ES2173932T3 - Procedimiento sulfinilacion de compuestos heterociclicos. - Google Patents

Procedimiento sulfinilacion de compuestos heterociclicos.

Info

Publication number
ES2173932T3
ES2173932T3 ES95102219T ES95102219T ES2173932T3 ES 2173932 T3 ES2173932 T3 ES 2173932T3 ES 95102219 T ES95102219 T ES 95102219T ES 95102219 T ES95102219 T ES 95102219T ES 2173932 T3 ES2173932 T3 ES 2173932T3
Authority
ES
Spain
Prior art keywords
group
arilo
groups
atoms
replaced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95102219T
Other languages
English (en)
Inventor
Michel Casado
Roy Pierre Le
Virginie Pevere
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience SA
Original Assignee
Aventis CropScience SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9460460&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2173932(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Aventis CropScience SA filed Critical Aventis CropScience SA
Application granted granted Critical
Publication of ES2173932T3 publication Critical patent/ES2173932T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/88—Nitrogen atoms, e.g. allantoin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/38—Nitrogen atoms
    • C07D231/40—Acylated on said nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyrrole Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Coloring (AREA)
  • Cephalosporin Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

LA INVENCION SE REFIERE A UN NUEVO PROCESO DE SULFINILACION DE COMPUESTOS HETROCICLICOS QUE CONSISTE EN HACER REACCIONAR: UN DERIVADO DE FORMULA RS(O)X, EN LA QUE R ES UN GRUPO ALKILO QUE TIENE DE UNO A CUATRO ATOMOS DE CARBONO, LINEAL O RAMIFICADA, SUSTITUIDO POR UNO O VARIOS ATOMOS DE HALOGENO IDENTICOS O DIFERENTES Y X ES UN ATOMO DE HALOGENO, EL GRUPO HIDROXI O UNA DE SUS SALES, UN GRUPO DIALKILAMINO NR2R3, R2 Y R3 SIENDO GRUPOS ALKILO O HALOALKILO DE 1 A 4 ATOMOS DE CARBONO, O UN GRUPO ARILOXI, EN EL QUE LA PARTE ARILO CORRESPONDE PREFERENTEMENTE A UN GRUPO FENILO, EVENTUALMENTE SUSTITUIDO POR UNO O VARIOS ATOMOS DE HALOGENO O GRUPOS ALKILO O HALOALKILO DE 1 A 4 ATOMOS DE CARBONO, - CON UN COMPUESTO HETEROCICLICO HET ELEGIDO EN EL GRUPO QUE COMPRENDE LOS PIROLES, LOS PIRAZOLES, LOS IMIDAZOLES, LOS OXAZOLES, LOS ISOXAZOLES, LOS ISOTIAZOLES, LOS TIAZOLES, LOS TRIAZOLES, ESTANDO TODOS ESTOS HETEROCICLOS HET EVENTUALMENTE SUSTITUIDOS POR UNO O VARIOS ATOMOS O GRUPOS ELEGIDOS ENTRE HALOGENO, AMINO, MONO- O DIALKILAMINO, NITRILO, ARILO, ARILO, ARILO SUSTITUIDOS POR UNO O VARIOS ATOMOS DE HALOGENO Y/O UN O VARIOS GRUPOS ALKILO, HALOALKILO O SF5.
ES95102219T 1994-02-22 1995-02-17 Procedimiento sulfinilacion de compuestos heterociclicos. Expired - Lifetime ES2173932T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9402222A FR2716453B1 (fr) 1994-02-22 1994-02-22 Procédé de sulfinylation de composés hétérocycliques.

Publications (1)

Publication Number Publication Date
ES2173932T3 true ES2173932T3 (es) 2002-11-01

Family

ID=9460460

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95102219T Expired - Lifetime ES2173932T3 (es) 1994-02-22 1995-02-17 Procedimiento sulfinilacion de compuestos heterociclicos.

