ES2178849T3 - Composiciones dentales fotopolimerizables. - Google Patents
Composiciones dentales fotopolimerizables.Info
- Publication number
- ES2178849T3 ES2178849T3 ES98950892T ES98950892T ES2178849T3 ES 2178849 T3 ES2178849 T3 ES 2178849T3 ES 98950892 T ES98950892 T ES 98950892T ES 98950892 T ES98950892 T ES 98950892T ES 2178849 T3 ES2178849 T3 ES 2178849T3
- Authority
- ES
- Spain
- Prior art keywords
- functional group
- free radical
- active
- polymerization
- cationic polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 125000000524 functional group Chemical group 0.000 abstract 5
- 238000010538 cationic polymerization reaction Methods 0.000 abstract 4
- 230000006698 induction Effects 0.000 abstract 3
- 150000003254 radicals Chemical class 0.000 abstract 3
- 230000000977 initiatory effect Effects 0.000 abstract 2
- 239000003607 modifier Substances 0.000 abstract 2
- 238000010526 radical polymerization reaction Methods 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/105—Onium compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S522/908—Dental utility
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dental Preparations (AREA)
- Polymerisation Methods In General (AREA)
- Epoxy Resins (AREA)
Abstract
Una composición fotopolimerizable, que comprende: (a) un grupo funcional activo catiónicamente, (b) un grupo funcional activo a radicales libres, y (c) un sistema de fotoiniciación capaz de iniciar, a una temperatura de reacción menor que 40°C, la polimerización por radicales libres del citado grupo funcional activo a radicales libres después de un período finito de inducción T1 y la polimerización catiónica del citado grupo funcional activo catiónicamente después de un período finito de inducción T3, siendo T3 mayor que T1, comprendiendo el citado sistema de fotoiniciación: (i) una fuente de especies capaces de iniciar la polimerización por radicales libres del citado grupo funcional activo a radicales libres y la polimerización catiónica del citado grupo funcional activo catiónicamente, y (ii) un modificador de la polimerización catiónica, en la que, en ausencia del citado modificador, la polimerización catiónica del citado grupo funcional activo catiónicamente se inicia bajo las mismas condiciones de irradiación al final de un período finito de inducción T2, siendo T2 menor que T3.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/092,550 US6187836B1 (en) | 1998-06-05 | 1998-06-05 | Compositions featuring cationically active and free radically active functional groups, and methods for polymerizing such compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2178849T3 true ES2178849T3 (es) | 2003-01-01 |
Family
ID=22233774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98950892T Expired - Lifetime ES2178849T3 (es) | 1998-06-05 | 1998-10-02 | Composiciones dentales fotopolimerizables. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6187836B1 (es) |
| EP (1) | EP1083859B1 (es) |
| JP (1) | JP4369051B2 (es) |
| KR (1) | KR20010052534A (es) |
| CN (1) | CN1102846C (es) |
| AU (1) | AU740495B2 (es) |
| BR (1) | BR9815890B1 (es) |
| CA (1) | CA2332496C (es) |
| DE (1) | DE69807756T2 (es) |
| ES (1) | ES2178849T3 (es) |
| WO (1) | WO1999062460A1 (es) |
Families Citing this family (92)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19753461A1 (de) * | 1997-12-02 | 1999-06-10 | Espe Dental Ag | Lagerstabile kationisch polymerisierende Zubereitungen mit verbessertem Härtungsverhalten |
| DE69936995T2 (de) * | 1998-03-20 | 2008-05-21 | Nippon Soda Co. Ltd. | Photohärtbare zusammensetzung welche ein iodoniumsalz enthält |
| US6379866B2 (en) * | 2000-03-31 | 2002-04-30 | Dsm Desotech Inc | Solid imaging compositions for preparing polypropylene-like articles |
| US6287748B1 (en) * | 1998-07-10 | 2001-09-11 | Dsm N.V. | Solid imaging compositions for preparing polyethylene-like articles |
| US6762002B2 (en) | 1998-07-10 | 2004-07-13 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polypropylene-like articles |
| US20060154175A9 (en) * | 1998-07-10 | 2006-07-13 | Lawton John A | Solid imaging compositions for preparing polypropylene-like articles |
