ES2171655T3 - Composicion de revestimiento que incluye un oligoester-diol, un endurecedor de carbamato y agua. - Google Patents
Composicion de revestimiento que incluye un oligoester-diol, un endurecedor de carbamato y agua.Info
- Publication number
- ES2171655T3 ES2171655T3 ES96905184T ES96905184T ES2171655T3 ES 2171655 T3 ES2171655 T3 ES 2171655T3 ES 96905184 T ES96905184 T ES 96905184T ES 96905184 T ES96905184 T ES 96905184T ES 2171655 T3 ES2171655 T3 ES 2171655T3
- Authority
- ES
- Spain
- Prior art keywords
- carbamate
- coating composition
- oligoester
- diol
- provides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000008199 coating composition Substances 0.000 title abstract 4
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002009 diols Chemical class 0.000 abstract 2
- 229920002601 oligoester Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/302—Water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3221—Polyhydroxy compounds hydroxylated esters of carboxylic acids other than higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8077—Oximes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
ESTA INVENCION PROPORCIONA UN VEHICULO POLIMERICO Y COMPOSICIONES DE RECUBRIMIENTOFORMULADAS LAS CUALES TIENEN ALTO CONTENIDO EN SOLIDOS Y USAN AGUA PARA EFECTUAR VISCOSIDADES PARA PERMITIR LA APLICACION DE DICHOS VEHICULOS POLIMERICOS Y COMPOSICIONES DE RECUBRIMIENTO FORMULADAS CON EL EQUIPAMIENTO DE APLICACION COMERCIAL EXISTENTE. LOS VEHICULOS POLIMERICOS Y LOS REVESTIMIENTOS FORMULADOS INCLUYEN AL MENOS UN DIOL OLIGOESTER, UN CARBAMATO ENDURECEDOR, Y EN ALGUNOS CASOS, UN AGENTE RETICULANTE ADICIONAL. LA COMBINACION DEL DIOL OLIGOESTER CON EL CARBAMATO ENDURECEDOR PROPORCIONA UNA COMPOSICION DE RECUBRIMIENTO DE BAJA VISCOSIDAD CON UN CONTENIDO DE VOC BAJO O CERO, Y PROPORCIONA UN AGLUTINANTE DE CAPA CON UNAS PROPIEDADES DE PELICULA EXTREMADAMENTE BUENAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37804295A | 1995-01-24 | 1995-01-24 | |
| US08/484,640 US5610263A (en) | 1994-01-25 | 1995-06-07 | Water thinned polymeric vehicle for coating compositions with low amounts of volatile oragnic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2171655T3 true ES2171655T3 (es) | 2002-09-16 |
Family
ID=27008054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96905184T Expired - Lifetime ES2171655T3 (es) | 1995-01-24 | 1996-01-24 | Composicion de revestimiento que incluye un oligoester-diol, un endurecedor de carbamato y agua. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5610263A (es) |
| EP (1) | EP0751969B1 (es) |
| JP (1) | JPH10501580A (es) |
| AT (1) | ATE216406T1 (es) |
| CA (1) | CA2185453A1 (es) |
| DE (1) | DE69620683T2 (es) |
| ES (1) | ES2171655T3 (es) |
| WO (1) | WO1996023016A1 (es) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5969085A (en) * | 1994-01-25 | 1999-10-19 | Exxon Chemical Patents, Inc. | Polymeric vehicle for high solids coatings |
| US5955550A (en) * | 1994-01-25 | 1999-09-21 | Exxon Chemical Patents, Inc. | Polymeric vehicle for providing solventless coating compositions |
| US5910563A (en) * | 1994-01-25 | 1999-06-08 | Exxon Chemical Patents, Inc. | Water thinned polymeric vehicle for coating compositions with low amounts of volatile organic compounds |
| US6103826A (en) * | 1995-04-19 | 2000-08-15 | Eastern Michigan University | Clearcoat compositions containing phenolic ester compounds |
| US5681906A (en) * | 1995-04-19 | 1997-10-28 | Exxon Chemical Patents Inc. | Thermoset coating compositions having improved hardness |
| JP2001527586A (ja) * | 1995-04-19 | 2001-12-25 | エクソン ケミカル カンパニー | ポリオール、フェノールエステルアルコール及びイソシアネート化合物を含むポリマービヒクル |
| US6051674A (en) * | 1996-08-26 | 2000-04-18 | Exxon Chemical Patents, Inc. | Polymeric vehicles which include a phenol blocked isocyanate having aliphatic hydroxyl fucntionality |
| US5817722A (en) * | 1995-10-10 | 1998-10-06 | Exxon Chemical Patents Inc. | Low viscosity, high solids polyesterdiols and compositions containing same |
