ES2172015T3 - Microcapsulas de quitina o de derivados de quitina que contienen una substancia hidrofoba, en particular un filtro solar y procedimiento de preparacion de dichas microcapsulas. - Google Patents
Microcapsulas de quitina o de derivados de quitina que contienen una substancia hidrofoba, en particular un filtro solar y procedimiento de preparacion de dichas microcapsulas.Info
- Publication number
- ES2172015T3 ES2172015T3 ES97947105T ES97947105T ES2172015T3 ES 2172015 T3 ES2172015 T3 ES 2172015T3 ES 97947105 T ES97947105 T ES 97947105T ES 97947105 T ES97947105 T ES 97947105T ES 2172015 T3 ES2172015 T3 ES 2172015T3
- Authority
- ES
- Spain
- Prior art keywords
- chitosan
- microcapsules
- quitina
- derivatives
- polyhydroxylated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003094 microcapsule Substances 0.000 title abstract 4
- 239000000126 substance Substances 0.000 title abstract 3
- 229920001661 Chitosan Polymers 0.000 abstract 8
- 229920000768 polyamine Polymers 0.000 abstract 5
- 230000002209 hydrophobic effect Effects 0.000 abstract 4
- 229920002101 Chitin Polymers 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 239000012071 phase Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 230000021736 acetylation Effects 0.000 abstract 1
- 238000006640 acetylation reaction Methods 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000005354 coacervation Methods 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000475 sunscreen effect Effects 0.000 abstract 1
- 239000000516 sunscreening agent Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/445—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof aromatic, i.e. the carboxylic acid directly linked to the aromatic ring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/48—Preparations in capsules, e.g. of gelatin, of chocolate
- A61K9/50—Microcapsules having a gas, liquid or semi-solid filling; Solid microparticles or pellets surrounded by a distinct coating layer, e.g. coated microspheres, coated drug crystals
- A61K9/5005—Wall or coating material
- A61K9/5021—Organic macromolecular compounds
- A61K9/5036—Polysaccharides, e.g. gums, alginate; Cyclodextrin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2989—Microcapsule with solid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Emergency Medicine (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Cosmetics (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
Abstract
LA INVENCION SE REFIERE A UNAS MICROCAPSULAS FORMADAS POR UNA PARED DE QUITINA O UN DERIVADO DE LA MISMA O DE POLIAMINAS POLIHIDROXILADAS O UNA SAL DE LAS MISMAS QUE ENVUELVE UNA SUSTANCIA HIDROFOBA. SE REFIERE ASIMISMO AL PROCEDIMIENTO DE ELABORACION DE LAS MICROCAPSULAS, QUE CONSISTE EN: FORMAR UNA EMULSION DE UNA FASE HIDROFOBA CONSTITUIDA POR LA SUSTANCIA HIDROFOBA EN UNA FASE ACUOSA QUE CONTENGA UN AGENTE TENSIOACTIVO ANIONICO ELEGIDO ENTRE LOS TENSIOACTIVOS CAPACES DE PROVOCAR LA INSOLUBILIZACION DEL QUITOSANO O SUS DERIVADOS O DE POLIAMINAS POLIHIDROXILADAS; MEZCLAR DICHA EMULSION CON UNA SAL ORGANICA DE QUITOSANO O SUS DERIVADOS O DE POLIAMINAS POLIHIDROXILADAS A FIN DE PROVOCAR LA COACERVACION DEL QUITOSANO