ES2146841T3 - Procedimiento para la inhibicion de la formacion de coque en los hornos de pirolisis. - Google Patents
Procedimiento para la inhibicion de la formacion de coque en los hornos de pirolisis.Info
- Publication number
- ES2146841T3 ES2146841T3 ES96307868T ES96307868T ES2146841T3 ES 2146841 T3 ES2146841 T3 ES 2146841T3 ES 96307868 T ES96307868 T ES 96307868T ES 96307868 T ES96307868 T ES 96307868T ES 2146841 T3 ES2146841 T3 ES 2146841T3
- Authority
- ES
- Spain
- Prior art keywords
- oven
- pyrolysis
- coke
- formation
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000197 pyrolysis Methods 0.000 title abstract 6
- 230000015572 biosynthetic process Effects 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 230000005764 inhibitory process Effects 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical class C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical class C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000203 mixture Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/04—Thermal processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
- C10G9/16—Preventing or removing incrustation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
LOS COMPUESTOS AROMATICOS EN PEQUEÑAS CANTIDADES ACTUAN COMO ADITIVOS ANTIINCRUSTANTES EN LOS HORNOS PARA PIROLISIS QUE ESTAN SOMETIDOS A TEMPERATURAS ELEVADAS, DESDE APROXIMADAMENTE 500 LOS HIDROCARBUROS EN ETILENO ASI COMO EN OTROS PRODUCTOS UTILES. ESTOS HORNOS PRODUCEN MATERIAL QUE SE DEPOSITA Y ACUMULA SOBRE LAS SUPERFICIES DEL HORNO, ENTRE LAS QUE SE INCLUYEN LOS SERPENTINES RADIANTES DEL HORNO Y LOS INTERCAMBIADORES DEL CIRCUITO DE TRANSFERENCIA. LOS PRESENTES ADITIVOS ANTIINCRUSTANTES INHIBEN Y SUPRIMEN LA FORMACION Y DEPOSICION DE MATERIAL SOBRE LAS SUPERFICIES DEL HORNO. LA PRESENTE INVENCION CONSISTE EN UN METODO PARA INHIBIR LA FORMACION DE COQUE SOBRE LAS SUPERFICIES DE UNA SECCION DE CALEFACCION POR CALOR RADIANTE DE UN HORNO PARA PIROLISIS Y LAS SUPERFICIES SITUADAS INMEDIATAMENTE A CONTINUACION DE ESA SECCION EN CONTACTO CON UNA CARGA DE HIDROCARBUROS QUE COMPRENDE EL RASCADO DEL HORNO PARA PIROLISIS Y, ANTES DE PROCESAR LA CARGA DE HIDROCARBUROS, LA ADICION DE UN COMPUESTOINHIBIDOR AL HORNO PARA PIROLISIS. EL COMPUESTO INHIBIDOR SE ELIGE ENTRE UN GRUPO DE COMPUESTOS QUE INCLUYE BENCENOS SUSTITUIDOS, NAFTALENOS SUSTITUIDOS, ANTRACENOS SUSTITUIDOS, FENANTRENOS SUSTITUIDOS Y MEZCLAS DE LOS MISMOS DONDE EL COMPUESTO INHIBIDOR CONTIENE AL MENOS UN SUSTITUYENTE QUE TIENE AL MENOS 2 ATOMOS DE CARBONO. SOBRE LAS SUPERFICIES DEL HORNO PARA PIROLISIS, SE FORMA UNA FINA CAPA DE COQUE SIN ACTIVIDAD CATALITICA. A CONTINUACION, SE ALIMENTA EL HORNO CON LA CARGA DE HIDROCARBUROS, DE MANERA QUE LAS SUPERFICIES DEL HORNO QUEDAN PROTEGIDAS DE LA FORMACION DE COQUE CON ACTIVIDAD CATALITICA DURANTE EL PROCESAMIENTO DE LA CARGA DE HIDROCARBUROS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19960307868 EP0839782B1 (en) | 1996-10-30 | 1996-10-30 | Process for the inhibition of coke formation in pyrolysis furnaces |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2146841T3 true ES2146841T3 (es) | 2000-08-16 |
Family
ID=8225136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96307868T Expired - Lifetime ES2146841T3 (es) | 1996-10-30 | 1996-10-30 | Procedimiento para la inhibicion de la formacion de coque en los hornos de pirolisis. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0839782B1 (es) |
| DE (1) | DE69607623T2 (es) |
| DK (1) | DK0839782T3 (es) |
