ES2157475T3 - Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester. - Google Patents
Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester.Info
- Publication number
- ES2157475T3 ES2157475T3 ES96942058T ES96942058T ES2157475T3 ES 2157475 T3 ES2157475 T3 ES 2157475T3 ES 96942058 T ES96942058 T ES 96942058T ES 96942058 T ES96942058 T ES 96942058T ES 2157475 T3 ES2157475 T3 ES 2157475T3
- Authority
- ES
- Spain
- Prior art keywords
- polyester
- procedure
- oligomero
- monomero
- glycolisis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 4
- 239000000463 material Substances 0.000 title abstract 3
- 238000000746 purification Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000012634 fragment Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
LA INVENCION DESCRIBE UN NUEVO PROCEDIMIENTO DE RECICLAJE DE POLIESTERES. DE ACUERDO CON EL PROCEDIMIENTO DESCRITO, UN POLIESTER USADO O FRAGMENTOS DE POLIESTER SE HACE REACCIONAR CON GLICOL PARA PRODUCIR UN MONOMERO U OLIGOMERO DE BAJO PESO MOLECULAR, POR DESPOLIMERIZACION DE DICHO POLIESTER. DICHO MONOMERO U OLIGOMERO, SEGUN SEA EL CASO, SE PURIFICA A CONTINUACION UTILIZANDO UNA O MAS DE LAS SIGUIENTES FASES: FILTRACION, CRISTALIZACION Y, OPCIONALMENTE, TRATAMIENTO CON ADSORBENTE O EVAPORACION. EL MONOMERO U OLIGOMERO ASI PRODUCIDO ES ESPECIALMENTE ADECUADO COMO MATERIAL BRUTO PARA LA PRODUCCION DE POLIESTER DE TIPO DE EMBALAJE A BASE DE ACIDOS O ESTERES. DEBIDO A QUE EL PROCEDIMIENTO INCLUYE FASES DE PURIFICACION, LOS REQUISITOS REFERENTES AL MATERIAL DE POLIESTER USADO NO TIENEN QUE SER ESTRICTOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/570,177 US5635584A (en) | 1995-12-07 | 1995-12-07 | Process including glycolysis and subsequent purification for recycling polyester materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2157475T3 true ES2157475T3 (es) | 2001-08-16 |
Family
ID=24278573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96942058T Expired - Lifetime ES2157475T3 (es) | 1995-12-07 | 1996-11-26 | Procedimiento que incluye glicolisis y purificacion posterior para reciclar materiales de poliester. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5635584A (es) |
| EP (1) | EP0865464B1 (es) |
| AR (1) | AR004363A1 (es) |
| AU (1) | AU1123397A (es) |
| BR (1) | BR9611564A (es) |
| CA (1) | CA2239003A1 (es) |
| DE (1) | DE69613142T2 (es) |
| ES (1) | ES2157475T3 (es) |
| MX (1) | MX9804145A (es) |
| WO (1) | WO1997020886A1 (es) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103774A (en) * | 1997-04-02 | 2000-08-15 | The Coca-Cola Company | Process for removing contaminants from polyesters and controlling polymer molecular weight |
| US6136869A (en) * | 1997-10-17 | 2000-10-24 | Eastman Chemical Company | Depolymerization process for recycling polyesters |
| AUPP261498A0 (en) * | 1998-03-27 | 1998-04-23 | Swig Pty Ltd | Improved conversion of contaminated polyethylene terephthalate to polybutylene terephthalate |
| US6410607B1 (en) * | 1999-02-10 | 2002-06-25 | Eastman Chemical Company | Glycolysis process for recycling of post-consumer pet |
| KR100765744B1 (ko) * | 2001-12-15 | 2007-10-15 | 김도균 | 폐 폴리에스테르를 재활용하여 토너, 잉크 및 코팅제용중합체 제조방법 및 그 조성물 |
