ES2178751T3 - Procedimiento y composicion regeneradora destinados a extraer sulfuros de las corrientes gaseosas. - Google Patents
Procedimiento y composicion regeneradora destinados a extraer sulfuros de las corrientes gaseosas.Info
- Publication number
- ES2178751T3 ES2178751T3 ES97902872T ES97902872T ES2178751T3 ES 2178751 T3 ES2178751 T3 ES 2178751T3 ES 97902872 T ES97902872 T ES 97902872T ES 97902872 T ES97902872 T ES 97902872T ES 2178751 T3 ES2178751 T3 ES 2178751T3
- Authority
- ES
- Spain
- Prior art keywords
- sulfures
- procedure
- remove
- composition intended
- gaseous currents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 230000001172 regenerating effect Effects 0.000 title 1
- 239000002131 composite material Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910001410 inorganic ion Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/80—Organic bases or salts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN METODO Y A UNA COMPOSICION PARA ELIMINAR LOS SULFUROS DE UN CAUDAL GASEOSO. EL METODO INCLUYE LA PUESTA EN CONTACTO DEL CAUDAL DE GAS QUE CONTIENE LOS SULFUROS CON UNA MEZCLA ACUOSA DE RESCATE QUE INCLUYE UN COMPUESTO DE BARRIDO, UN ION INORGANICO Y UN CATALIZADOR DE OXIDACION, QUE REGENERA AL MENOS UNA PARTE DEL COMPUESTO DE BARRIDO CON UN GAS QUE CONTIENE OXIGENO Y DEVUELVE, AL MENOS, UNA PARTE DE LA MEZCLA ACUOSA DE RESCATE A LA ZONA DE CONTACTO. SE FACILITA TAMBIEN UN COMPUESTO DE BARRIDO QUE CONSTA DEL PRODUCTO DE REACCION ENTRE UN ALDEHIDO Y UNA AMINA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/587,837 US5698171A (en) | 1996-01-10 | 1996-01-10 | Regenerative method for removing sulfides from gas streams |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2178751T3 true ES2178751T3 (es) | 2003-01-01 |
Family
ID=24351405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97902872T Expired - Lifetime ES2178751T3 (es) | 1996-01-10 | 1997-01-09 | Procedimiento y composicion regeneradora destinados a extraer sulfuros de las corrientes gaseosas. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US5698171A (es) |
| EP (1) | EP0877647B1 (es) |
| JP (1) | JP2001508349A (es) |
| CN (1) | CN1133483C (es) |
| AR (1) | AR005435A1 (es) |
| AT (1) | ATE218389T1 (es) |
| AU (1) | AU710674B2 (es) |
| BR (1) | BR9706952A (es) |
| CA (1) | CA2240820C (es) |
| DE (1) | DE69713058T2 (es) |
| EG (1) | EG21187A (es) |
| ES (1) | ES2178751T3 (es) |
| ID (1) | ID19812A (es) |
| IS (1) | IS2098B (es) |
| NO (1) | NO322393B1 (es) |
| TR (1) | TR199801285T2 (es) |
| WO (1) | WO1997025126A2 (es) |
| ZA (1) | ZA97183B (es) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5885538A (en) * | 1997-07-02 | 1999-03-23 | Quaker Chemical Corporation | Method and composition for the regeneration of an aminal compound |
| US6063346A (en) * | 1998-06-05 | 2000-05-16 | Intevep, S. A. | Process for scavenging hydrogen sulfide and mercaptan contaminants from a fluid |
| CN1086147C (zh) * | 1999-04-14 | 2002-06-12 | 唐山市新世纪环保设计研究所 | 消烟除尘脱硫烟气净化剂 |
| WO2002086021A1 (en) * | 2001-04-25 | 2002-10-31 | Clearwater International, LLC. | Treatment of hydrocarbons containing sulfides |
| US8562820B2 (en) | 2001-11-09 | 2013-10-22 | Clearwater International, L.L.C. | Sulfide scavenger |
| US7211665B2 (en) * | 2001-11-09 | 2007-05-01 | Clearwater International, L.L.C. | Sulfide scavenger |
| US6773582B2 (en) * | 2002-09-25 | 2004-08-10 | Precision Control Technology, Inc. | Drinking water treatment system including hydrogen sulfide scrubber using triazine compound and associated methods |
