ES2145492T3 - Procedimiento para la preparacion de polialcoholes. - Google Patents

Procedimiento para la preparacion de polialcoholes.

Info

Publication number
ES2145492T3
ES2145492T3 ES96938170T ES96938170T ES2145492T3 ES 2145492 T3 ES2145492 T3 ES 2145492T3 ES 96938170 T ES96938170 T ES 96938170T ES 96938170 T ES96938170 T ES 96938170T ES 2145492 T3 ES2145492 T3 ES 2145492T3
Authority
ES
Spain
Prior art keywords
phase
amine
polyalcoholes
formaldehyde
transesterification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96938170T
Other languages
English (en)
Inventor
Detlef Kratz
Achim Stammer
Tom Witzel
Martin Brudermuller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2145492T3 publication Critical patent/ES2145492T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
    • C07C29/1285—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/22—Trihydroxylic alcohols, e.g. glycerol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA PRODUCCION DE POLIALCOHOLES, QUE COMPRENDE LAS SIGUIENTES FASES: (A) REACCION DE UN ALCANAL O CETONA CON UN FORMALDEHIDO EN UNA SOLUCION ACUOSA Y EN PRESENCIA DE UNA AMINA TERCIARIA; (B) SEPARACION DEL AGUA, LA AMINA TERCIARIA SOBRANTE Y EL FORMALDEHIDO SOBRANTE; (C) CALENTAMIENTO DE LA MEZCLA QUE QUEDA DE (B), SEPARANDO OTRO FORMALDEHIDO Y LA AMINA TERCIARIA Y FORMANDO FORMIATOS POLIALCOHOLICOS; (D) TRANSFORMACION DE LA AMINA TERCIARIA SEPARADA DE LA FASE (B) Y/O DE LA FASE (C), EN LA FASE DE SINTESIS (A) Y/O EN LA POSTERIOR FASE DE TRANSESTERIFICACION (E); (E) TRANSESTERIFICACION DE LOS FORMIATOS POLIALCOHOLICOS OBTENIDOS EN LA FASE (C) CON UN ALCOHOL DE FORMULA ROH, EN PRESENCIA DE UN CATALIZADOR DE TRANSESTERIFICACION, CONVIRTIENDOSE EN POLIALCOHOLES Y FORMIATOS DE FORMULA (I), A CUYO EFECTO R ES UN RADICAL HIDROCARBURO, PREFERIBLEMENTE UN RADICAL ALQUILO CON 1 A 6, PREFERENTEMENTE DE 1 A 2, ATOMOS DE C; (F) OBTENCION DE LOS POLIALCOHOLES.
ES96938170T 1995-11-10 1996-11-11 Procedimiento para la preparacion de polialcoholes. Expired - Lifetime ES2145492T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19542036A DE19542036A1 (de) 1995-11-10 1995-11-10 Verfahren zur Herstellung von Polyalkoholen

Publications (1)

Publication Number Publication Date
ES2145492T3 true ES2145492T3 (es) 2000-07-01

Family

ID=7777191

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96938170T Expired - Lifetime ES2145492T3 (es) 1995-11-10 1996-11-11 Procedimiento para la preparacion de polialcoholes.

Country Status (9)

