ES2179021T3 - Procedimiento de glicolisis para reciclar poli(tereftalato de etileno)(pet) despues de su consumo. - Google Patents
Procedimiento de glicolisis para reciclar poli(tereftalato de etileno)(pet) despues de su consumo.Info
- Publication number
- ES2179021T3 ES2179021T3 ES00907128T ES00907128T ES2179021T3 ES 2179021 T3 ES2179021 T3 ES 2179021T3 ES 00907128 T ES00907128 T ES 00907128T ES 00907128 T ES00907128 T ES 00907128T ES 2179021 T3 ES2179021 T3 ES 2179021T3
- Authority
- ES
- Spain
- Prior art keywords
- reactor
- polyester
- upper layer
- lower layer
- glycholisis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- 229920000728 polyester Polymers 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000356 contaminant Substances 0.000 abstract 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 abstract 1
- 125000003827 glycol group Chemical group 0.000 abstract 1
- 230000034659 glycolysis Effects 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/88—Post-polymerisation treatment
- C08G63/90—Purification; Drying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
- Saccharide Compounds (AREA)
Abstract
Un procedimiento de despolimerización y purificación, que comprende: (a) poner en contacto un poliéster contaminado con una cantidad de un glicol para proporcionar una relación molar entre unidades totales de glicol y unidades totales de ácido dicarboxílico mayor que 1 a 5, a una temperatura entre 150 a 300°C y una presión absoluta de 0, 49 a 2, 96 atmósferas en un reactor con agitación durante un tiempo suficiente para producir, en el reactor, una capa superior que comprende un contaminante de densidad relativamente baja flotando por encima de una capa inferior que comprende un oligómero despolimerizado de dicho poliéster; y (b) separar dicha capa superior de dicha capa inferior retirando dicha capa superior del reactor en una primera corriente y retirando dicha capa inferior del reactor en una segunda corriente.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11944799P | 1999-02-10 | 1999-02-10 | |
| US09/478,018 US6410607B1 (en) | 1999-02-10 | 2000-01-05 | Glycolysis process for recycling of post-consumer pet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2179021T3 true ES2179021T3 (es) | 2003-01-16 |
Family
ID=26817346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00907128T Expired - Lifetime ES2179021T3 (es) | 1999-02-10 | 2000-02-04 | Procedimiento de glicolisis para reciclar poli(tereftalato de etileno)(pet) despues de su consumo. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6410607B1 (es) |
| EP (1) | EP1153070B1 (es) |
| JP (1) | JP4531988B2 (es) |
| CN (1) | CN1149254C (es) |
| AT (1) | ATE223456T1 (es) |
| BR (1) | BR0008127A (es) |
| CA (1) | CA2359727C (es) |
| DE (1) | DE60000414T2 (es) |
| ES (1) | ES2179021T3 (es) |
| WO (1) | WO2000047659A1 (es) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1264804C (zh) * | 2002-06-04 | 2006-07-19 | 株式会社爱维塑 | 对苯二甲酸二(2-羟乙基)酯的精制方法 |
| US7297721B2 (en) * | 2003-06-20 | 2007-11-20 | Futura Polyesters Limited | Process for controlled polymerization of a mixed polymer |
| US8034870B2 (en) * | 2003-12-17 | 2011-10-11 | Sabic Innovative Plastics Ip B.V. | Flame-retardant polyester composition |
| US8067493B2 (en) * | 2003-12-30 | 2011-11-29 | Sabic Innovative Plastics Ip B.V. | Polymer compositions, method of manufacture, and articles formed therefrom |
| US7247742B2 (en) * | 2004-05-20 | 2007-07-24 | Bp Corporation North America Inc. | Recycling polyethylene naphthalate containing materials in a process to produce diesters |
| AU2006207500B2 (en) * | 2005-01-18 | 2010-07-08 | APG Polytech, LLC | Compartmentalized pellet for improved contaminant removal |
