ES2157475T3 - Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester. - Google Patents

Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester.

Info

Publication number
ES2157475T3
ES2157475T3 ES96942058T ES96942058T ES2157475T3 ES 2157475 T3 ES2157475 T3 ES 2157475T3 ES 96942058 T ES96942058 T ES 96942058T ES 96942058 T ES96942058 T ES 96942058T ES 2157475 T3 ES2157475 T3 ES 2157475T3
Authority
ES
Spain
Prior art keywords
polyester
procedure
oligomero
monomero
glycolisis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96942058T
Other languages
English (en)
Inventor
Michael Paul Ekart
Thomas Michael Pell Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of ES2157475T3 publication Critical patent/ES2157475T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/18Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
    • C08J11/22Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
    • C08J11/24Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

LA INVENCION DESCRIBE UN NUEVO PROCEDIMIENTO DE RECICLAJE DE POLIESTERES. DE ACUERDO CON EL PROCEDIMIENTO DESCRITO, UN POLIESTER USADO O FRAGMENTOS DE POLIESTER SE HACE REACCIONAR CON GLICOL PARA PRODUCIR UN MONOMERO U OLIGOMERO DE BAJO PESO MOLECULAR, POR DESPOLIMERIZACION DE DICHO POLIESTER. DICHO MONOMERO U OLIGOMERO, SEGUN SEA EL CASO, SE PURIFICA A CONTINUACION UTILIZANDO UNA O MAS DE LAS SIGUIENTES FASES: FILTRACION, CRISTALIZACION Y, OPCIONALMENTE, TRATAMIENTO CON ADSORBENTE O EVAPORACION. EL MONOMERO U OLIGOMERO ASI PRODUCIDO ES ESPECIALMENTE ADECUADO COMO MATERIAL BRUTO PARA LA PRODUCCION DE POLIESTER DE TIPO DE EMBALAJE A BASE DE ACIDOS O ESTERES. DEBIDO A QUE EL PROCEDIMIENTO INCLUYE FASES DE PURIFICACION, LOS REQUISITOS REFERENTES AL MATERIAL DE POLIESTER USADO NO TIENEN QUE SER ESTRICTOS.
ES96942058T 1995-12-07 1996-11-26 Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester. Expired - Lifetime ES2157475T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/570,177 US5635584A (en) 1995-12-07 1995-12-07 Process including glycolysis and subsequent purification for recycling polyester materials

Publications (1)

Publication Number Publication Date
ES2157475T3 true ES2157475T3 (es) 2001-08-16

Family

ID=24278573

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96942058T Expired - Lifetime ES2157475T3 (es) 1995-12-07 1996-11-26 Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester.

Country Status (10)

Country Link
US (1) US5635584A (es)
EP (1) EP0865464B1 (es)
AR (1) AR004363A1 (es)
AU (1) AU1123397A (es)
BR (1) BR9611564A (es)
CA (1) CA2239003A1 (es)
DE (1) DE69613142T2 (es)
ES (1) ES2157475T3 (es)
MX (1) MX9804145A (es)
WO (1) WO1997020886A1 (es)

