ES2173932T3 - Procedimiento sulfinilacion de compuestos heterociclicos. - Google Patents

Procedimiento sulfinilacion de compuestos heterociclicos.

Info

Publication number
ES2173932T3
ES2173932T3 ES95102219T ES95102219T ES2173932T3 ES 2173932 T3 ES2173932 T3 ES 2173932T3 ES 95102219 T ES95102219 T ES 95102219T ES 95102219 T ES95102219 T ES 95102219T ES 2173932 T3 ES2173932 T3 ES 2173932T3
Authority
ES
Spain
Prior art keywords
group
arilo
groups
atoms
replaced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95102219T
Other languages
English (en)
Inventor
Michel Casado
Roy Pierre Le
Virginie Pevere
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience SA
Original Assignee
Aventis CropScience SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9460460&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2173932(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Aventis CropScience SA filed Critical Aventis CropScience SA
Application granted granted Critical
Publication of ES2173932T3 publication Critical patent/ES2173932T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/88—Nitrogen atoms, e.g. allantoin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/38—Nitrogen atoms
    • C07D231/40—Acylated on said nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Cephalosporin Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Coloring (AREA)

Abstract

LA INVENCION SE REFIERE A UN NUEVO PROCESO DE SULFINILACION DE COMPUESTOS HETROCICLICOS QUE CONSISTE EN HACER REACCIONAR: UN DERIVADO DE FORMULA RS(O)X, EN LA QUE R ES UN GRUPO ALKILO QUE TIENE DE UNO A CUATRO ATOMOS DE CARBONO, LINEAL O RAMIFICADA, SUSTITUIDO POR UNO O VARIOS ATOMOS DE HALOGENO IDENTICOS O DIFERENTES Y X ES UN ATOMO DE HALOGENO, EL GRUPO HIDROXI O UNA DE SUS SALES, UN GRUPO DIALKILAMINO NR2R3, R2 Y R3 SIENDO GRUPOS ALKILO O HALOALKILO DE 1 A 4 ATOMOS DE CARBONO, O UN GRUPO ARILOXI, EN EL QUE LA PARTE ARILO CORRESPONDE PREFERENTEMENTE A UN GRUPO FENILO, EVENTUALMENTE SUSTITUIDO POR UNO O VARIOS ATOMOS DE HALOGENO O GRUPOS ALKILO O HALOALKILO DE 1 A 4 ATOMOS DE CARBONO, - CON UN COMPUESTO HETEROCICLICO HET ELEGIDO EN EL GRUPO QUE COMPRENDE LOS PIROLES, LOS PIRAZOLES, LOS IMIDAZOLES, LOS OXAZOLES, LOS ISOXAZOLES, LOS ISOTIAZOLES, LOS TIAZOLES, LOS TRIAZOLES, ESTANDO TODOS ESTOS HETEROCICLOS HET EVENTUALMENTE SUSTITUIDOS POR UNO O VARIOS ATOMOS O GRUPOS ELEGIDOS ENTRE HALOGENO, AMINO, MONO- O DIALKILAMINO, NITRILO, ARILO, ARILO, ARILO SUSTITUIDOS POR UNO O VARIOS ATOMOS DE HALOGENO Y/O UN O VARIOS GRUPOS ALKILO, HALOALKILO O SF5.
ES95102219T 1994-02-22 1995-02-17 Procedimiento sulfinilacion de compuestos heterociclicos. Expired - Lifetime ES2173932T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9402222A FR2716453B1 (fr) 1994-02-22 1994-02-22 Procédé de sulfinylation de composés hétérocycliques.

Publications (1)

Publication Number Publication Date
ES2173932T3 true ES2173932T3 (es) 2002-11-01

Family

ID=9460460

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95102219T Expired - Lifetime ES2173932T3 (es) 1994-02-22 1995-02-17 Procedimiento sulfinilacion de compuestos heterociclicos.

Country Status (24)

Country Link
US (1) US5618945A (es)
EP (1) EP0668269B1 (es)
JP (3) JP3963965B2 (es)
KR (1) KR100370990B1 (es)
CN (1) CN1056833C (es)
AT (1) ATE218127T1 (es)
AU (1) AU678876B2 (es)
BR (1) BR9500858A (es)
CA (1) CA2143135C (es)
CZ (1) CZ294640B6 (es)
DE (1) DE69526815T2 (es)
DK (1) DK0668269T3 (es)
ES (1) ES2173932T3 (es)
FI (1) FI113764B (es)
FR (1) FR2716453B1 (es)
HU (1) HU214283B (es)
IL (1) IL112708A (es)
PL (1) PL183151B1 (es)
PT (1) PT668269E (es)
RO (1) RO113639B1 (es)
RU (1) RU2136665C1 (es)
SK (1) SK282510B6 (es)
UA (1) UA44226C2 (es)
ZA (1) ZA951468B (es)