O SUS DERIVADOS O DE LAS POLIAMINAS POLIHIDROXILADAS EN TORNO DE LAS GOTITAS DE LA FASE HIDROFOBA; SOMETER EL COACERVADO DE QUITOSANO O SUS DERIVADOS O DE POLIAMINAS POLIHIDROXILADAS A UNA REACCION DE ACETILACION O RETICULACION; RETIRAR LAS MICROCAPSULAS. APLICACION A LAS COMPOSICIONES COSMETICAS QUE INCORPORAN FILTROS SOLARES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9614215A FR2755856B1 (fr) | 1996-11-21 | 1996-11-21 | Microcapsules de chitine ou de derives de chitine contenant une substance hydrophobe, notamment un filtre solaire et procede de preparation de telles microcapsules |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2172015T3 true ES2172015T3 (es) | 2002-09-16 |
Family
ID=9497859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97947105T Expired - Lifetime ES2172015T3 (es) | 1996-11-21 | 1997-11-20 | Microcapsulas de quitina o de derivados de quitina que contienen una substancia hidrofoba, en particular un filtro solar y procedimiento de preparacion de dichas microcapsulas. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6242099B1 (es) |
| EP (1) | EP0885061B1 (es) |
| JP (1) | JP2000504033A (es) |
| AT (1) | ATE213432T1 (es) |
| AU (1) | AU5227498A (es) |
| DE (1) | DE69710571T2 (es) |
| ES (1) | ES2172015T3 (es) |
| FR (1) | FR2755856B1 (es) |
| WO (1) | WO1998022210A1 (es) |
Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6468509B2 (en) | 1998-12-18 | 2002-10-22 | Sol-Gel Technologies Ltd. | Sunscreen composition containing sol-gel microcapsules |
| FR2787799B1 (fr) * | 1998-12-23 | 2001-03-09 | Rhodia Chimie Sa | Composition comprenant une ecorce inorganique et un noyau comportant au moins un compose polyhydroxyle |
| NO20002309L (no) * | 1999-05-12 | 2000-11-13 | Hoffmann La Roche | Fotostabile kosmetiske lysavskjermende sammensetninger |
| EP1181000B1 (en) * | 1999-05-25 | 2007-02-07 | Sol-Gel Technologies Ltd. | A method for obtaining photostable sunscreen compositions |
| ATE304343T1 (de) * | 1999-07-02 | 2005-09-15 | Cognis Ip Man Gmbh | Mikrokapseln - iv |
| EP1064913B1 (de) | 1999-07-02 | 2005-09-14 | Cognis IP Management GmbH | Mikrokapseln - III |
| DE59908471D1 (de) * | 1999-07-02 | 2004-03-11 | Cognis Iberia Sl | Mikrokapseln - II |
| US20030206958A1 (en) * | 2000-12-22 | 2003-11-06 | Cattaneo Maurizio V. | Chitosan biopolymer for the topical delivery of active agents |
| FR2805761B1 (fr) * | 2000-03-02 | 2002-08-30 | Mainelab | Nanocapsules lipidiques, procede de preparation et utilisation comme medicament |
| JP2001288064A (ja) * | 2000-04-10 | 2001-10-16 | Kao Corp | 化粧料 |
| US7758888B2 (en) * | 2000-04-21 | 2010-07-20 | Sol-Gel Technologies Ltd. | Composition exhibiting enhanced formulation stability and delivery of topical active ingredients |
| DE50010978D1 (de) * | 2000-09-01 | 2005-09-22 | Cognis Ip Man Gmbh | Kosmetische Stiftzubereitung |
| EP1243321A1 (de) * | 2001-03-22 | 2002-09-25 | Primacare S.L., c/o Cognis Iberica S.L. | Mikrokapseln(IX) |
| WO2003007906A1 (en) | 2001-07-16 | 2003-01-30 | Merck Patent Gmbh | Photostable organic sunscreen compounds with antioxidant properties and compositions obtained therefrom |