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US6103774A (en) * 1997-04-02 2000-08-15 The Coca-Cola Company Process for removing contaminants from polyesters and controlling polymer molecular weight
US6136869A (en) * 1997-10-17 2000-10-24 Eastman Chemical Company Depolymerization process for recycling polyesters
AUPP261498A0 (en) * 1998-03-27 1998-04-23 Swig Pty Ltd Improved conversion of contaminated polyethylene terephthalate to polybutylene terephthalate
US6410607B1 (en) * 1999-02-10 2002-06-25 Eastman Chemical Company Glycolysis process for recycling of post-consumer pet
KR100765744B1 (ko) * 2001-12-15 2007-10-15 김도균 폐 폴리에스테르를 재활용하여 토너, 잉크 및 코팅제용중합체 제조방법 및 그 조성물
CN100414441C (zh) * 2001-12-15 2008-08-27 三星电子株式会社 静电显影用的调色剂及其通过反向中和进行悬浮体处理的生产方法
WO2003051956A1 (en) * 2001-12-15 2003-06-26 Samsung Electronics Co., Ltd. Recycled method for a wasted polyester and reclaimed materials thereof
CN1264804C (zh) * 2002-06-04 2006-07-19 株式会社爱维塑 对苯二甲酸二(2-羟乙基)酯的精制方法
US7297721B2 (en) * 2003-06-20 2007-11-20 Futura Polyesters Limited Process for controlled polymerization of a mixed polymer
US7247742B2 (en) * 2004-05-20 2007-07-24 Bp Corporation North America Inc. Recycling polyethylene naphthalate containing materials in a process to produce diesters
US7192988B2 (en) * 2004-09-30 2007-03-20 Invista North America S.Ar.L. Process for recycling polyester materials
US9458354B2 (en) 2010-10-06 2016-10-04 Resinate Technologies, Inc. Polyurethane dispersions and methods of making and using same
JP2014520008A (ja) 2011-06-10 2014-08-21 フェリス、クリストファー、エム. 透明アクリルコーティング
EP2751214B1 (en) 2011-08-31 2021-03-24 Avery Dennison Corporation Adhesive acrylate-olefin copolymers, methods for producing same and compositions utilizing same
SG11201406229PA (en) 2012-04-20 2014-11-27 Perpetual Global Technologies Ltd Flakes of ester mixtures and methods for their production
US9732026B2 (en) 2012-12-14 2017-08-15 Resinate Technologies, Inc. Reaction products containing hydroxyalkylterephthalates and methods of making and using same
EP2931798B1 (en) * 2012-12-14 2019-10-16 Resinate Materials Group, Inc. Reaction products containing hydroxyalkylterephthalates and methods of making and using same
US9255194B2 (en) 2013-10-15 2016-02-09 International Business Machines Corporation Methods and materials for depolymerizing polyesters
WO2015069662A1 (en) 2013-11-06 2015-05-14 The Board Of Trustees Of The Leland Stanford Junior University Methods for modifying a hydrophobic polymer surface and devices thereof
US9815808B2 (en) 2016-02-29 2017-11-14 Regents Of The University Of Minnesota Recovery of monomer from polyurethane materials by depolymerization
FR3053691B1 (fr) 2016-07-05 2018-08-03 IFP Energies Nouvelles Procede de depolymerisation d'un polyester comprenant du polyethylene terephtalate opaque
FR3092323B1 (fr) 2019-02-01 2021-06-04 Ifp Energies Now Procédé de production d’un polyester téréphtalate à partir d’un mélange monomérique comprenant un diester
FR3092324B1 (fr) 2019-02-01 2021-04-23 Ifp Energies Now Procédé de production d’un polyester téréphtalate intégrant un procédé de dépolymérisation
EP4004094A1 (en) * 2019-07-29 2022-06-01 Eastman Chemical Company Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis
WO2021072020A1 (en) 2019-10-08 2021-04-15 Eastman Chemical Company Catalyst systems for crystallizable reactor grade resins with recycled content
EP4048727A1 (en) 2019-10-25 2022-08-31 Eastman Chemical Company Crystallizable shrinkable films and thermoformable films and sheets made from reactor grade resins with recycled content
NL2024181B1 (en) * 2019-11-07 2021-07-20 Ioniqa Tech B V Reactor system and method of separating a first contaminant from a feed stream
FR3105235B1 (fr) 2019-12-19 2022-10-07 Ifp Energies Now Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate
FR3105236B1 (fr) 2019-12-19 2022-12-16 Ifp Energies Now Procédé optimisé de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate
FR3106134B1 (fr) 2020-01-09 2022-12-16 Ifp Energies Now Procédé optimisé de dépolymérisation par glycolyse d’un polyester comprenant du polyéthylène téréphtalate
FR3106133A1 (fr) * 2020-01-10 2021-07-16 IFP Energies Nouvelles Procédé d’obtention d’un effluent monomere diester purifie par dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate coloré et/ou opaque et/ou multicouche
EP3875523A1 (en) * 2020-03-03 2021-09-08 UAB Neo Group Processes for recycling polyethylene terephthalate
JP7798364B2 (ja) 2020-07-02 2026-01-14 キュア・テクノロジー・ベー・フェー ポリエステル廃棄物のリサイクルを可能にする方法及びその方法を適用するシステム
KR102873612B1 (ko) * 2020-11-03 2025-10-17 에스케이케미칼 주식회사 비스-2-하이드록시에틸 테레프탈레이트의 고순도화 정제 방법 및 이를 포함하는 폴리에스테르 수지
EP4288260A1 (de) * 2021-02-08 2023-12-13 ALPLA Werke Alwin Lehner GmbH & Co. KG Verfahren zur herstellung eines rpet-kunststoffmaterials zur verwendung in einem dünnwand-spritzgussverfahren und im dünnwand-spritzgussverfahren hergestellter hohlkörper
FR3124185B1 (fr) * 2021-06-17 2024-04-12 Ifp Energies Now Procédé de purification d’un monomere diester terephtalate par adsorption
FR3124186B1 (fr) * 2021-06-17 2024-04-12 Ifp Energies Now Procédé de preparation d’un monomere diester purifie et decolore par dépolymérisation d’une charge polyester
NL2028900B1 (en) 2021-08-02 2023-02-17 Arapaha B V A method of closed loop recycling of polylactic acid
US20250002641A1 (en) 2021-11-22 2025-01-02 Eastman Chemical Company Recyclable copolyesters articles with living hinges
CN118339083A (zh) 2021-11-22 2024-07-12 伊士曼化工公司 制造具有活动铰链的可回收共聚酯制品的方法
EP4436891A1 (en) 2021-11-22 2024-10-02 Eastman Chemical Company Recyclable copolyesters articles with living hinges
US20250002642A1 (en) 2021-11-22 2025-01-02 Eastman Chemical Company Process for making recyclable copolyesters articles with living hinges
CH719622A1 (de) 2022-04-22 2023-10-31 Alpla Werke Alwin Lehner Gmbh & Co Kg Verfahren zur Herstellung eines rPET-Kunststoffmaterials zur Verwendung in einem Dünnwand­ Spritzgussverfahren und im Dünnwand-Spritzgussverfahren hergestellte Behälter, wie Becher, Schalen, Wannen oder Stegverpackungen.
NL2034182B1 (en) 2023-02-20 2024-09-03 Cure Tech Bv A method to recycle a stream of polyester waste material and a system for applying the method
WO2024220454A1 (en) 2023-04-19 2024-10-24 Eastman Chemical Company Copolyester compositions for recyclable heavy gauge sheet articles
WO2024220458A1 (en) 2023-04-19 2024-10-24 Eastman Chemical Company Copolyester compositions for recyclable heavy gauge sheet articles
NL2036920B1 (en) 2024-01-30 2025-08-08 Cure Tech B V A method to enable the recycling a stream of polyester waste material and a system for applying the method
WO2025193488A1 (en) 2024-03-13 2025-09-18 Eastman Chemical Company Cavitated copolyester shrink film with improved density reduction and toughness

