ES2175845T3 - Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia. - Google Patents

Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia.

Info

Publication number
ES2175845T3
ES2175845T3 ES98965218T ES98965218T ES2175845T3 ES 2175845 T3 ES2175845 T3 ES 2175845T3 ES 98965218 T ES98965218 T ES 98965218T ES 98965218 T ES98965218 T ES 98965218T ES 2175845 T3 ES2175845 T3 ES 2175845T3
Authority
ES
Spain
Prior art keywords
copolymers
tubular reactor
reactorestubulars
fluence
improvers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98965218T
Other languages
English (en)
Inventor
Andreas Deckers
Bernd Wenderoth
Peter Wedel
Wilhelm Weber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2175845T3 publication Critical patent/ES2175845T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Detergent Compositions (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Procedimiento para la obtención de copolímeros de etileno/acetato de vinilo, en el cual se polimeriza de forma continua una mezcla, constituida por etileno y acetato de vinilo en presencia de iniciadores de polimerización radicales y, en caso dado, reguladores del peso molecular en un reactor tubular refrigerado a una presión en el intervalo de 1000 hasta 3500 bar, caracterizado porque se agrega el iniciador de polimerización al principio y en varios lugares a lo largo del reactor tubular por dosificación y situándose las alteraciones de temperatura en la mezcla de reacción a lo largo del reactor tubular entre el primer máximo de temperatura y la última dosificación del iniciador de polimerización en un intervalo de un máximo de 20 C.
ES98965218T 1997-12-05 1998-12-01 Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia. Expired - Lifetime ES2175845T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19754039A DE19754039A1 (de) 1997-12-05 1997-12-05 Verfahren zur Herstellung von Ethylencopolymeren in segmentierten Rohrreaktoren und Verwendung der Copolymere als Fließverbesserer

Publications (1)

Publication Number Publication Date
ES2175845T3 true ES2175845T3 (es) 2002-11-16

Family

ID=7850888

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98965218T Expired - Lifetime ES2175845T3 (es) 1997-12-05 1998-12-01 Procedimiento para la obtencion de copolimeros de etileno en reactorestubulares segmentados y el empleo de los copolimeros como mejoradores de la fluencia.

Country Status (12)