Families Citing this family (31)

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WO1998045274A1 (en) * 1997-04-07 1998-10-15 Mitsubishi Chemical Corporation Pyrazole derivatives, process for preparing the same, intermediates, and pest control agent containing the same as active ingredient
FR2784101B1 (fr) * 1998-09-14 2000-11-17 Rhodia Chimie Sa Procede de condensation de derive(s) aromatique(s) et d'un derive sulfinique dont la chaine carbonee est attachee a la fonction sulfinique par un atome de carbone perhalogene
GB9907458D0 (en) * 1999-03-31 1999-05-26 Rhone Poulenc Agrochimie Processes for preparing pesticidal intermediates
CN1160349C (zh) 1999-06-29 2004-08-04 日本农药株式会社 吡唑衍生物及其制备方法,以及含有该衍生物作为有效成分的有害生物防治剂
HRP20020438B1 (en) * 1999-10-22 2011-01-31 BASF Agro B.V. Process for preparing 4-trifluoromethylsulphinylpyrazole derivative
EP1331222A1 (en) * 2002-01-28 2003-07-30 Virbac S.A. Environment friendly reagents and process for halogenoalkylsulfinylation of organic compounds
BRPI0409860A (pt) * 2003-04-29 2006-05-16 Akzo Nobel Nv processo de solidificação anti-solvente
EP1735284A1 (en) * 2004-03-18 2006-12-27 Pfizer Limited N-(1-arylpyrazol-4l)sulfonamides and their use as parasiticides
WO2007069254A2 (en) 2005-12-14 2007-06-21 Makhteshim Chemical Works Ltd. POLYMORPHS AND AMORPHOUS FORMS OF 5-AMINO-l-[2,6- DICHLORO-4-(TRIFLUOROMETHYL)PHENYL]-4- [(TRIFLUOROMETHYL)SULFINYL]-IH-PYRAZOLE-3-CARBONITRILE
CN101168529B (zh) * 2006-10-24 2011-03-23 温州大学 氟虫腈、乙虫腈及其衍生物的合成方法
BRPI0718717A2 (pt) 2006-11-10 2013-11-26 Basf Se Modificação cristalina ii de fipronil, fipronil sólido, processo para preparar a modificação cristalina ii, mistura pesticida ou parasiticida sinergística, composição pesticida ou parasiticida, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, métodos para controlar pragas, para proteger uma planta da infestação e ataque por pragas, para proteger semente, e para tratar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas, semente, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, e, processo para a preparação de uma composição para trtar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas
JP5931322B2 (ja) 2006-11-10 2016-06-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ フィプロニルの結晶変態
JP5450079B2 (ja) * 2006-11-10 2014-03-26 ビーエーエスエフ ソシエタス・ヨーロピア ピラゾール誘導体のスルフィニル化の方法
AU2007316720B2 (en) * 2006-11-10 2013-05-09 Basf Se Process for the sulfinylation of a pyrazole derivative
US8791046B2 (en) 2006-11-10 2014-07-29 Basf Se Crystalline modification of fipronil
PT2081908E (pt) * 2006-11-10 2013-06-28 Basf Agro B V Arnhem Nl Zurich Branch Processo de sulfinilação de um derivado pirazolo
UA110598C2 (uk) 2006-11-10 2016-01-25 Басф Се Спосіб одержання кристалічної модифікації фіпронілу
US7378547B1 (en) 2006-11-28 2008-05-27 E.I. Du Pont De Nemours And Company Process for the synthesis of hydroxy aromatic acids
FR2925493B1 (fr) * 2007-12-19 2011-09-30 Vetoquinol Procede de preparation du fipronil et d'analogues de celui-ci.
DK2349987T3 (da) 2008-10-02 2013-03-11 Basf Se Fremgangsmåde til fremstilling og oprensning af trifluormethansulfinsyre
AU2012100035A4 (en) 2011-01-14 2012-02-09 Keki Hormusji Gharda Polymorphism in 5-amino-1-(2,6-dichloro-4-trifluoromethylphenyl)-3-cyano-4-trifluoro methyl sulfinyl pyrazole
CN102093295A (zh) * 2011-03-10 2011-06-15 江苏长青农化股份有限公司 一种农药杀虫剂氟虫腈的合成方法
TWI579274B (zh) 2012-04-20 2017-04-21 龍馬躍公司 製備１－芳基－５－烷基吡唑化合物的改良方法
US9049860B2 (en) 2013-04-17 2015-06-09 The Hartz Mountain Corporation Ectoparasiticidal methods
CN104557713B (zh) * 2013-10-22 2018-08-21 江苏托球农化股份有限公司 高纯度氟虫腈制备方法
EP3412659A1 (en) * 2017-06-09 2018-12-12 Solvay Sa Processes for the manufacture of sulfur-substituted pyrazole derivatives
CN107963993A (zh) * 2018-01-06 2018-04-27 江苏托球农化股份有限公司 一种高纯度氟虫腈的制备方法
WO2020188376A1 (en) * 2019-03-19 2020-09-24 Gharda Chemicals Limited A process for synthesis of fipronil
CN113149873A (zh) * 2021-03-10 2021-07-23 浙江埃森化学有限公司 一种三氟甲基亚磺酰氯的制备方法
CN115650919A (zh) * 2022-04-13 2023-01-31 华东理工大学 一种自三氯甲基亚磺酰氯制备氟虫腈的方法
CN115353490A (zh) * 2022-09-26 2022-11-18 安徽美诺华药物化学有限公司 一种氟虫腈的纯化工艺

