ES2143649T3 - Metodo para incrementar la velocidad de hidrogenacion de amidas aromaticas. - Google Patents
Metodo para incrementar la velocidad de hidrogenacion de amidas aromaticas.Info
- Publication number
- ES2143649T3 ES2143649T3 ES95930286T ES95930286T ES2143649T3 ES 2143649 T3 ES2143649 T3 ES 2143649T3 ES 95930286 T ES95930286 T ES 95930286T ES 95930286 T ES95930286 T ES 95930286T ES 2143649 T3 ES2143649 T3 ES 2143649T3
- Authority
- ES
- Spain
- Prior art keywords
- increase
- speed
- aromatic amides
- hydrogenation
- hydrogenation speed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000008430 aromatic amides Chemical class 0.000 title 1
- 150000004982 aromatic amines Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
- C07C211/35—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing only non-condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
- C07C211/36—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing at least two amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
- C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
UN PROCEDIMIENTO PARA AUMENTAR LA VELOCIDAD DE HIDROGENACION CATALITICA DE AMINAS AROMATICAS MEDIANTE LA REACCION DE AMINAS AROMATICAS CON HIDROGENO EN PRESENCIA DE UN CATALIZADOR DE METAL NOBLE, UN SOLVENTE ORGANICO MISCIBLE EN AGUA, UN PROMOTOR DE CATALIZADOR DE HIDROXIDO DE LITIO, Y AGUA EN UNA CANTIDAD EFECTIVA PARA AUMENTAR LA VELOCIDAD DE LA REACCION DE HIDROGENACION SIN UN AUMENTO APRECIABLE EN LAS CANTIDADES TOTALES DE SUB-PRODUCTOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/307,215 US5550294A (en) | 1992-02-05 | 1994-09-16 | Method of increasing hydrogenation rate of aromatic amines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2143649T3 true ES2143649T3 (es) | 2000-05-16 |
Family
ID=23188757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95930286T Expired - Lifetime ES2143649T3 (es) | 1994-09-16 | 1995-08-28 | Metodo para incrementar la velocidad de hidrogenacion de amidas aromaticas. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5550294A (es) |
| EP (1) | EP0781267B1 (es) |
| JP (1) | JPH10506386A (es) |
| KR (1) | KR970706237A (es) |
| AU (1) | AU3373495A (es) |
| DE (1) | DE69515046T2 (es) |
| ES (1) | ES2143649T3 (es) |
| WO (1) | WO1996008462A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7304183B2 (en) * | 2004-12-16 | 2007-12-04 | Huntsman Petrochemical Corporation | Co-production of cyclohexylamine and bis(para-aminocyclohexyl) methane |
| CN102030657A (zh) * | 2010-11-25 | 2011-04-27 | 浙江台州清泉医药化工有限公司 | 一种3,3′-二甲基-4,4′-二氨基二环己基甲烷的合成方法 |
| TWI534131B (zh) | 2014-11-27 | 2016-05-21 | 財團法人工業技術研究院 | 氫化4,4’-二胺基二苯甲烷的觸媒與方法 |
| CN110078627B (zh) * | 2019-06-03 | 2022-01-07 | 万华化学集团股份有限公司 | 一种高收率合成h6mda的方法 |
| CN114160127B (zh) * | 2021-12-01 | 2023-11-14 | 常州大学 | 一种防脱胺加氢催化剂及其制备方法和应用 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2551028A (en) * | 1946-10-05 | 1951-05-01 | Wallace & Tiernan Inc | Lamp changing apparatus |
| US2606928A (en) * | 1947-11-18 | 1952-08-12 | Du Pont | Preparation of amino alicyclic compounds |
| US2606924A (en) * | 1949-06-09 | 1952-08-12 | Du Pont | Bis (4-aminocyclohexyl)-methane |
| US2606925A (en) * | 1949-12-15 | 1952-08-12 | Du Pont | Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds |
| US3155724A (en) * | 1961-12-29 | 1964-11-03 | Du Pont | Process for bringing stereoisomeric mixture of bis-(4-aminocyclohexane) methane close to the equilibrium concentration |
| US3347917A (en) * | 1961-12-29 | 1967-10-17 | Du Pont | Process for the preparation of di (paraaminocyclohexyl) methane |