| CN100414441C (zh) * | 2001-12-15 | 2008-08-27 | 三星电子株式会社 | 静电显影用的调色剂及其通过反向中和进行悬浮体处理的生产方法 |
| WO2003051956A1 (en) * | 2001-12-15 | 2003-06-26 | Samsung Electronics Co., Ltd. | Recycled method for a wasted polyester and reclaimed materials thereof |
| CN1264804C (zh) * | 2002-06-04 | 2006-07-19 | 株式会社爱维塑 | 对苯二甲酸二(2-羟乙基)酯的精制方法 |
| US7297721B2 (en) * | 2003-06-20 | 2007-11-20 | Futura Polyesters Limited | Process for controlled polymerization of a mixed polymer |
| US7247742B2 (en) * | 2004-05-20 | 2007-07-24 | Bp Corporation North America Inc. | Recycling polyethylene naphthalate containing materials in a process to produce diesters |
| US7192988B2 (en) * | 2004-09-30 | 2007-03-20 | Invista North America S.Ar.L. | Process for recycling polyester materials |
| US9458354B2 (en) | 2010-10-06 | 2016-10-04 | Resinate Technologies, Inc. | Polyurethane dispersions and methods of making and using same |
| JP2014520008A (ja) | 2011-06-10 | 2014-08-21 | フェリス、クリストファー、エム. | 透明アクリルコーティング |
| EP2751214B1 (en) | 2011-08-31 | 2021-03-24 | Avery Dennison Corporation | Adhesive acrylate-olefin copolymers, methods for producing same and compositions utilizing same |
| SG11201406229PA (en) | 2012-04-20 | 2014-11-27 | Perpetual Global Technologies Ltd | Flakes of ester mixtures and methods for their production |
| US9732026B2 (en) | 2012-12-14 | 2017-08-15 | Resinate Technologies, Inc. | Reaction products containing hydroxyalkylterephthalates and methods of making and using same |
| EP2931798B1 (en) * | 2012-12-14 | 2019-10-16 | Resinate Materials Group, Inc. | Reaction products containing hydroxyalkylterephthalates and methods of making and using same |
| US9255194B2 (en) | 2013-10-15 | 2016-02-09 | International Business Machines Corporation | Methods and materials for depolymerizing polyesters |
| WO2015069662A1 (en) | 2013-11-06 | 2015-05-14 | The Board Of Trustees Of The Leland Stanford Junior University | Methods for modifying a hydrophobic polymer surface and devices thereof |
| US9815808B2 (en) | 2016-02-29 | 2017-11-14 | Regents Of The University Of Minnesota | Recovery of monomer from polyurethane materials by depolymerization |
| FR3053691B1 (fr) | 2016-07-05 | 2018-08-03 | IFP Energies Nouvelles | Procede de depolymerisation d'un polyester comprenant du polyethylene terephtalate opaque |
| FR3092323B1 (fr) | 2019-02-01 | 2021-06-04 | Ifp Energies Now | Procédé de production d’un polyester téréphtalate à partir d’un mélange monomérique comprenant un diester |
| FR3092324B1 (fr) | 2019-02-01 | 2021-04-23 | Ifp Energies Now | Procédé de production d’un polyester téréphtalate intégrant un procédé de dépolymérisation |
| EP4004094A1 (en) * | 2019-07-29 | 2022-06-01 | Eastman Chemical Company | Process for the preparation of polyesters with recycled monomers from pyrolysis and methanolysis |
| WO2021072020A1 (en) | 2019-10-08 | 2021-04-15 | Eastman Chemical Company | Catalyst systems for crystallizable reactor grade resins with recycled content |
| EP4048727A1 (en) | 2019-10-25 | 2022-08-31 | Eastman Chemical Company | Crystallizable shrinkable films and thermoformable films and sheets made from reactor grade resins with recycled content |