| US7140433B2 (en) * | 2003-12-12 | 2006-11-28 | Clearwater International, Llc | Diamine terminated primary amine-aldehyde sulfur converting compositions and methods for making and using same |
| US7077884B2 (en) * | 2004-06-09 | 2006-07-18 | Precision Control Technology, Inc. | Hydrogen sulfide scrubber using polymeric amine and associated methods |
| US7438877B2 (en) * | 2006-09-01 | 2008-10-21 | Baker Hughes Incorporated | Fast, high capacity hydrogen sulfide scavengers |
| US7985881B2 (en) * | 2007-09-12 | 2011-07-26 | Guard Products Llc | Aromatic imine compounds for use as sulfide scavengers |
| TWI383837B (zh) * | 2007-12-26 | 2013-02-01 | Ind Tech Res Inst | 還原性氣體污染物的處理方法 |
| US7931882B1 (en) | 2008-12-19 | 2011-04-26 | Syneco Systems Inc | Sulfide scavenging media and associated methods |
| FR2942802B1 (fr) * | 2009-03-03 | 2012-06-01 | Total Raffinage Marketing | Composition reticulante sous forme de granule pour preparer des compositions bitume/elastomere reticulees |
| CN101538478A (zh) * | 2009-04-01 | 2009-09-23 | 孙文村 | 一种脱硫化氢试剂的制作方法 |
| US20120055808A1 (en) * | 2009-05-14 | 2012-03-08 | Basf Se | Process for the electrolytic dissociation of hydrogen sulfide |
| US20120012505A1 (en) * | 2010-07-14 | 2012-01-19 | Compton Dennis R | Use of alpha-amino ethers for the removal of mercaptans from hydrocarbons |
| US8409535B2 (en) | 2010-11-03 | 2013-04-02 | Calpine Corporation | System and method for removing a contaminant from a gas stream |
| US9637691B2 (en) * | 2010-11-22 | 2017-05-02 | Dorf Ketal Chemicals (India) Private Limtied | Additive composition and method for scavenging hydrogen sulfide in hydrocarbon streams |
| US9052289B2 (en) * | 2010-12-13 | 2015-06-09 | Schlumberger Technology Corporation | Hydrogen sulfide (H2S) detection using functionalized nanoparticles |
| US9394396B2 (en) * | 2011-06-21 | 2016-07-19 | Baker Hughes Incorporated | Hydrogen sulfide scavenger for use in hydrocarbons |
| US9463989B2 (en) | 2011-06-29 | 2016-10-11 | Baker Hughes Incorporated | Synergistic method for enhanced H2S/mercaptan scavenging |
| KR101349973B1 (ko) * | 2011-08-03 | 2014-01-23 | 주식회사 그린솔루스 | 가스상 황화수소 처리 장치 |
| US9278307B2 (en) | 2012-05-29 | 2016-03-08 | Baker Hughes Incorporated | Synergistic H2 S scavengers |
| US9327211B2 (en) | 2013-06-18 | 2016-05-03 | Uop Llc | Process for removing carbonyl sulfide in a gas phase hydrocarbon stream and apparatus relating thereto |
| WO2016029038A1 (en) | 2014-08-21 | 2016-02-25 | Hexion Inc. | Curing compositions and methods of preparing |
| US20160060520A1 (en) * | 2014-09-03 | 2016-03-03 | Baker Hughes Incorporated | Scavengers for sulfur species and/or phosphorus containing compounds |
| US10655232B2 (en) | 2014-09-03 | 2020-05-19 | Baker Hughes, A Ge Company, Llc | Additives to control hydrogen sulfide release of sulfur containing and/or phosphorus containing corrosion inhibitors |
| CA3010550C (en) * | 2016-01-05 | 2021-06-22 | Dorf Ketal Chemicals (India) Private Limited | Hydrogen sulfide scavenging additive composition and method of use thereof. |
| EP3400088B1 (en) * | 2016-01-08 | 2021-08-18 | Dorf Ketal Chemicals (India) Private Limited | Nitrogen based hydrogen sulfide scavengers and method of use thereof |
| US20190184383A1 (en) * | 2016-04-25 | 2019-06-20 | Liudmila Aleksandrovna TYURINA | Catalyst intended for desulfurization/demercaptanization/dehydration of gaseous hydrocarbons |
