ES2151279T3 - Procesos de polimerizacion a presion elevada con sistemas de catalizadores de metales de transicion retardada - Google Patents
Procesos de polimerizacion a presion elevada con sistemas de catalizadores de metales de transicion retardadaInfo
- Publication number
- ES2151279T3 ES2151279T3 ES97928038T ES97928038T ES2151279T3 ES 2151279 T3 ES2151279 T3 ES 2151279T3 ES 97928038 T ES97928038 T ES 97928038T ES 97928038 T ES97928038 T ES 97928038T ES 2151279 T3 ES2151279 T3 ES 2151279T3
- Authority
- ES
- Spain
- Prior art keywords
- transition metal
- metal catalyst
- catalyst systems
- polymerization processes
- high pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 230000003111 delayed effect Effects 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 title abstract 2
- 150000003624 transition metals Chemical class 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 230000002051 biphasic effect Effects 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA INVENCION SE REFIERE SISTEMAS DE CATALIZADORES DE METALES DE TRANSICION RETARDADA Y A SU USO EN PROCESOS DE POLIMERIZACION, EN PARTICULAR EN UNA POLIMERIZACION EN SOLUCION, EN SUSPENSION BIFASICA Y EN FASE SUPERCRITICA DE POLIMEROS QUE CONTIENEN ETILENO. LAS REALIZACIONES PREFERENTES DE LA INVENCION COMPRENDEN EL USO DE UN SISTEMA DE CATALIZADORES DE METALES DE TRANSICION RETARDADA QUE CONTIENEN UN COMPLEJO DE METALES DEL GRUPO 9, 10 U 11 ESTABILIZADO MEDIANTE UNA ESTRUCTURA DE LIGANDO BIDENTADO PARA UNA POLIMERIZACION BAJO CONDICIONES DE PRESION, O CONCENTRACION, DE ETILENO ELEVADAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2009596P | 1996-06-17 | 1996-06-17 | |
| US2019996P | 1996-06-21 | 1996-06-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2151279T3 true ES2151279T3 (es) | 2000-12-16 |
Family
ID=26693016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97928038T Expired - Lifetime ES2151279T3 (es) | 1996-06-17 | 1997-06-17 | Procesos de polimerizacion a presion elevada con sistemas de catalizadores de metales de transicion retardada |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6127497A (es) |
| EP (1) | EP0906344B2 (es) |
| JP (1) | JP2000513398A (es) |
| CN (1) | CN1125829C (es) |
| AU (1) | AU736911B2 (es) |
| CA (1) | CA2257818C (es) |
| DE (1) | DE69702978T3 (es) |
| ES (1) | ES2151279T3 (es) |
| HU (1) | HUP0003447A3 (es) |
| WO (1) | WO1997048737A1 (es) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6812184B1 (en) * | 1996-06-17 | 2004-11-02 | Exxonmobil Chemical Patents Inc. | Supported late transition metal catalyst systems |
| US6103658A (en) | 1997-03-10 | 2000-08-15 | Eastman Chemical Company | Olefin polymerization catalysts containing group 8-10 transition metals, processes employing such catalysts and polymers obtained therefrom |
| US6660677B1 (en) * | 1997-03-10 | 2003-12-09 | Eastman Chemical Company | Supported group 8-10 transition metal olefin polymerization catalysts |
| US6822062B2 (en) | 1997-03-10 | 2004-11-23 | Eastman Chemical Company | Supported group 8-10 transition metal olefin polymerization catalysts |
| US6200925B1 (en) | 1997-03-13 | 2001-03-13 | Eastman Chemical Company | Catalyst compositions for the polymerization of olefins |
| US6245871B1 (en) | 1997-04-18 | 2001-06-12 | Eastman Chemical Company | Group 8-10 transition metal olefin polymerization catalysts |
| US6511936B1 (en) * | 1998-02-12 | 2003-01-28 | University Of Delaware | Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins |
| US6232259B1 (en) | 1998-03-31 | 2001-05-15 | E. I. Du Pont De Nemours And Company | Preparation of transition metal imine complexes |
| US6117959A (en) * | 1998-09-02 | 2000-09-12 | Eastman Chemical Company | Polyolefin catalysts |
| JP2000080125A (ja) * | 1998-09-08 | 2000-03-21 | Idemitsu Petrochem Co Ltd | エチレン単独重合体及びそれを成形してなる成形体 |
