ES2171687T3 - Sintesis de base de piridina. - Google Patents
Sintesis de base de piridina.Info
- Publication number
- ES2171687T3 ES2171687T3 ES96921748T ES96921748T ES2171687T3 ES 2171687 T3 ES2171687 T3 ES 2171687T3 ES 96921748 T ES96921748 T ES 96921748T ES 96921748 T ES96921748 T ES 96921748T ES 2171687 T3 ES2171687 T3 ES 2171687T3
- Authority
- ES
- Spain
- Prior art keywords
- zeolite
- base synthesis
- twelve
- dimension
- piridine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 4
- 239000010457 zeolite Substances 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/08—Preparation by ring-closure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/08—Preparation by ring-closure
- C07D213/09—Preparation by ring-closure involving the use of ammonia, amines, amine salts, or nitriles
- C07D213/10—Preparation by ring-closure involving the use of ammonia, amines, amine salts, or nitriles from acetaldehyde or cyclic polymers thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
UN PROCESO DE BASE DE SINTESIS Y UN CATALIZADOR PARA LA PREPARACION DE PIRIDINA O DE SUS DERIVADOS ALQUILPIRIDINICOS QUE IMPLICA LA REACCION CATALITICA DE UNO O MAS ALDEHIDOS Y/O CETONAS QUE CONTIENEN DESDE UNO A ALREDEDOR DE CINCO ATOMOS DE CARBONO, EN DONDE AL MENOS UN REACTANTE TIENE MAS DE UN ATOMO DE CARBONO Y CON AMONIACO EN FASE GASEOSA. EL CATALIZADOR COMPRENDE UNA CANTIDAD EFECTIVA DE UNA ZEOLITA DE PORO GRANDE, PREPARADA CON UNA RELACION DE AL MENOS 15 ENTRE EL SILICATO Y LA ALUMINA, Y AL MENOS UNA PRIMERA DIMENSION QUE CONTIENE PRIMEROS CANALES FORMADOS POR ANILLOS DE DOCE MIEMBROS, Y UNA SEGUNDA DIMENSION QUE CONTIENE SEGUNDOS CANALES FORMADOS POR ANILLOS DE DIEZ O DOCE MIEMBROS DE QUE SE CRUZAN CON LOS PRIMEROS CANALES. LA ZEOLITA PREFERIDA ES UNA ZEOLITA QUE POSEE LA ESTRUCTURA BETA ZEOLITA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47095P | 1995-06-23 | 1995-06-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2171687T3 true ES2171687T3 (es) | 2002-09-16 |
Family
ID=21691651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96921748T Expired - Lifetime ES2171687T3 (es) | 1995-06-23 | 1996-06-21 | Sintesis de base de piridina. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5780635A (es) |
| EP (1) | EP0837849B1 (es) |
| JP (1) | JP4135972B2 (es) |
| CN (1) | CN1152862C (es) |
| AT (1) | ATE214369T1 (es) |
| AU (1) | AU6288596A (es) |
| BR (1) | BR9609520A (es) |
| DE (1) | DE69619821T2 (es) |
| ES (1) | ES2171687T3 (es) |
| PT (1) | PT837849E (es) |
| TW (1) | TW378204B (es) |
| WO (1) | WO1997000861A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4313854B2 (ja) * | 1997-06-16 | 2009-08-12 | 広栄化学工業株式会社 | 2,3,5−コリジン及び2−エチル−5−メチルピリジンの製造方法 |
| US5969143A (en) * | 1997-12-31 | 1999-10-19 | Mobil Oil Corporation | Pyridine/picoline production process |
| US5994550A (en) * | 1998-12-30 | 1999-11-30 | Mobil Oil Corporation | Pyridine/picoline production process |
| US6281362B1 (en) * | 2000-06-23 | 2001-08-28 | Koel Chemical Company, Ltd. | Method for producing pyridine bases |
| US6495690B2 (en) | 2001-03-27 | 2002-12-17 | Council Of Scientific And Industrial Research | Process for the synthesis of an annulated pyridine base |
| WO2002079166A1 (en) * | 2001-03-30 | 2002-10-10 | Council Of Scientific And Industrial Research | A process for the synthesis of an annulated pyridine base |
| DE10300094A1 (de) * | 2001-07-06 | 2004-07-15 | Tricat Zeolites Gmbh | Zeolith mit Schichtaggregation und Verfahren zu seiner Herstellung |
| TWI598335B (zh) | 2012-10-25 | 2017-09-11 | W R 康格雷氏公司 | 用於製造吡啶及其烷基衍生物之改良方法、觸媒 |
| CA3080597A1 (en) * | 2017-11-02 | 2019-05-09 | Vertellus Holdings Llc | Zeolite catalyst |
| CN114522718B (zh) * | 2022-02-18 | 2024-05-07 | 山东明化新材料有限公司 | 一种zsm-5/bea共结晶分子筛催化剂的制备及在3-甲基吡啶制备过程中的应用 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3020280A (en) * | 1962-02-06 | Quinoline synthesis | ||
| US3020281A (en) * | 1957-07-22 | 1962-02-06 | Reilly Tar & Chem Corp | Method of preparing quinoline |