| ES (1) | ES2146841T3 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG55335A1 (en) * | 1996-06-28 | 1998-12-21 | Nippon Catalytic Chem Ind | Method for reducing deposition of cokes in heat-refining process of petroleum high-nolecular hydrocarbons and additive used in the method |
| US7658838B2 (en) | 2003-05-16 | 2010-02-09 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using polymeric additives |
| US7645375B2 (en) | 2003-05-16 | 2010-01-12 | Exxonmobil Research And Engineering Company | Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives |
| JP2007537342A (ja) | 2004-05-14 | 2007-12-20 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 弾性率を変えることによる重質油の粘弾性向上 |
| BRPI0510522A (pt) | 2004-05-14 | 2007-10-30 | Exxonmobil Res & Eng Co | processo para produzir e remover coque, e, coque |
| JP2007537346A (ja) | 2004-05-14 | 2007-12-20 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 重油の熱処理におけるファウリングの抑制 |
| WO2015000950A1 (en) * | 2013-07-02 | 2015-01-08 | Shell Internationale Research Maatschappij B.V. | A process of converting oxygenates to olefins and a reactor comprising a inner surface coated with a protective layer of carbonaceous material |
| WO2015000948A1 (en) * | 2013-07-02 | 2015-01-08 | Shell Internationale Research Maatschappij B.V. | A method of converting oxygenates to olefins in a reactor having a protective layer of carbonaceous material |
| CN113265268A (zh) * | 2021-05-20 | 2021-08-17 | 江苏卓然智能重工有限公司 | 一种高效抑制炉管结焦的乙烯裂解炉 |
| CN116020356B (zh) * | 2021-10-25 | 2024-10-11 | 中国石油化工股份有限公司 | 一种逆流移动床低碳烷烃脱氢的方法和系统 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3437583A (en) * | 1967-06-13 | 1969-04-08 | Betz Laboratories | Anti-foulant agents for petroleum hydrocarbons |
| US3574088A (en) * | 1969-08-25 | 1971-04-06 | Petrolite Corp | Use of oxyalkylated phenylene diamines as heat exchange anti-foulants |
| US4176045A (en) | 1978-07-10 | 1979-11-27 | Pullman Incorporated | Pyrolysis coke inhibition |
| US4440625A (en) * | 1981-09-24 | 1984-04-03 | Atlantic Richfield Co. | Method for minimizing fouling of heat exchanges |
| US4456526A (en) * | 1982-09-24 | 1984-06-26 | Atlantic Richfield Company | Method for minimizing fouling of heat exchangers |
| DD222324A1 (de) | 1983-12-30 | 1985-05-15 | Adw D Ddr Zi F Org Chemie | Verfahren zur herstellung von niederen olefinen und aromaten |
| JPS61166882A (ja) * | 1985-01-18 | 1986-07-28 | Hakutou Kagaku Kk | 炭化水素処理プロセスのコ−キング防止方法 |
| US4599480A (en) | 1985-07-12 | 1986-07-08 | Shell Oil Company | Sequential cracking of hydrocarbons |
| US5221461A (en) * | 1992-06-09 | 1993-06-22 | Betz Laboratories, Inc. | Antioxidant compositions and methods using catechol compounds and organic acid compounds |
| US5271824A (en) * | 1993-01-12 | 1993-12-21 | Betz Laboratories, Inc. | Methods for controlling fouling deposit formation in a liquid hydrocarbonaceous medium |
| US5460712A (en) * | 1994-11-30 | 1995-10-24 | Nalco Chemical Company | Coker/visbreaker and ethylene furnace antifoulant |
-
1996
- 1996-10-30 EP EP19960307868 patent/EP0839782B1/en not_active Expired - Lifetime
- 1996-10-30 DK DK96307868T patent/DK0839782T3/da active
- 1996-10-30 DE DE1996607623 patent/DE69607623T2/de not_active Expired - Fee Related
- 1996-10-30 ES ES96307868T patent/ES2146841T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0839782A1 (en) | 1998-05-06 |
| EP0839782B1 (en) | 2000-04-05 |
| DK0839782T3 (da) | 2000-08-14 |
| DE69607623T2 (de) | 2000-10-19 |
| DE69607623D1 (de) | 2000-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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