| US6184171B1 (en) * | 1998-10-05 | 2001-02-06 | W.R. Grace & Co. -Conn | Supported bidentate and tridentate catalyst compositions and olefin polymerization using same |
| WO2000035974A1 (en) | 1998-12-15 | 2000-06-22 | Basell Technology Company B.V. | Catalyst system for olefin polymerization |
| CA2363628A1 (en) | 1999-02-22 | 2000-08-31 | James Allen Ponasik Jr. | Catalysts containing n-pyrrolyl substituted nitrogen donors |
| US6545108B1 (en) | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
| US6620896B1 (en) | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
| US6281303B1 (en) | 1999-07-27 | 2001-08-28 | Eastman Chemical Company | Olefin oligomerization and polymerization catalysts |
| US6451940B1 (en) * | 1999-10-22 | 2002-09-17 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerizations |
| US6579823B2 (en) | 2000-02-18 | 2003-06-17 | Eastman Chemical Company | Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors |
| US7056996B2 (en) | 2000-02-18 | 2006-06-06 | E. I. Du Pont De Nemours And Company | Productivity catalysts and microstructure control |
| US6605677B2 (en) | 2000-02-18 | 2003-08-12 | Eastman Chemical Company | Olefin polymerization processes using supported catalysts |
| MXPA02011836A (es) | 2000-05-31 | 2003-05-14 | Du Pont | Catalizadores para la polimerizacion de olefinas. |
| BR0113137A (pt) * | 2000-08-03 | 2003-07-01 | Du Pont | Método para a redução da formação de ceras de polietileno e polìmeros em um processo contìnuo para a fabricação de um produto de (alfa)-olefina linear e processo |
| US6706891B2 (en) | 2000-11-06 | 2004-03-16 | Eastman Chemical Company | Process for the preparation of ligands for olefin polymerization catalysts |
| JP3965319B2 (ja) * | 2001-03-08 | 2007-08-29 | ザ ユニヴァーシティ オブ ホンコン | 有機金属発光材料 |
| US20040010105A1 (en) * | 2002-07-11 | 2004-01-15 | Winslow Linda N. | Slurry polymerization with unsupported late transition metal catalyst |
| AU2003291627A1 (en) | 2002-09-20 | 2004-04-08 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| US7144934B2 (en) * | 2002-10-24 | 2006-12-05 | Dow Global Technologies Inc. | Charge dissipation modifiers for olefinic interpolymer compositions |
| US6844402B1 (en) | 2003-12-11 | 2005-01-18 | Equistar Chemicals, Lp | Preparation of olefin-acrylic copolymers with late transition metal catalysts |
| US6903169B1 (en) | 2003-12-30 | 2005-06-07 | Equistar Chemicals, Lp | LTMC polymerization of unsaturated monomers |
| GB0411742D0 (en) | 2004-05-26 | 2004-06-30 | Exxonmobil Chem Patents Inc | Transition metal compounds for olefin polymerization and oligomerization |
| DE602005010255D1 (de) | 2004-07-08 | 2008-11-20 | Exxonmobil Chem Patents Inc | Katalysator system für die olefinpolymerisation und verfahren zu seiner verwendung |
| ATE529431T1 (de) | 2005-12-14 | 2011-11-15 | Exxonmobil Chem Patents Inc | Halogensubstituierte metallocenverbindungen für die olefinpolymerisation |
| EP2112173A1 (en) | 2008-04-16 | 2009-10-28 | ExxonMobil Chemical Patents Inc. | Catalyst compounds and use thereof |
| US8058461B2 (en) | 2010-03-01 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Mono-indenyl transition metal compounds and polymerization therewith |
| WO2011126788A1 (en) * | 2010-03-29 | 2011-10-13 | E. I. Du Pont De Nemours And Company | Lubricant component |
| EP3440118A1 (en) * | 2016-05-20 | 2019-02-13 | Chevron Phillips Chemical Company LP | Low pressure process for preparing low-density polyethylene |
| WO2020060889A2 (en) * | 2018-09-17 | 2020-03-26 | Chevron Phillips Chemical Company Lp | Light treatment of chromium catalysts and related catalyst preparation systems and polymerization processes |
| CN114316104B (zh) * | 2022-01-07 | 2023-12-19 | 万华化学集团股份有限公司 | 一种烯烃聚合催化剂的减活化方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3686159A (en) * | 1969-12-19 | 1972-08-22 | Shell Oil Co | Ethylene polymerization |
