ES2163030T3 - Procedimiento para la transformacion catalitica de hidrocarburos en compuestos aromaticos utilizando un catalizador que contiene silicona. - Google Patents
Procedimiento para la transformacion catalitica de hidrocarburos en compuestos aromaticos utilizando un catalizador que contiene silicona.Info
- Publication number
- ES2163030T3 ES2163030T3 ES96922932T ES96922932T ES2163030T3 ES 2163030 T3 ES2163030 T3 ES 2163030T3 ES 96922932 T ES96922932 T ES 96922932T ES 96922932 T ES96922932 T ES 96922932T ES 2163030 T3 ES2163030 T3 ES 2163030T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- hydrocarbons
- aromatic compounds
- procedure
- catalyst containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001491 aromatic compounds Chemical class 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000009466 transformation Effects 0.000 title abstract 2
- 229920001296 polysiloxane Polymers 0.000 title 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 230000007704 transition Effects 0.000 abstract 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 241001101998 Galium Species 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
- B01J27/13—Platinum group metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
LA INVENCION CONSISTE EN UN PROCEDIMIENTO DE TRANSFORMACION DE HIDROCARBUROS EN COMPUESTOS AROMATICOS, EN ESPECIAL DE RETRANSFORMACION CATALITICA DE GASOLINAS Y PRODUCCION DE COMPUESTOS AROMATICOS A PARTIR DE HIDROCARBUROS PARAFINICOS Y NAFTENICOS, PROCEDIMIENTO EN EL QUE LA CARGA A TRATAR SE SOMETE A LA ACCION DE UN CATALIZADOR. EL CATALIZADOR COMPRENDE UNA MATRIZ DE ALUMINA DE TRANSICION ET}, ALUMINA DE TRANSICION GA} O UNA MEZCLA DE DICHAS ALUMINAS, Y DEL 0,001 AL 2 % EN PESO DE SILICIO, DEL 0,1 AL 15 % EN PESO DE POR LO MENOS UN HALOGENO ELEGIDO DENTRO DEL GRUPO FORMADO POR EL FLUOR, EL CLORO, EL BROMO Y EL YODO, DEL 0,01 AL 2 % EN PESO DE POR LO MENOS UN METAL NOBLE DE LA FAMILIA DEL PLATINO Y DEL 0,005 AL 10 % EN PESO DE POR LO MENOS UN METAL PROMOTOR ELEGIDO DENTRO DEL GRUPO FORMADO POR EL ESTAÑO, EL GERMANIO, EL INDIO, EL GALIO, EL TALIO, EL ANTIMONIO, EL PLOMO, EL RENIO, EL MANGANESO, EL CROMO, EL MOLIBDENO Y EL TUNGSTENO Y, EVENTUALMENTE, DEL 0,001 AL 10 % EN PESO DE UN METAL DOPANTE.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9507189A FR2735493B1 (fr) | 1995-06-16 | 1995-06-16 | Procede de transformation catalytique d'hydrocarbures en composes aromatiques avec un catalyseur comprenant du silicium et des metaux alcalins ou alcalino-terreux |
| FR9507186A FR2735491B1 (fr) | 1995-06-16 | 1995-06-16 | Procede de transformation catalytique d'hydrocarbures en composes aromatiques avec un catalyseur comprenant du silicium |
| FR9507188A FR2735492B1 (fr) | 1995-06-16 | 1995-06-16 | Procede de transformation catalytique d'hydrocarbures en composes aromatiques, avec un catalyseur contenant des lanthanides et du silicium |
| FR9507182A FR2735490B1 (fr) | 1995-06-16 | 1995-06-16 | Procede de transformation catalytique d'hydrocarbures en composes aromatiques avec un catalyseur contenant du silicium et du titane, zirconium, hafnium, cobalt, nickel et/ou zinc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2163030T3 true ES2163030T3 (es) | 2002-01-16 |
Family
ID=27446946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96922932T Expired - Lifetime ES2163030T3 (es) | 1995-06-16 | 1996-06-14 | Procedimiento para la transformacion catalitica de hidrocarburos en compuestos aromaticos utilizando un catalizador que contiene silicona. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6045689A (es) |
| EP (1) | EP0832170B1 (es) |
| JP (1) | JPH11507685A (es) |
| KR (1) | KR100399307B1 (es) |
| CN (1) | CN1053690C (es) |
| CA (1) | CA2225498A1 (es) |
| DE (1) | DE69614688T2 (es) |
| ES (1) | ES2163030T3 (es) |
| MY (1) | MY113914A (es) |
| RU (1) | RU2157826C2 (es) |
| WO (1) | WO1997000306A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2778341B1 (fr) * | 1998-05-07 | 2000-06-09 | Inst Francais Du Petrole | Catalyseur a base d'un metal noble du groupe viii contenant du bore et/ou du silicium et son utilisation en hydrotraitement de charge hydrocarbonees |