| CH515882A (de) * | 1965-12-23 | 1971-11-30 | Du Pont | Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin) |
| US3636108A (en) * | 1965-12-23 | 1972-01-18 | Du Pont | Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium |
| US3591635A (en) * | 1968-09-25 | 1971-07-06 | Upjohn Co | Catalytic hydrogenation process for preparing di(4 - aminocyclohexyl) methane |
| US3644522A (en) * | 1969-04-04 | 1972-02-22 | Du Pont | Catalytic hydrogenation of nitrogen containing compounds over supported ruthenium catalysts |
| US3679746A (en) * | 1969-10-27 | 1972-07-25 | Du Pont | Isomer enrichment of bicyclohexyl-4,4{40 -diamine |
| US3711550A (en) * | 1970-02-16 | 1973-01-16 | Du Pont | Isomerization of 4,4'-methylenedi (cyclohexylamine) over moderated ruthenium catalyst |
| US3697449A (en) * | 1970-12-14 | 1972-10-10 | Du Pont | Alkali moderation of supported ruthenium catalysts |
| US3766272A (en) * | 1972-08-25 | 1973-10-16 | Du Pont | 4,4'-methylenedi(cyclohexylamine)isomerization over a supported catalyst |
| US3856862A (en) * | 1973-06-25 | 1974-12-24 | Upjohn Co | Process for hydrogenation of di(4-aminophenyl)methane with a rhodium catalyst |
| US3959374A (en) * | 1974-05-30 | 1976-05-25 | Jefferson Chemical Company, Inc. | Process for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines |
| JPS5379840A (en) * | 1976-12-23 | 1978-07-14 | Takeda Chem Ind Ltd | Preparation of bis(aminomethyl)cyclohexane |
| JPS5416452A (en) * | 1977-07-08 | 1979-02-07 | Takeda Chem Ind Ltd | Preparation of dis(amnomethyl) cyclohexane |
| US4181680A (en) * | 1979-02-01 | 1980-01-01 | Suntech, Inc. | Hydrogenation of aromatic amines |
| US4394522A (en) * | 1981-06-01 | 1983-07-19 | Mobay Chemical Corporation | Catalytic hydrogenation of di(4-aminophenyl)methane |
| US4394523A (en) * | 1981-06-01 | 1983-07-19 | Mobay Chemical Corporation | Catalytic hydrogenation of di (4-aminophenyl) methane |
| US4448995A (en) * | 1982-12-13 | 1984-05-15 | Mobay Chemical Corporation | Catalytic hydrogenation of di(4-aminophenyl)methane |
| US4754070A (en) * | 1986-01-23 | 1988-06-28 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane |
| US4960941A (en) * | 1988-03-30 | 1990-10-02 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts |
| WO1993016030A1 (en) * | 1992-02-05 | 1993-08-19 | Olin Corporation | Promoters for hydrogenation of aromatic amines |
-
1994
- 1994-09-16 US US08/307,215 patent/US5550294A/en not_active Expired - Lifetime
-
1995
- 1995-08-28 JP JP8510203A patent/JPH10506386A/ja active Pending
- 1995-08-28 AU AU33734/95A patent/AU3373495A/en not_active Abandoned
- 1995-08-28 WO PCT/US1995/010851 patent/WO1996008462A1/en not_active Ceased
- 1995-08-28 DE DE69515046T patent/DE69515046T2/de not_active Expired - Fee Related
- 1995-08-28 EP EP95930286A patent/EP0781267B1/en not_active Revoked
- 1995-08-28 ES ES95930286T patent/ES2143649T3/es not_active Expired - Lifetime
- 1995-08-28 KR KR1019970701701A patent/KR970706237A/ko not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JPH10506386A (ja) | 1998-06-23 |
| EP0781267B1 (en) | 2000-02-09 |
| DE69515046T2 (de) | 2000-06-29 |
| KR970706237A (ko) | 1997-11-03 |
| AU3373495A (en) | 1996-03-29 |
| US5550294A (en) | 1996-08-27 |
| EP0781267A1 (en) | 1997-07-02 |
| EP0781267A4 (en) | 1997-11-05 |
| WO1996008462A1 (en) | 1996-03-21 |
| DE69515046D1 (de) | 2000-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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