Country Link
US (1) US6610797B1 (es)
EP (1) EP1036100B1 (es)
JP (1) JP4488463B2 (es)
KR (1) KR100567636B1 (es)
AT (1) ATE215570T1 (es)
CA (1) CA2311413C (es)
DE (2) DE19754039A1 (es)
DK (1) DK1036100T3 (es)
ES (1) ES2175845T3 (es)
NO (1) NO324462B1 (es)
PT (1) PT1036100E (es)
WO (1) WO1999029748A1 (es)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10021886A1 (de) 2000-05-05 2001-11-15 Basell Polyolefine Gmbh Verfahren zum Herstellen von Phillips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Paricle-Form-Verfahren
EP1391498B1 (en) * 2001-05-08 2016-09-07 Sanyo Chemical Industries, Ltd. Fluidity improver and fuel oil composition
US6673878B2 (en) * 2001-12-19 2004-01-06 Exxonmobil Chemical Patents Inc. Tubular polymerization reactors and polymers made therein
US7745550B2 (en) 2001-12-19 2010-06-29 Exxonmobil Chemical Patents Inc. Tubular polymerization reactors and polymers made therein
DE102010001408A1 (de) 2009-02-06 2010-08-12 Basf Se Verwendung von Ketonen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauches von Dieselmotoren
DE102010039039A1 (de) 2009-08-24 2011-03-03 Basf Se Verwendung von organischen Verbindungen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauchs von Dieselmotoren
CN102858811B (zh) 2010-04-27 2015-01-28 巴斯夫欧洲公司 季铵化三元共聚物
US8790426B2 (en) 2010-04-27 2014-07-29 Basf Se Quaternized terpolymer
US8911516B2 (en) 2010-06-25 2014-12-16 Basf Se Quaternized copolymer
PL2585498T3 (pl) 2010-06-25 2018-10-31 Basf Se Kwaternizowany kopolimer
EP2591016B1 (de) 2010-07-06 2015-01-21 Basf Se Säurefreie quaternisierte stickstoffverbindungen und deren verwendung als additive in kraft- und schmierstoffen
EP2655444B2 (en) † 2010-12-22 2018-11-21 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers in the presence of free-radical polymerization initiator by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers
EP2540808A1 (de) 2011-06-28 2013-01-02 Basf Se Quaternisierte Stickstoffverbindungen und deren Verwendung als Additive in Kraft- und Schmierstoffen
US20130133243A1 (en) 2011-06-28 2013-05-30 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
EP2589647A1 (de) 2011-11-04 2013-05-08 Basf Se Quaternisierte Polyetheramine und deren Verwendung als Additive in Kraft- und Schmierstoffen
EP2604674A1 (de) 2011-12-12 2013-06-19 Basf Se Verwendung quaternisierter Alkylamine als Additive in Kraft- und Schmierstoffen
TR201901211T4 (tr) 2012-02-10 2019-02-21 Basf Se Yakitlar ve yakacak maddeler i̇çi̇n katki olarak i̇mi̇dazolyum tuzlari
US9062266B2 (en) 2012-02-10 2015-06-23 Basf Se Imidazolium salts as additives for fuels
US9458401B2 (en) 2012-03-07 2016-10-04 Basf Se Use of substituted ureas or urethanes for improvement of the use properties of mineral and synthetic nonaqueous industrial fluids
CN104160000A (zh) 2012-03-07 2014-11-19 巴斯夫欧洲公司 取代的脲或氨基甲酸酯用于进一步改善矿物油和原油的低温流动性能的用途
EP2823023A1 (de) 2012-03-07 2015-01-14 Basf Se Verwendung von substituierten harnstoffen oder urethanen zur verbesserung der gebrauchseigenschaften von mineralischen und synthetischen nicht-wässrigen industrieflüssigkeiten, insbesondere kraftstoffen oder schmierstoffen
AU2013336727A1 (en) 2012-10-23 2015-05-14 Basf Se Quaternized ammonium salts of hydrocarbyl epoxides and use thereof as additives in fuels and lubricants
EP2811007A1 (de) 2013-06-07 2014-12-10 Basf Se Verwendung mit Alkylenoxid und Hydrocarbyl-substituierter Polycarbonsäure quaternisierter Alkylamine als Additive in Kraft- und Schmierstoffen
EP3205705B1 (de) 2013-06-07 2020-08-12 Basf Se Mit alkylenoxid und hydrocarbyl-substituierter polycarbonsäure quaternisierte stickstoffverbindungen und ihre verwendung als additiv in kraft- und schmierstoffen
EP3483234B1 (de) 2013-09-20 2021-06-02 Basf Se Verwendung spezieller derivate quaternisierter stickstoffverbindungen als additive in kraftstoffen
PL3099768T3 (pl) 2014-01-29 2020-02-28 Basf Se Inhibitory korozji dla paliw silnikowych
WO2015113681A1 (de) 2014-01-29 2015-08-06 Basf Se Polycarbonsäure-basierte additive für kraft und schmierstoffe
WO2016083090A1 (de) 2014-11-25 2016-06-02 Basf Se Korrosionsinhibitoren für kraft- und schmierstoffe
CA2969027C (en) 2014-11-27 2023-02-28 Basf Se Copolymer and use thereof for reducing crystallization of paraffin crystals in fuels
KR20160080453A (ko) * 2014-12-29 2016-07-08 한화토탈 주식회사 태양전지 봉지재 시트용 에틸렌비닐아세테이트 공중합체 수지의 제조방법 및 그 수지
JP6547371B2 (ja) * 2015-03-30 2019-07-24 大日本印刷株式会社 積層シート、発泡積層シート及びそれらの製造方法
RU2018105763A (ru) 2015-07-16 2019-08-16 Басф Се Сополимеры в качестве добавок для топлив и смазочных веществ
WO2017016909A1 (de) 2015-07-24 2017-02-02 Basf Se Korrosionsinhibitoren für kraft- und schmierstoffe
US10829568B2 (en) 2015-12-22 2020-11-10 Braskem S.A. Tubular reactor polymerization initiator injector device, tubular reactor for continuous polymerization of olefins, and a process for production of polymers and copolymers of ethylene
US11060044B2 (en) 2016-05-24 2021-07-13 Basf Se Copolymer and use thereof for reducing crystallization of paraffin crystals in fuels
ES2896694T3 (es) 2016-07-05 2022-02-25 Basf Se Uso de inhibidores de la corrosión para combustibles y lubricantes
US10844308B2 (en) 2016-07-05 2020-11-24 Basf Se Corrosion inhibitors for fuels and lubricants
CN109312242A (zh) 2016-07-07 2019-02-05 巴斯夫欧洲公司 作为用于燃料和润滑剂的添加剂的共聚物
WO2018007445A1 (de) 2016-07-07 2018-01-11 Basf Se Korrosionsinhibitoren für kraft- und schmierstoffe
WO2018007486A1 (de) 2016-07-07 2018-01-11 Basf Se Polymere als additive für kraft und schmierstoffe
CN110088253B (zh) 2016-12-15 2022-03-18 巴斯夫欧洲公司 作为燃料添加剂的聚合物
WO2018114348A1 (de) 2016-12-19 2018-06-28 Basf Se Additive zur verbesserung der thermischen stabilität von kraftstoffen
WO2018188986A1 (de) 2017-04-13 2018-10-18 Basf Se Polymere als additive für kraft und schmierstoffe
WO2019124675A1 (ko) * 2017-12-18 2019-06-27 주식회사 엘지화학 에틸렌 비닐아세테이트 공중합체 및 그 제조방법
US12157781B2 (en) 2018-11-08 2024-12-03 Sabic Global Technologies B.V. Process for the preparation of ethylene homo- or copolymers in a tubular reactor
CN114051527A (zh) 2019-06-26 2022-02-15 巴斯夫欧洲公司 新的汽油燃料添加剂包
US11292857B2 (en) 2019-10-31 2022-04-05 Exxonmobil Chemical Patents Inc. Methods and systems for the production of high molecular weight ethylene-based polymers
EP3913035A1 (en) 2020-05-20 2021-11-24 Basf Se Novel compositions for reducing crystallization of paraffin crystals in fuels
ES2964845T3 (es) 2020-07-14 2024-04-09 Basf Se Inhibidores de corrosión para combustibles y lubricantes
RS65269B1 (sr) 2021-04-15 2024-03-29 Basf Se Nove kompozicije za smanjenje kristalizacije kristala parafina u gorivima
KR102540867B1 (ko) 2021-04-29 2023-06-07 한화토탈에너지스 주식회사 개시제 투입구 위치 선정을 통한 높은 생산성으로 제품을 생산하기 위한 에틸렌 중합방법
EP4392504A1 (en) 2021-08-27 2024-07-03 Basf Se Aqueous dispersions of paraffin inhibitors
WO2023089354A1 (de) 2021-11-16 2023-05-25 Hediger Richard Verfahren zur herstellung eines kraftstoffzusatzes
WO2024056479A1 (en) 2022-09-12 2024-03-21 Basf Se New compositions for reducing crystallization of paraffin crystals in fuels
WO2024115211A1 (en) 2022-11-30 2024-06-06 Basf Se Homo- and copolymers of vinyl ethers for reducing crystallization of paraffin crystals in fuels
EP4382588A1 (de) 2022-12-06 2024-06-12 Basf Se Additive zur verbesserung der thermischen stabilität von kraftstoffen
EP4682227A1 (en) 2024-07-18 2026-01-21 Basf Se Novel diesel fuel additive packages