Country Status (24)

Country Link
US (1) US5618945A (es)
EP (1) EP0668269B1 (es)
JP (3) JP3963965B2 (es)
KR (1) KR100370990B1 (es)
CN (1) CN1056833C (es)
AT (1) ATE218127T1 (es)
AU (1) AU678876B2 (es)
BR (1) BR9500858A (es)
CA (1) CA2143135C (es)
CZ (1) CZ294640B6 (es)
DE (1) DE69526815T2 (es)
DK (1) DK0668269T3 (es)
ES (1) ES2173932T3 (es)
FI (1) FI113764B (es)
FR (1) FR2716453B1 (es)
HU (1) HU214283B (es)
IL (1) IL112708A (es)
PL (1) PL183151B1 (es)
PT (1) PT668269E (es)
RO (1) RO113639B1 (es)
RU (1) RU2136665C1 (es)
SK (1) SK282510B6 (es)
UA (1) UA44226C2 (es)
ZA (1) ZA951468B (es)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0976737B1 (en) * 1997-04-07 2009-06-10 Nihon Nohyaku Co., Ltd. Pyrazole derivatives, process for preparing the same, intermediates, and pest control agent containing the same as active ingredient
FR2784101B1 (fr) * 1998-09-14 2000-11-17 Rhodia Chimie Sa Procede de condensation de derive(s) aromatique(s) et d'un derive sulfinique dont la chaine carbonee est attachee a la fonction sulfinique par un atome de carbone perhalogene
GB9907458D0 (en) * 1999-03-31 1999-05-26 Rhone Poulenc Agrochimie Processes for preparing pesticidal intermediates
AU763625B2 (en) 1999-06-29 2003-07-31 Nihon Nohyaku Co., Ltd. Pyrazole derivatives and process for producing the same, and pesticides containing the same as the active ingredient
PL206482B1 (pl) 1999-10-22 2010-08-31 Basf Agro B V Arnhem Nl Sposób wytwarzania pochodnych 4-trifluorometylosulfinylopirazolu
EP1331222A1 (en) * 2002-01-28 2003-07-30 Virbac S.A. Environment friendly reagents and process for halogenoalkylsulfinylation of organic compounds
KR20060006949A (ko) * 2003-04-29 2006-01-20 아크조 노벨 엔.브이. 반용매 고화 방법
CA2560510C (en) * 2004-03-18 2009-10-13 Pfizer Inc. N-(1-arylpyrazol-4yl) sulfonamides and their use as parasiticides
CA2630849C (en) 2005-12-14 2013-05-14 Makhteshim Chemical Works Ltd. Polymorphs and amorphous forms of 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1h-pyrazole-3-carbonitrile
CN101168529B (zh) * 2006-10-24 2011-03-23 温州大学 氟虫腈、乙虫腈及其衍生物的合成方法
PL2081908T3 (pl) * 2006-11-10 2013-09-30 Basf Agro B V Arnhem Nl Zuerich Branch Sposób sulfinylowania pochodnej pirazolu
ES2422297T3 (es) * 2006-11-10 2013-09-10 Basf Se Proceso para la sulfinilación de un derivado de pirazol
AU2007316720B2 (en) * 2006-11-10 2013-05-09 Basf Se Process for the sulfinylation of a pyrazole derivative
EP2083628A1 (en) 2006-11-10 2009-08-05 Basf Se Crystalline modification of fipronil
UA110598C2 (uk) 2006-11-10 2016-01-25 Басф Се Спосіб одержання кристалічної модифікації фіпронілу
HRP20110641T4 (hr) 2006-11-10 2015-05-22 Basf Se Kristalna modifikacija fipronila
AU2007316639B2 (en) 2006-11-10 2012-12-20 Basf Se Crystalline modification of fipronil
US7378547B1 (en) 2006-11-28 2008-05-27 E.I. Du Pont De Nemours And Company Process for the synthesis of hydroxy aromatic acids
FR2925493B1 (fr) * 2007-12-19 2011-09-30 Vetoquinol Procede de preparation du fipronil et d'analogues de celui-ci.
DK2349987T3 (da) * 2008-10-02 2013-03-11 Basf Se Fremgangsmåde til fremstilling og oprensning af trifluormethansulfinsyre
WO2012095871A2 (en) 2011-01-14 2012-07-19 Keki Hormusji Gharda Polymorphism in 5-amino- 1 -(2,6-dichloro-4- trifluoromethylphenyl)-3-cyano-4-trifluoro methyl sulfinyl pyrazole
CN102093295A (zh) * 2011-03-10 2011-06-15 江苏长青农化股份有限公司 一种农药杀虫剂氟虫腈的合成方法
TWI579274B (zh) 2012-04-20 2017-04-21 龍馬躍公司 製備１－芳基－５－烷基吡唑化合物的改良方法
US8993613B2 (en) 2013-04-17 2015-03-31 The Hartz Mountain Corporation Ectoparasiticidal formulations
CN104557713B (zh) * 2013-10-22 2018-08-21 江苏托球农化股份有限公司 高纯度氟虫腈制备方法
EP3412659A1 (en) * 2017-06-09 2018-12-12 Solvay Sa Processes for the manufacture of sulfur-substituted pyrazole derivatives
CN107963993A (zh) * 2018-01-06 2018-04-27 江苏托球农化股份有限公司 一种高纯度氟虫腈的制备方法
EP3941907A4 (en) * 2019-03-19 2023-01-04 Gharda Chemicals Limited FIPRONIL SYNTHESIS METHOD
CN113149873A (zh) * 2021-03-10 2021-07-23 浙江埃森化学有限公司 一种三氟甲基亚磺酰氯的制备方法
CN115650919A (zh) * 2022-04-13 2023-01-31 华东理工大学 一种自三氯甲基亚磺酰氯制备氟虫腈的方法
CN115353490A (zh) * 2022-09-26 2022-11-18 安徽美诺华药物化学有限公司 一种氟虫腈的纯化工艺

