ES2178145T3 - Nuevas composiciones de catalizador homogeneas de la polimerizacion deolefina. - Google Patents

Nuevas composiciones de catalizador homogeneas de la polimerizacion deolefina.

Info

Publication number
ES2178145T3
ES2178145T3 ES98901993T ES98901993T ES2178145T3 ES 2178145 T3 ES2178145 T3 ES 2178145T3 ES 98901993 T ES98901993 T ES 98901993T ES 98901993 T ES98901993 T ES 98901993T ES 2178145 T3 ES2178145 T3 ES 2178145T3
Authority
ES
Spain
Prior art keywords
group
legends
binding
linked
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98901993T
Other languages
English (en)
Inventor
Kalle Kallio
Hilkka Knuuttila
Jyrki Kauhanen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FI970349A external-priority patent/FI970349A7/fi
Priority claimed from FI971565A external-priority patent/FI971565A7/fi
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of ES2178145T3 publication Critical patent/ES2178145T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

ESTA INVENCION SE REFIERE A UNAS COMPOSICIONES HOMOGENEAS DE CATALIZADOR DE POLIMERIZACION DE OLEFINAS PREPARADAS MEDIANTE CONTACTO DE A) UN METALOCENO CUYA FORMULA GENERAL (1) ES: (CPY Q ) M MX N Z O DONDE CP ES UNO DE LOS LIGANDOS MONO - O POLISUSTITUIDO, FUNDIDO O NO FUNDIDO, HOMO (= ISO -) O CICLOPENTADIENILO HETEROCICLICO, Y ES UN SUSTITUYENTE EN EL ANILLO CICLOPENTADIENILO Y ES UNO DE LOS RADICALES DE - OR, - SR, - NR 2 , - C (H O R) =, O - PR 2 , M ES UN METAL DE TRANSICION DEL GRUPO 4 DE LA TABLA PERIODICA Y VINCULADO CON EL LIGANDO O LOS LIGANDOS CP EN, POR LO MENOS, UN MODO DE ENLACE DE 5 A; X ESTA VINCULADO CON M Y PERTENECE AL GRUPO HIDROCARBILICO DE HIDROGENO, HALOGENO, C SUB, 1 - C 8 , UN GRUPO (O, S, N, P) HIDROCARBILHETEROAT OMO C 1 - C 8 O UN GRUPO SILICO HIDROCARBILICO TRI C 1 - C 8 O DOS X FORMAN JUNTOS CON N UNA ESTRUCTURA DE ANILLO METALOCICLICO C 4 - C 20 ; Z ES UN ATOMO DE PUENTE O UN GRUPO ENTRE DOS LIGANDOS CP O ENTRE UN LIGANDO CP Y EL METAL DE TRANSICION M; Q ES 0- 5; M ES 1 O 2; M.Q M; O ES 0 O 1 Y N ES 4 - M - O, EXCEPTO CUANDO HAY UN PUENTE Z ENTRE DOS LIGANDOS CP, Y EN ESTE CASO N ES 4 M, Y B) UN ALUMINOXANO DE UNO DE FORMULAS (2), (OAIR'') P (2 GENERAL ), DONDE CADA R'' ES IGUAL O DIFERENTE Y ES UN GRUPO DE ALQUILO C 2 - C 10 ; Y P ES UN ENTERO COMPRENDIDO ENTRE 1 Y 40.
ES98901993T 1997-01-28 1998-01-27 Nuevas composiciones de catalizador homogeneas de la polimerizacion deolefina. Expired - Lifetime ES2178145T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI970349A FI970349A7 (fi) 1997-01-28 1997-01-28 Uudet metalloseeniyhdisteiden aktivaattorisysteemit
FI971565A FI971565A7 (fi) 1997-04-14 1997-04-14 Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
FI972230A FI972230A7 (fi) 1997-01-28 1997-05-27 Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus

Publications (1)

Publication Number Publication Date
ES2178145T3 true ES2178145T3 (es) 2002-12-16

Family

ID=27241701

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98901993T Expired - Lifetime ES2178145T3 (es) 1997-01-28 1998-01-27 Nuevas composiciones de catalizador homogeneas de la polimerizacion deolefina.

Country Status (16)

Country Link
US (1) US6316556B1 (es)
EP (1) EP0956308B1 (es)
JP (1) JP2001508486A (es)
KR (1) KR100536961B1 (es)
CN (1) CN100379767C (es)
AR (1) AR010401A1 (es)
AT (1) ATE218590T1 (es)
AU (1) AU744887B2 (es)
BR (1) BR9806936A (es)
CA (1) CA2279242C (es)
DE (1) DE69805751T2 (es)
ES (1) ES2178145T3 (es)
FI (1) FI972230A7 (es)
MY (1) MY120313A (es)
TW (1) TW589332B (es)
WO (1) WO1998032776A1 (es)

Families Citing this family (117)

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FI972230A7 (fi) 1998-07-29
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AR010401A1 (es) 2000-06-07
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