| US3759889A (en) * | 1970-01-15 | 1973-09-18 | Shell Oil Co | Ethylene polymerization in the presence of complex nickel catalysts containing a glycolic acid thioglycolic or thiolactic acid ligand |
| NL8204876A (nl) * | 1982-12-17 | 1984-07-16 | Stamicarbon | Katalysator en polymerisatie van olefinen met die katalysator. |
| JPS6067508A (ja) † | 1983-09-22 | 1985-04-17 | Toa Nenryo Kogyo Kk | オレフインの重合方法 |
| US4716205A (en) * | 1985-10-15 | 1987-12-29 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed polymerization of ethylene |
| US5030606A (en) * | 1985-10-15 | 1991-07-09 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed copolymerization of ethylene |
| US5084534A (en) * | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
| US5408017A (en) † | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| US5324799A (en) * | 1990-03-06 | 1994-06-28 | Akihiro Yano | Polyethylene and process of production thereof |
| EP0454231A3 (en) * | 1990-04-20 | 1992-01-15 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for olefin polymerization |
| DE69127811T3 (de) * | 1990-11-30 | 2012-04-26 | Idemitsu Kosan Co., Ltd. | Verfahren zur herstellung von olefinpolymeren |
| GB9103527D0 (en) † | 1991-02-20 | 1991-04-10 | Exxon Chemical Patents Inc | Hp catalyst killer |
| DE4131229C1 (es) * | 1991-09-19 | 1993-01-21 | Dr. Karlheinz Schmidt Apparatebau, 5205 Sankt Augustin, De | |
| CA2117888C (en) * | 1992-06-15 | 2001-05-15 | Howard William Turner | High temperature polymerization process using ionic catalysts to produce polyolefins |
| ES2137266T3 (es) * | 1992-07-01 | 1999-12-16 | Exxon Chemical Patents Inc | Catalizadores de polimerizacion de olefinas a base de metales de transicion. |
| US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
| GB9319340D0 (en) † | 1993-09-17 | 1993-11-03 | Exxon Chemical Patents Inc | Olefin polymersisation process |
| US5502128A (en) * | 1994-12-12 | 1996-03-26 | University Of Massachusetts | Group 4 metal amidinate catalysts and addition polymerization process using same |
| KR100418168B1 (ko) † | 1995-01-24 | 2004-02-14 | 이.아이,듀우판드네모아앤드캄파니 | 중합 방법 |
| US5714556A (en) * | 1995-06-30 | 1998-02-03 | E. I. Dupont De Nemours And Company | Olefin polymerization process |
| US5916982A (en) * | 1995-09-29 | 1999-06-29 | Nippon Oil Co., Ltd. | Process for the production of polyolefins |
-
1997
- 1997-06-17 DE DE69702978T patent/DE69702978T3/de not_active Expired - Lifetime
- 1997-06-17 CA CA002257818A patent/CA2257818C/en not_active Expired - Fee Related
- 1997-06-17 JP JP10503219A patent/JP2000513398A/ja active Pending
- 1997-06-17 WO PCT/US1997/010419 patent/WO1997048737A1/en not_active Ceased
- 1997-06-17 CN CN97195607A patent/CN1125829C/zh not_active Expired - Fee Related
- 1997-06-17 US US08/877,213 patent/US6127497A/en not_active Expired - Lifetime
- 1997-06-17 AU AU32350/97A patent/AU736911B2/en not_active Ceased
- 1997-06-17 EP EP97928038A patent/EP0906344B2/en not_active Expired - Lifetime
- 1997-06-17 HU HU0003447A patent/HUP0003447A3/hu unknown
- 1997-06-17 ES ES97928038T patent/ES2151279T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0906344B2 (en) | 2009-02-18 |
| HUP0003447A3 (en) | 2004-03-01 |
| EP0906344B1 (en) | 2000-08-30 |
| AU736911B2 (en) | 2001-08-02 |
| DE69702978T2 (de) | 2001-03-15 |
| CN1222164A (zh) | 1999-07-07 |
| CA2257818A1 (en) | 1997-12-24 |
| DE69702978D1 (de) | 2000-10-05 |
| WO1997048737A1 (en) | 1997-12-24 |
| EP0906344A1 (en) | 1999-04-07 |
| US6127497A (en) | 2000-10-03 |
| CA2257818C (en) | 2005-08-09 |
| JP2000513398A (ja) | 2000-10-10 |
| DE69702978T3 (de) | 2009-08-13 |
| AU3235097A (en) | 1998-01-07 |
| HUP0003447A2 (hu) | 2001-02-28 |
| CN1125829C (zh) | 2003-10-29 |
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| FG2A | Definitive protection |
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