ES2157378T3 - Piezas moldeadas formadas por masas de moldeo termoplasticas. - Google Patents
Piezas moldeadas formadas por masas de moldeo termoplasticas.Info
- Publication number
- ES2157378T3 ES2157378T3 ES96115411T ES96115411T ES2157378T3 ES 2157378 T3 ES2157378 T3 ES 2157378T3 ES 96115411 T ES96115411 T ES 96115411T ES 96115411 T ES96115411 T ES 96115411T ES 2157378 T3 ES2157378 T3 ES 2157378T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- sub
- polymer
- rent
- sup
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009757 thermoplastic moulding Methods 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- -1 STYRENE COMPOUND Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 150000002735 metacrylic acids Chemical class 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- 208000027418 Wounds and injury Diseases 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000006378 damage Effects 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 208000014674 injury Diseases 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
PIEZAS DE MOLDEO, OBTENIDAS DE MASAS TERMOPLASTICAS DE MOLDEO, QUE CONTIENEN A) 30 A 99,8 % EN PESO DE UN POLIMERO TERMOPLASTICO HECHO DE A1) 50 A 100 % EN PESO DE UN COMPUESTO DE ESTIRENO DE FORMULA GENERAL EN LA QUE R{SUP,1} Y R{SUP,2} SON HIDROGENO O UN ALQUILO DE C{SUB,1}-C{SUB,8}, Y/O UN ESTER DE ALQUILO (ALQUILO DE C{SUB,1}C{SUB,8} DEL ACIDO ACRILICO O METACRILICO, A2) 0 A 40 % EN PESO DE ACRILONITRILO Y/O METACRILONITRILO, Y A3) 0 A 40 % EN PESO DE OTROS MONOMEROS MONOETILENICAMENTE INSATURADOS DIFERENTES DE A2), B) 0,1 A 70 % EN PESO DE UN POLIMERO DE INJERTO CON UN DIAMETRO MEDIO DE PARTICULA D{SUB,50} MENOR QUE 500 NM HECHO DE B1) 30 A 90 % EN PESO DE UN NUCLEO DE INJERTO ELASTICO COMO CAUCHO DE UN POLIMERO CON UNA TEMPERATURA DE TRANSICION AL VIDRIO POR DEBAJO DE 0 C, QUE SE OBTIENE POR COPOLIMERIZACION DE B11) 50 A 99,99 % EN PESO DE UN ESTER (DE ALQUILO DE C{SUB,1}C{SUB,10} DEL ACIDO ACRILICO, B12) 0,01 A 5 % EN PESO DE UN MONOMERO POLIFUNCIONAL RETICULABLE, Y B13) 0 A 40 % ENPESO DE OTRO MONOMERO MONOETILENICAMENTE INSATURADO DIFERENTE DE B11), Y B2) 20 A 70 % EN PESO DE UNA CUBIERTA DE INJERTO HECHA DE B21) 50 A 100 % EN PESO DE UN COMPUESTO DE ESTIRENO DE FORMULA GENERAL EN LA QUE R{SUP,1} Y R{SUP,2} SON HIDROGENO O ALQUILO DE C{SUB,1}-C{SUB,8}, Y/O UN ESTER (DE ALQUILO DE C{SUB,1}-C{SUB,8} DEL ACIDO ACRILICO O METACRILICO, B22) 0 A 40 % EN PESO DE ACRILONITRILO Y/O METACRILONITRILO, Y B23) 0 A 40 5 EN PESO DE OTRO U OTROS MONOMEROS MONOETILENICAMENTE INSATURADOS, C) 0,1 A 70 % EN PESO DE UN POLIMERO EN PARTICULAS COMO COMPUESTO DE MATEADO, ESTANDO EL POLIMERO C) FORMADO ESENCIALMENTE POR C1) UN POLIMERO DE INJERTO ELASTICO