ES2178179T3 - Procedimiento para preparar acido 2,6-naftalenodicarboxilico. - Google Patents
Procedimiento para preparar acido 2,6-naftalenodicarboxilico.Info
- Publication number
- ES2178179T3 ES2178179T3 ES98911730T ES98911730T ES2178179T3 ES 2178179 T3 ES2178179 T3 ES 2178179T3 ES 98911730 T ES98911730 T ES 98911730T ES 98911730 T ES98911730 T ES 98911730T ES 2178179 T3 ES2178179 T3 ES 2178179T3
- Authority
- ES
- Spain
- Prior art keywords
- reaction zone
- solvent
- cobalt
- manganese
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 8
- YGYNBBAUIYTWBF-UHFFFAOYSA-N 2,6-dimethylnaphthalene Chemical compound C1=C(C)C=CC2=CC(C)=CC=C21 YGYNBBAUIYTWBF-UHFFFAOYSA-N 0.000 abstract 6
- 239000002904 solvent Substances 0.000 abstract 5
- 229910017052 cobalt Inorganic materials 0.000 abstract 4
- 239000010941 cobalt Substances 0.000 abstract 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 3
- 229910052748 manganese Inorganic materials 0.000 abstract 3
- 239000011572 manganese Substances 0.000 abstract 3
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 239000007791 liquid phase Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- -1 aliphatic monocarboxylic acid Chemical class 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007810 chemical reaction solvent Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Se describe un procedimiento de producción de ácido 2,6- naftalendicarboxílico mediane oxidación exotérmica en fase líquida de 2,6-dimetilnataleno que comprende la adición en una zona de reacción los componenetes de la reacción de oxidación que comprenden el 2,6- dimetilnaftaleno, una fuente de oxígeno molecular, un disolvente que comprende un ácido monocarboxílico alifático y un catalizador que comprende componentes de cobalto, manganeso y bromo en el que la relación atómica de cobalto a manganeso es de al menos aproximadamente 1:1 y el cobalto y manganeso totales, calculado como cobalto elemental y manganeso elemental añadido a la zona de reacción, es menor de aproximadamente 0,40% en peso basado en el peso del disolvente añadido a la zona de reacción; se mantiene el contenido de la zona de reacción a una temperatura y a una presión suficiente para causar la oxidación del 2,6-dimetilnaftaleno a ácido 2,6-naftalendicarboxílico y la vaporización de al menos una parte del disolvente de la reacción mientras se mantiene una mezcla de reacción en fase líquida; se condensa el disolvente vaporizado y se devuelve una cantidad del disolvente condensado a la zona de reacción para mantener la cantidad de agua en la zona de reacción y no más del 15% en peso basado en el peso del disolvente en la zona de reacción; y se extrae de la zona de reacción una mezcla que comprende ácido 2,6-naftalendicarboxílico.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/827,039 US6114575A (en) | 1997-03-25 | 1997-03-25 | Process for preparing 2,6-naphthalenedicarboxylic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2178179T3 true ES2178179T3 (es) | 2002-12-16 |
Family
ID=25248172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98911730T Expired - Lifetime ES2178179T3 (es) | 1997-03-25 | 1998-03-17 | Procedimiento para preparar acido 2,6-naftalenodicarboxilico. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6114575A (es) |
| EP (1) | EP0971872B1 (es) |
| JP (1) | JP2002510287A (es) |
| KR (1) | KR100660308B1 (es) |
| AT (1) | ATE218529T1 (es) |
| AU (1) | AU6561798A (es) |
| CA (1) | CA2284721C (es) |
