ES2157987T3 - Catalizador para la obtencion de oxido de etileno. - Google Patents
Catalizador para la obtencion de oxido de etileno.Info
- Publication number
- ES2157987T3 ES2157987T3 ES94926216T ES94926216T ES2157987T3 ES 2157987 T3 ES2157987 T3 ES 2157987T3 ES 94926216 T ES94926216 T ES 94926216T ES 94926216 T ES94926216 T ES 94926216T ES 2157987 T3 ES2157987 T3 ES 2157987T3
- Authority
- ES
- Spain
- Prior art keywords
- ethylene oxide
- catalyst
- sup
- obtaining ethylene
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000004332 silver Substances 0.000 abstract 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
ESTA INVENCION SE REFIERE A UN CATALIZADOR DE OXIDO ETILENICO QUE CONTIENE, ANTES DEL PRIMER USO DEL CATALIZADOR EN LA CONVERSION DE ETILENO A OXIDO ETILENICO, PLATA, UNO O MAS PROMOTORES DE METAL ALCALI Y DE 0,4 X 10{SUP,-3} A 4,0 X 10{SUP,3} MOLES DE CLORO POR MOL DE PLATA DEPOSITADA EN UN PORTADOR ALFA ALUMINA. EL CATALIZADOR PROPORCIONA UNA PUESTA EN MARCHA MEJORADA CUANDO SE PONE EN MARCHA EN LA PRESENCIA DE OXIDO ETILENICO, OXIGENO Y UN MODERADOR DE CLOROHIDROCARBURO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11028293A | 1993-08-23 | 1993-08-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2157987T3 true ES2157987T3 (es) | 2001-09-01 |
Family
ID=22332188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94926216T Expired - Lifetime ES2157987T3 (es) | 1993-08-23 | 1994-08-22 | Catalizador para la obtencion de oxido de etileno. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0724479B1 (es) |
| JP (1) | JP4245191B2 (es) |
| AU (1) | AU7614394A (es) |
| CA (1) | CA2170032C (es) |
| DE (1) | DE69427482T2 (es) |
| ES (1) | ES2157987T3 (es) |
| WO (1) | WO1995005896A1 (es) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5780657A (en) * | 1997-06-23 | 1998-07-14 | Arco Chemical Technology, L.P. | Propylene epoxidation using chloride-containing silver catalysts |
| KR100355845B1 (ko) * | 1999-11-11 | 2002-10-12 | 삼성종합화학주식회사 | 에틸렌옥사이드 제조공정에서 반응억제제 주입 경로 개선공정 |
| US6372925B1 (en) * | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| WO2004002954A2 (en) | 2002-06-28 | 2004-01-08 | Shell Internationale Research Maatschappij B.V. | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| DE60304197T2 (de) * | 2002-06-28 | 2006-12-14 | Shell Internationale Research Maatschappij B.V. | Verfahren zum initiieren eines epoxidationsverfahrens, katalysator und verfahren zur epoxidation eines olefins |
| MX245604B (es) | 2002-06-28 | 2007-05-04 | Shell Int Research | Metodo para iniciar un proceso de epoxidacion y proceso de epoxidacion de una olefina. |
| US7348444B2 (en) | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
| WO2009137431A2 (en) | 2008-05-07 | 2009-11-12 | Shell Oil Company | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CA2723517C (en) * | 2008-05-07 | 2017-03-07 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CN103261178B (zh) | 2010-12-15 | 2016-11-09 | 陶氏技术投资有限责任公司 | 使用高效催化剂生产环氧烷的工艺的启动方法 |
| WO2012141942A1 (en) | 2011-04-11 | 2012-10-18 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
| EP2788337B1 (en) | 2011-12-09 | 2016-03-02 | Dow Technology Investments LLC | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| CN105618046B (zh) * | 2014-11-03 | 2018-10-16 | 中国石油化工股份有限公司 | 银催化剂的制备方法、银催化剂以及生产环氧乙烷的方法 |
| CN105618036B (zh) * | 2014-11-03 | 2018-10-16 | 中国石油化工股份有限公司 | 银催化剂的制备方法、银催化剂以及生产环氧乙烷的方法 |
| BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
| EP3642188A1 (en) | 2017-06-23 | 2020-04-29 | Haldor Topsøe A/S | A process for oxidation of a lower alkene at low temperatures in ammonia-containing gas mixtures |
| CN110785392A (zh) | 2017-06-23 | 2020-02-11 | 托普索公司 | 在低温下在含氨的气体混合物中氧化低级烷烃的方法 |
| US11439986B2 (en) | 2017-12-13 | 2022-09-13 | Scientific Design Company, Inc. | Silver impregnation solution containing high-boiling oxygenated additive and its use in ethylene oxide catalyst preparation |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3264712D1 (en) * | 1981-02-25 | 1985-08-22 | Mitsubishi Petrochemical Co | Silver-based catalyst for production of ethylene oxide |
| JPS5898144A (ja) * | 1981-12-08 | 1983-06-10 | Mitsubishi Petrochem Co Ltd | エチレンオキシド製造用銀触媒 |
| DE3582097D1 (de) * | 1984-08-21 | 1991-04-18 | Mitsubishi Petrochemical Co | Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung. |
| JPH084745B2 (ja) * | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| SU1685510A1 (ru) * | 1989-07-03 | 1991-10-23 | Государственный Научно-Исследовательский И Проектный Институт Хлорной Промышленности С Опытным Заводом И Конструкторским Бюро | Способ приготовлени катализатора дл получени окиси этилена |
-
1994
- 1994-08-22 AU AU76143/94A patent/AU7614394A/en not_active Abandoned
- 1994-08-22 DE DE69427482T patent/DE69427482T2/de not_active Revoked
- 1994-08-22 CA CA002170032A patent/CA2170032C/en not_active Expired - Lifetime
- 1994-08-22 ES ES94926216T patent/ES2157987T3/es not_active Expired - Lifetime
- 1994-08-22 JP JP50734295A patent/JP4245191B2/ja not_active Expired - Lifetime
- 1994-08-22 WO PCT/EP1994/002783 patent/WO1995005896A1/en not_active Ceased
- 1994-08-22 EP EP94926216A patent/EP0724479B1/en not_active Revoked
Also Published As
| Publication number | Publication date |
|---|---|
| JPH09501606A (ja) | 1997-02-18 |
| EP0724479A1 (en) | 1996-08-07 |
| EP0724479B1 (en) | 2001-06-13 |
| JP4245191B2 (ja) | 2009-03-25 |
| CA2170032A1 (en) | 1995-03-02 |
| CA2170032C (en) | 2005-06-21 |
| DE69427482T2 (de) | 2001-11-08 |
| AU7614394A (en) | 1995-03-21 |
| DE69427482D1 (de) | 2001-07-19 |
| WO1995005896A1 (en) | 1995-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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