| US6248843B1 (en) | 1998-09-18 | 2001-06-19 | Mcwhorter Technologies, Inc. | Powder coatings based on branched oligoesters and triazole blocked polyisocyanates |
| US6255523B1 (en) * | 1998-09-18 | 2001-07-03 | Mcwhorter Technologies, Inc. | Power coatings based on branched oligoesters and non-emissive uretdione polyisocyanates |
| JP2002105396A (ja) * | 2000-10-03 | 2002-04-10 | Kansai Paint Co Ltd | 水性塗料組成物 |
| JP2004530738A (ja) * | 2001-02-22 | 2004-10-07 | バルスパー ソーシング,インコーポレイティド | 低voc化合物含有コーティング組成物 |
| US7812079B2 (en) * | 2001-02-22 | 2010-10-12 | Valspar Sourcing, Inc. | Coating compositions containing low VOC compounds |
| US6849682B2 (en) * | 2002-09-30 | 2005-02-01 | Omnova Solutions Inc. | VOC containment coating, methods and articles |
| US20040071953A1 (en) * | 2002-09-30 | 2004-04-15 | Sobieski Robert T. | Ink formulations and methods |
| US7732555B2 (en) * | 2004-01-27 | 2010-06-08 | Ppg Industries Ohio, Inc. | Urethane polyol precursors for coating compositions |
| US20070117955A1 (en) * | 2005-11-18 | 2007-05-24 | Basf Corporation | Coating composition |
| US12539525B2 (en) | 2017-11-30 | 2026-02-03 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
| KR102634160B1 (ko) | 2017-11-30 | 2024-02-06 | 악살타 코팅 시스템즈 게엠베하 | 고 전달 효율 어플리케이터를 활용하는 코팅 조성물의 적용을 위한 시스템, 코팅 층 및 상응하는 방법 |
| US12122932B2 (en) | 2020-05-29 | 2024-10-22 | Axalta Coating Systems Ip Co., Llc | Coating compositions for application utilizing a high transfer efficiency applicator and methods and systems thereof |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3652713A (en) * | 1969-02-18 | 1972-03-28 | Toray Industries | Polyester composition having improved antistatic properties and process for the preparation thereof |
| US3804920A (en) * | 1972-03-29 | 1974-04-16 | Sherwin Williams Co | Resin compositions |
| AU466953B2 (en) * | 1972-05-24 | 1975-11-13 | Dulux Australia Limited | Thermosetting coating compositions |
| US3994851A (en) * | 1972-10-26 | 1976-11-30 | Ppg Industries, Inc. | High solids polyester coating composition |
| DE2500308A1 (de) * | 1975-01-07 | 1976-07-15 | Basf Ag | Vernetzbare ueberzugsmasse |
| GB1560785A (en) * | 1975-07-04 | 1980-02-13 | Unilever Ltd | Polyesters |
| NL179063C (nl) * | 1975-12-15 | 1986-07-01 | Akzo Nv | Werkwijze voor de bereiding van een pigmentbevattende bekledingssamenstelling met een hoog vaste-stofgehalte. |
| US4128526A (en) * | 1976-12-23 | 1978-12-05 | General Electric Company | Copolyesters of poly(alkylene glycol aromatic acid esters) and diesters comprising aromatic diols |
| US4188477A (en) * | 1977-09-29 | 1980-02-12 | Union Carbide Corporation | Isocyanate derivatives of ester diol alkoxylates and compositions thereof |
| EP0014808A1 (en) * | 1979-01-04 | 1980-09-03 | Ford Motor Company Limited | Coating composition |
| JPS5688454A (en) * | 1979-12-21 | 1981-07-17 | Toyobo Co Ltd | Aqueous dispersion |
| US4465815A (en) * | 1981-12-28 | 1984-08-14 | Ford Motor Company | Polyhydroxy oligomers for high solids coatings II |
| US4459401A (en) * | 1983-05-04 | 1984-07-10 | Desoto, Inc. | Polyester oligomer and high solids thermosetting coatings |
| US4753975A (en) * | 1983-05-11 | 1988-06-28 | Allied-Signal Inc. | Polyester molding composition containing low viscosity polyester reaction product |
| US4631320A (en) * | 1984-02-17 | 1986-12-23 | American Cyanamid Company | Coating compositions containing polyurethane or polyurea polymers and amino resins |
| US5011894A (en) * | 1984-06-29 | 1991-04-30 | Amoco Corporation | Blends of a poly(aryl ether ketone) and a polyarylate |
| US5143985A (en) * | 1984-06-29 | 1992-09-01 | Amoco Corporation | Blends of a poly(aryl ether ketone) and a polyarylate |
| US4576997A (en) * | 1984-09-14 | 1986-03-18 | Eastman Kodak Company | Adhesive blends |
| US4922002A (en) * | 1984-12-21 | 1990-05-01 | King Industries, Inc. | Linear, low-molecular-weight polyester-based polyol |
