grace & Co.-Conn. | Sox/nox sorbent and process of use |
-
1993
- 1993-02-24 US US08/021,709 patent/US5427995A/en not_active Expired - Lifetime
-
1994
- 1994-02-15 EP EP96250043A patent/EP0720864B1/en not_active Expired - Lifetime
- 1994-02-15 AT AT96250043T patent/ATE184809T1/de not_active IP Right Cessation
- 1994-02-15 ES ES94250033T patent/ES2108369T3/es not_active Expired - Lifetime
- 1994-02-15 AT AT94250033T patent/ATE159433T1/de not_active IP Right Cessation
- 1994-02-15 DE DE69406335T patent/DE69406335T2/de not_active Expired - Lifetime
- 1994-02-15 DK DK96250043T patent/DK0720864T3/da active
- 1994-02-15 EP EP94250033A patent/EP0618004B1/en not_active Expired - Lifetime
- 1994-02-15 DE DE69420855T patent/DE69420855T2/de not_active Expired - Fee Related
- 1994-02-15 ES ES96250043T patent/ES2141439T3/es not_active Expired - Lifetime
- 1994-02-15 DK DK94250033.1T patent/DK0618004T3/da active
-
1995
- 1995-03-24 US US08/410,244 patent/US5585082A/en not_active Expired - Fee Related
-
1997
- 1997-12-03 GR GR970403230T patent/GR3025580T3/el unknown
-
1999
- 1999-12-22 GR GR990403336T patent/GR3032248T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK0720864T3 (da) | 1999-12-20 |
| EP0618004A1 (en) | 1994-10-05 |
| EP0720864A1 (en) | 1996-07-10 |
| DE69420855D1 (de) | 1999-10-28 |
| US5585082A (en) | 1996-12-17 |
| EP0618004B1 (en) | 1997-10-22 |
| ATE184809T1 (de) | 1999-10-15 |
| US5427995A (en) | 1995-06-27 |
| GR3032248T3 (en) | 2000-04-27 |
| DE69406335T2 (de) | 1998-05-20 |
| ATE159433T1 (de) | 1997-11-15 |
| DK0618004T3 (da) | 1997-12-01 |
| EP0720864B1 (en) | 1999-09-22 |
| ES2108369T3 (es) | 1997-12-16 |
| GR3025580T3 (en) | 1998-03-31 |
| DE69406335D1 (de) | 1997-11-27 |
| DE69420855T2 (de) | 2000-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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