| EP1411888A2 (en) | 2001-07-31 | 2004-04-28 | MERCK PATENT GmbH | Sunscreen composition |
| US20030219465A1 (en) * | 2002-05-23 | 2003-11-27 | Suresh Kumar Gidwani | Composition for delivery of dithranol |
| US20040018237A1 (en) * | 2002-05-31 | 2004-01-29 | Perricone Nicholas V. | Topical drug delivery using phosphatidylcholine |
| US7923030B2 (en) | 2003-03-14 | 2011-04-12 | Sol-Gel Technologies, Inc. | Agent-encapsulating micro- and nanoparticles, methods for preparation of same and products containing same |
| US7166273B2 (en) * | 2003-06-03 | 2007-01-23 | Emd Chemicals, Inc. | Photo stable organic sunscreen compositions |
| EA008771B1 (ru) * | 2003-07-31 | 2007-08-31 | Сол-Джел Текнолоджиз Лтд. | Микрокапсулы, заполненные активными ингредиентами, и способ их приготовления |
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| JP2007536259A (ja) * | 2004-05-06 | 2007-12-13 | イヴレア ファーマスーティカルズ インコーポレイテッド | 活性薬剤の送達のための粒子 |
| JP4436189B2 (ja) * | 2004-05-24 | 2010-03-24 | セイコーエプソン株式会社 | 電気泳動表示装置用マイクロカプセルの製造方法 |
| US7265895B2 (en) * | 2004-05-24 | 2007-09-04 | Seiko Epson Corporation | Microcapsule for electrophoretic display device, process for manufacturing the same and use thereof |
| US20050283004A1 (en) * | 2004-06-18 | 2005-12-22 | Hopax Chemicals Manufacturing Co., Ltd. | Alkylsulfonated polyaminosaccharides |
| BRPI0614143A2 (pt) | 2005-08-02 | 2012-11-20 | Sol Gel Technologies Ltd | processo para revestir um material particulado insolével em Água, sàlido, com um àxido metÁlico, material particulado revestido, composiÇço, mÉtodo para o tratamento de uma condiÇço superficial em um induvÍduo, e, uso de material particulado revestido |
| DE102005047647A1 (de) | 2005-10-05 | 2007-04-12 | Merck Patent Gmbh | a,a'-Dihydroxyketonderivate und deren Verwendung als UV-Filter |
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| US8598228B2 (en) | 2009-05-08 | 2013-12-03 | Merck Patent Gmbh | Cinnamic acid ascorbates |
| US8404281B2 (en) | 2009-06-08 | 2013-03-26 | Avant Garde Therapeutics & Technologies Llc | Formulations |
| DE112010002929A5 (de) | 2009-07-14 | 2012-08-30 | Merck Patent Gmbh | Monomethoxy-hydroxy-benzylmalonate |
| DE102009038206A1 (de) | 2009-08-20 | 2011-03-03 | Merck Patent Gmbh | Glycerinaldehydderivate und deren Acetale |
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| ES2675097T3 (es) | 2010-03-26 | 2018-07-06 | Merck Patent Gmbh | Partículas de óxido metálico con tratamiento posterior con compuestos orgánicos de fósforo |
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| US9320758B2 (en) | 2013-03-13 | 2016-04-26 | Transdermal Biotechnology, Inc. | Brain and neural treatments comprising peptides and other compositions |
| US10285926B2 (en) | 2015-06-29 | 2019-05-14 | The Procter & Gamble Company | Superabsorbent polymers and starch powders for use in skin care compositions |
| US10154947B2 (en) | 2016-01-06 | 2018-12-18 | The Procter & Gamble Company | Antiperspirant composition |
| US9732303B2 (en) | 2016-01-06 | 2017-08-15 | The Procter & Gamble Company | Microcapsules formed from phosphate esters and compositions containing same |
| CN105832611B (zh) * | 2016-05-11 | 2018-08-17 | 广东科玮生物技术股份有限公司 | 一种天然植物提取物组合物及其制备方法和应用 |
