ES2170283T3 - Procedimiento de oxidacion de h2s en azufre. - Google Patents
Procedimiento de oxidacion de h2s en azufre.Info
- Publication number
- ES2170283T3 ES2170283T3 ES96937360T ES96937360T ES2170283T3 ES 2170283 T3 ES2170283 T3 ES 2170283T3 ES 96937360 T ES96937360 T ES 96937360T ES 96937360 T ES96937360 T ES 96937360T ES 2170283 T3 ES2170283 T3 ES 2170283T3
- Authority
- ES
- Spain
- Prior art keywords
- hydrogen sulfide
- gas
- pct
- amount
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052717 sulfur Inorganic materials 0.000 title abstract 3
- 239000011593 sulfur Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 6
- 239000007789 gas Substances 0.000 abstract 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910001570 bauxite Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/046—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide
- C01B17/0469—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process without intermediate formation of sulfur dioxide at least one catalyst bed operating below the dew-point of sulfur
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/06—Temperature control
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Treating Waste Gases (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
SE TRABAJA EN UNA UNIDAD DE OXIDACION (2A) QUE COMPRENDE, EN SERIE, TRES ETAPAS CATALITICAS (3A, 4A, 5A), DONDE CADA UNA CONTIENEN UN CATALIZADOR PROMOTOR DE LA OXIDACION SELECTIVA DE H2 S EN AZUFRE HASTA UNA TEMPERATURA S INFERIOR O IGUAL A 150º C. SE HACE PASAR EL GAS A TRATAR (16) SUCESIVAMENTE POR CADA UNA DE DICHAS ETAPAS Y SE INYECTA AIRE (50, 53A, 55A) EN CADA ETAPA. SE OXIDA A AZUFRE, DE MANERA ADIABATICA, UNA FRACCION DE H2 S DE DICHO GAS EN CADA UNA DE LAS DOS PRIMERAS ETAPAS (3A, 4A) CON UNA CANTIDAD DE AIRE QUE GARANTIZA QUE EN LA SALIDA DE ESTAS ETAPAS LA TEMPERATURA ES COMO MAXIMO S. SE OXIDA LA TOTALIDAD DEL H2 S DEL GAS QUE PASA EN LA ETAPA FINAL (5A) EN EXCESO CONTROLADO DE AIRE Y A UNA TEMPERATURA MAXIMA DE S. ESTE PROCEDIMIENTO ES DE APLICACION EN EL TRATAMIENTO DE GASES QUE CONTIENEN H2 S OBTENIDOS POR HIDROGENACION/HIDROLISIS DE GASES RESIDUALES EN FABRICAS DE AZUFRE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9512989A FR2740767B1 (fr) | 1995-11-03 | 1995-11-03 | Procede d'oxydation complete en soufre de l'h2s present dans un gaz et son application a la recuperation quasi totale, sous la forme de soufre, des composes soufres contenus dans un gaz residuaire d'usine a soufre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2170283T3 true ES2170283T3 (es) | 2002-08-01 |
Family
ID=9484199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96937360T Expired - Lifetime ES2170283T3 (es) | 1995-11-03 | 1996-10-30 | Procedimiento de oxidacion de h2s en azufre. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6017507A (es) |
| EP (1) | EP0801633B1 (es) |
| JP (1) | JP3869856B2 (es) |
| AT (1) | ATE212318T1 (es) |
| CA (1) | CA2209331C (es) |
| DE (1) | DE69618761T2 (es) |
| ES (1) | ES2170283T3 (es) |
| FR (1) | FR2740767B1 (es) |
| NO (1) | NO973030L (es) |
| PT (1) | PT801633E (es) |
| RU (1) | RU2142403C1 (es) |
| TW (1) | TW326003B (es) |
| UA (1) | UA42051C2 (es) |
| WO (1) | WO1997017284A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6579510B2 (en) | 1999-07-30 | 2003-06-17 | Alfred E. Keller | SPOX-enhanced process for production of synthesis gas |