| US7902264B2 (en) * | 2006-01-27 | 2011-03-08 | Sabic Innovative Plastics Ip B.V. | Polytrimethylene terephthalate (PTT) derived from polyethylene terephthalate (PET) and containing PET residues |
| US8680167B2 (en) * | 2006-01-27 | 2014-03-25 | Sabic Innovative Plastics Ip B.V. | Molding compositions containing fillers and modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET) |
| US7795320B2 (en) * | 2006-01-27 | 2010-09-14 | Sabic Innovative Plastics Ip B.V. | Copolyetheresters derived from polyethylene terephthalate |
| US7923506B2 (en) * | 2006-01-27 | 2011-04-12 | Sabic Innovative Plastics Ip B.V. | Molding compositions containing modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET) |
| US7902263B2 (en) * | 2006-01-27 | 2011-03-08 | Sabic Innovative Plastics Ip B.V. | Process for making polybutylene terephthalate (PBT) from polyethylene terephthalate (PET) |
| EP1979403B1 (en) * | 2006-01-27 | 2009-12-30 | General Electric Company | Articles derived from compositions containing modified polybutylene terephthalate (pbt) random copolymers derived from polyethylene terephthalate (pet) |
| US7799836B2 (en) * | 2006-03-01 | 2010-09-21 | Sabic Innovative Plastics Ip B.V. | Process for making polybutylene terephthalate (PBT) from polyethylene terephthalate (PET) |
| US8309656B2 (en) * | 2006-07-26 | 2012-11-13 | Sabic Innovative Plastics Ip B.V. | Elastomer blends containing polycarbonates and copolyetheresters derived from polyethylene terephthalate, method of manufacture, and articles therefrom |
| US7928150B2 (en) * | 2008-05-06 | 2011-04-19 | Sabic Innovative Plastics Ip B.V. | Process for the manufacture of lonomeric polybutylene terephthalate from polyethylene terephthalate, and compositions and articles thereof |
| CN105778150A (zh) * | 2008-09-12 | 2016-07-20 | 住友电木株式会社 | 分解聚合物材料的方法、制备再生树脂的方法以及回收无机填料的方法 |
| US20100168328A1 (en) * | 2008-12-30 | 2010-07-01 | Ganesh Kannan | Process for the manufacture of polycyclohexane dimethylene terephthalate copolymers from polyethylene terephthalate, and compositions and articles thereof |
| US8138244B2 (en) * | 2008-12-30 | 2012-03-20 | Sabic Innovative Plastics Ip B.V. | Reinforced polyester compositions, method of manufacture, and articles thereof |
| US20100168317A1 (en) * | 2008-12-30 | 2010-07-01 | Cahoon-Brister Kristen | Poly(butylene terephthalate) compositions, methods of manufacture, and articles thereof |
| US7910657B2 (en) * | 2008-12-30 | 2011-03-22 | Sabic Innovative Plastics Ip B.V. | Process for the manufacture of polybutylene terephthalate copolymers from polyethylene terephthalate, and compositions and articles thereof |
| US20100168321A1 (en) * | 2008-12-30 | 2010-07-01 | Cahoon-Brister Kristen | Poly(butylene terephthalate) compositions, methods of manufacture, and articles thereof |
| RU2012103457A (ru) * | 2009-07-02 | 2013-08-10 | БЕПЕКС ИНТЕРНЭШНЛ, ЭлЭлСи | Устройство и способ для парофазной переработки бывших в употреблении полимеров |
| US8686072B2 (en) | 2010-06-29 | 2014-04-01 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles therof |
| US8716378B2 (en) | 2010-06-29 | 2014-05-06 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles thereof |
| US20120046411A1 (en) * | 2010-08-20 | 2012-02-23 | Becton, Dickinson And Company | Recycled Resin Compositions And Disposable Medical Devices Made Therefrom |
| US9458354B2 (en) | 2010-10-06 | 2016-10-04 | Resinate Technologies, Inc. | Polyurethane dispersions and methods of making and using same |
| CN103703086A (zh) | 2011-06-10 | 2014-04-02 | 克里斯托弗·M·费利斯 | 透明涂层,丙烯酸类涂层 |