| US6306926B1 (en) * | 1998-10-07 | 2001-10-23 | 3M Innovative Properties Company | Radiopaque cationically polymerizable compositions comprising a radiopacifying filler, and method for polymerizing same |
| DE69922413T2 (de) * | 1999-01-08 | 2005-11-24 | 3M Innovative Properties Co., Saint Paul | Dentale fräsrohlinge |
| DE19937093A1 (de) * | 1999-08-06 | 2001-02-08 | Espe Dental Ag | Adhäsivsysteme III |
| US6800671B1 (en) * | 2000-04-21 | 2004-10-05 | Britesmile, Inc. | Low peak exotherm curable compositions |
| BR0114127A (pt) | 2000-09-11 | 2003-07-22 | Dow Global Technologies Inc | Método de dispositivo para preparar suporte de pneu |
| DE10108381A1 (de) | 2001-02-21 | 2002-09-05 | Delo Industrieklebstoffe Gmbh | Verfahren und Vorrichtung zur Voraktivierung kationisch polymerisierender Massen |
| US7160941B2 (en) * | 2001-05-01 | 2007-01-09 | Pentron Clinical Technologies, Llc | Dental composite materials and method of manufacture thereof |
| US7589132B2 (en) * | 2001-05-01 | 2009-09-15 | Pentron Clinical Technologies, Llc | Dental resins, dental composite materials, and method of manufacture thereof |
| US7470728B2 (en) * | 2001-05-01 | 2008-12-30 | Pentron Clinical Technologies Llc | Dental glazes and method of manufacture and use thereof |
| US7241856B2 (en) * | 2003-06-02 | 2007-07-10 | Pentron Clinical Technologies Llc | Dental resins, dental composite materials, and method of manufacture thereof |
| JP5329734B2 (ja) * | 2001-08-15 | 2013-10-30 | スリーエム イノベイティブ プロパティズ カンパニー | 硬化性自己支持形構造および方法 |
| US6765036B2 (en) * | 2002-01-15 | 2004-07-20 | 3M Innovative Properties Company | Ternary photoinitiator system for cationically polymerizable resins |
| US6713535B2 (en) * | 2002-02-28 | 2004-03-30 | Turbine Controls, Inc. | Low-friction chromate-free coating of epoxy resins and sulfonyldianiline |
| JP4485117B2 (ja) * | 2002-06-27 | 2010-06-16 | 日東電工株式会社 | 保護剥離用フィルム |
| US6773261B2 (en) * | 2002-06-28 | 2004-08-10 | 3M Innovative Properties Company | Processes for forming dental materials |
| US7134875B2 (en) * | 2002-06-28 | 2006-11-14 | 3M Innovative Properties Company | Processes for forming dental materials and device |
| US20040120901A1 (en) * | 2002-12-20 | 2004-06-24 | Dong Wu | Dental compositions including enzymes and methods |
| US20040122126A1 (en) * | 2002-12-20 | 2004-06-24 | Dong Wu | Free-radical initiator systems containing enzymes, compositions, and methods |
| DE10261241A1 (de) * | 2002-12-20 | 2004-07-15 | 3M Espe Ag | Dentalmaterial mit bakteriostatischen und/oder bakteriziden Substanzen |
| US20040206932A1 (en) * | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
| US7084182B2 (en) * | 2003-03-13 | 2006-08-01 | Tokuyama Corporation | Photopolymerization initiator |
| US7632098B2 (en) * | 2003-08-12 | 2009-12-15 | 3M Innovative Properties Company | Self-adhesive dental compositions and methods |
| US20050040551A1 (en) * | 2003-08-19 | 2005-02-24 | Biegler Robert M. | Hardenable dental article and method of manufacturing the same |
| US20050042577A1 (en) * | 2003-08-19 | 2005-02-24 | Kvitrud James R. | Dental crown forms and methods |
| US20050042576A1 (en) * | 2003-08-19 | 2005-02-24 | Oxman Joel D. | Dental article forms and methods |
| US7030169B2 (en) * | 2003-09-26 | 2006-04-18 | 3M Innovative Properties Company | Arylsulfinate salts in initiator systems for polymeric reactions |
| US20050165127A1 (en) * | 2003-12-31 | 2005-07-28 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polyethylene-like articles |
| EP1778164B1 (en) * | 2004-06-15 | 2010-04-21 | Dentsply International, Inc. | Radical polymerizable macrocyclic resin compositions with low polymerization stress |
| JP2008502697A (ja) | 2004-06-15 | 2008-01-31 | デンツプライ インターナショナル インコーポレーテッド | 低収縮且つ低応力の歯科用組成物 |
| US8465284B2 (en) * | 2004-07-08 | 2013-06-18 | 3M Innovative Properties Company | Dental methods, compositions, and kits including acid-sensitive dyes |
| US20080085494A1 (en) * | 2004-07-14 | 2008-04-10 | Mader Roger M | Dental Compositions Containing Oxirane Monomers |
