ES2113680T3 - Composicion de revestimiento en polvo a base de polimeros que contienen epoxi y a base de agentes de endurecimiento con poliacido. - Google Patents
Composicion de revestimiento en polvo a base de polimeros que contienen epoxi y a base de agentes de endurecimiento con poliacido.Info
- Publication number
- ES2113680T3 ES2113680T3 ES94930816T ES94930816T ES2113680T3 ES 2113680 T3 ES2113680 T3 ES 2113680T3 ES 94930816 T ES94930816 T ES 94930816T ES 94930816 T ES94930816 T ES 94930816T ES 2113680 T3 ES2113680 T3 ES 2113680T3
- Authority
- ES
- Spain
- Prior art keywords
- powder coating
- compositions
- polyacid
- composition
- containing polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000004593 Epoxy Substances 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/068—Copolymers with monomers not covered by C09D133/06 containing glycidyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
SE PRESENTAN COMPOSICIONES DE REVESTIMIENTO BASADAS EN COPOLIMEROS FUNCIONALES EPOXIDO Y AGENTES DE CURACION DE ACIDO POLICARBOXILICO. LAS COMPOSICIONES QUE CONTIENEN UN ALTO CONTENIDO DE EPOXIDO PRESENTAN UNAS PROPIEDADES FISICAS Y QUIMICAS EXCELENTES. ADEMAS, LAS COMPOSICIONES SE FORMULAN DE TAL MODO QUE TIENEN UNA VISCOSIDAD RELATIVAMENTE BAJA EN FUSION LO QUE HACE QUE PUEDAN FLUIR BIEN Y PRESENTEN UN ASPECTO DE REVESTIMIENTO EXCELENTE. LAS COMPOSICIONES SON UTILES COMO REVESTIMIENTOS TRANSPARENTES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/143,722 US5407707A (en) | 1993-11-01 | 1993-11-01 | Powder coating composition based on epoxy containing polymers and polyacid curing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2113680T3 true ES2113680T3 (es) | 1998-05-01 |
Family
ID=22505299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94930816T Expired - Lifetime ES2113680T3 (es) | 1993-11-01 | 1994-10-18 | Composicion de revestimiento en polvo a base de polimeros que contienen epoxi y a base de agentes de endurecimiento con poliacido. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5407707A (es) |
| EP (1) | EP0728163B1 (es) |
| JP (1) | JP2898094B2 (es) |
| AT (1) | ATE161568T1 (es) |
| AU (1) | AU7982694A (es) |
| CA (1) | CA2174842C (es) |
| DE (1) | DE69407617T2 (es) |
| ES (1) | ES2113680T3 (es) |
| WO (1) | WO1995012639A1 (es) |
| ZA (1) | ZA948351B (es) |
Families Citing this family (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523349A (en) * | 1993-11-08 | 1996-06-04 | Nippon Paint Co., Ltd. | Powder coating composition |
| US6013733A (en) * | 1996-02-16 | 2000-01-11 | Ppg Industries Ohio, Inc. | Coating of film-forming resin and functional flow control copolymer |
| US5939195A (en) * | 1996-02-20 | 1999-08-17 | Ppg Industries Ohio, Inc. | Color-plus-clear composite coating and process and coated article for improved properties |
| US6077608A (en) | 1996-09-19 | 2000-06-20 | Ppg Industries Ohio, Inc. | Multilayered coating with powder clear coating and substrates therewith and method |
| US8653213B2 (en) * | 1997-02-03 | 2014-02-18 | Cytonix, Llc | Hydrophobic coating compositions and articles coated with said compositions |
| EP0968241A1 (en) * | 1997-03-21 | 2000-01-05 | Rhodia Inc. | Acrylic powder coating including high homopolymer glass transition temperature cyclic (meth)acrylate monomer as viscosity modifier |