| PL3595778T3 (pl) * | 2017-03-16 | 2026-06-01 | The Procter And Gamble Company | Kompozycje produktów konsumenckich zawierające mikrokapsułki |
| HUE073201T2 (hu) | 2017-07-12 | 2026-01-28 | Sol Gel Tech Ltd | Kapszulázott tretinoint tartalmazó készítmények |
| EP3908246B1 (en) * | 2019-01-11 | 2024-11-20 | Encapsys, LLC | Incorporation of chitosan in microcapsule wall |
| CN111514829B (zh) * | 2019-02-01 | 2021-08-03 | 武汉大学 | 连续制备不同脱乙酰度甲壳素/壳聚糖微球材料的方法 |
| WO2024034506A1 (ja) | 2022-08-10 | 2024-02-15 | サントリーホールディングス株式会社 | コアシェル粒子及びその製造方法、色素組成物、経口組成物、液状経口組成物及びその製造方法並びに液体中にパターンを形成する方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE506896C (de) | 1929-02-25 | 1930-09-10 | Ringfeder Gmbh | Reibungsfeder |
| BE460670A (es) | 1944-01-28 | |||
| JPS5090578A (es) * | 1973-12-13 | 1975-07-19 | ||
| US4687657A (en) * | 1986-06-09 | 1987-08-18 | Celanese Corporation | Fabrication of SiC - AlN alloys |
| IT1219942B (it) * | 1988-05-13 | 1990-05-24 | Fidia Farmaceutici | Esteri polisaccaridici |
| EP0371878A1 (fr) * | 1988-11-30 | 1990-06-06 | Rhone-Poulenc Sante | Compositions pour l'enrobage d'additifs alimentaires destinés aux ruminants |
| EP0460945B1 (en) * | 1990-06-05 | 1995-10-11 | Mitsubishi Paper Mills, Ltd. | Process for producing microcapsules |
| IT1243390B (it) * | 1990-11-22 | 1994-06-10 | Vectorpharma Int | Composizioni farmaceutiche in forma di particelle atte al rilascio controllato di sostanze farmacologicamente attive e procedimento per la loro preparazione. |
| WO1993009176A2 (en) * | 1991-10-29 | 1993-05-13 | Clover Consolidated, Limited | Crosslinkable polysaccharides, polycations and lipids useful for encapsulation and drug release |
| US5744155A (en) * | 1993-08-13 | 1998-04-28 | Friedman; Doron | Bioadhesive emulsion preparations for enhanced drug delivery |
| US5594694A (en) * | 1995-07-28 | 1997-01-14 | Micron Quantum Devices, Inc. | Memory circuit with switch for selectively connecting an input/output pad directly to a nonvolatile memory cell |
-
1996
- 1996-11-21 FR FR9614215A patent/FR2755856B1/fr not_active Expired - Fee Related
-
1997
- 1997-11-20 AU AU52274/98A patent/AU5227498A/en not_active Abandoned
- 1997-11-20 DE DE69710571T patent/DE69710571T2/de not_active Expired - Fee Related
- 1997-11-20 ES ES97947105T patent/ES2172015T3/es not_active Expired - Lifetime
- 1997-11-20 AT AT97947105T patent/ATE213432T1/de not_active IP Right Cessation
- 1997-11-20 EP EP97947105A patent/EP0885061B1/fr not_active Expired - Lifetime
- 1997-11-20 WO PCT/FR1997/002095 patent/WO1998022210A1/fr not_active Ceased
- 1997-11-20 US US09/101,954 patent/US6242099B1/en not_active Expired - Fee Related
- 1997-11-20 JP JP10505697A patent/JP2000504033A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2755856A1 (fr) | 1998-05-22 |
| DE69710571T2 (de) | 2002-11-21 |
| DE69710571D1 (de) | 2002-03-28 |
| EP0885061B1 (fr) | 2002-02-20 |
| WO1998022210A1 (fr) | 1998-05-28 |
| ATE213432T1 (de) | 2002-03-15 |
| EP0885061A1 (fr) | 1998-12-23 |
| US6242099B1 (en) | 2001-06-05 |
| FR2755856B1 (fr) | 1999-01-29 |
| AU5227498A (en) | 1998-06-10 |
| JP2000504033A (ja) | 2000-04-04 |
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