| EP1784155B1 (en) * | 2004-08-11 | 2011-09-28 | 3M Innovative Properties Company | Self-adhesive compositions including a plurality of acidic compounds |
| US7704643B2 (en) * | 2005-02-28 | 2010-04-27 | Inphase Technologies, Inc. | Holographic recording medium with control of photopolymerization and dark reactions |
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| DE102005016762A1 (de) * | 2005-04-11 | 2006-10-19 | Kettenbach Gmbh & Co. Kg | Photopolymerisierbares Einkomponenten-Kronen- und Brückenmaterial |
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| JP5507256B2 (ja) | 2006-12-13 | 2014-05-28 | スリーエム イノベイティブ プロパティズ カンパニー | 酸性成分及び光退色性染料を有する歯科用組成物の使用方法 |
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| BRPI0913521A2 (pt) * | 2008-09-04 | 2015-10-13 | 3M Innovative Properties Co | composição dental endurecível e artigo dental |
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| BRPI0914464A2 (pt) * | 2008-10-22 | 2015-10-27 | 3M Innovative Properties Co | "composição dentária endurecível, artigos dentários e monômero bifenil di(met)acrilato" |
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| EP2688508A1 (en) | 2011-03-24 | 2014-01-29 | 3M Innovative Properties Company | Dental adhesive comprising a coated polymeric component |
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| EP3075372A1 (en) * | 2015-03-30 | 2016-10-05 | Dentsply DeTrey GmbH | Dental composition |
| US10532009B2 (en) * | 2015-03-30 | 2020-01-14 | Dentsply Sirona Inc. | Dental composition |
| US10106643B2 (en) * | 2015-03-31 | 2018-10-23 | 3M Innovative Properties Company | Dual-cure nanostructure transfer film |
| EP3397711B1 (en) | 2015-12-30 | 2023-02-15 | 3M Innovative Properties Company | Dual stage structural bonding adhesive |
| EP3397426B1 (en) | 2015-12-30 | 2021-06-23 | 3M Innovative Properties Company | Abrasive articles and related methods |
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| CA3034533A1 (en) * | 2016-08-23 | 2018-03-01 | The University Of Massachusetts | Polymerizing composition, method of manufacture thereof and articles comprising the same |
| US10329460B2 (en) | 2016-09-14 | 2019-06-25 | 3M Innovative Properties Company | Fast curing optical adhesive |
| TWI786141B (zh) | 2017-06-30 | 2022-12-11 | 美商3M新設資產公司 | 可印刷可固化混合物及經固化組成物 |
| EP3470048B1 (en) | 2017-10-13 | 2021-11-10 | Dentsply DeTrey GmbH | Photocurable dental composition |
| WO2019123260A2 (en) | 2017-12-19 | 2019-06-27 | 3M Innovative Properties Company | Multi-part composition having staged viscosity prior to hardening |
| JP2020105267A (ja) | 2018-12-26 | 2020-07-09 | スリーエム イノベイティブ プロパティズ カンパニー | 硬化性接着剤、並びにその接着剤を含む層を備える、接着テープ、積層体及び積層ミラーボタン |
| CN113402665B (zh) * | 2020-03-16 | 2024-11-15 | 株式会社松风 | 包含高溶解性光致酸产生剂的牙科用光固化性组合物 |
| US11779524B2 (en) | 2020-03-16 | 2023-10-10 | Kabushiki Kaisha Shofu | Photopolymerization initiator comprising an aryliodonium salt for dental photocurable compositions |
| CN111961150B (zh) * | 2020-07-22 | 2021-06-18 | 福州大学 | 一种光控制阳离子聚合制备乙烯基醚类聚合物的方法 |
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| CA1323949C (en) * | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US4735632A (en) * | 1987-04-02 | 1988-04-05 | Minnesota Mining And Manufacturing Company | Coated abrasive binder containing ternary photoinitiator system |
| US4828583A (en) * | 1987-04-02 | 1989-05-09 | Minnesota Mining And Manufacturing Company | Coated abrasive binder containing ternary photoinitiator system |
| US4933376A (en) * | 1987-05-06 | 1990-06-12 | Mitsubishi Rayon Company Limited | Photopolymerizable dental composition |
| US4950696A (en) * | 1987-08-28 | 1990-08-21 | Minnesota Mining And Manufacturing Company | Energy-induced dual curable compositions |
| JPH01174523A (ja) | 1987-12-28 | 1989-07-11 | Mitsubishi Rayon Co Ltd | 光重合性組成物 |
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| JPH01213330A (ja) | 1988-02-22 | 1989-08-28 | Mitsubishi Rayon Co Ltd | 光重合性組成物 |
| US4985340A (en) | 1988-06-01 | 1991-01-15 | Minnesota Mining And Manufacturing Company | Energy curable compositions: two component curing agents |
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| DE3924308A1 (de) | 1989-07-22 | 1991-01-31 | Bayer Ag | Mehrstufig haertende kunststoffe |
