ES2157930T3 - Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion. - Google Patents

Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion.

Info

Publication number
ES2157930T3
ES2157930T3 ES93922144T ES93922144T ES2157930T3 ES 2157930 T3 ES2157930 T3 ES 2157930T3 ES 93922144 T ES93922144 T ES 93922144T ES 93922144 T ES93922144 T ES 93922144T ES 2157930 T3 ES2157930 T3 ES 2157930T3
Authority
ES
Spain
Prior art keywords
rent
propylene
relationship
alcoxi
donor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93922144T
Other languages
English (en)
Inventor
Andres Sustic
George C Allen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials LLC
Original Assignee
Huntsman Polymers Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Polymers Corp filed Critical Huntsman Polymers Corp
Application granted granted Critical
Publication of ES2157930T3 publication Critical patent/ES2157930T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

UN PROCESO PARA LA PRODUCCION DE COPOLIMEROS DE PROPILENO/1-BUTENO QUE COMPRENDE: HACER REACCIONAR PROPILENO Y MONOMEROS 1-BUTENO EN PRESENCIA DE UN SISTEMA CATALIZADOR QUE COMPRENDE: (A) UN COMPONENTE CATALIZADOR SOPORTADO EN SOLIDO QUE SE PREPARA POR EL METODO QUE COMPRENDE: (I) CO-TRITURAR BASE DE SOPORTE DE HALURO DE MAGNESIO Y TRIHALURO DE ALUMINIO EN UNA PROPORCION MOLAR DE 8:0,5 DE 8:3 EN AUSENCIA DE DONANTE DE ELECTRONES AÑADIDOS; Y (II) CO-TRITURAR ENTONCES EL PRODUCTO DEL PASO (I) EN AUSENCIA DE DONANTE DE ELECTRONES AÑADIDOS CON SUFICIENTE TETRAHALURO DE TITANIO PARA PROPORCIONAR UNA RELACION MOLAR DE HALURO DE MAGNESIO RESPECTO A TETRAHALURO DE TITANIO DE 8:0,1 A 8:10; (B) UN COCATALIZADOR DE TRIALQUILALUMINIO, QUE TIENE DE 1 A 9 ATOMOS DE CARBONO EN CADA GRUPO ALQUILO EN UNA CANTIDAD TAL QUE LA RELACION AL/TI ESTA ENTRE 50:1 Y 500:1; (C) UN COMPONENTE ALCOXI SILANO DE LA FORMULA RNSI(OR'')4-N DONDE N = 1-3, R = ARILO O ALQUILO Y R'' = ALQUILO C1-3 EN UNA CANTIDAD SUFICIENTE TAL QUE LA RELACION MOLAR DE CO-CATALIZADOR DE ORGANOALUMINIO RESPECTO A ALCOXI SILANO ESTA EN EL MARGEN DE 20:1 A 45:1. ESTANDO CARACTERIZADO DICHO COPOLIMERO POR UN CONTENIDO DE PROPILENO DE 25 A 50 % DE PESO, UN CONTENIDO 1-BUTENO DE 50 A 75 % DE PESO Y UNA RESISTENCIA A LA TENSION DE AL MENOS 300 PSIG.
ES93922144T 1992-09-08 1993-09-08 Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion. Expired - Lifetime ES2157930T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/941,916 US5302675A (en) 1992-09-08 1992-09-08 High tensile strength amorphous 1-butene/propylene copolymers

Publications (1)

Publication Number Publication Date
ES2157930T3 true ES2157930T3 (es) 2001-09-01

Family

ID=25477292

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93922144T Expired - Lifetime ES2157930T3 (es) 1992-09-08 1993-09-08 Copolimeros de 1-buteno/propileno amorfos de alta resistencia a la traccion.

Country Status (10)