| US6069221A (en) * | 1997-08-01 | 2000-05-30 | Ppg Industries Ohio, Inc. | Powder coating compositions containing a carboxylic acid functional polyester |
| US6093774A (en) * | 1997-09-26 | 2000-07-25 | Reichhold Chemicals, Inc. | Low gloss powder coating composition |
| US5969058A (en) * | 1997-12-23 | 1999-10-19 | Ppg Industries Ohio, Inc. | Color-plus-clear composite coating composition containing tin catalysts |
| WO1999032496A1 (en) | 1997-12-23 | 1999-07-01 | Ppg Industries Ohio, Inc. | Catalysts for epoxy-acid coating compositions |
| EP1042379A1 (en) | 1997-12-24 | 2000-10-11 | Shell Internationale Researchmaatschappij B.V. | Copolymers of ethylenically unsaturated monomers to be used in powder coatings |
| JPH11207255A (ja) * | 1998-01-23 | 1999-08-03 | Kansai Paint Co Ltd | 複層上塗塗膜形成法 |
| US6184279B1 (en) * | 1998-06-02 | 2001-02-06 | Ppg Industries Ohio, Inc. | Coating compositions and coated substrates with good appearance properties |
| US6268433B1 (en) | 1998-08-31 | 2001-07-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization |
| US6068797A (en) * | 1998-12-11 | 2000-05-30 | Ppg Industries Ohio, Inc. | Method of preparing a shaped article having a photochromic coating thereon |
| US6180181B1 (en) | 1998-12-14 | 2001-01-30 | Ppg Industries Ohio, Inc. | Methods for forming composite coatings on substrates |
| US6197883B1 (en) | 1999-06-03 | 2001-03-06 | Ppg Industries Ohio, Inc. | Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization |
| US6599992B1 (en) | 1999-06-04 | 2003-07-29 | Reichhold, Inc. | Powder coating composition |
| US6610777B1 (en) | 1999-07-30 | 2003-08-26 | Ppg Industries Ohio, Inc. | Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto |
| BR0012882A (pt) | 1999-07-30 | 2002-04-09 | Ppg Ind Ohio Inc | Revestimentos curados tendo resistência ao risco melhorada, substratos revestidos e métodos a eles relacionados |
| CN1209427C (zh) | 1999-07-30 | 2005-07-06 | 匹兹堡玻璃板工业俄亥俄股份有限公司 | 具有改进抗刮性的涂料组合物、涂覆基材及其有关方法 |
| PT1204709E (pt) | 1999-07-30 | 2007-05-31 | Ppg Ind Ohio Inc | Composições de revestimento que têm resistência ao arranhão melhorada, substratos revestidos e métodos relacionados com eles |
| US6623791B2 (en) | 1999-07-30 | 2003-09-23 | Ppg Industries Ohio, Inc. | Coating compositions having improved adhesion, coated substrates and methods related thereto |
| US6310139B1 (en) | 1999-08-31 | 2001-10-30 | Reichhold, Inc. | Burnish resistant powder coating compositions |
| US6294610B1 (en) | 1999-11-29 | 2001-09-25 | Rohm And Haas Company | Coating powders for heat-sensitive substrates |
| US6531043B1 (en) | 2000-06-29 | 2003-03-11 | Ppg Industries Ohio, Inc. | Methods for electrocoating a metallic substrate with a primer-surfacer and articles produced thereby |
| US6635341B1 (en) | 2000-07-31 | 2003-10-21 | Ppg Industries Ohio, Inc. | Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto |
| ATE337359T1 (de) | 2000-10-03 | 2006-09-15 | Anderson Dev Co | Verfahren zur entgasung eines acrylharzes, verfahren zur herstellung einer pulverbeschichtungszusammensetzung, sowie zu einer pulverbeschichtung verarbeitbare zusammensetzung |
| US6875832B2 (en) * | 2001-04-24 | 2005-04-05 | Ppg Industries Ohio, Inc. | Synthesis of vinyl polymers by controlled radical polymerization |
| US6699942B2 (en) | 2001-09-14 | 2004-03-02 | Ppg Industries Ohio, Inc. | Powder coating compositions demonstrating improved mar resistance |