COMO CAUCHO CON UN DIAMETRO MEDIO DE PARTICULA D{SUB,50} DE 700 NM O MAS, QUE CONTIENE ESENCIALMENTE UN NUCLEO DE INJERTO A BASE DE BUTADIENO Y UNA CUBIERTA DE INJERTO A BASE DE ESTIRENO Y ACRILONITRILO Y QUE SE SINTETIZA SEGUN EL PROCEDIMIENTO DE POLIMERIZACION EN DISOLUCION, O C2) UN POLIMERO DURO A BASE DE METACRILATOS DE POLIALQUILO, OC3) UN POLIMERO, QUE ES INCOMPATIBLE O COMPATIBLE CON MEZCLAS QUE CONTIENEN LOS COMPONENTES A) Y B) ANTES DEFINIDOS, O C4) UN POLIMERO DE INJERTO, DEFINIDO COMO EN B) PERO QUE SIN EMBARGO EL DIAMETRO MEDIO DE PARTICULA D{SUB,50} ES 700 NM O MAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19536892 | 1995-10-04 | ||
| DE19536892A DE19536892A1 (de) | 1995-10-04 | 1995-10-04 | Formteile aus thermoplastischen Formmassen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2157378T3 true ES2157378T3 (es) | 2001-08-16 |
| ES2157378T5 ES2157378T5 (es) | 2006-04-16 |
Family
ID=7773951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96115411T Expired - Lifetime ES2157378T5 (es) | 1995-10-04 | 1996-09-26 | Empleo de piezas moldeadas de masas de moldeo termoplasticas. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5821302A (es) |
| EP (1) | EP0769524B2 (es) |
| JP (1) | JPH09194656A (es) |
| KR (1) | KR970021189A (es) |
| CN (1) | CN1156736A (es) |
| DE (2) | DE19536892A1 (es) |
| ES (1) | ES2157378T5 (es) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19614844A1 (de) * | 1996-04-15 | 1997-10-16 | Basf Ag | Formmassen zur Herstellung von Formteilen mit vermindertem Oberflächenglanz |
| DE19617068A1 (de) * | 1996-04-29 | 1997-10-30 | Basf Ag | Formteile, hergestellt aus thermoplastischen Formmassen |
| DE19630099A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Radkappen |
| DE19630116A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Heckspoiler |
| CA2221266A1 (en) | 1996-12-10 | 1998-06-10 | Achim Grefenstein | Laminated sheets or films and moldings thereof |
| DE10014171A1 (de) | 2000-03-23 | 2001-09-27 | Barlog Plastics Gmbh | Fahrzeugtüraußengriff und Verfahren zu seiner Herstellung |
| KR100426123B1 (ko) * | 2001-07-04 | 2004-04-08 | 주식회사 엘지화학 | 내후성 열가소성 수지의 제조방법 |
| US20030236350A1 (en) * | 2002-06-21 | 2003-12-25 | General Electric Company | Impact-modified compositions |
| US8969476B2 (en) * | 2002-06-21 | 2015-03-03 | Sabic Global Technologies B.V. | Impact-modified compositions |
| DE10319745A1 (de) * | 2003-04-30 | 2004-11-25 | Ticona Gmbh | Thermoplastische teilkristalline Formmasse mit reduziertem Oberflächenglanz und Produkte hieraus |
| ITMI20031420A1 (it) * | 2003-07-11 | 2005-01-12 | Polimeri Europa Spa | Polimeri vinilaromatici rinforzati con gomma |
| DE10349144A1 (de) * | 2003-10-17 | 2005-05-12 | Roehm Gmbh | Polymermischung für mattierte Spritzgußteile |