Country Link
US (1) US5302675A (es)
EP (1) EP0660847B1 (es)
JP (2) JP3513518B2 (es)
KR (1) KR950703010A (es)
AT (1) ATE201702T1 (es)
AU (1) AU664318B2 (es)
DE (1) DE69330279T2 (es)
ES (1) ES2157930T3 (es)
FI (1) FI111375B (es)
WO (1) WO1994005711A1 (es)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
US5693729A (en) * 1993-08-27 1997-12-02 Showa Denko K.K. Catalyst for polymerization of olefin and process for the preparation of olefin polymer
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
KR100607538B1 (ko) * 1999-04-20 2006-08-02 삼성토탈 주식회사 열접착성 필름용 프로필렌-에틸렌-부텐-1 공중합체 및 이를 포함하는 수지조성물
JP4897670B2 (ja) * 2004-05-04 2012-03-14 バーゼル・ポリオレフィン・ゲーエムベーハー アタクチック１−ブテンポリマー類の製造方法
US8048054B2 (en) * 2004-10-21 2011-11-01 Adherent Laboratories, Inc. Disposable article tab attachment adhesive
US20060089617A1 (en) * 2004-10-21 2006-04-27 Adherent Laboratories, Inc. Disposable article tab attachment adhesive
CA2807966C (en) 2010-08-26 2019-10-29 Henkel Corporation Low application temperature amorphous poly-.alpha.-olefin adhesive
US9469791B2 (en) 2011-04-28 2016-10-18 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
EP2723825B1 (en) 2011-06-27 2015-08-26 H. B. Fuller Company Free radical initiator modified hot melt adhesive composition including functionalized polyethylene and propylene-alpha-olefin polymer
BR112013033142A2 (pt) 2011-06-27 2017-01-24 Fuller H B Co polímeros de propileno alfa-olefina, composições adesivas termofundidas que incluem polímeros de propileno-alfa-olefina e artigos que incluem os mesmos
US8865824B2 (en) 2012-09-19 2014-10-21 IFS Industries Inc. Hot melt adhesive
US9241843B2 (en) 2012-09-19 2016-01-26 The Procter & Gamble Company Article with tackifier-free adhesive
US9267060B2 (en) 2013-02-15 2016-02-23 H.B. Fuller Company Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same
US9593235B2 (en) 2013-02-15 2017-03-14 H.B. Fuller Company Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same
US20150174281A1 (en) 2013-12-19 2015-06-25 The Procter & Gamble Company Hot melt adhesive
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
CN103951898B (zh) * 2014-04-12 2016-02-17 青岛科技大学 聚1-丁烯/1-丁烯-丙烯共聚物釜内合金及其制备方法
US10160888B2 (en) 2015-09-30 2018-12-25 RexTac LLC. Propylene-based amorphous poly-alpha-olefins (APAOs) formulated with hexene-1 monomer containing amorphous poly-alpha-olefins for use in hot melt adhesives
US10752815B2 (en) 2016-04-12 2020-08-25 Rextac Llc Low molecular weight butene-1-co-hexene-1 amorphous poly alpha olefins for hot-melt adhesives with enhanced properties
US20170292047A1 (en) 2016-04-12 2017-10-12 Rextac Llc Hexene-1 Containing Amorphous Polyalphaolefins For Improved Hot Melt Adhesives
KR101924121B1 (ko) 2016-11-28 2019-02-22 주식회사 일렘테크놀러지 저온-고신율 특성을 가지는 1-부텐계 공중합체 및 이의 제조방법
EP3781104A1 (en) 2018-04-20 2021-02-24 The Procter & Gamble Company Absorbent article comprising an adhesive composition
CN111971359A (zh) * 2018-04-20 2020-11-20 宝洁公司 用于吸收制品的粘合剂组合物
WO2019204543A1 (en) 2018-04-20 2019-10-24 The Procter & Gamble Company Adhesive composition for absorbent articles
EP3781640A1 (en) * 2018-04-20 2021-02-24 The Procter & Gamble Company Adhesive composition for absorbent articles
CN111971007B (zh) 2018-04-20 2022-06-24 宝洁公司 包含粘合剂组合物的吸收制品
US11707548B2 (en) 2018-10-09 2023-07-25 The Procter & Gamble Company Absorbent article comprising a lotion resistant polymeric filler composition
US20210316036A1 (en) 2020-04-08 2021-10-14 The Procter & Gamble Company Method for applying a polymeric composition and absorbent articles comprising such composition
CN115322275A (zh) * 2022-03-07 2022-11-11 陕西延长中煤榆林能源化工有限公司 一种丙烯/1-丁烯共聚聚丙烯树脂的工业化生产方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3923758A (en) * 1973-07-02 1975-12-02 Eastman Kodak Co Substantially hexane soluble propylene/butene-1 copolymer containing 30 to 75 weight percent butene-1
JPS5379984A (en) * 1976-12-24 1978-07-14 Mitsui Petrochem Ind Ltd Copolymer and production
US4347158A (en) * 1980-05-02 1982-08-31 Dart Industries, Inc. Supported high efficiency polyolefin catalyst component and methods of making and using the same
US4451688A (en) * 1981-12-03 1984-05-29 Nippon Oil Company, Limited Process for preparing polyolefins
JPS6038414A (ja) * 1983-08-12 1985-02-28 Mitsui Petrochem Ind Ltd 熱可塑性樹脂共重合体
US4736002A (en) * 1986-06-30 1988-04-05 El Paso Products Company Novel propylene polymerization process
US4859757A (en) * 1986-06-30 1989-08-22 Rexene Products Company Novel propylene polymers
US4847340A (en) * 1986-06-30 1989-07-11 Rexene Products Company Novel propylene polymerization process
CA1308857C (en) * 1988-03-30 1992-10-13 Brian J. Pellon Propylene copolymerization process
JP2854886B2 (ja) * 1989-08-10 1999-02-10 三井化学株式会社 プロピレンとブテンの共重合体

Also Published As

Publication number Publication date
WO1994005711A1 (en) 1994-03-17
KR950703010A (ko) 1995-08-23
ATE201702T1 (de) 2001-06-15
US5302675A (en) 1994-04-12
JP3640024B2 (ja) 2005-04-20
EP0660847A1 (en) 1995-07-05
JPH08501337A (ja) 1996-02-13
DE69330279D1 (de) 2001-07-05
EP0660847A4 (en) 1995-05-09
JP2004002882A (ja) 2004-01-08
FI951042L (fi) 1995-03-07
JP3513518B2 (ja) 2004-03-31
EP0660847B1 (en) 2001-05-30
AU664318B2 (en) 1995-11-09
FI951042A0 (fi) 1995-03-07
FI111375B (fi) 2003-07-15
AU5125193A (en) 1994-03-29
DE69330279T2 (de) 2001-10-31

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