| CN102250449B (zh) * | 2011-06-27 | 2012-11-28 | 沈阳化工大学 | 利用回收的对苯二甲酸合成饱和聚酯树脂的方法 |
| CN102532815B (zh) * | 2011-12-06 | 2013-09-25 | 上海聚友化工有限公司 | 一种废聚酯纺织品回收再利用的方法 |
| CN102731760B (zh) * | 2012-07-17 | 2014-03-26 | 龙福环能科技股份有限公司 | 一种将回收聚酯瓶片料熔体醇解后再聚合的方法 |
| PL2719529T3 (pl) | 2012-10-10 | 2017-08-31 | Armacell Enterprise Gmbh & Co. Kg | Zapobieganie depolimeryzacji politereftalanu alkilenowego w strukturach laminowanych |
| DE102012220498A1 (de) * | 2012-11-09 | 2014-05-15 | Aquafil Engineering Gmbh | Verfahren und Vorrichtung zur Behandlung von Polymeren |
| EP2784110B1 (en) | 2013-03-26 | 2017-03-29 | Oxxynova GmbH | Method and apparatus for colour removal from shredded pet-flakes |
| US9255194B2 (en) | 2013-10-15 | 2016-02-09 | International Business Machines Corporation | Methods and materials for depolymerizing polyesters |
| WO2015069662A1 (en) | 2013-11-06 | 2015-05-14 | The Board Of Trustees Of The Leland Stanford Junior University | Methods for modifying a hydrophobic polymer surface and devices thereof |
| WO2016069622A1 (en) * | 2014-10-29 | 2016-05-06 | Resinate Materials Group, Inc. | High recycle content polyester polyols from hydroxy-functional ketal acids, esters or amides |
| ITUB20151922A1 (it) * | 2015-07-06 | 2017-01-06 | Gianni Monte | Procedimento per la produzione di polietilene tereftalato modificato glicole da materie prime di riciclo |
| US9550713B1 (en) | 2015-07-09 | 2017-01-24 | Loop Industries, Inc. | Polyethylene terephthalate depolymerization |
| AU2017431676B2 (en) | 2017-09-14 | 2022-02-24 | Petróleo Brasileiro S.A. - Petrobras | Enzymatic process for depolymerization of post-consumer poly(ethylene terephthalate) by a glycolysis reaction, process for recycling post-consumer poly(ethylene terephthalate) and recycled poly(ethylene terephthalate) |
| US12071519B2 (en) | 2017-09-15 | 2024-08-27 | 9449710 Canada Inc. | Terephthalic acid esters formation |
| US10252976B1 (en) | 2017-09-15 | 2019-04-09 | 9449710 Canada Inc. | Terephthalic acid esters formation |
| US10808096B2 (en) | 2018-06-25 | 2020-10-20 | 9449710 Canada Inc. | Terephthalic acid esters formation |
| WO2020085912A1 (en) | 2018-10-26 | 2020-04-30 | Dsm Ip Assets B.V. | Polyester powders and the use thereof in three-dimensional printing processes |
| WO2020188548A1 (en) * | 2019-03-15 | 2020-09-24 | Polyplex Corporation Limited | A process and an apparatus for manufacturing bi-axially oriented polyester film from rpet |
| US11248103B2 (en) | 2019-03-20 | 2022-02-15 | 9449710 Canada Inc. | Process for the depolymerization of polyethylene terephthalate (PET) |
| US12522695B2 (en) | 2019-10-08 | 2026-01-13 | Eastman Chemical Company | Catalyst systems for crystallizable reactor grade resins with recycled content |
| NL2024181B1 (en) * | 2019-11-07 | 2021-07-20 | Ioniqa Tech B V | Reactor system and method of separating a first contaminant from a feed stream |
| CN110845761B (zh) * | 2019-11-25 | 2022-05-20 | 浙江海利环保科技股份有限公司 | 一种醇解液中杂质去除的方法 |
| BR112022014572A2 (pt) * | 2020-01-23 | 2022-10-04 | Premirr Plastics Inc | Processo e sistema para a despolimerização de plástico residual |
| US11639431B2 (en) * | 2020-01-23 | 2023-05-02 | Premirr Plastics Inc. | Process and system for depolymerizing plastic |
| KR20220141319A (ko) * | 2020-02-10 | 2022-10-19 | 이스트만 케미칼 컴파니 | 가용매분해 테레프탈릴 칼럼 탑저 부산물 스트림의 화학적 재활용 |
| EP4136195A4 (en) * | 2020-04-13 | 2024-07-17 | Eastman Chemical Company | VITRIFICATION MATERIALS FOR PARTIAL OXIDATION GASIFIER |
| PL4176000T3 (pl) * | 2020-07-02 | 2025-09-01 | Cure Technology B.V. | Sposób umożliwiający recykling odpadów poliesterowych oraz system stosowania tego sposobu |