| NL2024181B1 (en) * | 2019-11-07 | 2021-07-20 | Ioniqa Tech B V | Reactor system and method of separating a first contaminant from a feed stream |
| FR3105235B1 (fr) | 2019-12-19 | 2022-10-07 | Ifp Energies Now | Procédé amélioré de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate |
| FR3105236B1 (fr) | 2019-12-19 | 2022-12-16 | Ifp Energies Now | Procédé optimisé de dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate |
| FR3106134B1 (fr) | 2020-01-09 | 2022-12-16 | Ifp Energies Now | Procédé optimisé de dépolymérisation par glycolyse d’un polyester comprenant du polyéthylène téréphtalate |
| FR3106133A1 (fr) * | 2020-01-10 | 2021-07-16 | IFP Energies Nouvelles | Procédé d’obtention d’un effluent monomere diester purifie par dépolymérisation d’un polyester comprenant du polyéthylène téréphtalate coloré et/ou opaque et/ou multicouche |
| EP3875523A1 (en) * | 2020-03-03 | 2021-09-08 | UAB Neo Group | Processes for recycling polyethylene terephthalate |
| JP7798364B2 (ja) | 2020-07-02 | 2026-01-14 | キュア・テクノロジー・ベー・フェー | ポリエステル廃棄物のリサイクルを可能にする方法及びその方法を適用するシステム |
| KR102873612B1 (ko) * | 2020-11-03 | 2025-10-17 | 에스케이케미칼 주식회사 | 비스-2-하이드록시에틸 테레프탈레이트의 고순도화 정제 방법 및 이를 포함하는 폴리에스테르 수지 |
| EP4288260A1 (de) * | 2021-02-08 | 2023-12-13 | ALPLA Werke Alwin Lehner GmbH & Co. KG | Verfahren zur herstellung eines rpet-kunststoffmaterials zur verwendung in einem dünnwand-spritzgussverfahren und im dünnwand-spritzgussverfahren hergestellter hohlkörper |
| FR3124185B1 (fr) * | 2021-06-17 | 2024-04-12 | Ifp Energies Now | Procédé de purification d’un monomere diester terephtalate par adsorption |
| FR3124186B1 (fr) * | 2021-06-17 | 2024-04-12 | Ifp Energies Now | Procédé de preparation d’un monomere diester purifie et decolore par dépolymérisation d’une charge polyester |
| NL2028900B1 (en) | 2021-08-02 | 2023-02-17 | Arapaha B V | A method of closed loop recycling of polylactic acid |
| US20250002641A1 (en) | 2021-11-22 | 2025-01-02 | Eastman Chemical Company | Recyclable copolyesters articles with living hinges |
| CN118339083A (zh) | 2021-11-22 | 2024-07-12 | 伊士曼化工公司 | 制造具有活动铰链的可回收共聚酯制品的方法 |
| EP4436891A1 (en) | 2021-11-22 | 2024-10-02 | Eastman Chemical Company | Recyclable copolyesters articles with living hinges |
| US20250002642A1 (en) | 2021-11-22 | 2025-01-02 | Eastman Chemical Company | Process for making recyclable copolyesters articles with living hinges |
| CH719622A1 (de) | 2022-04-22 | 2023-10-31 | Alpla Werke Alwin Lehner Gmbh & Co Kg | Verfahren zur Herstellung eines rPET-Kunststoffmaterials zur Verwendung in einem Dünnwand Spritzgussverfahren und im Dünnwand-Spritzgussverfahren hergestellte Behälter, wie Becher, Schalen, Wannen oder Stegverpackungen. |
| NL2034182B1 (en) | 2023-02-20 | 2024-09-03 | Cure Tech Bv | A method to recycle a stream of polyester waste material and a system for applying the method |
| WO2024220454A1 (en) | 2023-04-19 | 2024-10-24 | Eastman Chemical Company | Copolyester compositions for recyclable heavy gauge sheet articles |
| WO2024220458A1 (en) | 2023-04-19 | 2024-10-24 | Eastman Chemical Company | Copolyester compositions for recyclable heavy gauge sheet articles |
