ES2182172T3 - Agentes dispersantes para pigmentos o cargas a base de polimeros de acrilato de alquilo. - Google Patents
Agentes dispersantes para pigmentos o cargas a base de polimeros de acrilato de alquilo.Info
- Publication number
- ES2182172T3 ES2182172T3 ES98108505T ES98108505T ES2182172T3 ES 2182172 T3 ES2182172 T3 ES 2182172T3 ES 98108505 T ES98108505 T ES 98108505T ES 98108505 T ES98108505 T ES 98108505T ES 2182172 T3 ES2182172 T3 ES 2182172T3
- Authority
- ES
- Spain
- Prior art keywords
- rental
- dispersants
- carbon atoms
- pigments
- rented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002270 dispersing agent Substances 0.000 title abstract 4
- 239000000049 pigment Substances 0.000 title abstract 2
- 229920000058 polyacrylate Polymers 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000001131 transforming effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/16—Amines or polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
LA PRESENTE INVENCION TRATA DE UNOS DISPERSANTES PARA PIGMENTOS O SUSTANCIAS DE RELLENO BASADOS EN POLIMEROS DE ESTER AQUILICO DEL ACIDO ACRILICO, TRANSFORMANDOSE AL MENOS UNA PARTE DE LOS GRUPOS DE ESTERES DE LOS POLIMEROS EN AMIDAS ACIDAS, PUDIENDO OBTENERSE EL DISPERSANTE MEDIANTE AMINOLISIS DE LOS GRUPOS DE ESTERES DEL POLIMERO POR MEDIO DE UNAS AMINAS Y UTILIZANDOSE PARA LA AMINOLISIS AL MENOS UNA AMINA PERTENECIENTE AL GRUPO A) DE AMINAS DE FORMULA GENERAL NH 2 R 1 NR SUP ,2 R 3 , A CUYO EFECTO R 1 ES UN RADICAL ALQUILENO BIVALENTE CON 2 A 4 ATOMOS DE CARBONO, SIENDO R 2 Y R 3 UNOS RADICALES ALQUILOS ALIFATICOS Y/O ALICICLICOS, CON 1 A 12, PREFERENTEMENTE CON 1 A 6 ATOMOS DE CARBONO, QUE PUEDEN SER IGUALES O DIFERENTES, Y B) UNAS AMINAS DE FORMULA GENERAL NH SUB,2 R 1 Z, A CUYO EFECTO R 1 ES UN RADICAL ALQUILE NO BIVALENTE CON 2 A 4 ATOMOS DE CARBONO Y Z ES UN HETEROCICLO DE 5 O 6 MIEMBROS, QUE CONTIENE N Y QUE PUEDE MOSTRAR HASTA 2 ATOMOS DE NITROGENO O ADICIONALMENTE OXIGENO. LA INVENCION TRATA ADEMAS DEL EMPLEO DE LOS DISPERSANTES CORRESPONDIENTES A LA INVENCION PARA LA PRODUCCION DE CONCENTRADOS PIGMENTARIOS Y MEDIOS DE RECUBRIMIENTO, ASI COMO DE UN PROCEDIMIENTO PARA LA PRODUCCION DE DICHOS DISPERSANTES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19721728A DE19721728C2 (de) | 1997-05-24 | 1997-05-24 | Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2182172T3 true ES2182172T3 (es) | 2003-03-01 |
Family
ID=7830355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98108505T Expired - Lifetime ES2182172T3 (es) | 1997-05-24 | 1998-05-11 | Agentes dispersantes para pigmentos o cargas a base de polimeros de acrilato de alquilo. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6596816B1 (es) |
| EP (1) | EP0879860B1 (es) |
| JP (1) | JP3657430B2 (es) |
| AT (1) | ATE221909T1 (es) |
| CA (1) | CA2237443C (es) |
| DE (2) | DE19721728C2 (es) |
| DK (1) | DK0879860T3 (es) |
| ES (1) | ES2182172T3 (es) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19721728C2 (de) * | 1997-05-24 | 2001-07-12 | Byk Chemie Gmbh | Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung |
| DE19904603A1 (de) | 1999-02-05 | 2000-08-10 | Goldschmidt Ag Th | Aminoxidgruppen enthaltende Maleinsäureanhydrid-Copolymere und ihre Verwendung als Dispergiermittel für Pigmente oder Füllstoffe |
| AU5200401A (en) * | 2000-07-03 | 2002-01-10 | Rohm And Haas Company | Semi-telechelic nitrogen-functional oligomer |
| DE10163985A1 (de) * | 2001-12-24 | 2003-07-03 | Sued Chemie Ag | Aminoplasteinheiten enthaltende Copolymere und ihre Verwendung als Dispergier- oder Stabilisiermittel |