| DE (1) | DE69805786T2 (es) |
| ES (1) | ES2178179T3 (es) |
| ID (1) | ID23802A (es) |
| TW (1) | TW500717B (es) |
| WO (1) | WO1998042649A1 (es) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0999199B1 (en) * | 1998-11-04 | 2004-03-31 | Mitsubishi Gas Chemical Company, Inc. | Method of producing naphthalenedicarboxylic acid |
| US6642407B2 (en) | 2001-05-18 | 2003-11-04 | Exxon Mobil Chemical Patents Inc. | Production, purification and polymerization of aromatic dicarboxylic acids |
| WO2003022791A1 (en) * | 2001-09-07 | 2003-03-20 | Lonza Spa | Process for the preparation of 2,6-naphthalenedicarboxylic acid |
| KR20030069370A (ko) * | 2002-02-20 | 2003-08-27 | 주식회사 효성 | 나프탈렌디카르복실산의 제조 방법 |
| KR20030072789A (ko) * | 2002-03-06 | 2003-09-19 | 주식회사 효성 | 2,6-나프탈렌디카복실산의 제조방법 |
| US6657068B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Liquid phase oxidation of halogenated ortho-xylenes |
| US6657067B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Method for the manufacture of chlorophthalic anhydride |
| KR100717650B1 (ko) * | 2002-08-08 | 2007-05-11 | 에스케이케미칼주식회사 | 나프탈렌 디카르복실산의 제조 방법 |
| US7541489B2 (en) | 2004-06-30 | 2009-06-02 | Sabic Innovative Plastics Ip B.V. | Method of making halophthalic acids and halophthalic anhydrides |
| KR100770516B1 (ko) * | 2004-12-30 | 2007-10-25 | 주식회사 효성 | 벤즈알데히드 디하이드로게나제를 발현하는 형질전환체의제조방법 및 이를 이용한 2,6-나프탈렌 디카르복실산의정제방법 |
| US7955674B2 (en) * | 2005-03-02 | 2011-06-07 | Eastman Chemical Company | Transparent polymer blends containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US20060199871A1 (en) * | 2005-03-02 | 2006-09-07 | Hale Wesley R | Multilayered, transparent articles and a process for their preparation |
| US20100184940A1 (en) * | 2005-03-02 | 2010-07-22 | Eastman Chemical Company | Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof |
| US7959836B2 (en) * | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Process for the preparation of transparent, shaped articles containing polyesters comprising a cyclobutanediol |
| US7510768B2 (en) | 2005-06-17 | 2009-03-31 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| US7959998B2 (en) * | 2005-03-02 | 2011-06-14 | Eastman Chemical Company | Transparent, oxygen-scavenging compositions containing polyesters comprising a cyclobutanediol and articles prepared therefrom |
| US7704605B2 (en) | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| US8193302B2 (en) | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| US8586701B2 (en) * | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| MY146045A (en) * | 2005-10-28 | 2012-06-15 | Eastman Chem Co | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US20070106054A1 (en) * | 2005-10-28 | 2007-05-10 | Crawford Emmett D | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom |
| US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US7737246B2 (en) | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| KR100790206B1 (ko) | 2006-12-28 | 2008-01-02 | 주식회사 효성 | 2,6-나프탈렌디카르복실산의 제조방법 |
| US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| JP5635411B2 (ja) | 2007-11-21 | 2014-12-03 | イーストマン ケミカル カンパニー | プラスチック製哺乳瓶、他のブロー成形物品及びそれらの製造方法 |
| US8198371B2 (en) | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
| US20100099828A1 (en) * | 2008-10-21 | 2010-04-22 | Eastman Chemical Company | Clear Binary Blends of Aliphatic Polyesters and Aliphatic-Aromatic Polyesters |
| US8895654B2 (en) * | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