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5187185A (en) * 1988-12-09 1993-02-16 Rhone-Poulenc Ag Company Pesticidal 1-arylpyrroles
JPS55157570A (en) * 1979-05-26 1980-12-08 Nissan Chem Ind Ltd Sulfamylimidazole derivative, and agricultural and horticultural fungicide
MA19539A1 (fr) * 1981-07-17 1983-04-01 May & Baker Ltd N Acylaminophenylpyrazoles
GB8713768D0 (en) * 1987-06-12 1987-07-15 May & Baker Ltd Compositions of matter
US5232940A (en) * 1985-12-20 1993-08-03 Hatton Leslie R Derivatives of N-phenylpyrazoles
DE3719732A1 (de) * 1987-06-12 1989-01-05 Bayer Ag Substituierte 5-methylamino-1-arylpyrazole
DE3719733A1 (de) * 1987-06-12 1989-01-05 Bayer Ag Substituierte 5-ethylamino-1-arylpyrazole
DE3724919A1 (de) * 1987-07-28 1989-02-09 Bayer Ag 1-arylpyrazole
DE3820190A1 (de) * 1988-06-14 1989-12-21 Cassella Ag Pyrrolderivate, ihre herstellung und ihre verwendung als pharmazeutische wirkstoffe
CA2004776C (fr) * 1988-12-13 2000-04-25 Claude Wakselman Procede de preparation de perfluoroalkylthioethers
US5223525A (en) * 1989-05-05 1993-06-29 Rhone-Poulenc Ag Company Pesticidal 1-arylimidazoles
GB9120641D0 (en) * 1991-09-27 1991-11-06 Ici Plc Heterocyclic compounds

Also Published As

Publication number Publication date
EP0668269B1 (fr) 2002-05-29
IL112708A0 (en) 1995-05-26
CZ294640B6 (cs) 2005-02-16
CZ46195A3 (en) 1995-10-18
JP2007153906A (ja) 2007-06-21
FI950800A0 (fi) 1995-02-21
JP4731503B2 (ja) 2011-07-27
PL307393A1 (en) 1995-09-04
PT668269E (pt) 2002-09-30
DE69526815D1 (de) 2002-07-04
HUT69333A (en) 1995-09-28
FR2716453B1 (fr) 1996-03-29
DE69526815T2 (de) 2002-11-14
US5618945A (en) 1997-04-08
KR950032134A (ko) 1995-12-20
RU2136665C1 (ru) 1999-09-10
IL112708A (en) 2005-05-17
EP0668269A1 (fr) 1995-08-23
JP3963965B2 (ja) 2007-08-22
JP2005187478A (ja) 2005-07-14
CN1110682A (zh) 1995-10-25
FI950800L (fi) 1995-08-23
JPH07278106A (ja) 1995-10-24
SK23495A3 (en) 1995-09-13
CA2143135C (fr) 2010-01-19
FR2716453A1 (fr) 1995-08-25
RO113639B1 (ro) 1998-09-30
PL183151B1 (pl) 2002-05-31
HU9500522D0 (en) 1995-04-28
CN1056833C (zh) 2000-09-27
BR9500858A (pt) 1995-10-24
ZA951468B (en) 1996-02-16
JP4447478B2 (ja) 2010-04-07
AU678876B2 (en) 1997-06-12
SK282510B6 (sk) 2002-10-08
HU214283B (hu) 1998-03-02
FI113764B (fi) 2004-06-15
AU1238395A (en) 1995-08-31
RU95102481A (ru) 1996-11-20
DK0668269T3 (da) 2002-06-17
UA44226C2 (uk) 2002-02-15
CA2143135A1 (fr) 1995-08-23
ATE218127T1 (de) 2002-06-15
KR100370990B1 (ko) 2003-04-21

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