| WO2003070782A1 (en) * | 2002-02-15 | 2003-08-28 | Ppg Industries Ohio, Inc. | Compositions containing copolymers of post-polymerization reacted (meth)acrylate monomers |
| US6784248B2 (en) | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
| DE10302743A1 (de) | 2003-01-24 | 2004-07-29 | Goldschmidt Ag | Verwendung von Siliconharzen als Dispergiermittel |
| US8824553B2 (en) | 2003-05-12 | 2014-09-02 | Google Inc. | Video compression method |
| US7910022B2 (en) | 2006-09-15 | 2011-03-22 | Performance Indicator, Llc | Phosphorescent compositions for identification |
| CA2591803A1 (en) | 2004-12-20 | 2006-06-29 | Performance Indicator L.L.C. | High-intensity, persistent photoluminescent formulations and objects, and methods for creating the same |
| DE102005003299A1 (de) | 2005-01-24 | 2006-07-27 | Goldschmidt Gmbh | Nanopartikel für die Herstellung von Polyurethanschaum |
| GB0526231D0 (en) | 2005-12-22 | 2006-02-01 | Eastman Kodak Co | Dispersant for reducing viscosity of solids |
| US7547894B2 (en) | 2006-09-15 | 2009-06-16 | Performance Indicator, L.L.C. | Phosphorescent compositions and methods for identification using the same |
| DE102006055106C5 (de) | 2006-11-14 | 2018-08-23 | Byk-Chemie Gmbh | Dispergierverfahren |
| FR2913981B1 (fr) * | 2007-03-21 | 2011-03-25 | Chryso | Suspension pigmentaire presentant une force de teinte amelioree |
| US7842128B2 (en) | 2007-09-13 | 2010-11-30 | Performance Indicatior LLC | Tissue marking compositions |
| US8039193B2 (en) | 2007-09-13 | 2011-10-18 | Performance Indicator Llc | Tissue markings and methods for reversibly marking tissue employing the same |
| DE102008045296A1 (de) | 2008-09-02 | 2010-03-04 | Byk-Chemie Gmbh | Monocarbonsäureester enthaltendes Dispergiermedium für Feststoffpräparationen |
| DE102009015470A1 (de) | 2008-12-12 | 2010-06-17 | Byk-Chemie Gmbh | Verfahren zur Herstellung von Metallnanopartikeln und auf diese Weise erhaltene Metallnanopartikel und ihre Verwendung |
| US20100323112A1 (en) | 2009-06-18 | 2010-12-23 | Basf Corporation | Method for improving sag resistance |
| CN102753628A (zh) | 2009-11-11 | 2012-10-24 | 比克化学股份有限公司 | 涂料组合物 |
| MX2013003557A (es) | 2010-10-05 | 2013-05-01 | Gen Instrument Corp | Codificacion y decodificacion utilizando seleccion de modelo adaptativo al contexto con escaneo en zigzag. |
| CN101962481B (zh) * | 2010-10-19 | 2012-09-05 | 中山大桥化工集团有限公司 | 一种适用于用作溶剂型颜料分散剂的高分子化合物 |
| US8938001B1 (en) | 2011-04-05 | 2015-01-20 | Google Inc. | Apparatus and method for coding using combinations |
| US8891616B1 (en) | 2011-07-27 | 2014-11-18 | Google Inc. | Method and apparatus for entropy encoding based on encoding cost |
| CN103059228B (zh) * | 2011-10-24 | 2015-05-13 | 中国石油化工股份有限公司 | 一种改性丙烯腈-苯乙烯-丙烯酸酯三元共聚物树脂及其制备方法和制品 |
| EP2771418B2 (en) | 2011-10-26 | 2021-12-29 | Lubrizol Advanced Materials, Inc. | Dispersant composition |
| US9034979B2 (en) | 2011-10-26 | 2015-05-19 | Lubrizol Advanced Materials, Inc. | Dispersant composition |
| US9247257B1 (en) | 2011-11-30 | 2016-01-26 | Google Inc. | Segmentation based entropy encoding and decoding |
| US11039138B1 (en) | 2012-03-08 | 2021-06-15 | Google Llc | Adaptive coding of prediction modes using probability distributions |
| US9080070B2 (en) | 2012-04-03 | 2015-07-14 | Gem Gravure Co., Inc. | Inkjet ink for printing on fluoropolymers |
| US9774856B1 (en) | 2012-07-02 | 2017-09-26 | Google Inc. | Adaptive stochastic entropy coding |
| EP2852631B1 (en) | 2012-07-06 | 2019-11-20 | Akzo Nobel Coatings International B.V. | Method for producing a nanocomposite dispersion comprising composite particles of inorganic nanoparticles and organic polymers |
