ES2162460T3 - Procedimiento para la preparacion de productos liquidos y, opcionalmente, gaseosos a partir de reactivos gaseosos. - Google Patents

Procedimiento para la preparacion de productos liquidos y, opcionalmente, gaseosos a partir de reactivos gaseosos.

Info

Publication number
ES2162460T3
ES2162460T3 ES98933793T ES98933793T ES2162460T3 ES 2162460 T3 ES2162460 T3 ES 2162460T3 ES 98933793 T ES98933793 T ES 98933793T ES 98933793 T ES98933793 T ES 98933793T ES 2162460 T3 ES2162460 T3 ES 2162460T3
Authority
ES
Spain
Prior art keywords
gaseous
bed
reagents
products
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98933793T
Other languages
English (en)
Inventor
Andre Peter Steynberg
Herman Gerhardus Nel
Roy W Silverman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Technology Pty Ltd
Original Assignee
Sasol Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Technology Pty Ltd filed Critical Sasol Technology Pty Ltd
Application granted granted Critical
Publication of ES2162460T3 publication Critical patent/ES2162460T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
    • C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/0007—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00141—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00725—Mathematical modelling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

Procedimiento que sirve para obtener productos líquidos y, eventualmente, productos gaseosos a partir de reactivos gaseosos, y que consiste en introducir (14) estos reactivos en un lecho (40) de reactor compuesto de partículas en suspensión en un líquido, para efectuar su reacción simultáneamente a su subida a través del lecho, lo que constituye los productos, los reactivos y cualquier producto gaseosos que contribuya a mantener la suspensión. El producto líquido constituye, con el líquido en suspensión, la fase líquida del lecho. Cualquier producto gaseoso y los reactivos que no ha experimentado ninguna reacción suben desde el lecho para constituir una fase gaseosa (44). La suspensión desciende en el lecho a través de los tubos de descenso (22) situados respectivamente en una fase gaseosa 844). La suspensión desciende al lecho a través de los tubos de descenso (22, 32) situados respectivamente en una primera y una segunda zona (20, 30) de l lecho, lo que permite redistribuir las partículassólidas en el interior del lecho. La segunda zona de tubos de descenso se aleja de la primera zona en un sentido vertical. Se retira (16) cualquier producto gaseoso y los reactivos que no han experimentado ninguna reacción desde la fase gaseosa (44) y se retira (18) la fase líquida del lecho. Se realiza, preferentemente, una síntesis de Fischer-Tropsch, presentándose los reactivos gaseosos en forma de un flujo de gas de síntesis que contiene principalmente óxido de carbono e hidrógeno.
ES98933793T 1997-07-15 1998-07-14 Procedimiento para la preparacion de productos liquidos y, opcionalmente, gaseosos a partir de reactivos gaseosos. Expired - Lifetime ES2162460T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA976254 1997-07-15

Publications (1)

Publication Number Publication Date
ES2162460T3 true ES2162460T3 (es) 2001-12-16

Family

ID=25586480

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98933793T Expired - Lifetime ES2162460T3 (es) 1997-07-15 1998-07-14 Procedimiento para la preparacion de productos liquidos y, opcionalmente, gaseosos a partir de reactivos gaseosos.

Country Status (16)