| NL2026273B1 (en) | 2020-08-14 | 2022-04-13 | Ioniqa Tech B V | Depolymerization method of a waste polymer material and system therefore |
| CN112225661B (zh) * | 2020-10-16 | 2022-11-18 | 艾凡佳德(上海)环保科技有限公司 | 一种废旧聚酯连续醇解后醇解物的除杂方法及设备 |
| EP4402202A4 (en) * | 2021-09-16 | 2025-07-09 | Circ Llc | PROCESS FOR FORMING A POLYESTER FROM A REGENERATED DIACID FORMED FROM THE DEPOLYMERIZATION OF A WASTE MATERIAL |
| IT202200016851A1 (it) | 2022-08-05 | 2024-02-05 | Chempet Srl | Processo per purificare bis(2-idrossietil)tereftalato ottenuto da depolimerizzazione di rifiuti contenenti polietilene tereftalato. |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3703488A (en) | 1968-03-22 | 1972-11-21 | Goodyear Tire & Rubber | Process for reuse of polyester resin |
| US3884850A (en) | 1970-02-13 | 1975-05-20 | Fiber Industries Inc | Continuous atmospheric depolymerization of polyester |
| JPS60248646A (ja) | 1984-05-25 | 1985-12-09 | Toray Ind Inc | ポリエステル屑の解重合方法 |
| US5223544A (en) | 1992-03-31 | 1993-06-29 | Shell Oil Company | Process for the removal of foreign materials from a post-consumer plyethylene terephthalate feed stream |
| US5298530A (en) * | 1992-11-25 | 1994-03-29 | Eastman Kodak Company | Process of recovering components from scrap polyester |
| WO1994025517A1 (en) * | 1993-05-04 | 1994-11-10 | Ashland Oil, Inc. | Cured unsaturated polyesters glycolysis for recycle reactant |
| ATE176780T1 (de) * | 1993-07-05 | 1999-03-15 | Du Pont | Herstellung von dicarbonsäuren oder ihren estern |
| US5620665A (en) * | 1994-06-21 | 1997-04-15 | Miyaso Chemical Co. | Method of recycling unsaturated polyester resin waste and recycling apparatus |
| JP2701012B2 (ja) * | 1994-06-21 | 1998-01-21 | 和歌山県 | 不飽和ポリエステル樹脂廃棄物の再利用法および再利用装置 |
| US5635584A (en) * | 1995-12-07 | 1997-06-03 | Eastman Chemical Company | Process including glycolysis and subsequent purification for recycling polyester materials |
| JP3739170B2 (ja) * | 1997-05-12 | 2006-01-25 | 日本エステル株式会社 | スクラップ利用ポリエステルの製造法 |
| US5981672A (en) * | 1998-09-25 | 1999-11-09 | Peterson; Donny L. | Apparatus and method for converting polyethylene terephthalate into polyester polyols |
| US6048907A (en) * | 1998-09-25 | 2000-04-11 | Peterson; Don | Apparatus and method for converting polyethylene terephthalate into polyester polyols |
-
2000
- 2000-01-05 US US09/478,018 patent/US6410607B1/en not_active Expired - Fee Related
- 2000-02-04 JP JP2000598569A patent/JP4531988B2/ja not_active Expired - Fee Related
- 2000-02-04 ES ES00907128T patent/ES2179021T3/es not_active Expired - Lifetime
- 2000-02-04 EP EP20000907128 patent/EP1153070B1/en not_active Expired - Lifetime
- 2000-02-04 BR BR0008127A patent/BR0008127A/pt active Search and Examination
- 2000-02-04 CN CNB008036276A patent/CN1149254C/zh not_active Expired - Fee Related
- 2000-02-04 DE DE60000414T patent/DE60000414T2/de not_active Expired - Lifetime
- 2000-02-04 AT AT00907128T patent/ATE223456T1/de not_active IP Right Cessation
- 2000-02-04 WO PCT/US2000/002813 patent/WO2000047659A1/en not_active Ceased
- 2000-02-04 CA CA 2359727 patent/CA2359727C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2000047659A1 (en) | 2000-08-17 |
| CA2359727A1 (en) | 2000-08-17 |
| CA2359727C (en) | 2008-03-25 |
| JP2002536519A (ja) | 2002-10-29 |
| JP4531988B2 (ja) | 2010-08-25 |
| DE60000414D1 (de) | 2002-10-10 |
| DE60000414T2 (de) | 2003-08-07 |
| US6410607B1 (en) | 2002-06-25 |
| EP1153070B1 (en) | 2002-09-04 |
| CN1149254C (zh) | 2004-05-12 |
| BR0008127A (pt) | 2001-11-06 |
| CN1340077A (zh) | 2002-03-13 |
| EP1153070A1 (en) | 2001-11-14 |
| ATE223456T1 (de) | 2002-09-15 |
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