| CA2028259A1 (en) | 1989-11-20 | 1991-05-21 | Stefan Weigl | Tacky photopolymerizable adhesive compositions |
| EP0434334B1 (en) | 1989-12-21 | 1994-02-02 | Minnesota Mining And Manufacturing Company | Dental compositions, a method of making shaped dental articals via photoiniferter polymerization of the dental compositions, and shaped dental articles produced thereby |
| US5639802A (en) * | 1991-05-20 | 1997-06-17 | Spectra Group Limited, Inc. | Cationic polymerization |
| JPH0533250A (ja) | 1991-07-29 | 1993-02-09 | Mitsubishi Rayon Co Ltd | 不織布の製法 |
| US5256170A (en) | 1992-01-22 | 1993-10-26 | Minnesota Mining And Manufacturing Company | Coated abrasive article and method of making same |
| RU2057522C1 (ru) | 1992-03-09 | 1996-04-10 | Московский энергетический институт | Быстроотверждающаяся композиция |
| DE4220958C2 (de) | 1992-06-25 | 1994-04-28 | Ivoclar Ag Schaan | Dentalmaterial |
| US5624976A (en) | 1994-03-25 | 1997-04-29 | Dentsply Gmbh | Dental filling composition and method |
| US5494943A (en) | 1993-06-16 | 1996-02-27 | Minnesota Mining And Manufacturing Company | Stabilized cationically-curable compositions |
| US5453450A (en) | 1993-06-16 | 1995-09-26 | Minnesota Mining And Manufacturing Company | Stabilized curable adhesives |
| CA2146816A1 (en) | 1994-04-22 | 1995-10-23 | Joachim E. Klee | Process and composition for preparing a dental polymer product |
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| JP3321173B2 (ja) | 1994-10-31 | 2002-09-03 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 増強された硬化深さを有する可視光硬化性エポキシ系 |
| US5856373A (en) * | 1994-10-31 | 1999-01-05 | Minnesota Mining And Manufacturing Company | Dental visible light curable epoxy system with enhanced depth of cure |
| US5721289A (en) | 1994-11-04 | 1998-02-24 | Minnesota Mining And Manufacturing Company | Stable, low cure-temperature semi-structural pressure sensitive adhesive |
| US5658963A (en) * | 1995-02-02 | 1997-08-19 | Bisco, Inc. | One-component primer/bonding-resin systems |
| US5750590A (en) * | 1995-02-22 | 1998-05-12 | Heraeus Kulzer Gmbh | Polymerizable material |
| DE19506222B4 (de) | 1995-02-22 | 2004-11-25 | Heraeus Kulzer Gmbh & Co. Kg | Verwendung von polymerisierbaren Verbindungen für medizinische und dentale Zwecke |
| US5571297A (en) | 1995-06-06 | 1996-11-05 | Norton Company | Dual-cure binder system |
| DE19608313C2 (de) * | 1996-02-22 | 2000-08-31 | Ivoclar Ag Schaan | Polymerisierbare Hybridmonomere, Verfahren zu deren Herstellung und deren Verwendung |
-
1998
- 1998-06-05 US US09/092,550 patent/US6187836B1/en not_active Expired - Lifetime
- 1998-10-02 EP EP98950892A patent/EP1083859B1/en not_active Expired - Lifetime
- 1998-10-02 CA CA002332496A patent/CA2332496C/en not_active Expired - Fee Related
- 1998-10-02 AU AU96817/98A patent/AU740495B2/en not_active Ceased
- 1998-10-02 KR KR1020007013680A patent/KR20010052534A/ko not_active Withdrawn
- 1998-10-02 DE DE69807756T patent/DE69807756T2/de not_active Expired - Lifetime
- 1998-10-02 WO PCT/US1998/020836 patent/WO1999062460A1/en not_active Ceased
- 1998-10-02 CN CN98814105A patent/CN1102846C/zh not_active Expired - Fee Related
- 1998-10-02 BR BRPI9815890-2A patent/BR9815890B1/pt not_active IP Right Cessation
- 1998-10-02 JP JP2000551720A patent/JP4369051B2/ja not_active Expired - Fee Related
- 1998-10-02 ES ES98950892T patent/ES2178849T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU740495B2 (en) | 2001-11-08 |
| WO1999062460A1 (en) | 1999-12-09 |
| DE69807756D1 (de) | 2002-10-10 |
| EP1083859A1 (en) | 2001-03-21 |
| CN1102846C (zh) | 2003-03-12 |
| US6187836B1 (en) | 2001-02-13 |
| JP2002516830A (ja) | 2002-06-11 |
| BR9815890A (pt) | 2001-10-09 |
| AU9681798A (en) | 1999-12-20 |
| JP4369051B2 (ja) | 2009-11-18 |
| CN1295455A (zh) | 2001-05-16 |
| EP1083859B1 (en) | 2002-09-04 |
| CA2332496A1 (en) | 1999-12-09 |
| DE69807756T2 (de) | 2003-05-28 |
| CA2332496C (en) | 2008-02-12 |
| KR20010052534A (ko) | 2001-06-25 |
| BR9815890B1 (pt) | 2010-07-13 |
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