| US6715196B2 (en) | 2001-12-19 | 2004-04-06 | Ppg Industries Ohio, Inc. | Method of powder coating weldable substrates |
| US20040143079A1 (en) * | 2003-01-21 | 2004-07-22 | Simion Coca | Compositions containing copolymers of isobutylene type monomers |
| US7132477B2 (en) * | 2002-02-15 | 2006-11-07 | Ppg Industries Ohio, Inc. | Powder coating compositions |
| WO2003070825A2 (en) * | 2002-02-15 | 2003-08-28 | Ppg Industries Ohio, Inc. | Waterborne compositions containing copolymers of isobutylene |
| CN1308358C (zh) * | 2002-02-15 | 2007-04-04 | Ppg工业俄亥俄公司 | 含异丁烯型单体交替共聚物的水性成膜用组合物 |
| US6686432B2 (en) | 2002-02-15 | 2004-02-03 | Ppg Industries Ohio, Inc. | Alternating copolymers of isobutylene type monomers |
| US7619040B2 (en) * | 2002-02-15 | 2009-11-17 | Ppg Industries Ohio, Inc. | Compositions containing copolymers of olefinic monomers |
| US6677422B2 (en) | 2002-02-15 | 2004-01-13 | Ppg Industries Ohio, Inc. | Method of making alternating copolymers of isobutylene type monomers |
| US6784248B2 (en) * | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
| US7001952B2 (en) * | 2002-04-19 | 2006-02-21 | Ppg Industries Ohio, Inc. | Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles |
| US20050228124A1 (en) * | 2002-04-19 | 2005-10-13 | Shanti Swarup | Coating compositions containing highly crosslinked polymer particles and a hydrophobic polymer |
| US6762240B2 (en) | 2002-04-19 | 2004-07-13 | Ppg Industries Ohio, Inc. | Highly crosslinked polymer particles and coating compositions containing the same |
| DE60306576T2 (de) * | 2002-05-07 | 2007-07-05 | Mitsui Chemicals, Inc. | Wärmehärtende Pulverbeschichtungszusammensetzung, Verfahren zur Herstellung eines Beschichtungsfilms mit der Zusammensetzung und Beschichtungsfilm |
| WO2004067190A2 (en) | 2003-01-29 | 2004-08-12 | Ppg Industries Ohio Inc. | Method of powder coating weldable substrates |
| US7323529B2 (en) * | 2003-11-26 | 2008-01-29 | Pp6 Industries Ohio, Inc. | Method of making copolymers containing olefinic type monomers |
| US7144966B2 (en) * | 2004-03-04 | 2006-12-05 | Basf Corporation | Acrylic composition for use in coating applications and a method of forming the same |
| US7261843B2 (en) * | 2004-03-04 | 2007-08-28 | Transitions Optical, Inc. | Photochromic optical article |
| US7592040B2 (en) * | 2005-02-23 | 2009-09-22 | Ppg Industries Ohio, Inc. | Two-tone color effect coating process |
| US7507440B2 (en) * | 2005-02-23 | 2009-03-24 | Ppg Industries Ohio, Inc. | Methods of forming composite coatings |
| US7871708B2 (en) * | 2005-02-23 | 2011-01-18 | Ppg Industries Ohio, Inc. | Metal and polymer substrates having a powder basecoat and liquid topcoat |
| US7335402B2 (en) * | 2005-03-09 | 2008-02-26 | Ppg Industries Ohio, Inc. | Radiation curable putty compositions and methods for refinishing a substrate using such compositions |
| US20080113103A1 (en) * | 2006-11-10 | 2008-05-15 | Ppg Industries Ohio, Inc. | Halogen treatment of polymer films using atmospheric plasma |
| US20080118729A1 (en) * | 2006-11-16 | 2008-05-22 | General Electric Company | Thermoplastic composition, method of making, and articles formed therefrom |
| JP2010514874A (ja) * | 2006-12-28 | 2010-05-06 | ヌプレクス レジンズ ビー.ブイ. | 修飾されたナノ粒子を含んでいる膜形成組成物および修飾されたナノ粒子を膜形成組成物中に使用する方法 |