| CN106076092A (zh) * | 2016-07-05 | 2016-11-09 | 西安赫立盖斯新能源科技有限公司 | 一种适用于液相氧化工艺的螯合稳定剂 |
| DE102016113930A1 (de) | 2016-07-28 | 2018-02-01 | Schülke & Mayr GmbH | Kondensationsprodukt aus 1-Aminopropan-2-ol und Formaldehyd und dessen Verwendung zur Verminderung der Menge von Schwefelwasserstoff in Flüssigkeiten und Gasen |
| CN106281406A (zh) * | 2016-08-30 | 2017-01-04 | 句容宁武高新技术发展有限公司 | 油田脱硫剂及其制备方法 |
| CN106554804B (zh) * | 2016-11-18 | 2018-06-26 | 中国海洋石油总公司 | 一种油田防垢脱硫剂及其制备方法 |
| WO2018097108A1 (ja) * | 2016-11-22 | 2018-05-31 | 株式会社クラレ | 含硫黄化合物除去用の組成物 |
| US10513662B2 (en) | 2017-02-02 | 2019-12-24 | Baker Hughes, A Ge Company, Llc | Functionalized aldehydes as H2S and mercaptan scavengers |
| EA039258B1 (ru) * | 2017-06-21 | 2021-12-23 | Курарей Ко., Лтд. | Композиция для удаления серосодержащего соединения |
| EP3737781A4 (en) * | 2018-01-12 | 2021-04-14 | Baker Hughes Holdings LLC | ADDITIVES FOR CONTROLLING THE RELEASE OF HYDROGEN SULFUR FROM SULFUR AND / OR PHOSPHORUS CONTAINING CORROSION INHIBITORS |
| EP3760293A4 (en) * | 2018-02-28 | 2021-11-10 | Kuraray Co., Ltd. | COMPOSITION FOR THE REMOVAL OF A SULFURY COMPOUND |
| US11198828B2 (en) * | 2018-03-28 | 2021-12-14 | Bionomic Industries Inc. | Process for hydrogen sulfide scrubbing and method for ferric ion regeneration |
| CN109092277B (zh) * | 2018-09-19 | 2021-07-16 | 上海交通大学 | 一种对金属硫化物除汞吸附剂的活化与再生方法 |
| US11945999B2 (en) * | 2018-12-04 | 2024-04-02 | Total Marketing Services | Hydrogen sulphide and mercaptans scavenging compositions |
| CN109603487B (zh) * | 2019-01-28 | 2021-09-21 | 烟台新瑞环保科技有限公司 | 一种液相氧化脱硫工艺中螯合铁催化剂的稳定剂及包含其的脱硫剂 |
| WO2023215440A1 (en) * | 2022-05-04 | 2023-11-09 | Nexgen Oilfield Chemicals, Llc | Compositions and methods for scavenging hydrogen sulfide |
| CN115893625B (zh) | 2022-10-26 | 2023-09-15 | 中国石油化工股份有限公司 | 一种用于压返液中有机硫去除的生物脱硫剂及其制备方法 |
| CN118852036A (zh) * | 2024-06-28 | 2024-10-29 | 南京洛德斯通工程技术有限公司 | 一种脱硫剂及其制备方法和用途 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2776870A (en) * | 1953-11-27 | 1957-01-08 | Union Oil Co | Corrosion prevention in gas recovery systems |
| US3622273A (en) * | 1970-02-06 | 1971-11-23 | Nalco Chemical Co | Method for the removal of hydrogen sulfide from gaseous streams |
| JPS5092294A (es) * | 1973-12-18 | 1975-07-23 | ||
| AU506199B2 (en) * | 1975-06-26 | 1979-12-20 | Exxon Research And Engineering Company | Absorbtion of co2 from gaseous feeds |
| US4076621A (en) * | 1976-03-15 | 1978-02-28 | Air Resources, Inc. | Chelate oxidation of hydrogen sulfide in sour water |
| SU1237241A1 (ru) * | 1980-10-29 | 1986-06-15 | Всесоюзный научно-исследовательский институт углеводородного сырья | Абсорбент дл очистки газов от сероводорода |
| US4414194A (en) * | 1981-05-26 | 1983-11-08 | Shell Oil Company | Extraction process |
| CA1205276A (en) * | 1981-06-15 | 1986-06-03 | Malcolm W. Mcewan | Process for the removal of co.sub.2 and, if present h.sub.2s from a gas mixture |
| US4455287A (en) * | 1982-03-15 | 1984-06-19 | Ari Technologies, Inc. | Method of stabilizing chelated polyvalent metal solutions |
| DE3219762A1 (de) * | 1982-05-26 | 1983-12-01 | Linde Ag, 6200 Wiesbaden | Verfahren zur verhinderung der thiosulfatbildung bei oxidativen schwefelwasserstoffwaeschen |
| US4436714A (en) * | 1982-09-30 | 1984-03-13 | Shell Oil Company | Method of removing hydrogen sulfide from gases utilizing a polyvalent metal chelate of nitrilotriacetic acid and electrolytically regenerating the solution |
