ES2178910A1 - Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6. - Google Patents

Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.

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Publication number
ES2178910A1
ES2178910A1 ES009902655A ES9902655A ES2178910A1 ES 2178910 A1 ES2178910 A1 ES 2178910A1 ES 009902655 A ES009902655 A ES 009902655A ES 9902655 A ES9902655 A ES 9902655A ES 2178910 A1 ES2178910 A1 ES 2178910A1
Authority
ES
Spain
Prior art keywords
tiq
metiq
oxidation reactions
preparation
called
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009902655A
Other languages
English (en)
Other versions
ES2178910B1 (es
Inventor
Canos Avelino Corma
Morales Urbano Diaz
Marcelo Eduardo Domine
Segui Vicente Fornes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES009902655A priority Critical patent/ES2178910B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to AT00979683T priority patent/ATE286432T1/de
Priority to AU17085/01A priority patent/AU782301B2/en
Priority to DK00979683T priority patent/DK1243333T3/da
Priority to ES00979683T priority patent/ES2236000T3/es
Priority to PCT/ES2000/000456 priority patent/WO2001037629A2/es
Priority to EP00979683A priority patent/EP1243333B1/en
Priority to EA200200583A priority patent/EA004784B1/ru
Priority to DE60017286T priority patent/DE60017286T2/de
Priority to JP2001539268A priority patent/JP2003514751A/ja
Priority to NZ51965700A priority patent/NZ519657A/en
Priority to CNB008186006A priority patent/CN1191884C/zh
Priority to US10/155,564 priority patent/US6843978B2/en
Priority to IN840KO2002 priority patent/IN2002KO00840A/en
Publication of ES2178910A1 publication Critical patent/ES2178910A1/es
Application granted granted Critical
Publication of ES2178910B1 publication Critical patent/ES2178910B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085—Group IVB- metallosilicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/04—Formation or introduction of functional groups containing sulfur of sulfonyl or sulfinyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/23—Ferrierite, e.g. SR-D ZSM-33

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

"Materiales microporosos de alta superficie activos en reacciones de oxidación. TIQ-6 y METIQ-6". La presente invención se refiere a un material microporoso formado por oxígeno, silicio, germanio, aluminio, boro, galio, zirconio y/o titanio en su composición, denominado TIQ-6, al procedimiento de su preparación y a sus aplicaciones catalíticas en reacciones de oxidación. El método de preparación del material TIQ-6 se basa en la síntesis de un gel con contenido en titanio y/o zirconio, su tratamiento hidrotermal en condiciones controladas, y el tratamiento del material laminar resultante con una solución de un compuesto orgánico, preferentemente de cadena hidrocarbonada larga, que contenga un grupo aceptor de protones. Este material hinchado es sometido a un tratamiento específico mediante agitación, ultrasonidos o por cualquier otro método conocido en el arte, para obtener un sólido deslaminado de elevada superficie externa. Asimismo, se reivindica un material con características similaresal TIQ-6, pero que además posee grupos orgánicos anclados en su superficie denominado METIQ-6, al procedimiento de su preparación y a sus aplicaciones como catalizador en reacciones de oxidación. La incorporación de las especies orgánicas durante la síntesis del material denominado METIQ-6 se realiza mediante un proceso postsíntesis sobre el material TIQ-6.
ES009902655A 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6. Expired - Fee Related ES2178910B1 (es)

Priority Applications (14)

Application Number Priority Date Filing Date Title
ES009902655A ES2178910B1 (es) 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.
NZ51965700A NZ519657A (en) 1999-11-24 2000-11-24 High surface microporous materials which are active in oxidation reactions. tiq-6 and metiq-6
DK00979683T DK1243333T3 (da) 1999-11-24 2000-11-24 Mikroporöse materialer med stor overflade, hvilke er aktive i oxidationsreaktioner. TIQ-6 og METIQ-6
ES00979683T ES2236000T3 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion tiq-6 y metiq-6.
PCT/ES2000/000456 WO2001037629A2 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidación. tiq-6 y metiq-6
EP00979683A EP1243333B1 (en) 1999-11-24 2000-11-24 High surface microporous materials which are active in oxidation reactions. tiq-6 and metiq-6
EA200200583A EA004784B1 (ru) 1999-11-24 2000-11-24 Микропористые материалы (tiq-6 и metiq-6) с большой площадью поверхности, проявляющие активность в окислительных реакциях
DE60017286T DE60017286T2 (de) 1999-11-24 2000-11-24 Mikroporöse materialien grosser oberfläche, welche in den oxidationsreaktionen tiq-6 und metiq-6 aktiv sind
AT00979683T ATE286432T1 (de) 1999-11-24 2000-11-24 Mikroporöse materialien grosser oberfläche, welche in den oxidationsreaktionen tiq-6 und metiq-6 aktiv sind
AU17085/01A AU782301B2 (en) 1999-11-24 2000-11-24 Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions
CNB008186006A CN1191884C (zh) 1999-11-24 2000-11-24 在氧化反应中有活性的高表面积微孔材料(tiq－6和metiq－6)
JP2001539268A JP2003514751A (ja) 1999-11-24 2000-11-24 酸化反応に活性を有する高表面積微多孔質物質（ｔｉｑ−６およびｍｅｔｉｑ−６）
US10/155,564 US6843978B2 (en) 1999-11-24 2002-05-24 Microporous materials (TIQ-6 and METIQ-6) of high surface area active in oxidation reactions
IN840KO2002 IN2002KO00840A (es) 1999-11-24 2002-06-24

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009902655A ES2178910B1 (es) 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.