| EP2719270A1 (de) | 2012-10-11 | 2014-04-16 | BYK-Chemie GmbH | Beschichtungszusammensetzung und deren Verwendung |
| US9509998B1 (en) | 2013-04-04 | 2016-11-29 | Google Inc. | Conditional predictive multi-symbol run-length coding |
| US9392288B2 (en) | 2013-10-17 | 2016-07-12 | Google Inc. | Video coding using scatter-based scan tables |
| US9179151B2 (en) | 2013-10-18 | 2015-11-03 | Google Inc. | Spatial proximity context entropy coding |
| EP2873657A1 (en) | 2013-11-13 | 2015-05-20 | Huntsman Petrochemical LLC | Admixture composition to improve strength of cement cured products |
| EP3161036B1 (de) | 2014-06-24 | 2018-01-24 | BYK-Chemie GmbH | Epoxidharz-epoxidhärter-systeme mit latenter verdickungsneigung |
| EP3161058B1 (de) | 2014-06-24 | 2017-11-22 | BYK-Chemie GmbH | Acrylat-systeme mit latenter verdickungsneigung |
| US10392494B2 (en) | 2014-06-24 | 2019-08-27 | Byk-Chemie Gmbh | Latent thickeners, rheology control kit and multi-component systems |
| JP2017525795A (ja) | 2014-06-24 | 2017-09-07 | ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング | 潜在的増粘傾向を有するポリウレタン二成分又は多成分系 |
| JP6423459B2 (ja) | 2014-06-24 | 2018-11-14 | ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング | 潜在的増粘傾向を有する不飽和ポリエステル樹脂系 |
| DE102017105755A1 (de) * | 2017-03-17 | 2018-09-20 | Lohmann Gmbh & Co. Kg | Funktionalisierte Acrylate (aus der Schmelze) |
| EP3765545A1 (de) | 2018-03-15 | 2021-01-20 | Covestro Intellectual Property GmbH & Co. KG | Lagerstabile pigmentierte isocyanatgruppen-haltige formulierungen und deren verwendung |
| CN113518791B (zh) | 2019-02-28 | 2023-08-08 | 科思创知识产权两合公司 | 具有含异氰酸酯基团的研磨型树脂的储存稳定的含颜料的含异氰酸酯基团的配制剂及其用途 |
| EP4183842A1 (de) | 2021-11-23 | 2023-05-24 | Ewald Dörken Ag | Pigmentpaste und ihre verwendung |
| KR20240164552A (ko) | 2022-03-21 | 2024-11-19 | 비와이케이-케미 게엠베하 | 배터리 제조에 사용하기 위한 분산제 조성물 |
| EP4484503A1 (de) | 2023-06-27 | 2025-01-01 | Ewald Dörken Ag | Wässrige stabilisatorzusammensetzung und ihre verwendung |
| EP4545612A1 (de) | 2023-10-26 | 2025-04-30 | Ewald Dörken Ag | Pigmentpaste und ihre verwendung |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2595907A (en) * | 1950-12-30 | 1952-05-06 | American Cyanamid Co | Polymerizable and polymerized acrylonitrile-dialkylaminopropylacrylamide compositions |
| US2980657A (en) * | 1954-07-06 | 1961-04-18 | Rohm & Haas | Quaternary ammonium compounds of polymers of acrylamido type and methods for making them |
| US3069390A (en) * | 1959-07-17 | 1962-12-18 | Borden Co | Polymeric amides from polymeric acrylic acid esters and n-aminoalkyl alkanol amines and reaction products therefrom |
| US4079166A (en) * | 1974-08-26 | 1978-03-14 | Xerox Corporation | Aminolyzed carrier coatings |
| US3980602A (en) | 1975-02-28 | 1976-09-14 | E. I. Du Pont De Nemours And Company | Acrylic polymer dispersant for aqueous acrylic coating compositions |
| DE2519581C2 (de) * | 1975-05-02 | 1983-09-29 | Basf Ag, 6700 Ludwigshafen | Papierleimungsmittel |
| US4120839A (en) * | 1977-01-13 | 1978-10-17 | Rohm And Haas Company | Oligomeric amino-containing aminolysis products of polymethacrylates or polyacrylates, and epoxy resin coating compositions containing such aminolysis products as curing agents |
| US4303563A (en) * | 1977-12-29 | 1981-12-01 | Emmons William D | Coating, impregnating and adhesive compositions curable at ambient temperature |
| US4302561A (en) * | 1980-07-07 | 1981-11-24 | Ppg Industries, Inc. | Pigment dispersants for coating compositions |
| DE3465599D1 (en) * | 1984-01-27 | 1987-10-01 | Byk Chemie Gmbh | Addition compounds suited as dispersing agents, process for their preparation, their use and solid materials coated with them |