| US5025061A (en) * | 1986-12-22 | 1991-06-18 | Nippon Oil And Fats Co., Ltd. | Aqueous dispersion coating material |
| US5115016A (en) * | 1986-12-30 | 1992-05-19 | General Electric Company | Reinforced polyester molding compositions having high gloss and improved resistance to warping |
| US4847314A (en) * | 1987-01-21 | 1989-07-11 | Desoto, Inc. | Polyester coatings from terephthalate polyester and hydroxy-functional linear polyester |
| US5043192A (en) * | 1988-03-15 | 1991-08-27 | North Dakota State University | Polymeric vehicle for coating |
| US5244699A (en) * | 1987-03-27 | 1993-09-14 | North Dakota State University | Polymeric vehicle for coatings |
| US5041476A (en) * | 1988-04-05 | 1991-08-20 | Phillips Petroleum Company | Rapidly crystallizing polyethylene terephthalate blends |
| NO891754L (no) * | 1988-06-02 | 1989-12-04 | Minnesota Mining & Mfg | Ikke-traaddannende fuktighets-herdende blandinger. |
| GB8819563D0 (en) * | 1988-08-17 | 1988-09-21 | Scott Bader Co | Thickened moulding compositions |
| US5239018A (en) * | 1989-09-06 | 1993-08-24 | Exxon Chemical Patents Inc. | Liquid polymer and polyol compositions, and process for preparing phenol-functional polymer |
| DE3930995A1 (de) * | 1989-09-16 | 1991-03-28 | Bayer Ag | Verfahren zur herstellung von polyester (urethan) polyolen enger molekulargewichtsverteilung und ihre verwendung |
| US5171778A (en) * | 1990-03-12 | 1992-12-15 | General Electric Company | Melt blends of polyesters |
| US5057392A (en) * | 1990-08-06 | 1991-10-15 | Eastman Kodak Company | Low fusing temperature toner powder of cross-linked crystalline and amorphous polyester blends |
| US5210155A (en) * | 1990-08-24 | 1993-05-11 | Exxon Chemical Patents Inc. | Phenol terminated diester compositions derived from dicarboxylic acids, polyester polymers or alkyd polymers, and curable compositions containing same |
| US5166289A (en) * | 1990-12-19 | 1992-11-24 | Exxon Chemical Patents Inc. | Thermoset coating composition having improved hardness |
| US5338479A (en) * | 1991-02-12 | 1994-08-16 | Cargill, Incorporated | Blocked isocyanate blend having a high isocyanate content |
| US5245002A (en) * | 1991-06-10 | 1993-09-14 | Eastman Kodak Company | Thermosetting coating compositions |
| US5162455A (en) * | 1991-10-08 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Copolyetherester elastomer |
| US5194569A (en) * | 1991-10-18 | 1993-03-16 | Akzo Nv | Synthesis of block liquid crystal copolymer |
| US5162153A (en) * | 1991-12-23 | 1992-11-10 | Hoechst Celanese Corporation | Poly(butylene terephthalate) copolyester and a process for preparing it |
| US5134222A (en) * | 1991-12-23 | 1992-07-28 | Hoechst Celanese Corporation | Poly(butylene terephthalate) copolyester and a process for preparing it |
-
1995
- 1995-06-07 US US08/484,640 patent/US5610263A/en not_active Expired - Fee Related
-
1996
- 1996-01-24 EP EP19960905184 patent/EP0751969B1/en not_active Expired - Lifetime
- 1996-01-24 JP JP52296296A patent/JPH10501580A/ja active Pending
- 1996-01-24 DE DE69620683T patent/DE69620683T2/de not_active Expired - Fee Related
- 1996-01-24 ES ES96905184T patent/ES2171655T3/es not_active Expired - Lifetime
- 1996-01-24 CA CA 2185453 patent/CA2185453A1/en not_active Abandoned
- 1996-01-24 WO PCT/US1996/000852 patent/WO1996023016A1/en not_active Ceased
- 1996-01-24 AT AT96905184T patent/ATE216406T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2185453A1 (en) | 1996-08-01 |
| MX9604246A (es) | 1998-05-31 |
| ATE216406T1 (de) | 2002-05-15 |
| EP0751969B1 (en) | 2002-04-17 |
| WO1996023016A1 (en) | 1996-08-01 |
| JPH10501580A (ja) | 1998-02-10 |
| AU718252B2 (en) | 2000-04-13 |
| AU4901196A (en) | 1996-08-14 |
| US5610263A (en) | 1997-03-11 |
| EP0751969A1 (en) | 1997-01-08 |
| DE69620683T2 (de) | 2003-01-02 |
| DE69620683D1 (de) | 2002-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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