| US6800269B2 (en) | 1999-07-30 | 2004-10-05 | Conocophillips Company | Short contact time catalytic sulfur recovery system for removing H2S from a waste gas stream |
| US6403051B1 (en) * | 1999-07-30 | 2002-06-11 | Conoco Inc. | Recovery of sulfur from H2S and concurrent production of H2 using short contact time CPOX |
| US6946111B2 (en) | 1999-07-30 | 2005-09-20 | Conocophilips Company | Short contact time catalytic partial oxidation process for recovering sulfur from an H2S containing gas stream |
| US6342651B1 (en) | 1999-08-05 | 2002-01-29 | Novus International, Inc. | Reductive combustion of ammonium salts of sulfuric acid |
| US7122170B2 (en) * | 2000-07-25 | 2006-10-17 | Conocophillips Company | Catalysts for SPOC™ enhanced synthesis gas production |
| US7357908B2 (en) * | 2000-12-18 | 2008-04-15 | Conocophillips Company | Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| US7326397B2 (en) * | 2000-12-18 | 2008-02-05 | Conocophillips Company | Catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream |
| CA2434233C (en) * | 2003-07-03 | 2010-02-16 | Clean-Flo Gas Filtration Systems (1987) Ltd. | Method of scrubbing lower mass sulfides with a sulfide scrubbing medium capable of regeneration |
| US7108842B2 (en) * | 2004-01-15 | 2006-09-19 | Conocophillips Company | Process for the catalytic partial oxidation of H2S using staged addition of oxygen |
| US7138101B2 (en) * | 2004-01-15 | 2006-11-21 | Conocophillips Company | Two-stage catalytic process for recovering sulfur from an H2S-containing gas stream |
| US7226572B1 (en) | 2006-03-03 | 2007-06-05 | Conocophillips Company | Compact sulfur recovery plant and process |
| US7501111B2 (en) | 2006-08-25 | 2009-03-10 | Conoco Phillips Company | Increased capacity sulfur recovery plant and process for recovering elemental sulfur |
| MX342214B (es) | 2011-04-18 | 2016-09-20 | M-I L L C | Sistema y metodo para la regeneracion de catalizadores. |
| ES2711612T3 (es) | 2015-03-12 | 2019-05-06 | Prosernat | Proceso de eliminación de compuestos de azufre a partir de un gas con etapas de hidrogenación y oxidación directa |
| CN105565279A (zh) * | 2015-12-21 | 2016-05-11 | 中国科学院生态环境研究中心 | 一种用于Claus尾气净化硫磺回收的SCOT+联合催化氧化工艺 |
| RU2649444C2 (ru) * | 2016-04-25 | 2018-04-03 | Общество с ограниченной ответственностью "Старт-Катализатор" | Установка, способ и катализатор осушки и очистки газообразного углеводородного сырья от сероводорода и меркаптанов |
| RU2649442C2 (ru) * | 2016-04-25 | 2018-04-03 | Общество с ограниченной ответственностью "Старт-Катализатор" | Установка, способ и катализатор очистки газообразного углеводородного сырья от сероводорода и меркаптанов |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA749277A (en) * | 1966-12-27 | Pan American Petroleum Corporation | Sulfur recovery process | |
| US2971824A (en) * | 1958-08-11 | 1961-02-14 | Socony Mobil Oil Co Inc | Process for recovering sulfur from hydrogen sulfide-containing gases |
| FR2277877A1 (fr) * | 1974-07-11 | 1976-02-06 | Aquitaine Petrole | Procede de desulfuration des gaz contenant de l'hydrogene sulfure |
| FR2511663A1 (fr) * | 1981-08-19 | 1983-02-25 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s |
| DE3143400A1 (de) * | 1981-11-02 | 1983-06-01 | Mobil Oil Corp., 10017 New York, N.Y. | Verfahren zur verringerung des schwefelgehaltes in gasstroemen unter gewinnung von elementarem schwefel |