| DE19838021C2 (de) * | 1998-08-21 | 2002-07-18 | Sintec Keramik Gmbh | Kolben aus Feinstkornkohlenstoff, Verfahren zu seiner Herstellung und seine Verwendung |
| RU2145518C1 (ru) * | 1998-12-17 | 2000-02-20 | Общество с ограниченной ответственностью Научно-внедренческая фирма "Катализатор" | Катализатор для риформинга бензиновых фракций |
| KR100293530B1 (ko) * | 1998-12-26 | 2001-11-14 | 윤덕용 | 탄화수소의방향족화반응에유용한격자내부에Pt을포함하는트리메탈로실리케이트촉매 |
| FR2792550B1 (fr) * | 1999-04-26 | 2001-06-01 | Inst Francais Du Petrole | Catalyseur comprenant un element des groupes 8,9 et 10 presentant une bonne accessibilite et son utilisation dans un procede de deshydrogenation des paraffines |
| US6667270B2 (en) * | 2002-05-22 | 2003-12-23 | Shell Oil Company | Bismuth-and phosphorus-containing catalyst support, reforming catalysts made from same, method of making and naphtha reforming process |
| FR2846574B1 (fr) * | 2002-10-30 | 2006-05-26 | Inst Francais Du Petrole | Catalyseur et procede d'hydrocraquage de charges hydrocarbonees |
| RU2288779C1 (ru) * | 2005-06-28 | 2006-12-10 | Институт проблем переработки углеводородов Сибирского отделения Российской Академии наук | Способ приготовления катализатора для риформинга бензиновых фракций |
| RU2289475C1 (ru) * | 2005-08-12 | 2006-12-20 | Институт проблем переработки углеводородов Сибирского отделения Российской Академии Наук (ИППУ СО РАН) | Катализатор для риформинга бензиновых фракций и способ его приготовления |
| CN101190413B (zh) * | 2006-11-30 | 2010-05-12 | 中国石油化工股份有限公司 | 一种石脑油重整催化剂及其制备方法 |
| EP2412785B1 (en) * | 2009-03-27 | 2019-06-05 | JX Nippon Oil & Energy Corporation | Method for producing aromatic hydrocarbons |
| US9592498B2 (en) * | 2010-11-16 | 2017-03-14 | Rhodia Operations | Porous inorganic composite oxide |
| US20160045899A1 (en) * | 2013-03-28 | 2016-02-18 | Jx Nippon Oil & Energy Corporation | Dehydrogenation catalyst for naphthenic hydrocarbons, method for producing dehydrogenation catalyst for naphthenic hydrocarbons, system for producing hydrogen, and method for producing hydrogen |
| CN109692696B (zh) * | 2017-10-23 | 2022-03-11 | 中国石油化工股份有限公司 | 一种重整催化剂及其制备方法与应用 |
| US12427507B2 (en) | 2020-02-13 | 2025-09-30 | Hindustan Petroleum Corporation Limited | Reforming catalyst and a method of modification and application thereof |
| WO2026006184A1 (en) * | 2024-06-28 | 2026-01-02 | Uop Llc | Multimetallic reforming catalyst and catalytic reforming process |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3177136A (en) * | 1961-08-24 | 1965-04-06 | Socony Mobil Oil Co Inc | Reforming with steamed platinum catalyst |
| FR2187887A1 (en) * | 1972-06-13 | 1974-01-18 | Inst Francais Du Petrole | Reforming with alumina/platinum/chromium catalyst - contg lanthanide(s) for increased activity and life |
| US3972805A (en) * | 1973-03-22 | 1976-08-03 | Universal Oil Products Company | Hydrocarbon conversion with an acidic, sulfur-free trimetallic catalytic composite |
| US3915845A (en) * | 1973-12-06 | 1975-10-28 | Universal Oil Prod Co | Hydrocarbon conversion with a multimetallic catalytic composite |
| FR2280426A1 (fr) * | 1974-07-30 | 1976-02-27 | Raffinage Cie Francaise | Catalyseurs d'hydrotraitement d'hydrocarbures et application desdits catalyseurs |
| US4032587A (en) * | 1975-05-05 | 1977-06-28 | Uop Inc. | Dehydrocyclization with an acidic multimetallic catalytic composite |
| US3972806A (en) * | 1975-07-03 | 1976-08-03 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic catalyst composite |
| US4213849A (en) * | 1976-04-05 | 1980-07-22 | Compagnie Francaise De Raffinage | Method of using catalysts for reforming or isomerizing hydrocarbons |
| GB2008431A (en) * | 1977-09-06 | 1979-06-06 | Uop Inc | Acidic multimetallic catalytic composite and use thereof in hydrocarbon conversion |
| US4190557A (en) * | 1977-09-14 | 1980-02-26 | Uop Inc. | Attenuated superactive multimetallic catalytic composite |