Country Link
US (1) US6018074A (es)
EP (1) EP0876316B1 (es)
JP (1) JP2001507668A (es)
KR (1) KR100463360B1 (es)
CN (1) CN1077093C (es)
DE (2) DE19542036A1 (es)
ES (1) ES2145492T3 (es)
MY (1) MY120911A (es)
WO (1) WO1997017313A1 (es)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11124348A (ja) * 1997-10-22 1999-05-11 Koei Chem Co Ltd トリメチロールアルカンを製造する方法
CN1116262C (zh) * 1997-10-22 2003-07-30 广荣化学工业株式会社 三羟甲基烷烃的生产方法
DE19963437A1 (de) 1999-12-28 2001-07-05 Basf Ag Verfahren zur Zersetzung von bei der Synthese mehrwertiger Alkohole gebildeter hochsiedender Nebenprodukte
DE19963435A1 (de) 1999-12-28 2001-07-05 Basf Ag Verfahren zur Reinigung von durch Hydrierung hergestelltem Trimethylolpropan durch kontinuierliche Destillation
DE19963445A1 (de) * 1999-12-28 2001-07-05 Basf Ag Verfahren zur Abtrennung von Formaldehyd aus polyolhaltigen Reaktionsgemischen unter Zusatz von Lösungsmitteln
DE10063937A1 (de) 2000-12-20 2002-07-18 Bayer Ag Verfahren zur Herstellung von Trimethylolverbindungen und Ameisensäure
DE10223055A1 (de) * 2002-05-24 2003-12-11 Basf Ag Verfahren zur Herstellung von Polyesterpolyolen mehrwertiger Alkohole
SE0301102D0 (sv) 2003-04-14 2003-04-14 Tetra Laval Holdings & Finance Method in connection with the production of a apckaging laminate thus produced and a packaging container manufactures from the packaging laminate
DE10317543A1 (de) 2003-04-16 2004-11-04 Basf Ag Verfahren zur Hydrierung von Methylolalkanalen
DE102006009838A1 (de) * 2006-03-01 2007-09-06 Basf Ag Verfahren zur Hydrierung von Methylolalkanalen
US7388116B2 (en) * 2006-06-06 2008-06-17 Basf Aktiengesellschaft Hydrogenation of methylolalkanals
US7462747B2 (en) * 2007-01-05 2008-12-09 Basf Aktiengesellschaft Process for preparing polyalcohols from formaldehyde having a low formic acid content
CN102105503B (zh) 2008-07-23 2014-03-19 巴斯夫欧洲公司 2-异丙基-2-烷基-1,3-丙二醇用于制备聚合物的用途
WO2010066674A2 (de) 2008-12-09 2010-06-17 Basf Se Verfahren zur herstellung von polymethylolen
WO2010079187A1 (de) * 2009-01-12 2010-07-15 Basf Se Verfahren zur herstellung von polymethylolen
US8853465B2 (en) 2010-05-12 2014-10-07 Basf Se Process for preparing neopentyl glycol
RU2012153379A (ru) 2010-05-12 2014-06-20 Басф Се Способ получения неопентилгликоля
DE102010033844B4 (de) 2010-08-11 2013-01-03 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
WO2012143309A1 (de) 2011-04-19 2012-10-26 Basf Se Verfahren zur herstellung von neopentylglykol
CN102304022A (zh) * 2011-07-05 2012-01-04 上海华谊（集团）公司 一种缩合加氢法制备三羟甲基丙烷反应过程中副产物2-乙基丙烯醛的回收利用方法
WO2013026758A1 (de) 2011-08-23 2013-02-28 Basf Se Verfahren zur herstellung von neopentylglykol
DE102011118956A1 (de) 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylolpropan und mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011118953B4 (de) 2011-11-19 2014-06-05 Oxea Gmbh Destillatives Verfahren zur Gewinnung von Di-Trimethylolpropan
DE102011118993A1 (de) 2011-11-19 2013-05-23 Oxea Gmbh Verfahren zur Gewinnung von Di-Trimethylpropan und mit Trimethylpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
DE102011122356A1 (de) 2011-12-23 2013-06-27 Oxea Gmbh Verfahren zur Gewinnung von mit Trimethylolpropan angereicherten Produktströmen aus den Nebenströmen der Trimethylolpropanherstellung
US8710278B1 (en) 2013-01-31 2014-04-29 Eastman Chemical Company Process for producing polyols
US9056824B2 (en) 2013-01-31 2015-06-16 Eastman Chemical Company Preparation of hydroxy aldehydes
KR102245932B1 (ko) 2017-10-23 2021-04-28 주식회사 엘지화학 트리메틸올프로판의 제조방법
CN114276214B (zh) * 2021-12-10 2024-06-25 湖北宜化化工科技研发有限公司 一种回收利用电石渣生产季戊四醇的生产方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2292926A (en) * 1938-05-10 1942-08-11 Du Pont Preparation of methyltrimethylolmethane
US2790837A (en) * 1954-06-08 1957-04-30 Celanese Corp Continuous production of trimethylolethane
US3097245A (en) * 1959-01-13 1963-07-09 Trojan Powder Co Process for the preparation of trimethylolalkane
US3478115A (en) * 1967-05-05 1969-11-11 Commercial Solvents Corp Method of making polymethylolalkane mixtures
DE2105922C3 (de) * 1971-02-09 1974-08-08 Institut Organitscheskoj Chimii Akademii Nauk Kirgisskoj Ssr, Frunse (Sowjetunion) Verfahren zur Herstellung von Aldehydalkoholen und Ketonalkoholen
DE2507461C3 (de) * 1975-02-21 1986-05-07 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von 2,2- Dimethylolalkanalen
DE2721186C2 (de) * 1977-05-11 1986-04-24 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung eines Gemisches von niedermolekularen Polyhydroxylverbindungen
FR2413348A1 (fr) * 1977-12-31 1979-07-27 Dynamit Nobel Ag Procede pour l'obtention d'alcools benzyliques
DE2813201A1 (de) * 1978-03-25 1979-10-04 Bayer Ag Verfahren zur herstellung von 2,2-dimethylolalkanalen
DE3340791A1 (de) * 1983-11-11 1985-05-23 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von trimethylolalkanen aus alkanalen und formaldehyd
DE3715035A1 (de) * 1987-05-06 1988-11-17 Basf Ag Verfahren zur gewinnung von trialkylaminen und methylformiat bei der herstellung von trimethylolalkanen
EP0614453A4 (en) * 1992-09-25 1994-09-21 Aristech Chemical Corp Manufacture of trimethylolpropane.

Also Published As

Publication number Publication date
DE19542036A1 (de) 1997-05-15
KR100463360B1 (ko) 2005-02-28
EP0876316B1 (de) 2000-04-05
MY120911A (en) 2005-12-30
DE59604922D1 (de) 2000-05-11
CN1077093C (zh) 2002-01-02
KR19990067461A (ko) 1999-08-16
JP2001507668A (ja) 2001-06-12
CN1202146A (zh) 1998-12-16
WO1997017313A1 (de) 1997-05-15
US6018074A (en) 2000-01-25
EP0876316A1 (de) 1998-11-11

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