| US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US20130217830A1 (en) | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
| CN112479861A (zh) * | 2020-12-10 | 2021-03-12 | 成家钢 | 液相常压催化氧气氧化安全方法及氧气氧化安全反应设备 |
| CN113845414B (zh) * | 2021-11-25 | 2022-03-04 | 中化学科学技术研究有限公司 | 一种合成2,6-萘二甲酸的方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3856855A (en) * | 1970-02-17 | 1974-12-24 | Teijin Ltd | Process for preparation of naphthalene monocarboxylic acid or naphthalene dicarboxylic acid |
| US3870754A (en) * | 1972-08-28 | 1975-03-11 | Teijin Ltd | Process for the preparation of 2,6-naphthalenedicarboxylic acid |
| JPS5621017A (en) * | 1979-07-31 | 1981-02-27 | Toukiyouto | Electronic liquid meter |
| EP0142719B1 (en) * | 1983-10-24 | 1987-07-08 | Teijin Petrochemical Industries Ltd. | Process for producing 2,6-naphthalenedicarboxylic acid |
| JPS62212340A (ja) * | 1986-03-14 | 1987-09-18 | Kureha Chem Ind Co Ltd | ２，６−ナフタレンジカルボン酸とトリメリツト酸の併産方法 |
| CA1303059C (en) * | 1986-03-14 | 1992-06-09 | Toshiharu Matsuda | Process for producing 2,6-naphthalenedicarboxylic acid by oxidizing 2,6-diisopropylnaphthalene |
| JPH078821B2 (ja) * | 1986-09-26 | 1995-02-01 | 三井石油化学工業株式会社 | 芳香族カルボン酸の製造方法 |
| CA1328115C (en) * | 1988-09-28 | 1994-03-29 | David Allen Young | Method for making 2,6-naphthalenedicarboxylic acid |
| US5055612A (en) * | 1988-12-19 | 1991-10-08 | Nkk Corporation | Process for the preparation of naphthalene carboxylic acids |
| US4933491A (en) * | 1989-10-02 | 1990-06-12 | Amoco Corporation | Method for purifying a crude naphthalene dicarboxylic acid |
| US5183933A (en) * | 1991-10-15 | 1993-02-02 | Amoco Corporation | Process for preparing 2,6-naphthalene-dicarboxylic acid |
| JPH06157403A (ja) * | 1992-11-30 | 1994-06-03 | Mitsubishi Petrochem Co Ltd | ２，６−ナフタレンジカルボン酸の製造方法 |
| US5510521A (en) * | 1995-03-27 | 1996-04-23 | Eastman Chemical Company | Process for the production of aromatic carboxylic acids |
-
1997
- 1997-03-25 US US08/827,039 patent/US6114575A/en not_active Expired - Lifetime
-
1998
- 1998-03-17 ID IDW991269A patent/ID23802A/id unknown
- 1998-03-17 AU AU65617/98A patent/AU6561798A/en not_active Abandoned
- 1998-03-17 WO PCT/US1998/005212 patent/WO1998042649A1/en not_active Ceased
- 1998-03-17 CA CA002284721A patent/CA2284721C/en not_active Expired - Fee Related
- 1998-03-17 KR KR1019997008715A patent/KR100660308B1/ko not_active Expired - Lifetime
- 1998-03-17 ES ES98911730T patent/ES2178179T3/es not_active Expired - Lifetime
- 1998-03-17 DE DE69805786T patent/DE69805786T2/de not_active Expired - Lifetime
- 1998-03-17 JP JP54577498A patent/JP2002510287A/ja not_active Ceased
- 1998-03-17 AT AT98911730T patent/ATE218529T1/de not_active IP Right Cessation
- 1998-03-17 EP EP98911730A patent/EP0971872B1/en not_active Expired - Lifetime
- 1998-03-31 TW TW087104484A patent/TW500717B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU6561798A (en) | 1998-10-20 |
| DE69805786D1 (de) | 2002-07-11 |
| TW500717B (en) | 2002-09-01 |
| EP0971872A1 (en) | 2000-01-19 |
| US6114575A (en) | 2000-09-05 |
| CA2284721A1 (en) | 1998-10-01 |
| KR20010005647A (ko) | 2001-01-15 |
| DE69805786T2 (de) | 2003-02-20 |
| WO1998042649A1 (en) | 1998-10-01 |
| KR100660308B1 (ko) | 2006-12-22 |
| JP2002510287A (ja) | 2002-04-02 |
| EP0971872B1 (en) | 2002-06-05 |
| ID23802A (id) | 2000-05-11 |
| ATE218529T1 (de) | 2002-06-15 |
| CA2284721C (en) | 2007-06-12 |
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