| NL8702089A (nl) * | 1987-09-04 | 1989-04-03 | Efka Chemicals Bv | Dispergeermiddel. |
| US4942213A (en) | 1987-12-04 | 1990-07-17 | Byk-Chemie Gmbh | Addition compounds useful as dispersing agents and dispersion stabilizers, process for producing them, their use and solids coated therewith |
| DE3842202C1 (es) | 1988-12-15 | 1990-05-03 | Th. Goldschmidt Ag, 4300 Essen, De | |
| US5338485A (en) | 1989-03-03 | 1994-08-16 | The Goldschmidt Ag | Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups and their use as surface active substances |
| DE3906702A1 (de) | 1989-03-03 | 1990-09-13 | Goldschmidt Ag Th | Polyacrylsaeureester mit langkettigen kohlenwasserstoff- und polyoxyalkylengruppen und deren verwendung als grenzflaechenaktive substanzen |
| JP2705356B2 (ja) * | 1990-05-02 | 1998-01-28 | 日本油脂株式会社 | 顔料分散剤 |
| DE4020943A1 (de) * | 1990-06-30 | 1992-01-02 | Bayer Ag | Verfahren zur herstellung von anionenaustausch-harzen vom poly(meth)-acrylamid-typ |
| DE4027843A1 (de) * | 1990-09-03 | 1992-03-05 | Roehm Gmbh | Kontinuierliches verfahren zur herstellung von n-substituierten acryl- und methacrylamiden |
| WO1993002131A1 (en) | 1991-07-16 | 1993-02-04 | Ppg Industries, Inc. | Amine-modified polyester pigment dispersing agents |
| JPH0616849A (ja) * | 1992-07-02 | 1994-01-25 | Dai Ichi Kogyo Seiyaku Co Ltd | 防曇性プラスチックフィルムおよびプラスチックフィルムの防曇方法 |
| DE4236337C1 (de) * | 1992-10-28 | 1994-01-27 | Goldschmidt Ag Th | Verwendung von Polyacrylsäureestern als Dispergiermittel |
| US5519093A (en) * | 1994-05-11 | 1996-05-21 | Air Products And Chemicals, Inc. | Synthesis of amine functional co-and terpolymers |
| US5717048A (en) * | 1994-12-07 | 1998-02-10 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Cation-modified acrylamide or methacrylamide copolymer as well as antistatic agent, thermoplastic resin composition, aqueous composition and thermoplastic resin laminate comprising same |
| US5516826A (en) * | 1995-03-13 | 1996-05-14 | Westvaco Corporation | Polyamine condensates of styrene-acrylic acid copolymers as corrosion inhibitors |
| DE19721728C2 (de) | 1997-05-24 | 2001-07-12 | Byk Chemie Gmbh | Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung |
-
1997
- 1997-05-24 DE DE19721728A patent/DE19721728C2/de not_active Expired - Fee Related
-
1998
- 1998-05-11 EP EP98108505A patent/EP0879860B1/de not_active Expired - Lifetime
- 1998-05-11 DE DE59805058T patent/DE59805058D1/de not_active Expired - Lifetime
- 1998-05-11 US US09/075,613 patent/US6596816B1/en not_active Expired - Lifetime
- 1998-05-11 DK DK98108505T patent/DK0879860T3/da active
- 1998-05-11 AT AT98108505T patent/ATE221909T1/de not_active IP Right Cessation
- 1998-05-11 ES ES98108505T patent/ES2182172T3/es not_active Expired - Lifetime
- 1998-05-12 CA CA002237443A patent/CA2237443C/en not_active Expired - Lifetime
- 1998-05-22 JP JP14073298A patent/JP3657430B2/ja not_active Expired - Lifetime
-
2003
- 2003-07-21 US US10/623,685 patent/US7432329B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE221909T1 (de) | 2002-08-15 |
| EP0879860A2 (de) | 1998-11-25 |
| EP0879860A3 (de) | 1999-02-10 |
| JP3657430B2 (ja) | 2005-06-08 |
| DK0879860T3 (da) | 2002-11-11 |
| US7432329B2 (en) | 2008-10-07 |
| JPH111515A (ja) | 1999-01-06 |
| CA2237443A1 (en) | 1998-11-24 |
| DE59805058D1 (de) | 2002-09-12 |
| US6596816B1 (en) | 2003-07-22 |
| DE19721728A1 (de) | 1998-11-26 |
| DE19721728C2 (de) | 2001-07-12 |
| US20040019147A1 (en) | 2004-01-29 |
| EP0879860B1 (de) | 2002-08-07 |
| CA2237443C (en) | 2009-07-14 |
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