| FR2540092B1 (fr) * | 1983-01-31 | 1986-02-21 | Elf Aquitaine | Procede catalytique de production de soufre a partir d'un gaz renfermant h2s |
| DE3535815A1 (de) * | 1985-10-08 | 1987-04-09 | Metallgesellschaft Ag | Verfahren zum reinigen von schwefelwasserstoff und schwefeldioxid enthaltendem abgas |
| FR2589141B1 (fr) * | 1985-10-25 | 1987-12-11 | Elf Aquitaine | Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre |
| RU2031696C1 (ru) * | 1988-06-08 | 1995-03-27 | Сосьете Насьональ ЕЛФ Акитэн (Продюксьон) | Способ очистки отходящих газов производства серы |
| FR2653422B1 (fr) * | 1989-10-19 | 1992-01-03 | Elf Aquitaine | Procede pour ameliorer le rendement en soufre d'un ensemble de production de soufre a partir d'un gaz acide renfermant h2s, ledit ensemble comportant une usine a soufre, puis une unite d'oxydation et d'hydrolyse suivie d'une unite d'epuration. |
| FR2702673B1 (fr) * | 1993-03-16 | 1995-04-28 | Elf Aquitaine | Procédé d'élimination de l'H2S contenu dans un gaz en concentration inférieure à 5 % en volume avec récupération de cet H2S sous la forme de soufre. |
| FR2702674B1 (fr) * | 1993-03-16 | 1995-04-28 | Elf Aquitaine | Procédé d'élimination des composés soufrés contenus dans un gaz résiduaire du type gaz résiduaire d'usine à soufre Claus, avec récupération desdits composés sous la forme de soufre. |
| EP0631978B1 (en) * | 1993-06-28 | 1996-05-08 | Shell Internationale Researchmaatschappij B.V. | Removing hydrogen sulphide from a gas stream |
-
1995
- 1995-11-03 FR FR9512989A patent/FR2740767B1/fr not_active Expired - Fee Related
-
1996
- 1996-10-30 RU RU97112933A patent/RU2142403C1/ru active
- 1996-10-30 CA CA002209331A patent/CA2209331C/fr not_active Expired - Lifetime
- 1996-10-30 PT PT96937360T patent/PT801633E/pt unknown
- 1996-10-30 AT AT96937360T patent/ATE212318T1/de not_active IP Right Cessation
- 1996-10-30 UA UA97074056A patent/UA42051C2/uk unknown
- 1996-10-30 DE DE69618761T patent/DE69618761T2/de not_active Expired - Lifetime
- 1996-10-30 US US08/860,581 patent/US6017507A/en not_active Expired - Fee Related
- 1996-10-30 JP JP51791197A patent/JP3869856B2/ja not_active Expired - Fee Related
- 1996-10-30 WO PCT/FR1996/001699 patent/WO1997017284A1/fr not_active Ceased
- 1996-10-30 ES ES96937360T patent/ES2170283T3/es not_active Expired - Lifetime
- 1996-10-30 EP EP96937360A patent/EP0801633B1/fr not_active Expired - Lifetime
- 1996-11-02 TW TW085113526A patent/TW326003B/zh active
-
1997
- 1997-06-27 NO NO973030A patent/NO973030L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0801633B1 (fr) | 2002-01-23 |
| DE69618761D1 (de) | 2002-03-14 |
| WO1997017284A1 (fr) | 1997-05-15 |
| ATE212318T1 (de) | 2002-02-15 |
| TW326003B (en) | 1998-02-01 |
| EP0801633A1 (fr) | 1997-10-22 |
| JP3869856B2 (ja) | 2007-01-17 |
| DE69618761T2 (de) | 2002-08-14 |
| PT801633E (pt) | 2002-06-28 |
| UA42051C2 (uk) | 2001-10-15 |
| NO973030D0 (no) | 1997-06-27 |
| RU2142403C1 (ru) | 1999-12-10 |
| US6017507A (en) | 2000-01-25 |
| CA2209331C (fr) | 2000-10-03 |
| JPH10512540A (ja) | 1998-12-02 |
| CA2209331A1 (fr) | 1997-05-15 |
| FR2740767A1 (fr) | 1997-05-09 |
| FR2740767B1 (fr) | 1997-12-26 |
| NO973030L (no) | 1997-08-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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