ES2159704T3 - Catalizador solido de alquilacion alifatica. - Google Patents

Catalizador solido de alquilacion alifatica.

Info

Publication number
ES2159704T3
ES2159704T3 ES96401896T ES96401896T ES2159704T3 ES 2159704 T3 ES2159704 T3 ES 2159704T3 ES 96401896 T ES96401896 T ES 96401896T ES 96401896 T ES96401896 T ES 96401896T ES 2159704 T3 ES2159704 T3 ES 2159704T3
Authority
ES
Spain
Prior art keywords
catalyst
alifatic
rental
active phase
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96401896T
Other languages
English (en)
Inventor
Eric Benazzi
Jean-Francois Joly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2159704T3 publication Critical patent/ES2159704T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/03—Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN CATALIZADOR QUE COMPRENDE UN SOPORTE ORGANICO O MINERAL Y AL MENOS UNA FASE ACTIVA QUE COMPRENDE AL MENOS UN ACIDO ELEGIDO ENTRE LOS ACIDOS DE FORMULA R-SO{SUB,3}H, DONDE R ES EL FLUOR O UN GRUPO ALQUILO O UN GRUPO ALQUILO FLUORADO, Y AL MENOS UN SOLVENTE APROTICO ORGANICO ESCASAMENTE BASICO, HABIENDO DICHO SOPORTE SIDO IMPREGNADO POR DICHA FASE ACTIVA, SIENDO DICHO CATALIZADOR TAL QUE ESTA CONSTITUIDO ESENCIALMENTE DE PARTICULAS DE DIAMETRO MEDIO COMPRENDIDO ENTRE 0,1 Y 150(MU)M, Y TAL QUE DICHO SOPORTE, ANTES DE SU IMPREGNACION POR DICHA FASE ACTIVA, POSEE UN VOLUMEN POROSO TOTAL COMPRENDIDO ENTRE 0,5 Y 6 CM{SUP,3}/G. LA INVENCION SE REFIERE TAMBIEN A LA UTILIZACION DE TAL CATALIZADOR EN ALQUILACION ALIFATICA.
ES96401896T 1995-09-11 1996-09-05 Catalizador solido de alquilacion alifatica. Expired - Lifetime ES2159704T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9510695A FR2738503B1 (fr) 1995-09-11 1995-09-11 Catalyseur solides d'alkylation aliphatique

Publications (1)

Publication Number Publication Date
ES2159704T3 true ES2159704T3 (es) 2001-10-16

Family

ID=9482483

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96401896T Expired - Lifetime ES2159704T3 (es) 1995-09-11 1996-09-05 Catalizador solido de alquilacion alifatica.

Country Status (6)

Country Link
US (1) US5906957A (es)
EP (1) EP0761306B1 (es)
JP (1) JPH09117670A (es)
DE (1) DE69612801T2 (es)
ES (1) ES2159704T3 (es)
FR (1) FR2738503B1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5849965A (en) * 1997-05-22 1998-12-15 Amoco Corporation Multistage alkylation process
US6395673B1 (en) 2000-06-29 2002-05-28 E. I. Du Pont De Nemours And Company Catalyst of mixed fluorosulfonic acids
US20180065900A1 (en) * 2016-09-08 2018-03-08 Alvega Technologies, Inc. Process of Alkylation of Isobutane with Olefins

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2081989A5 (es) * 1969-11-24 1971-12-10 Inst Francais Du Petrole
CA1020590A (en) * 1973-05-21 1977-11-08 Gulf Research And Development Company Hydrogen fluoride alkylation of iso-paraffins in the presence of trifluoromethanesulfonic acid
US4008178A (en) * 1974-11-04 1977-02-15 Texaco Inc. Alkylation catalyst for production of motor fuels
US4060565A (en) * 1976-03-04 1977-11-29 Shell Oil Company Hydrocarbon conversion process using a supported perfluorinated polymer catalyst
US4022847A (en) * 1976-03-04 1977-05-10 Shell Oil Company Hydrocarbon conversion process using an unsupported perfluorinated polymer catalyst
US4056578A (en) * 1976-03-04 1977-11-01 Shell Oil Company Isoparaffin-olefin alkylation process using a supported perfluorinated polymer catalyst
AU2252992A (en) * 1991-06-21 1993-01-25 Mobil Oil Corporation Improved liquid acid alkylation catalyst and isoparaffin:olefin alkylation process
US5196628A (en) * 1991-06-21 1993-03-23 Mobil Oil Corporation Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process
US5420093A (en) * 1991-10-25 1995-05-30 Institut Francais Du Petrole Catalyst based on silica and sulfuric acid and its use for the alkylation of paraffins
EP0539277B1 (fr) * 1991-10-25 1996-01-10 Institut Francais Du Petrole Utilisation d'un catalyseur en alkylation de paraffines
DE69302973T2 (de) * 1992-08-20 1996-10-10 Inst Francais Du Petrol Verfahren zur Alkylierung von Paraffinen
FR2699429B1 (fr) * 1992-12-22 1995-01-27 Inst Francais Du Petrole Catalyseur d'alkylation de paraffines.
FR2704161B1 (fr) * 1993-04-20 1995-06-02 Inst Francais Du Petrole Catalyseur d'alkylation de paraffines.
US5349116A (en) * 1993-06-25 1994-09-20 Phillips Petroleum Company Alkane alkylation and catalyst therefor
ES2108953T3 (es) * 1993-09-10 1998-01-01 Inst Francais Du Petrole Catalizador de alquilacion de isoparafinas c4-c5 por al menos una olefina c3-c6.
FR2714622B1 (fr) * 1994-01-06 1996-04-05 Inst Francais Du Petrole Nouveau procédé de régénération d'un catalyseur impur à base d'acide sulfurique déposé sur silice.
WO1995026814A1 (en) * 1994-03-31 1995-10-12 Exxon Chemical Patents Inc. Supported lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions

Also Published As

Publication number Publication date
EP0761306B1 (fr) 2001-05-16
DE69612801T2 (de) 2001-08-30
MX9603960A (es) 1997-07-31
FR2738503B1 (fr) 1997-10-03
US5906957A (en) 1999-05-25
FR2738503A1 (fr) 1997-03-14
DE69612801D1 (de) 2001-06-21
JPH09117670A (ja) 1997-05-06
EP0761306A1 (fr) 1997-03-12

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