| EP2014694A1 (en) | 2007-05-31 | 2009-01-14 | E.I. Du Pont De Nemours And Company | Powder clear coating composition |
| US20090186966A1 (en) * | 2008-01-22 | 2009-07-23 | Sabic Innovative Plastics Ip B.V. | Thermoplastic polyestercarbonate composition |
| PL2098575T3 (pl) * | 2008-03-04 | 2011-02-28 | Akzo Nobel Coatings Int Bv | Proszek powłokowy zawierający związki akrylowe z epoksydowymi grupami funkcyjnymi oraz powłoki proszkowe oporne na korozję nitkową wykonane z takiego proszku |
| US7737238B2 (en) * | 2008-03-04 | 2010-06-15 | Anderson Development Co. | Resin suitable for powder coating compositions |
| US20100104769A1 (en) * | 2008-10-23 | 2010-04-29 | Boisseau John E | Automotive coating surface enhancement using a plasma treatment technique |
| DE102009031724A1 (de) * | 2009-07-01 | 2011-01-20 | E.T.I. Gmbh | Zusammensetzung zur Verhinderung / Verringerung der Mikroben-induzierten Biokorrosion durch Sulfatreduzierende Bakterien (SRB) und andere Mikroorganismen |
| US8143348B2 (en) * | 2009-09-01 | 2012-03-27 | Ppg Industries Ohio, Inc. | Waterborne coating compositions, related methods and coated substrates |
| US8461253B2 (en) * | 2010-01-15 | 2013-06-11 | Ppg Industries Ohio, Inc. | One-component, ambient curable waterborne coating compositions, related methods and coated substrates |
| US20120082795A1 (en) | 2010-10-01 | 2012-04-05 | Ppg Industries Ohio, Inc. | Method for using a primer comprising a self-emulsified polyester microgel |
| CA2938782A1 (en) | 2014-02-27 | 2015-09-03 | Akzo Nobel Coatings International B.V. | Acrylic resins and powder coating compositions and powder coated substrates including the same |
| US9978529B2 (en) | 2016-01-11 | 2018-05-22 | Pacesetter, Inc. | Oxide on edges of metal anode foils |
| US10090112B2 (en) | 2016-01-15 | 2018-10-02 | Pacesetter, Inc. | Use of etch resist masked anode frame for facilitation of laser cutting, particle and leakage current reduction |
| US9969030B2 (en) | 2016-05-12 | 2018-05-15 | Pacesetter, Inc. | Laser drilling of metal foils for assembly in an electrolytic capacitor |
| US9852849B2 (en) | 2016-05-27 | 2017-12-26 | Pacesetter, Inc. | Using etch resist patterns and formation for facilitation of laser cutting, particle and leakage current reduction |
| EP3480261A1 (en) | 2017-11-03 | 2019-05-08 | PPG Industries Ohio, Inc. | Aqueous coating compositions and processes of forming multi-component composite coatings on substrates |
| KR102715114B1 (ko) * | 2018-12-03 | 2024-10-10 | 현대자동차주식회사 | 알루미늄 휠용 내식성 향상 분체 도료 |
| MX2023007222A (es) | 2020-12-28 | 2023-06-26 | Akzo Nobel Coatings Int Bv | Resinas de acrilato y composiciones de recubrimiento en polvo y sustratos en polvo recubiertos que incluyen los mismos. |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4042645A (en) * | 1969-11-27 | 1977-08-16 | Mitsui Toatsu Chemicals, Incorporated | Process for producing thermosetting finishing powders |
| JPS5312531B1 (es) * | 1971-03-26 | 1978-05-01 | ||
| US3781380A (en) * | 1971-08-16 | 1973-12-25 | Ford Motor Co | Powder coating compositions containing glycidyl ester copolymers,carboxy terminated polymeric crosslinking agents,and flow control agents |
| JPS568873B2 (es) * | 1974-07-31 | 1981-02-26 | ||
| US4027066A (en) * | 1975-12-01 | 1977-05-31 | E. I. Du Pont De Nemours And Company | Thermosetting powder coating composition of an acrylic polymer, dodecanedioic acid, cellulose acetate butyrate and a cross-linking agent |