| DE10354379A1 (de) * | 2003-11-20 | 2005-06-23 | Röhm GmbH & Co. KG | Formmasse, enthaltend ein Mattierungsmittel |
| US20110077355A1 (en) | 2007-08-21 | 2011-03-31 | Yoshifumi Shikisai | Method Of Producing Enlarged Rubber, Graft Copolymer, Thermoplastic Resin Composition And Molded Article |
| CN101565532B (zh) * | 2008-04-22 | 2011-01-05 | 奇美实业股份有限公司 | 橡胶改质(甲基)丙烯酸酯系树脂组成物 |
| CN101633769B (zh) * | 2008-07-24 | 2011-02-09 | 中国石油天然气股份有限公司 | 一种聚丙烯酸酯树脂组合物及其制备方法 |
| CN101880490B (zh) * | 2010-07-07 | 2012-02-15 | 宁波南海化学有限公司 | 一种消光固化剂、含消光固化剂的粉末涂料及其用途 |
| CN101985509B (zh) * | 2010-08-26 | 2012-07-04 | 上海锦湖日丽塑料有限公司 | 金属电镀层结合力优异的热塑性树脂组合物及其制备方法 |
| TWI481655B (zh) * | 2012-12-28 | 2015-04-21 | Chi Mei Corp | 橡膠改質甲基丙烯酸酯系樹脂組成物 |
| TWI455983B (zh) * | 2012-12-28 | 2014-10-11 | Chi Mei Corp | 橡膠改質甲基丙烯酸酯系樹脂組成物 |
| EP2976388B1 (de) | 2013-03-19 | 2017-10-18 | INEOS Styrolution Group GmbH | Matte witterungsbeständige formmassen für extrusionsverfahren |
| CN106459541B (zh) * | 2014-04-02 | 2020-06-23 | 英力士苯领集团股份公司 | 用于制备具有改良机械性能的热塑性成型组合物的方法 |
| CN114891308A (zh) * | 2016-08-10 | 2022-08-12 | 深圳毅彩鸿翔新材料科技有限公司 | 抗紫外耐候性asa树脂、共挤塑料制品、薄膜和制品 |
| KR102005364B1 (ko) * | 2016-11-02 | 2019-07-30 | 주식회사 엘지화학 | Asa계 그라프트 공중합체의 제조방법, 이를 포함하는 열가소성 asa계 수지 조성물의 제조방법 및 asa계 성형품의 제조방법 |
| JP7163283B2 (ja) * | 2017-06-02 | 2022-10-31 | テクノUmg株式会社 | 熱可塑性樹脂組成物及び成形体 |
| DE102020109280A1 (de) * | 2020-04-02 | 2021-10-07 | Kulzer Gmbh | Lichthärtende Zusammensetzung für die Herstellung dentaler Bauteile mit matten Oberflächen |
| EP4359477B1 (en) * | 2021-06-23 | 2025-06-04 | INEOS Styrolution Group GmbH | Weather resistant asa molding composition |
| CN119060485B (zh) * | 2024-08-26 | 2025-05-30 | 四川大学青岛研究院 | 离子聚合物吸氧复合材料及其制备方法、应用 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2826925A1 (de) * | 1978-06-20 | 1980-01-17 | Basf Ag | Witterungsbestaendige, schlagzaehe thermoplastische massen mit guter einfaerbbarkeit |
| DE2901576C2 (de) * | 1979-01-17 | 1987-02-26 | Basf Ag, 6700 Ludwigshafen | Schlagzähe thermoplastische Kunststoffmassen |
| DE3006804A1 (de) * | 1980-02-23 | 1981-09-10 | Bayer Ag, 5090 Leverkusen | Kerbschlagzaehe polymerisate mit verbesserter witterungsbestaendigkeit |
| DE3149358A1 (de) * | 1981-12-12 | 1983-06-16 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
| DE3638704A1 (de) * | 1986-11-13 | 1988-05-26 | Bayer Ag | Abs-formmassen mit reduziertem restbutadiengehalt |
| DE3802614A1 (de) * | 1988-01-29 | 1989-08-03 | Basf Ag | Formmasse und deren verwendung |
| DE4005210A1 (de) * | 1990-02-20 | 1991-08-22 | Basf Ag | Thermoplastische formmasse mit verbesserter zaehigkeit |
| DE4011162A1 (de) * | 1990-04-06 | 1991-10-10 | Basf Ag | Thermoplastische formmasse |