| US3020282A (en) * | 1957-07-22 | 1962-02-06 | Reilly Tar & Chem Corp | Process of preparing quinoline |
| US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| GB1235390A (en) * | 1968-01-27 | 1971-06-16 | Bp Chem Int Ltd | Pyridine bases |
| US4016218A (en) * | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| US4220783A (en) * | 1979-05-09 | 1980-09-02 | Mobil Oil Corporation | Synthesis of pyridine and alkylpyridines |
| US4388461A (en) * | 1981-12-01 | 1983-06-14 | Mobil Oil Corporation | Process for producing alpha-picoline |
| US4518485A (en) * | 1982-05-18 | 1985-05-21 | Mobil Oil Corporation | Hydrotreating/isomerization process to produce low pour point distillate fuels and lubricating oil stocks |
| NL8202884A (nl) * | 1982-07-16 | 1984-02-16 | Nl Org Zuiver Wetenschapp | Werkwijze voor de bereiding van pyridine-basen. |
| US4675410A (en) * | 1983-07-11 | 1987-06-23 | Nepera Inc. | Process for the production of pyridine or alkyl substituted pyridines |
| DE3332687A1 (de) * | 1983-09-10 | 1985-03-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von 2-amino-alkylpyridinen |
| US4714537A (en) * | 1985-06-08 | 1987-12-22 | Mobil Oil Corporation | Process for cyclic dewaxing/regeneration of hydrocarbon feedstocks |
| US4810794A (en) * | 1986-02-06 | 1989-03-07 | Koei Chemical Co., Ltd. | Process for producing pyridine bases |
| US4985384A (en) * | 1986-08-25 | 1991-01-15 | W. R. Grace & Co-Conn. | Cracking catalysts having aromatic selectivity |
| DE3634259A1 (de) * | 1986-10-08 | 1988-04-21 | Basf Ag | Verfahren zur herstellung von substituierten pyridinen |
| DE3714857A1 (de) * | 1987-05-05 | 1988-11-24 | Basf Ag | Verfahren zur herstellung von pyridinen |
| US4861894A (en) * | 1987-06-11 | 1989-08-29 | Mobil Oil Corp. | Pyridine and alkylpyridine synthesis using a crystalline silicate catalyst having the ZSM-5 structure |
| US4840929A (en) * | 1987-07-02 | 1989-06-20 | Mobil Oil Corporation | Zeolite beta with improved regeneration characteristics |
| EP0317227A3 (en) * | 1987-11-16 | 1989-06-14 | Mobil Oil Corporation | Gallosilicate zeolite beta and the preparation and use as catalyst thereof |
| US4910006A (en) * | 1988-03-23 | 1990-03-20 | Chevron Research Company | Zeolite SSZ-26 |
| US4866179A (en) * | 1988-06-06 | 1989-09-12 | Dairen Chemical Corporation | Process for the manufacture of pyridine in high yield and selectivity during a prolonged period of operation |
| US5218122A (en) * | 1988-09-30 | 1993-06-08 | Reilly Industries, Inc. | Pyridine base synthesis process and catalyst for same |
| CA1333793C (en) * | 1988-09-30 | 1995-01-03 | Gerald L. Goe | Pyridine base synthesis process and catalyst for same |
| DE68918412T2 (de) * | 1988-10-28 | 1995-03-30 | Nepera Inc | Synthese mit hoher Ausbeute von Pyridinen und/oder Alkylpyridinen durch Kondensation von ternären Mischungen von Aldehyden und/oder Ketonen mit Ammoniak. |
| JP2862257B2 (ja) * | 1989-02-08 | 1999-03-03 | 広栄化学工業株式会社 | ピリジン塩基類を製造する方法 |
| US5013843A (en) * | 1990-06-07 | 1991-05-07 | Nepera, Inc. | High yield of pyridine and/or alkylpyridine(s) in condensation reaction of ternary aldehydes and/or ketones with ammonia |
| US5164169A (en) * | 1991-06-14 | 1992-11-17 | Mobil Oil Corporation | Zeolite Beta |
| US5304698A (en) * | 1992-08-10 | 1994-04-19 | Mobil Oil Corporation | Solid catalyzed supercritical isoparaffin-olefin alkylation process |
| US5395940A (en) * | 1993-06-07 | 1995-03-07 | Mobil Oil Corp. | Synthesis of pyridine and 3-alkylpyridine |
| DE69423845T2 (de) * | 1993-11-04 | 2000-10-26 | Enitecnologie Spa | Verfahren und Katalysator zur Reduktion von NOx in Verbrennungsabgasen |
| US5364981A (en) * | 1993-11-08 | 1994-11-15 | Texaco Chemical Company | On-step synthesis of methyl t-butyl ether from t-butanol using platinum/palladium modified β-zeolite catalysts |
-
1996
- 1996-06-21 AU AU62885/96A patent/AU6288596A/en not_active Abandoned