| NL2036920B1 (en) | 2024-01-30 | 2025-08-08 | Cure Tech B V | A method to enable the recycling a stream of polyester waste material and a system for applying the method |
| WO2025193488A1 (en) | 2024-03-13 | 2025-09-18 | Eastman Chemical Company | Cavitated copolyester shrink film with improved density reduction and toughness |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB610136A (en) * | 1946-03-28 | 1948-10-12 | Royden Lewis Heath | Degradation of aromatic linear polyesters |
| NL297660A (es) * | 1962-09-27 | |||
| NL301426A (es) * | 1962-12-06 | |||
| US3703488A (en) * | 1968-03-22 | 1972-11-21 | Goodyear Tire & Rubber | Process for reuse of polyester resin |
| US3577454A (en) * | 1968-07-01 | 1971-05-04 | Goodyear Tire & Rubber | Process for crystallizing bis(beta-hydroxyethyl)terephthalate |
| US3663600A (en) * | 1969-12-15 | 1972-05-16 | Eastman Kodak Co | Purification of bis(beta-hydroxyethyl) terephthalate |
| US3884850A (en) * | 1970-02-13 | 1975-05-20 | Fiber Industries Inc | Continuous atmospheric depolymerization of polyester |
| JPS4915255B1 (es) * | 1970-07-23 | 1974-04-13 | ||
| JPS60248646A (ja) * | 1984-05-25 | 1985-12-09 | Toray Ind Inc | ポリエステル屑の解重合方法 |
| DE4034459A1 (de) * | 1990-10-30 | 1992-05-07 | Hoechst Ag | Verfahren zur aufbereitung thermisch beanspruchter polyester-abfaelle |
| JP3510885B2 (ja) * | 1992-05-18 | 2004-03-29 | ペトレサイクル プロプライエタリー リミテッド | 使用ずみpetの資源からのポリエチレンテレフタレートの再生方法 |
| DE4220473A1 (de) * | 1992-06-23 | 1994-01-05 | Zimmer Ag | Verfahren zur Herstellung von Polybutylenterephthalat aus PET-Abfall |
| US5298530A (en) * | 1992-11-25 | 1994-03-29 | Eastman Kodak Company | Process of recovering components from scrap polyester |
| WO1994025517A1 (en) * | 1993-05-04 | 1994-11-10 | Ashland Oil, Inc. | Cured unsaturated polyesters glycolysis for recycle reactant |
-
1995
- 1995-12-07 US US08/570,177 patent/US5635584A/en not_active Expired - Fee Related
-
1996
- 1996-11-26 WO PCT/US1996/018883 patent/WO1997020886A1/en not_active Ceased
- 1996-11-26 DE DE69613142T patent/DE69613142T2/de not_active Expired - Fee Related
- 1996-11-26 CA CA 2239003 patent/CA2239003A1/en not_active Abandoned
- 1996-11-26 EP EP19960942058 patent/EP0865464B1/en not_active Expired - Lifetime
- 1996-11-26 ES ES96942058T patent/ES2157475T3/es not_active Expired - Lifetime
- 1996-11-26 BR BR9611564A patent/BR9611564A/pt not_active Application Discontinuation
- 1996-11-26 AU AU11233/97A patent/AU1123397A/en not_active Abandoned
- 1996-12-05 AR ARP960105518 patent/AR004363A1/es unknown
-
1998
- 1998-05-26 MX MX9804145A patent/MX9804145A/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0865464A1 (en) | 1998-09-23 |
| WO1997020886A1 (en) | 1997-06-12 |
| AU1123397A (en) | 1997-06-27 |
| CA2239003A1 (en) | 1997-06-12 |
| BR9611564A (pt) | 1999-03-02 |
| EP0865464B1 (en) | 2001-05-30 |
| AR004363A1 (es) | 1998-11-04 |
| DE69613142T2 (de) | 2001-09-27 |
| DE69613142D1 (de) | 2001-07-05 |
| US5635584A (en) | 1997-06-03 |
| MX9804145A (es) | 1998-11-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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