ES2156362T3 - Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en fase gaseosa. - Google Patents

Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en fase gaseosa.

Info

Publication number
ES2156362T3
ES2156362T3 ES97905048T ES97905048T ES2156362T3 ES 2156362 T3 ES2156362 T3 ES 2156362T3 ES 97905048 T ES97905048 T ES 97905048T ES 97905048 T ES97905048 T ES 97905048T ES 2156362 T3 ES2156362 T3 ES 2156362T3
Authority
ES
Spain
Prior art keywords
phase polymerization
alkens
procedure
gaseous phase
obtaining polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97905048T
Other languages
English (en)
Inventor
John Lynch
David Fischer
Hans-Helmut Gortz
Gunther Schweier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2156362T3 publication Critical patent/ES2156362T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA PRODUCCION DE POLIMEROS DE ALQUENOS MEDIANTE POLIMERIZACION EN FASE GASEOSA EN PRESENCIA DE UNOS SISTEMAS CATALIZADORES, UTILIZANDOSE UNOS SISTEMAS CATALIZADORES PORTADOS COMO SISTEMAS CATALIZADORES, QUE SON OBTENIDOS A) HACIENDO REACCIONAR UN MATERIAL PORTANTE INORGANICO CON UN COMPUESTO METALICO DE FORMULA GENERAL (I) M 1 (R 1 ) R (R 2 ) S (R 3 ) T (R SUP,4 ) U , EN DONDE M 1 ES UN METAL ALCALINO O ALCALINOTERREO O UN METAL DEL III O IV GRUPO PRINCIPAL DEL SISTEMA PERIODICO; R 1 ES HIDROGENO, C 1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUILARILO O ARILALQUILO, EN CADA CASO, CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R 2 A R 4 SON HIDROGENO, HALOGENO, C 1 A C 10 ALQUILO, C 6 A C SUB,15 ARILO, ALQUILARILO, ARILALQUILO, ALCOXI O DIALQUILAMINO, EN CADA CASO CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R ES UN NUMERO ENTERO DEL 1 AL 4; S, T Y U SON NUMEROS ENTEROS DEL 0 AL 3, CORRESPONDIENDO LA SUMA R+S+T+U A LA VALENCIA DE M 1 ; B) HACIE NDO REACCIONAR EL MATERIAL OBTENIDO SEGUN A) CON UN COMPLEJO METALOCENO EN SU FORMA METALICA DIHALOGENA Y UN COMPUESTO FORMADOR DE IONES METALOCENOS; C) REACCION POSTERIOR CON UN COMPUESTO METALICO DE FORMULA GENERAL (II) M 2 (R 5 ) O ( R 6 ) P (R 7 )(SUB,Q , EN DONDE M 2 ES UN METAL DEL III GRUPO PRINCIPAL DEL SISTEMA PERIODICO; R 5 ES HIDROGENO, C 1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUILARILO O ARILALQUILO, EN CADA CASO, CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; R 6 Y R 7 SON HIDROGENO, HALOGENO, C SUB,1 A C 10 ALQUILO, C 6 A C 15 ARILO, ALQUIL ARILO, ARILALQUILO O ALCOXI, EN CADA CASO CON 1 A 10 ATOMOS DE C EN EL RADICAL ALQUILO Y CON 6 A 20 ATOMOS DE C EN EL RADICAL ARILO; O ES UN NUMERO ENTERO DEL 1 AL 3; P Y Q SON NUMEROS ENTEROS DEL 0 AL 2, CORRESPONDIENDO LA SUMA O+P+Q A LA VALENCIA DE M 2 .
ES97905048T 1996-02-20 1997-02-19 Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en fase gaseosa. Expired - Lifetime ES2156362T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19606165A DE19606165A1 (de) 1996-02-20 1996-02-20 Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation

Publications (1)

Publication Number Publication Date
ES2156362T3 true ES2156362T3 (es) 2001-06-16

Family

ID=7785834

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97905048T Expired - Lifetime ES2156362T3 (es) 1996-02-20 1997-02-19 Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en fase gaseosa.

Country Status (14)

Country Link
US (1) US6433110B1 (es)
EP (1) EP0882077B1 (es)
JP (1) JP2000504777A (es)
KR (1) KR100470578B1 (es)
CN (1) CN1128815C (es)
AT (1) ATE200904T1 (es)
AU (1) AU732527B2 (es)
BR (1) BR9707572A (es)
CA (1) CA2246307A1 (es)
DE (2) DE19606165A1 (es)
ES (1) ES2156362T3 (es)
NO (1) NO983786L (es)
TW (1) TW467920B (es)
WO (1) WO1997031039A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19806435A1 (de) * 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
DE19927766A1 (de) * 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
EP1146058A1 (de) * 2000-04-13 2001-10-17 Basf Aktiengesellschaft Katalysatorlösung, enthaltend ionisch aktivierte Metallocen-Verbindungen
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
JP5222544B2 (ja) * 2007-12-13 2013-06-26 日本ポリプロ株式会社 プロピレン（共）重合体の製造方法
KR101806758B1 (ko) 2008-09-25 2017-12-07 바젤 폴리올레핀 게엠베하 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름
EP2344551B1 (en) 2008-09-25 2014-05-28 Basell Polyolefine GmbH Impact resistant lldpe composition and films made thereof

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991009882A1 (en) 1990-01-02 1991-07-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
DE69222700T2 (de) * 1991-07-11 1998-03-26 Idemitsu Kosan Co Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren
DE69331112T2 (de) 1992-08-05 2002-06-20 Exxonmobil Chemical Patents Inc., Baytown Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation
JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
BE1006880A3 (fr) 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
EP0619326B1 (en) * 1993-04-09 1997-06-25 Tosoh Corporation Olefin polymerization catalyst and olefin polymerisation process
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
JP2882241B2 (ja) * 1993-06-07 1999-04-12 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
US5422325A (en) * 1993-09-17 1995-06-06 Exxon Chemical Patents Inc. Supported polymerization catalysts, their production and use
WO1995014044A1 (en) * 1993-11-19 1995-05-26 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
DE4431837A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
WO1996034020A1 (en) * 1995-04-28 1996-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use

Also Published As

Publication number Publication date
AU1874697A (en) 1997-09-10
DE59703469D1 (de) 2001-06-07
EP0882077B1 (de) 2001-05-02
DE19606165A1 (de) 1997-08-21
CN1211997A (zh) 1999-03-24
KR19990082667A (ko) 1999-11-25
NO983786D0 (no) 1998-08-19
CA2246307A1 (en) 1997-08-27
BR9707572A (pt) 1999-07-27
KR100470578B1 (ko) 2005-05-16
AU732527B2 (en) 2001-04-26
CN1128815C (zh) 2003-11-26
WO1997031039A1 (de) 1997-08-28
ATE200904T1 (de) 2001-05-15
NO983786L (no) 1998-10-19
US6433110B1 (en) 2002-08-13
JP2000504777A (ja) 2000-04-18
TW467920B (en) 2001-12-11
EP0882077A1 (de) 1998-12-09

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