| JPS5277137A (en) * | 1975-12-24 | 1977-06-29 | Daicel Chem Ind Ltd | Thermosetting resin composition for powder coating |
| DE2749576C3 (de) * | 1977-11-05 | 1980-04-24 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung eines Glycidylgruppen aufweisenden Acrylharzes und dessen Verwendung |
| JPS5819353B2 (ja) * | 1979-08-07 | 1983-04-18 | 三井東圧化学株式会社 | メタリック塗装仕上げ方法 |
| JPS56136856A (en) * | 1980-03-31 | 1981-10-26 | Dainippon Ink & Chem Inc | Powder coating resin composition |
| US4871806A (en) * | 1987-11-16 | 1989-10-03 | The Sherwin-Williams Company | Reactive coatings comprising an acid-functional compound, an anhydride-functional compound, an epoxy-functional compound and a hydroxy-functional compound |
| US4971837A (en) * | 1989-04-03 | 1990-11-20 | Ppg Industries, Inc. | Chip resistant coatings and methods of application |
| JP2893875B2 (ja) * | 1990-06-20 | 1999-05-24 | ジェイエスアール株式会社 | 保護膜形成用材料 |
| US5256452A (en) * | 1991-04-29 | 1993-10-26 | Ppg Industries, Inc. | One package stable etch resistant coating process |
| JP2774985B2 (ja) * | 1991-06-06 | 1998-07-09 | 日本ペイント株式会社 | 粉体塗料用樹脂組成物 |
| DE4134290A1 (de) * | 1991-10-17 | 1993-09-23 | Herberts Gmbh | Verfahren zur mehrschichtlackierung |
| JP3236677B2 (ja) * | 1991-11-27 | 2001-12-10 | 三井化学株式会社 | 熱硬化性粉体塗料用組成物 |
| US5270391A (en) * | 1991-11-27 | 1993-12-14 | Mitsui Toatsu Chemicals, Inc. | Composition for thermosetting powder coating |
| US5153252A (en) * | 1991-11-29 | 1992-10-06 | Estron Chemical, Inc. | Thermosetting powder coating compostions containing bisphenoxy-propanol as a melt viscosity modifier |
| US5270416A (en) * | 1992-09-04 | 1993-12-14 | Ferro Corporation | Thermosetting glycidyl modified acrylic powder coatings |
| US5384367A (en) * | 1993-04-19 | 1995-01-24 | Ppg Industries, Inc. | Carbamate urea or urethane-functional epoxy acrylic with polyacid |
-
1993
- 1993-11-01 US US08/143,722 patent/US5407707A/en not_active Expired - Lifetime
-
1994
- 1994-10-18 AU AU79826/94A patent/AU7982694A/en not_active Abandoned
- 1994-10-18 WO PCT/US1994/011863 patent/WO1995012639A1/en not_active Ceased
- 1994-10-18 CA CA002174842A patent/CA2174842C/en not_active Expired - Fee Related
- 1994-10-18 EP EP94930816A patent/EP0728163B1/en not_active Revoked
- 1994-10-18 AT AT94930816T patent/ATE161568T1/de not_active IP Right Cessation
- 1994-10-18 JP JP7513238A patent/JP2898094B2/ja not_active Expired - Lifetime
- 1994-10-18 ES ES94930816T patent/ES2113680T3/es not_active Expired - Lifetime
- 1994-10-18 DE DE69407617T patent/DE69407617T2/de not_active Revoked
- 1994-10-24 ZA ZA948351A patent/ZA948351B/xx unknown
-
1996
- 1996-03-14 US US08/615,745 patent/US5663240A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69407617D1 (de) | 1998-02-05 |
| AU7982694A (en) | 1995-05-23 |
| WO1995012639A1 (en) | 1995-05-11 |
| CA2174842A1 (en) | 1995-05-11 |
| ZA948351B (en) | 1996-04-24 |
| JP2898094B2 (ja) | 1999-05-31 |
| EP0728163A1 (en) | 1996-08-28 |
| CA2174842C (en) | 1999-07-13 |
| US5407707A (en) | 1995-04-18 |
| US5663240A (en) | 1997-09-02 |
| EP0728163B1 (en) | 1997-12-29 |
| ATE161568T1 (de) | 1998-01-15 |
| DE69407617T2 (de) | 1998-07-02 |
| JPH09500415A (ja) | 1997-01-14 |
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