| US4165276A (en) * | 1977-09-14 | 1979-08-21 | Uop Inc. | Hydrocarbon conversion with a superactive multimetallic catalytic composite |
| US4207172A (en) * | 1978-03-13 | 1980-06-10 | Uop Inc. | Hydrocarbon dehydrocyclization with an acidic multimetallic catalytic composite |
| US4290921A (en) * | 1978-11-30 | 1981-09-22 | Uop Inc. | Attenuated superactive multimetallic catalytic composite |
| FR2464095A1 (fr) * | 1979-08-27 | 1981-03-06 | Catalyse Soc Prod Francais | Nouveaux catalyseurs de conversion d'hydrocarbures |
| DE3069394D1 (en) * | 1980-02-15 | 1984-11-15 | Mobil Oil Corp | Reforming process |
| FR2481612A1 (en) * | 1980-04-30 | 1981-11-06 | Catalyse Soc Prod Francais | Hydrocarbon conversion catalysts - contg. platinum-and iron gp. metals and technetium |
| FR2483254A1 (fr) * | 1980-06-02 | 1981-12-04 | Catalyse Soc Prod Francais | Nouveaux catalyseurs de conversion d'hydrocarbures |
| CA1187864A (en) * | 1981-06-17 | 1985-05-28 | Standard Oil Company | Catalyst and support, their methods of preparation, and processes employing same |
| FR2527098B1 (fr) * | 1982-05-24 | 1986-11-14 | Prod Catalyse Ste Fse | No |
| US4769087A (en) * | 1986-06-02 | 1988-09-06 | United Technologies Corporation | Nickel base superalloy articles and method for making |
| ES2033398T3 (es) * | 1987-10-30 | 1993-03-16 | Degussa Aktiengesellschaft | Catalizador trivalente exento de rodio. |
| US4966881A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-alumina reforming catalysts |
| US4966682A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Reforming with modified alumina catalysts |
| US4966880A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-tin-alumina reforming catalysts |
| US5013704A (en) * | 1989-07-03 | 1991-05-07 | Exxon Research And Engineering Company | Novel platinum-rhenium-alumina catalysts for reforming |
| US4966879A (en) * | 1989-07-03 | 1990-10-30 | Exxon Research & Engineering Company | Novel platinum-iridium reforming catalysts |
| US4968408A (en) * | 1989-07-03 | 1990-11-06 | Exxon Research & Engineering Company | Reforming using platinum agglomerated iridium catalysts |
| CA2019848A1 (en) * | 1989-07-03 | 1991-01-04 | Ehsan Ibrahim Shoukry | Platinum reforming catalysts and support material |
| US5015614A (en) * | 1989-07-03 | 1991-05-14 | Exxon Research And Engineering Company | Novel alumina support materials |
| CN1020378C (zh) * | 1990-03-17 | 1993-04-28 | 中国石油化工总公司 | 一种石脑油重整催化剂 |
| DE4240862C2 (de) * | 1992-12-04 | 1995-01-19 | Degussa | Verwendung eines Katalysators zur Herstellung von BTX-Aromaten |
| US5665223A (en) * | 1995-06-05 | 1997-09-09 | Uop | Selective bifunctional multimetallic reforming catalyst |
-
1996
- 1996-06-13 MY MYPI96002404A patent/MY113914A/en unknown
- 1996-06-14 CN CN96194758A patent/CN1053690C/zh not_active Expired - Fee Related
- 1996-06-14 DE DE69614688T patent/DE69614688T2/de not_active Expired - Fee Related
- 1996-06-14 JP JP9502728A patent/JPH11507685A/ja active Pending
- 1996-06-14 CA CA002225498A patent/CA2225498A1/fr not_active Abandoned
- 1996-06-14 KR KR1019970709370A patent/KR100399307B1/ko not_active Expired - Fee Related
- 1996-06-14 US US08/973,402 patent/US6045689A/en not_active Expired - Fee Related
- 1996-06-14 EP EP96922932A patent/EP0832170B1/fr not_active Expired - Lifetime
- 1996-06-14 RU RU98100588/04A patent/RU2157826C2/ru not_active IP Right Cessation
- 1996-06-14 WO PCT/FR1996/000919 patent/WO1997000306A1/fr not_active Ceased
- 1996-06-14 ES ES96922932T patent/ES2163030T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR100399307B1 (ko) | 2003-12-31 |
| KR19990022901A (ko) | 1999-03-25 |
| JPH11507685A (ja) | 1999-07-06 |
| EP0832170A1 (fr) | 1998-04-01 |
| EP0832170B1 (fr) | 2001-08-22 |
| DE69614688D1 (de) | 2001-09-27 |
| CN1187843A (zh) | 1998-07-15 |
| WO1997000306A1 (fr) | 1997-01-03 |
| DE69614688T2 (de) | 2002-06-27 |
| MY113914A (en) | 2002-06-29 |
| RU2157826C2 (ru) | 2000-10-20 |
| US6045689A (en) | 2000-04-04 |
| CA2225498A1 (fr) | 1997-01-03 |
| CN1053690C (zh) | 2000-06-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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