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GB610136A (en) * 1946-03-28 1948-10-12 Royden Lewis Heath Degradation of aromatic linear polyesters
NL297660A (es) * 1962-09-27
NL301426A (es) * 1962-12-06
US3703488A (en) * 1968-03-22 1972-11-21 Goodyear Tire & Rubber Process for reuse of polyester resin
US3577454A (en) * 1968-07-01 1971-05-04 Goodyear Tire & Rubber Process for crystallizing bis(beta-hydroxyethyl)terephthalate
US3663600A (en) * 1969-12-15 1972-05-16 Eastman Kodak Co Purification of bis(beta-hydroxyethyl) terephthalate
US3884850A (en) * 1970-02-13 1975-05-20 Fiber Industries Inc Continuous atmospheric depolymerization of polyester
JPS4915255B1 (es) * 1970-07-23 1974-04-13
JPS60248646A (ja) * 1984-05-25 1985-12-09 Toray Ind Inc ポリエステル屑の解重合方法
DE4034459A1 (de) * 1990-10-30 1992-05-07 Hoechst Ag Verfahren zur aufbereitung thermisch beanspruchter polyester-abfaelle
JP3510885B2 (ja) * 1992-05-18 2004-03-29 ペトレサイクル プロプライエタリー リミテッド 使用ずみpetの資源からのポリエチレンテレフタレートの再生方法
DE4220473A1 (de) * 1992-06-23 1994-01-05 Zimmer Ag Verfahren zur Herstellung von Polybutylenterephthalat aus PET-Abfall
US5298530A (en) * 1992-11-25 1994-03-29 Eastman Kodak Company Process of recovering components from scrap polyester
WO1994025517A1 (en) * 1993-05-04 1994-11-10 Ashland Oil, Inc. Cured unsaturated polyesters glycolysis for recycle reactant

Also Published As

Publication number Publication date
EP0865464A1 (en) 1998-09-23
WO1997020886A1 (en) 1997-06-12
AU1123397A (en) 1997-06-27
CA2239003A1 (en) 1997-06-12
BR9611564A (pt) 1999-03-02
EP0865464B1 (en) 2001-05-30
AR004363A1 (es) 1998-11-04
DE69613142T2 (de) 2001-09-27
DE69613142D1 (de) 2001-07-05
US5635584A (en) 1997-06-03
MX9804145A (es) 1998-11-29

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