| US4647397A (en) * | 1984-01-23 | 1987-03-03 | Chevron Research Company | Composition for removing sulfides from industrial gas |
| US4624838A (en) * | 1985-04-29 | 1986-11-25 | Exxon Research And Engineering Company | Process for removing acidic gases from gaseous mixtures using aqueous scrubbing solutions containing heterocyclic nitrogen compounds |
| US4775519A (en) * | 1985-10-31 | 1988-10-04 | Texaco Inc. | Removal of acid gases from gas streams |
| US4978512B1 (en) * | 1988-12-23 | 1993-06-15 | Composition and method for sweetening hydrocarbons | |
| US5273734A (en) * | 1990-01-12 | 1993-12-28 | The Texas A&M University System | Conversion of H2 to sulfur |
| US5128049A (en) * | 1991-01-22 | 1992-07-07 | Gatlin Larry W | Hydrogen sulfide removal process |
| JPH04290547A (ja) * | 1991-03-15 | 1992-10-15 | Kuraray Chem Corp | 吸水性脱臭剤 |
| US5160714A (en) * | 1991-04-08 | 1992-11-03 | Ari Technologies, Inc. | Continuous autocirculation, multiple zone mass transfer apparatus and method |
| US5347003A (en) * | 1993-03-05 | 1994-09-13 | Quaker Chemical Corporation | Methods for regenerating a sulfur scavenging compound from a product of a sulfur scavenging reaction |
-
1996
- 1996-01-10 US US08/587,837 patent/US5698171A/en not_active Expired - Lifetime
-
1997
- 1997-01-09 JP JP52539297A patent/JP2001508349A/ja not_active Ceased
- 1997-01-09 EP EP97902872A patent/EP0877647B1/en not_active Expired - Lifetime
- 1997-01-09 TR TR1998/01285T patent/TR199801285T2/xx unknown
- 1997-01-09 ZA ZA9700183A patent/ZA97183B/xx unknown
- 1997-01-09 WO PCT/US1997/000324 patent/WO1997025126A2/en not_active Ceased
- 1997-01-09 DE DE69713058T patent/DE69713058T2/de not_active Expired - Fee Related
- 1997-01-09 BR BR9706952-3A patent/BR9706952A/pt not_active IP Right Cessation
- 1997-01-09 CN CNB971916365A patent/CN1133483C/zh not_active Expired - Fee Related
- 1997-01-09 AU AU16943/97A patent/AU710674B2/en not_active Ceased
- 1997-01-09 EG EG2397A patent/EG21187A/xx active
- 1997-01-09 CA CA002240820A patent/CA2240820C/en not_active Expired - Fee Related
- 1997-01-09 AT AT97902872T patent/ATE218389T1/de not_active IP Right Cessation
- 1997-01-09 ES ES97902872T patent/ES2178751T3/es not_active Expired - Lifetime
- 1997-01-10 ID IDP970053A patent/ID19812A/id unknown
- 1997-01-10 AR ARP970100107A patent/AR005435A1/es unknown
-
1998
- 1998-06-29 IS IS4786A patent/IS2098B/is unknown
- 1998-07-09 NO NO19983168A patent/NO322393B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO322393B1 (no) | 2006-10-02 |
| EG21187A (en) | 2000-12-31 |
| IS4786A (is) | 1998-06-29 |
| AU710674B2 (en) | 1999-09-30 |
| AU1694397A (en) | 1997-08-01 |
| EP0877647A2 (en) | 1998-11-18 |
| AR005435A1 (es) | 1999-06-23 |
| DE69713058D1 (de) | 2002-07-11 |
| ZA97183B (en) | 1997-08-18 |
| CN1207052A (zh) | 1999-02-03 |
| US5698171A (en) | 1997-12-16 |
| WO1997025126A2 (en) | 1997-07-17 |
| BR9706952A (pt) | 2000-01-04 |
| TR199801285T2 (xx) | 1998-10-21 |
| DE69713058T2 (de) | 2002-09-19 |
| ATE218389T1 (de) | 2002-06-15 |
| NO983168L (no) | 1998-07-10 |
| WO1997025126A3 (en) | 1997-12-04 |
| EP0877647B1 (en) | 2002-06-05 |
| CN1133483C (zh) | 2004-01-07 |
| IS2098B (is) | 2006-04-12 |
| JP2001508349A (ja) | 2001-06-26 |
| CA2240820A1 (en) | 1997-07-17 |
| ID19812A (id) | 1998-08-06 |
| CA2240820C (en) | 2002-03-19 |
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