| DE4011163A1 (de) * | 1990-04-06 | 1991-10-10 | Basf Ag | Teilchenfoermiges pfropfpolymerisat und daraus hergestellte thermoplastische formmasse mit verbesserter zaehigkeit |
| JP2738785B2 (ja) * | 1991-06-27 | 1998-04-08 | 三菱電機株式会社 | 光磁気記録再生装置 |
| DE4125857A1 (de) † | 1991-08-03 | 1993-02-04 | Roehm Gmbh | Mattierte polymethacrylat-folie |
| DE4142910A1 (de) * | 1991-12-24 | 1993-07-01 | Basf Ag | Schlagzaehmodifier und diesen enthaltende formmasse |
| US5492966A (en) * | 1992-04-03 | 1996-02-20 | General Electric Company | Impact modified resin compositions containing lobed graft copolymers and process for the making thereof |
| DE4211412C2 (de) * | 1992-04-04 | 1998-06-04 | Benecke Ag J H | Ein- oder mehrschichtige Oberflächenfolie zum Aufkaschieren auf Substrate |
| DE4221293A1 (de) * | 1992-06-29 | 1994-01-05 | Basf Ag | Formmasse mit matter Oberfläche |
| DE4226750A1 (de) * | 1992-08-13 | 1994-02-17 | Basf Ag | Thermoplastische Formmasse mit Matteffekt |
| DE4241555A1 (de) * | 1992-12-10 | 1994-06-16 | Basf Ag | Thermoplastische Formmassen auf der Basis von Polycarbonaten, Pfropfpolymerisaten und Styrol/Acrylnitril-Copolymerisaten |
| DE4242974A1 (de) * | 1992-12-18 | 1994-06-23 | Basf Ag | Thermoplastische Formmasse mit erhöhter Kerbschlagzähigkeit |
| DE4404750A1 (de) * | 1994-02-15 | 1995-08-17 | Bayer Ag | Matte ABS-Polymer-Zusammensetzungen |
| DE4431732A1 (de) * | 1994-09-06 | 1996-03-07 | Basf Ag | Transparente, schlagzähe Formmassen mit hoher Spannungsrißbeständigkeit und matter Oberfläche |
| DE4443966A1 (de) * | 1994-12-09 | 1996-06-13 | Basf Ag | Thermoplastische Formmassen |
-
1995
- 1995-10-04 DE DE19536892A patent/DE19536892A1/de not_active Withdrawn
-
1996
- 1996-09-26 ES ES96115411T patent/ES2157378T5/es not_active Expired - Lifetime
- 1996-09-26 US US08/721,544 patent/US5821302A/en not_active Expired - Lifetime
- 1996-09-26 EP EP96115411A patent/EP0769524B2/de not_active Expired - Lifetime
- 1996-09-26 DE DE59606942T patent/DE59606942D1/de not_active Expired - Lifetime
- 1996-10-02 KR KR1019960043653A patent/KR970021189A/ko not_active Withdrawn
- 1996-10-03 CN CN96113082A patent/CN1156736A/zh active Pending
- 1996-10-04 JP JP8264780A patent/JPH09194656A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP0769524A3 (de) | 1998-01-21 |
| DE59606942D1 (de) | 2001-06-28 |
| EP0769524B2 (de) | 2005-12-14 |
| KR970021189A (ko) | 1997-05-28 |
| DE19536892A1 (de) | 1997-04-10 |
| US5821302A (en) | 1998-10-13 |
| EP0769524B1 (de) | 2001-05-23 |
| EP0769524A2 (de) | 1997-04-23 |
| CN1156736A (zh) | 1997-08-13 |
| ES2157378T5 (es) | 2006-04-16 |
| JPH09194656A (ja) | 1997-07-29 |
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