- 1996-06-21 DE DE69619821T patent/DE69619821T2/de not_active Expired - Lifetime
- 1996-06-21 EP EP96921748A patent/EP0837849B1/en not_active Expired - Lifetime
- 1996-06-21 PT PT96921748T patent/PT837849E/pt unknown
- 1996-06-21 JP JP50397797A patent/JP4135972B2/ja not_active Expired - Fee Related
- 1996-06-21 WO PCT/US1996/010727 patent/WO1997000861A1/en not_active Ceased
- 1996-06-21 AT AT96921748T patent/ATE214369T1/de not_active IP Right Cessation
- 1996-06-21 BR BR9609520A patent/BR9609520A/pt not_active Application Discontinuation
- 1996-06-21 CN CNB961964626A patent/CN1152862C/zh not_active Expired - Lifetime
- 1996-06-21 ES ES96921748T patent/ES2171687T3/es not_active Expired - Lifetime
- 1996-06-21 US US08/668,580 patent/US5780635A/en not_active Expired - Lifetime
- 1996-07-15 TW TW085108564A patent/TW378204B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1152862C (zh) | 2004-06-09 |
| BR9609520A (pt) | 1999-02-23 |
| DE69619821T2 (de) | 2002-11-28 |
| PT837849E (pt) | 2002-06-28 |
| WO1997000861A1 (en) | 1997-01-09 |
| AU6288596A (en) | 1997-01-22 |
| DE69619821D1 (en) | 2002-04-18 |
| CN1193962A (zh) | 1998-09-23 |
| TW378204B (en) | 2000-01-01 |
| ATE214369T1 (de) | 2002-03-15 |
| JPH11508537A (ja) | 1999-07-27 |
| EP0837849A4 (en) | 1998-11-25 |
| EP0837849B1 (en) | 2002-03-13 |
| EP0837849A1 (en) | 1998-04-29 |
| US5780635A (en) | 1998-07-14 |
| JP4135972B2 (ja) | 2008-08-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2299466A1 (en) | Process for producing single wall nanotubes using unsupported metal catalysts and single wall nanotubes | |
| ES2171687T3 (es) | Sintesis de base de piridina. | |
| AU550415B2 (en) | Modified fischer-tropsch catalyst for producing hydrocarbon from synthesis gas | |
| MY117355A (en) | Use of transition metal containing small pore molecular sieve catalysts in oxygenate conversion. | |
| AU561323B2 (en) | Catalyst for selective conversion of synthesis gas | |
| FR2694013B1 (fr) | Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures. | |
| IN186365B (es) | ||
| BR8503204A (pt) | Processo para a preparacao de hidrocarbonetos por reacao catalitica de monoxido de carbono com hidrogenio | |
| MY111493A (en) | Method for preparing copper-containing hydrogenation reaction catalyst and method for producing alcohol. | |
| AU638741B2 (en) | Catalyst for conversion of synthesis gas into hydrocarbons | |
| NO902103L (no) | Fremgangsmaate for fremstilling av hydrokarboner. | |
| EP1043297B8 (en) | Process for the preparation of compounds having -ch2-chf- groups | |
| ES8607933A1 (es) | Procedimiento para preparar piridinas | |
| UA32509C2 (uk) | Спосіб екзотермічного гетерогенного синтезу і реактор для його здійснення | |
| GB2152486B (en) | Binder-free zeolite catalyst, process for its preparation, and catalytic reaction using same | |
| FR2611194B1 (fr) | Procede de fabrication de gaz de synthese ou d'hydrogene, par conversion catalytique du methanol en phase liquide | |
| ES8506542A1 (es) | Un procedimiento para producir zincosilicatos cristalinos porosos | |
| DE68924852D1 (de) | Verfahren zur herstellung von pyridinbasen und katalysator zur durchführung des verfahrens. | |
| WO2002028833A3 (en) | Process for the synthesis of 2,2,6,6-tetramethyl-4-oxopiperidine | |
| AU4213385A (en) | Catalyst, process for its preparation and use thereof in conversion of synthesis gas to hydrocarbons | |
| CA2185283A1 (en) | Production of methylamines | |
| AU1203997A (en) | Catalytic reactor and process for exothermic gas phase reactions | |
| ZA82874B (en) | Process for the catalytic synthesis of hydrocarbons,particularly of methane,from hydrogen and carbon monoxide | |
| Jiratthitikan | Catalytic cracking of n-octane over y-type zeolite catalyst | |
| AU7494987A (en) | Catalyst composition and a process for the preparation therewith of hydrocarbons from synthesis gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 837849 Country of ref document: ES |