Publications (2)

Publication Number Publication Date
ES2178910A1 true ES2178910A1 (es) 2003-01-01
ES2178910B1 ES2178910B1 (es) 2003-12-16

Family

ID=8310795

Family Applications (2)

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ES009902655A Expired - Fee Related ES2178910B1 (es) 1999-11-24 1999-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion. tiq-6 y metiq-6.
ES00979683T Expired - Lifetime ES2236000T3 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion tiq-6 y metiq-6.

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ES00979683T Expired - Lifetime ES2236000T3 (es) 1999-11-24 2000-11-24 Materiales microporosos de alta superficie activos en reacciones de oxidacion tiq-6 y metiq-6.

Country Status (13)

Country Link
US (1) US6843978B2 (es)
EP (1) EP1243333B1 (es)
JP (1) JP2003514751A (es)
CN (1) CN1191884C (es)
AT (1) ATE286432T1 (es)
AU (1) AU782301B2 (es)
DE (1) DE60017286T2 (es)
DK (1) DK1243333T3 (es)
EA (1) EA004784B1 (es)
ES (2) ES2178910B1 (es)
IN (1) IN2002KO00840A (es)
NZ (1) NZ519657A (es)
WO (1) WO2001037629A2 (es)

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CN111924852A (zh) * 2019-04-26 2020-11-13 中国石油大学(华东) 一种钛硅分子筛的制备方法

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ES2183710B1 (es) * 2001-04-12 2004-01-16 Univ Valencia Politecnica Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel.
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US7491316B2 (en) * 2004-07-29 2009-02-17 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
ES2281299B1 (es) * 2006-03-15 2008-12-16 Universidad Politecnica De Valencia Un procecimiento para la sintesis de esteres.
GB0702327D0 (en) * 2007-02-07 2007-03-21 Leuven K U Res & Dev Zeolite materials and synthesis method thereof
CN101602012B (zh) * 2008-06-12 2012-04-18 中国石油化工股份有限公司 含有芳烃磺酸基团的介孔材料及其制备方法和应用
TWI399242B (zh) * 2009-12-11 2013-06-21 China Petrochemical Dev Corp Taipei Taiwan Method for preparing large-diameter titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation
WO2012101176A1 (en) * 2011-01-27 2012-08-02 Solvay Sa Process for the manufacture of 1,2-epoxy-3-chloropropane
CN102442683A (zh) * 2011-09-27 2012-05-09 华东理工大学 一种制备多级孔道含钛沸石的溶剂挥发法
KR101394133B1 (ko) * 2012-08-22 2014-05-15 주식회사 이엔에프테크놀로지 몰리브덴 합금막 및 인듐 산화막 식각액 조성물
US20160122296A1 (en) * 2013-05-29 2016-05-05 Basf Se Process for the oxidation of sulfoxides
FR3007405B1 (fr) * 2013-06-21 2016-07-29 Centre Nat De La Rech Scient (C N R S ) Procede de preparation d'une composition comprenant des particules silico/germano-metalliques fonctionnalisees et composition obtenue
US20210370277A1 (en) * 2017-10-30 2021-12-02 Basf Se Process for the preparation of zeolites encapsulating transition metal nanoparticles from layered silicate precursors
CN108947939B (zh) * 2018-08-16 2022-03-11 福州大学 一种异松油烯4,8-环氧化物的合成方法
CN110902691B (zh) * 2019-11-25 2021-07-20 北京化工大学 一种y型分子筛疏水改性的方法
CN111167471B (zh) * 2020-01-17 2020-10-02 浙江新和成股份有限公司 一种金属氧化物涂覆的陶瓷波纹板催化剂、制备及其在制备柠檬醛关键中间体中的应用
US20250281906A1 (en) * 2022-04-25 2025-09-11 Sumitomo Chemical Company, Limited Method for producing titanium-containing silicon oxide, method for producing epoxide, and titanium-containing silicon oxide
CN118620617B (zh) * 2024-08-09 2025-03-04 电子科技大学长三角研究院(湖州) 一种晶态GaTiS-AEP有机开放骨架绿色光致发光源及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111924852A (zh) * 2019-04-26 2020-11-13 中国石油大学(华东) 一种钛硅分子筛的制备方法
CN111924852B (zh) * 2019-04-26 2023-11-03 中国石油大学(华东) 一种钛硅分子筛的制备方法

Also Published As

Publication number Publication date
DE60017286T2 (de) 2005-12-08
IN2002KO00840A (es) 2006-03-10
US6843978B2 (en) 2005-01-18
CN1191884C (zh) 2005-03-09
DE60017286D1 (de) 2005-02-10
WO2001037629A3 (es) 2002-03-14
EP1243333B1 (en) 2005-01-05
ATE286432T1 (de) 2005-01-15
NZ519657A (en) 2004-01-30
ES2236000T3 (es) 2005-07-16
EA004784B1 (ru) 2004-08-26
WO2001037629A8 (es) 2003-02-06
US20020193239A1 (en) 2002-12-19
JP2003514751A (ja) 2003-04-22
EA200200583A1 (ru) 2003-04-24
DK1243333T3 (da) 2005-04-25
EP1243333A2 (en) 2002-09-25
ES2178910B1 (es) 2003-12-16
AU782301B2 (en) 2005-07-14
CN1424938A (zh) 2003-06-18
AU1708501A (en) 2001-06-04
WO2001037629A2 (es) 2001-05-31

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