Country Link
US (1) US6201031B1 (es)
EP (1) EP0998346B1 (es)
JP (1) JP4203129B2 (es)
AR (1) AR015404A1 (es)
AT (1) ATE206070T1 (es)
AU (1) AU730075B2 (es)
CA (1) CA2293659C (es)
DE (1) DE69801826T2 (es)
DK (1) DK0998346T3 (es)
ES (1) ES2162460T3 (es)
MY (1) MY115757A (es)
NO (1) NO319808B1 (es)
PE (1) PE115199A1 (es)
RU (1) RU2201800C2 (es)
WO (1) WO1999003574A1 (es)
ZA (1) ZA985992B (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2038774C (en) 1990-04-04 2001-09-25 Eric Herbolzheimer Slurry bubble column
EG22489A (en) * 1999-02-05 2003-02-26 Sasol Technology Process for producing liquid and optionally gaseous products from gaseous reactants
FR2806736B1 (fr) * 2000-03-27 2002-05-10 Inst Francais Du Petrole Procede de production d'hydrocarbures a partir de gaz de synthese dans un reacteur triphasique
US6762209B1 (en) 2001-08-31 2004-07-13 University Of Kentucky Research Foundation Bubble column apparatus for separating wax from catalyst slurry
FR2832416B1 (fr) * 2001-11-20 2004-09-03 Inst Francais Du Petrole Procede de conversion de gaz de synthese dans des reacteurs en serie
US7022741B2 (en) * 2003-03-28 2006-04-04 Conocophillips Company Gas agitated multiphase catalytic reactor with reduced backmixing
WO2004088227A2 (en) * 2003-03-28 2004-10-14 Conocophillips Company Process and apparatus for controlling flow in a multiphase reactor
JP4966654B2 (ja) * 2003-05-16 2012-07-04 サソル テクノロジー （プロプリエタリ） リミテッド ガス状反応物から液状生成物を生成し、任意でガス状生成物を生成する方法
BRPI0412565A (pt) * 2003-07-15 2006-09-19 Sasol Tech Pty Ltd processo para produzir lìquidos e, opcionalmente, gasosos de reagentes gasosos
JP4731553B2 (ja) * 2004-05-10 2011-07-27 サソール テクノロジー（プロプライエタリー）リミテッド 膨張するスラリー床内への気体の反応物質からの液体のまた任意に気体の炭化水素の生成
FR2877950B1 (fr) † 2004-11-17 2006-12-29 Inst Francais Du Petrole Dispositif de production d'hydrocarbures liquides par synthese fischer-tropsch dans un reacteur a lit triphasique
BRPI0608541B1 (pt) * 2005-03-17 2015-07-28 Sasol Techology Proprietary Métodos para operar um reator de leito fluidizado bifásico e para operar um reator de lama trifásico, e, reatores de leito fluidizado bifásico e de lama trifásico
CN101396647B (zh) * 2007-09-29 2011-03-16 中科合成油技术有限公司 用于费-托合成的气-液-固三相悬浮床反应器及其应用
KR100992835B1 (ko) * 2008-02-29 2010-11-08 한국화학연구원 피셔-트롭쉬 합성반응용 고체촉매와 생성물의 연속분리배출장치 및 방법
AU2011298995B2 (en) 2010-09-07 2016-04-07 Sasol Technology (Pty) Ltd Diesel engine efficiency improvement
JP5990389B2 (ja) * 2012-03-26 2016-09-14 独立行政法人石油天然ガス・金属鉱物資源機構 炭化水素油の製造方法、気泡塔型スラリー床反応装置及び炭化水素油の製造システム
CA2888150C (en) 2012-10-30 2021-04-27 Sasol Technology (Pty) Ltd Diesel fuel composition with reduced zinc uptake
JP2014136767A (ja) * 2013-01-17 2014-07-28 Japan Oil Gas & Metals National Corp 炭化水素合成反応装置
CN103962069B (zh) * 2013-01-31 2017-03-08 中国科学院上海高等研究院 一种浆态床反应器
CN103962067B (zh) * 2013-01-31 2017-02-08 中国科学院上海高等研究院 一种用来进行浆态床反应的方法
CN113877488B (zh) * 2021-11-16 2023-07-04 中国石油大学(华东) 一种基于管式微孔介质发泡机理的上流式加氢反应装置

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3124518A (en) * 1964-03-10 Product
JPS565572B1 (es) * 1970-12-30 1981-02-05
SU477734A1 (ru) * 1973-01-23 1975-07-25 Институт тепло- и массообмена АН БССР Аппарат с псевдоожиженным слоем
JPS6490030A (en) * 1987-10-01 1989-04-05 Mitsubishi Heavy Ind Ltd Three-phase fluidized reactor
US5382748A (en) * 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5962537A (en) * 1997-05-06 1999-10-05 Exxon Research And Engineering Co Multizone downcomer for slurry hydrocarbon syntheses process

Also Published As

Publication number Publication date
EP0998346A1 (en) 2000-05-10
MY115757A (en) 2003-08-30
ZA985992B (en) 2000-01-10
CA2293659A1 (en) 1999-01-28
AR015404A1 (es) 2001-05-02
JP2002510246A (ja) 2002-04-02
WO1999003574A1 (en) 1999-01-28
PE115199A1 (es) 1999-12-03
DE69801826D1 (de) 2001-10-31
AU8349198A (en) 1999-02-10
JP4203129B2 (ja) 2008-12-24
DE69801826T2 (de) 2002-03-28
US6201031B1 (en) 2001-03-13
NO20000190D0 (no) 2000-01-14
DK0998346T3 (da) 2002-01-28
ATE206070T1 (de) 2001-10-15
CA2293659C (en) 2006-09-05
NO20000190L (no) 2000-03-01
NO319808B1 (no) 2005-09-19
RU2201800C2 (ru) 2003-04-10
AU730075B2 (en) 2001-02-22
EP0998346B1 (en) 2001-09-26

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