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5187185A (en) * 1988-12-09 1993-02-16 Rhone-Poulenc Ag Company Pesticidal 1-arylpyrroles
JPS55157570A (en) * 1979-05-26 1980-12-08 Nissan Chem Ind Ltd Sulfamylimidazole derivative, and agricultural and horticultural fungicide
MA19539A1 (fr) * 1981-07-17 1983-04-01 May & Baker Ltd N Acylaminophenylpyrazoles
US5232940A (en) * 1985-12-20 1993-08-03 Hatton Leslie R Derivatives of N-phenylpyrazoles
GB8713768D0 (en) * 1987-06-12 1987-07-15 May & Baker Ltd Compositions of matter
DE3719732A1 (de) * 1987-06-12 1989-01-05 Bayer Ag Substituierte 5-methylamino-1-arylpyrazole
DE3719733A1 (de) * 1987-06-12 1989-01-05 Bayer Ag Substituierte 5-ethylamino-1-arylpyrazole
DE3724919A1 (de) * 1987-07-28 1989-02-09 Bayer Ag 1-arylpyrazole
DE3820190A1 (de) * 1988-06-14 1989-12-21 Cassella Ag Pyrrolderivate, ihre herstellung und ihre verwendung als pharmazeutische wirkstoffe
CA2004776C (fr) * 1988-12-13 2000-04-25 Claude Wakselman Procede de preparation de perfluoroalkylthioethers
US5223525A (en) * 1989-05-05 1993-06-29 Rhone-Poulenc Ag Company Pesticidal 1-arylimidazoles
GB9120641D0 (en) * 1991-09-27 1991-11-06 Ici Plc Heterocyclic compounds

Also Published As

Publication number Publication date
DK0668269T3 (da) 2002-06-17
JP2007153906A (ja) 2007-06-21
KR100370990B1 (ko) 2003-04-21
JP2005187478A (ja) 2005-07-14
CA2143135C (fr) 2010-01-19
CZ46195A3 (en) 1995-10-18
RU2136665C1 (ru) 1999-09-10
EP0668269B1 (fr) 2002-05-29
CN1056833C (zh) 2000-09-27
BR9500858A (pt) 1995-10-24
DE69526815T2 (de) 2002-11-14
HUT69333A (en) 1995-09-28
FI950800L (fi) 1995-08-23
JP3963965B2 (ja) 2007-08-22
AU1238395A (en) 1995-08-31
KR950032134A (ko) 1995-12-20
FI113764B (fi) 2004-06-15
US5618945A (en) 1997-04-08
RU95102481A (ru) 1996-11-20
PL183151B1 (pl) 2002-05-31
CN1110682A (zh) 1995-10-25
AU678876B2 (en) 1997-06-12
IL112708A0 (en) 1995-05-26
JPH07278106A (ja) 1995-10-24
SK282510B6 (sk) 2002-10-08
JP4447478B2 (ja) 2010-04-07
HU214283B (hu) 1998-03-02
SK23495A3 (en) 1995-09-13
CA2143135A1 (fr) 1995-08-23
EP0668269A1 (fr) 1995-08-23
ZA951468B (en) 1996-02-16
FR2716453B1 (fr) 1996-03-29
UA44226C2 (uk) 2002-02-15
ATE218127T1 (de) 2002-06-15
PT668269E (pt) 2002-09-30
FI950800A0 (fi) 1995-02-21
PL307393A1 (en) 1995-09-04
DE69526815D1 (de) 2002-07-04
CZ294640B6 (cs) 2005-02-16
IL112708A (en) 2005-05-17
HU9500522D0 (en) 1995-04-28
RO113639B1 (ro) 1998-09-30
JP4731503B2 (ja) 2011-07-27
FR2716453A1 (fr) 1995-08-25

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