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1520227A1 (de) * 1960-03-07 1970-01-02 Monsanto Co Verfahren zur Mischpolymerisation von AEthylen und Vinylacetat
US3627838A (en) * 1964-12-11 1971-12-14 Exxon Research Engineering Co Process for manufacturing potent pour depressants
DE2403516C2 (de) * 1974-01-25 1983-02-17 VEB Leuna-Werke "Walter Ulbricht", DDR 4220 Leuna Verfahren zur Herstellung von Homo-, Co- und Terpolymerisaten sowie Polymerlegierungen des Äthylens
CA1043048A (en) * 1974-04-17 1978-11-21 Exxon Research And Engineering Company Copolymers of ethylene and ethylenically unsaturated monomers, process for their preparation and distillate oil containing said copolymers
FR2397429A1 (fr) * 1977-07-13 1979-02-09 Charbonnages Ste Chimique Procede pour purifier des gaz de recirculation de particules condensees de polymere
DE2960183D1 (en) * 1978-07-26 1981-04-02 Basf Ag Middle distillates of petroleum, suitable as diesel fuel or as light heating oil, and with improved filtration properties
DD159506A3 (de) * 1978-08-24 1983-03-16 Wolfgang Nette Verfahren zur herstellung von niedermolekularen aethylen-vinylazetat-kopolymeren
US4230811A (en) 1978-10-02 1980-10-28 Exxon Research & Engineering Co. Copolymers of ethylene and ethylenically unsaturated monomers, process for their preparation and distillate oil containing said copolymers
US4354011A (en) 1978-10-02 1982-10-12 Exxon Research & Engineering Co. Copolymers of ethylene and ethylenically unsaturated monomers, process for their preparation and distillate oil containing said copolymers
DD161028A1 (de) * 1979-09-27 1984-08-22 Leuna Werke Veb Verfahren zur herstellung von ethylen-vinylacetat-kopolymerisaten
DE3141507A1 (de) * 1981-10-20 1983-04-28 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von ethylenpolymerisaten in einem zweizonen-rohrreaktor bei druecken oberhalb 500 bar
DD243936B1 (de) * 1985-12-06 1988-08-31 Leuna Werke Veb Verfahren zur herstellung von niedermolekularen ethylen-vinylacetat-copolymeren
DE4027140A1 (de) * 1990-08-28 1992-03-05 Basf Ag Ethylen/vinylacetat-copolymerisate mit erhoehtem erstarrungspunkt
DE19741097A1 (de) * 1997-09-18 1999-03-25 Basf Ag Verfahren zur Copolymerisation von Ethylen mit Vinylcarboxylaten

Also Published As

Publication number Publication date
PT1036100E (pt) 2002-09-30
NO20002778L (no) 2000-07-31
NO324462B1 (no) 2007-10-22
DK1036100T3 (da) 2002-07-08
CA2311413C (en) 2008-02-05
US6610797B1 (en) 2003-08-26
EP1036100A1 (de) 2000-09-20
JP4488463B2 (ja) 2010-06-23
KR100567636B1 (ko) 2006-04-05
DE19754039A1 (de) 1999-06-24
KR20010032707A (ko) 2001-04-25
DE59803667D1 (de) 2002-05-08
JP2001525462A (ja) 2001-12-11
EP1036100B1 (de) 2002-04-03
NO20002778D0 (no) 2000-05-30
WO1999029748A1 (de) 1999-06-17
ATE215570T1 (de) 2002-04-15
CA2311413A1 (en) 1999-06-17

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